JP6637447B2 - 水素化処理ユニットのための供給原料の調製方法 - Google Patents
水素化処理ユニットのための供給原料の調製方法 Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
- C10G67/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
- C10G67/04—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only including solvent extraction as the refining step in the absence of hydrogen
- C10G67/0454—Solvent desasphalting
- C10G67/049—The hydrotreatment being a hydrocracking
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- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
- C10G69/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only
- C10G69/06—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only including at least one step of thermal cracking in the absence of hydrogen
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G9/34—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by direct contact with inert preheated fluids, e.g. with molten metals or salts
- C10G9/36—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by direct contact with inert preheated fluids, e.g. with molten metals or salts with heated gases or vapours
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/205—Metal content
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/205—Metal content
- C10G2300/206—Asphaltenes
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/30—Physical properties of feedstocks or products
- C10G2300/301—Boiling range
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/30—Physical properties of feedstocks or products
- C10G2300/302—Viscosity
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/44—Solvents
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Description
スチームクラッカー分解蒸留物(CD)、スチームクラッカー・カーボンブラック油(CBO)、沸点が300℃超の低アスファルテン含有原油残留物および芳香族に富んだ炭化水素の流れの群から選択される少なくとも1つである溶媒と、前記原油とを混合するステップであって、ここで、前記溶媒:前記原油の混合比は、前記溶媒と前記原油とを混合した混合物においてアスファルテンの凝集が混合条件下で起こらないものであるステップと;
前記溶媒と前記原油とを混合した混合物を1つ以上の水素化処理ユニットに供給するステップと、を備えることを特徴とする方法に関する。
スチームクラッカーからの分解蒸留物(CD)の飽和分、芳香族分、樹脂分およびアスファルテン分(SARA)の分析は、7.76/92.24/0/0である。アラブ重質原油由来340+℃残油(AHAR)のSARA分析は、53.7/34.8/3.1/8.1である。これらの流れの異なる質量比での組み合わせを下表において分析し、これらの組み合わせについて予測した安定したアスファルテン濃度を以下に示す。
アラビアンライト340+℃カット(ALAR)の飽和分、芳香族分、樹脂分およびアスファルテン分(SARA)の分析は、61.8/30.5/3.4/3.5である。アラブ重質原油由来340+℃残油(AHAR)のSARA分析は53.7/34.8/3.1/8.1である。これらの流れの異なる質量比での組み合わせを下表において分析し、組み合わせた混合物中の樹脂分および芳香族分の濃度に対するこれらの組み合わせについて予測した安定したアスファルテン濃度を示す。
Aijun Guoら、Fuel processing technology 89 (2008) 643−650には、錦州(Jinzhou)減圧残油(JnVR)の飽和分、芳香族分、樹脂分およびアスファルテン分(SARA)の分析が17.2/29.6/51.3/1.9であると記載されている。アラブ重質原油由来340+℃残油(AHAR)のSARA分析は53.7/34.8/3.1/8.1である。これらの流れの異なる質量比での組み合わせを下表において分析する。
アラビアンライト340+℃カット(ALAR)の飽和分、芳香族分、樹脂分およびアスファルテン分(SARA)の分析は、61.8/30.5/3.4/3.5である。アラブ重質原油由来340+℃残油(AHAR)のSARA分析は、53.7/34.8/3.1/8.1である。スチームクラッカーからの分解蒸留物(CD)の飽和分、芳香族分、樹脂分およびアスファルテン分(SARA)の分析は、7.76/92.24/0/0である。これらの流れの異なる質量比での組み合わせを下表にて分析した。
Claims (8)
- アスファルテンを含有する原油をベースとする、水素化処理ユニットのための供給原料の調製方法であって、
スチームクラッカー分解蒸留物(CD)、スチームクラッカー・カーボンブラック油(CBO)、沸点が300℃超の低アスファルテン含有原油残留物および芳香族に富んだ炭化水素の流れの群から選択される少なくとも1つである溶媒と、前記原油とを、加熱せずに混合するステップであって、ここで、前記溶媒:前記原油の混合比は、前記溶媒と前記原油とを混合した混合物においてアスファルテンの凝集が加熱なしの混合条件下で起こらないものであるステップと;
前記溶媒と前記原油とを混合した混合物を1つ以上の水素化処理ユニットに供給するステップと、を備え、
水素化処理ユニットの1つ以上、またはその供給物加熱器に入れる前の前記溶媒と前記原油とを混合した前記混合物の、ASTMD7157−12に従い測定したS値が1を超え、
前記溶媒と前記原油とを混合した前記混合物の溶液中にアスファルテンが保たれており、
前記溶媒と前記原油とを混合した前記混合物が、供給ブレンドの合計質量に対して、CDを25wt.%以上含むことを特徴とする方法。 - 前記芳香族に富んだ炭化水素の流れが、スチームクラッカー熱分解ガソリン(pygas)、混合した廃プラスチック熱分解油、FCC分解ガソリン、LCOおよびHCOからなる群より選択される請求項1に記載の方法。
- 前記原油が、原油蒸留ユニット(CDU)および/または真空蒸留ユニット(VDU)からの底部の流れであることを特徴とする請求項1または2に記載の方法。
- さらに、前記原油を脱れきするステップと、脱れきした原油を、低含有量のアスファルテンを有する流れと高含有量のアスファルテンを有する流れに分離するステップとを備え、前記高含有量のアスファルテンを有する流れが前記溶媒と混合されることを特徴とする請求項1乃至3のいずれか1項に記載の方法。
- 前記1つ以上の水素化処理ユニットが、残油水素化分解ユニットおよびコーキングユニットの群から選択されることを特徴とする請求項1乃至4のいずれか1項に記載の方法。
- 前記溶媒と前記原油とを混合した前記混合物が、供給ブレンドの合計質量に対して、前記低アスファルテン含有原油残留物を25wt.%超含むことを特徴とする請求項1乃至5のいずれか1項に記載の方法。
- 前記溶媒と前記原油とを混合した前記混合物が、前記低アスファルテン含有原油残留物および前記芳香族に富んだ炭化水素の流れと組み合わせて、アスファルテンがより多い原油の流れを最大55wt.%含むことを特徴とする請求項1乃至6のいずれか1項に記載の方法。
- 前記溶媒がCDである請求項1乃至5のいずれか1項に記載の方法。
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KR (1) | KR102387296B1 (ja) |
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EP3918037A1 (en) | 2019-01-29 | 2021-12-08 | SABIC Global Technologies B.V. | Conversion of heavy ends of crude oil or whole crude oil to high value chemicals using a combination of thermal hydroprocessing, hydrotreating with steam crackers under high severity conditions to maximize ethylene, propylene, butenes and benzene |
EP3918033A1 (en) | 2019-01-29 | 2021-12-08 | SABIC Global Technologies B.V. | Methods and systems for upgrading crude oils, heavy oils, and residues |
US20240059988A1 (en) * | 2020-12-28 | 2024-02-22 | Sabic Global Technologies B.V. | Producing olefins and aromatics |
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FR2981659B1 (fr) | 2011-10-20 | 2013-11-01 | Ifp Energies Now | Procede de conversion de charges petrolieres comprenant une etape d'hydroconversion en lit bouillonnant et une etape d'hydrotraitement en lit fixe pour la production de fiouls a basse teneur en soufre |
FR3027911B1 (fr) | 2014-11-04 | 2018-04-27 | IFP Energies Nouvelles | Procede de conversion de charges petrolieres comprenant une etape d'hydrocraquage en lit bouillonnant, une etape de maturation et une etape de separation des sediments pour la production de fiouls a basse teneur en sediments |
FR3027912B1 (fr) | 2014-11-04 | 2018-04-27 | IFP Energies Nouvelles | Procede de production de combustibles de type fuel lourd a partir d'une charge hydrocarbonee lourde utilisant une separation entre l'etape d'hydrotraitement et l'etape d'hydrocraquage |
FR3033797B1 (fr) | 2015-03-16 | 2018-12-07 | IFP Energies Nouvelles | Procede ameliore de conversion de charges hydrocarbonees lourdes |
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2014
- 2014-12-23 WO PCT/EP2014/079224 patent/WO2015128043A1/en active Application Filing
- 2014-12-23 ES ES14816332.2T patent/ES2659025T3/es active Active
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- 2014-12-23 CN CN201480076214.5A patent/CN106164224B/zh active Active
- 2014-12-23 KR KR1020167026457A patent/KR102387296B1/ko active IP Right Grant
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US10125329B2 (en) | 2018-11-13 |
EA032741B1 (ru) | 2019-07-31 |
CN106164224A (zh) | 2016-11-23 |
KR102387296B1 (ko) | 2022-04-14 |
EP3110913A1 (en) | 2017-01-04 |
JP2017509778A (ja) | 2017-04-06 |
WO2015128043A1 (en) | 2015-09-03 |
CN106164224B (zh) | 2018-09-14 |
US20170015916A1 (en) | 2017-01-19 |
EP3110913B1 (en) | 2017-11-29 |
JP2019104920A (ja) | 2019-06-27 |
EA201691359A1 (ru) | 2016-12-30 |
SG11201606307PA (en) | 2016-08-30 |
KR20160146675A (ko) | 2016-12-21 |
ES2659025T3 (es) | 2018-03-13 |
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