JP6476734B2 - 粘着テープ、粘着テープを用いて得られる物品及び物品の解体方法 - Google Patents
粘着テープ、粘着テープを用いて得られる物品及び物品の解体方法 Download PDFInfo
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- JP6476734B2 JP6476734B2 JP2014215352A JP2014215352A JP6476734B2 JP 6476734 B2 JP6476734 B2 JP 6476734B2 JP 2014215352 A JP2014215352 A JP 2014215352A JP 2014215352 A JP2014215352 A JP 2014215352A JP 6476734 B2 JP6476734 B2 JP 6476734B2
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- layer
- sensitive adhesive
- pressure
- adhesive tape
- foam
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- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 1
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Images
Landscapes
- Laminated Bodies (AREA)
- Adhesive Tapes (AREA)
Description
前記粘着テープを構成する易解体層(A)は、熱可塑性樹脂を含有する。前記易解体層(A)は、本発明の粘着テープにより貼り合わせられた被着体同士を分離する際に、被着体同士を引き離す等の剥離応力により破断される層である。
粘着剤層(b1)及び粘着剤層(b2)は、被接着体と接着する層である。粘着剤層(b1)及び粘着剤層(b2)は、同一の粘着力を有するものであってもよく、異なる粘着力を有するものであってもよい。具体的には、前記粘着剤層(b1)及び粘着剤層(b2)のいずれか一方が、いわゆる強粘着剤層であり、他方が弱粘着剤層であってもよい。前記粘着剤層(b1)及び粘着剤層(b2)は、同一の組成からなるものであってもよく、異なる組成からなるものであってもよい。
攪拌機、還流冷却管、窒素導入管、温度計を備えた反応容器に、n−ブチルアクリレート80.94質量部、2−エチルヘキシルアクリレート5質量部、シクロヘキシルアクリレート10質量部、アクリル酸4質量部、4−ヒドロキシブチルアクリレート0.06質量部、及び、酢酸エチル200質量部を仕込み、攪拌下、窒素を吹き込みながら72℃まで昇温させた。
GPC法による分子量の測定は、東ソー株式会社製GPC装置(HLC−8329GPC)を用いて測定される、スタンダードポリスチレン換算値である。
サンプル注入量:100μl
溶離液:THF(テトラヒドロフラン)
流速:1.0ml/分
測定温度:40℃
本カラム:TSKgel GMHHR−H(20)2本
ガードカラム:TSKgel HXL−H
検出器:示差屈折計
スタンダードポリスチレン分子量:1万〜2000万(東ソー株式会社製)
重量平均分子量20万のスチレン−イソプレンブロック共重合体S(トリブロック共重合体とジブロック共重合体との混合物。前記混合物の全量に対する前記ジブロック共重合体の占める割合は52質量%。前記スチレン−イソプレンブロック共重合体の全体に占めるポリスチレン単位の質量割合は15質量%、ポリイソプレン単位の質量割合は85質量%)を100質量部、C5石油系粘着付与樹脂(軟化点100℃、数平均分子量885)を40質量部、重合ロジンエステル系粘着付与樹脂(軟化点125℃、数平均分子量880)を30質量部、液状粘着付与樹脂としてHV−100(JX日鉱日石株式会社製、低分子量ポリブテン)を5質量部、の配合比で混合したものを、トルエンに溶解することによって、易解体層形成用の熱可塑性樹脂組成物を得た。
容器に、前記アクリル重合体(A−1)100質量部に対して、重合ロジンエステル系粘着付与樹脂であるD−125(荒川化学工業株式会社製)15質量部と不均化ロジンエステル系粘着付与樹脂であるA−125(荒川化学工業株式会社製)10質量部とを混合攪拌したのち、酢酸エチルを加えることによって固形分31質量%粘着剤溶液を得た。
23℃の環境下、実施例1で得た両面粘着テープを、1辺(外形)の長さが14mmの正方形で、幅2mmの額縁状に裁断した。前記裁断した両面粘着テープを、長さ15mm、幅15mm及び厚さ2mmの直方体であるアクリル板に貼付した。その際、前記裁断した両面粘着テープの1辺が、前記アクリル板の1辺15mmに対応するように貼付したものを積層体とした。
温度23℃及び相対湿度50%RHの環境下、前記粘着テープを裁断して、外形2mm×20mmの粘着テープ2枚を作成した。
2 発泡体層
3 易解体層
4 樹脂フィルム層
5 接着剤層
Claims (8)
- 熱可塑性樹脂を含む易解体層(A)の一方の面側に直接または他の層を介して発泡体層(C)及び粘着剤層(b1)を有し、前記易解体層(A)の他方の面側に直接または他の層を介して粘着剤層(b2)を有し、前記易解体層(A)が加熱溶融により剥離応力により分断される層であり、前記熱可塑性樹脂がスチレン系熱可塑性樹脂であることを特徴とする粘着テープ。
- 前記易解体層(A)の他方の面側に、少なくとも樹脂フィルム層(D)を介して、粘着剤層(b2)を有するものである請求項1に記載の粘着テープ。
- 前記易解体層(A)の一方の面側に、直接または他の層を介して、発泡体層(C)が積層され、前記発泡体層(C)の表面に、樹脂フィルム層(D)及び接着剤層(E)の少なくとも一つの層を介して、粘着剤層(b1)が積層され、かつ、前記易解体層(A)の他方の面側に、樹脂フィルム層(D)及び接着剤層(E)の少なくとも一つの層を介して、粘着剤層(b2)を有するものである請求項1に記載の粘着テープ。
- 前記発泡体層(C)を構成する発泡体基材が、層間強度10N/cm以上で、かつ、引張強さ500N/cm2〜1700N/cm2の高強度発泡体基材である請求項1〜3のいずれか1項に記載の粘着テープ。
- 前記発泡体層(C)が、厚さ1500μm以下である請求項1〜4のいずれか1項に記載の粘着テープ。
- 総厚さが100μm〜500μmである請求項1〜5のいずれか1項に記載の粘着テープ。
- 請求項1〜6のいずれか1項に記載の粘着テープによって、2以上の被着体が接着された構成を有することを特徴とする物品。
- 請求項7記載の物品における易解体層(A)の一部または全部を、直接的または間接的に加熱し、前記易解体層(A)を可塑化することによって、前記物品を構成する2以上の被着体を分離することを特徴とする物品の解体方法。
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