JP6348496B2 - クロロフルオロポリマーコート基材およびそれを作製するための方法 - Google Patents
クロロフルオロポリマーコート基材およびそれを作製するための方法 Download PDFInfo
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- JP6348496B2 JP6348496B2 JP2015533113A JP2015533113A JP6348496B2 JP 6348496 B2 JP6348496 B2 JP 6348496B2 JP 2015533113 A JP2015533113 A JP 2015533113A JP 2015533113 A JP2015533113 A JP 2015533113A JP 6348496 B2 JP6348496 B2 JP 6348496B2
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- Prior art keywords
- vinyl
- copolymer
- olefin
- group
- vinyl ester
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- 239000000758 substrate Substances 0.000 title claims description 27
- 238000000034 method Methods 0.000 title description 18
- 239000000123 paper Substances 0.000 claims description 53
- 229920001577 copolymer Polymers 0.000 claims description 33
- 239000000203 mixture Substances 0.000 claims description 32
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical group FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 claims description 22
- -1 chlorotrifluoroethylene, fluorotrichloroethylene, 1,1-dichlorodifluoroethylene Chemical group 0.000 claims description 22
- 229920001567 vinyl ester resin Polymers 0.000 claims description 22
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 claims description 20
- 238000000576 coating method Methods 0.000 claims description 19
- 239000000835 fiber Substances 0.000 claims description 19
- 239000011248 coating agent Substances 0.000 claims description 16
- 239000000178 monomer Substances 0.000 claims description 16
- 229910052801 chlorine Inorganic materials 0.000 claims description 13
- 229910052739 hydrogen Inorganic materials 0.000 claims description 13
- 229910052731 fluorine Inorganic materials 0.000 claims description 12
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical group CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 8
- 150000001336 alkenes Chemical class 0.000 claims description 8
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 8
- 150000007513 acids Chemical class 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 5
- 239000002657 fibrous material Substances 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 239000004711 α-olefin Substances 0.000 claims description 4
- MIZLGWKEZAPEFJ-UHFFFAOYSA-N 1,1,2-trifluoroethene Chemical group FC=C(F)F MIZLGWKEZAPEFJ-UHFFFAOYSA-N 0.000 claims description 3
- YRXNLBAUGRIIOM-UHFFFAOYSA-N 1,3,3,4,4,5,6,6,6-nonafluoro-5-(trifluoromethyl)hex-1-ene Chemical compound FC(C(C(F)(F)F)(C(C(C=CF)(F)F)(F)F)F)(F)F YRXNLBAUGRIIOM-UHFFFAOYSA-N 0.000 claims description 3
- HFNSTEOEZJBXIF-UHFFFAOYSA-N 2,2,4,5-tetrafluoro-1,3-dioxole Chemical compound FC1=C(F)OC(F)(F)O1 HFNSTEOEZJBXIF-UHFFFAOYSA-N 0.000 claims description 3
- 229920001131 Pulp (paper) Polymers 0.000 claims description 3
- MEGHWIAOTJPCHQ-UHFFFAOYSA-N ethenyl butanoate Chemical compound CCCC(=O)OC=C MEGHWIAOTJPCHQ-UHFFFAOYSA-N 0.000 claims description 3
- LZWYWAIOTBEZFN-UHFFFAOYSA-N ethenyl hexanoate Chemical compound CCCCCC(=O)OC=C LZWYWAIOTBEZFN-UHFFFAOYSA-N 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- WFLOTYSKFUPZQB-OWOJBTEDSA-N (e)-1,2-difluoroethene Chemical group F\C=C\F WFLOTYSKFUPZQB-OWOJBTEDSA-N 0.000 claims description 2
- IWBCAMACJYCXNV-UHFFFAOYSA-N 2,4,5-trichloro-2-fluoro-1,3-dioxole Chemical compound FC1(Cl)OC(Cl)=C(Cl)O1 IWBCAMACJYCXNV-UHFFFAOYSA-N 0.000 claims description 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 claims description 2
- OAOABCKPVCUNKO-UHFFFAOYSA-N 8-methyl Nonanoic acid Chemical compound CC(C)CCCCCCC(O)=O OAOABCKPVCUNKO-UHFFFAOYSA-N 0.000 claims description 2
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 claims description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 2
- 239000011111 cardboard Substances 0.000 claims description 2
- WNMORWGTPVWAIB-UHFFFAOYSA-N ethenyl 2-methylpropanoate Chemical compound CC(C)C(=O)OC=C WNMORWGTPVWAIB-UHFFFAOYSA-N 0.000 claims description 2
- WBZPMFHFKXZDRZ-UHFFFAOYSA-N ethenyl 6,6-dimethylheptanoate Chemical compound CC(C)(C)CCCCC(=O)OC=C WBZPMFHFKXZDRZ-UHFFFAOYSA-N 0.000 claims description 2
- AFSIMBWBBOJPJG-UHFFFAOYSA-N ethenyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC=C AFSIMBWBBOJPJG-UHFFFAOYSA-N 0.000 claims description 2
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 claims description 2
- RAJLHYZMTYVILB-UHFFFAOYSA-N 3-[4-(trifluoromethyl)phenyl]propanal Chemical compound FC(F)(F)C1=CC=C(CCC=O)C=C1 RAJLHYZMTYVILB-UHFFFAOYSA-N 0.000 claims 1
- ZHXNRJQVYHYIMK-UHFFFAOYSA-N ethenyl 2,2-dimethyloctanoate Chemical compound CCCCCCC(C)(C)C(=O)OC=C ZHXNRJQVYHYIMK-UHFFFAOYSA-N 0.000 claims 1
- HTBDFCHXYGXXSD-UHFFFAOYSA-N ethenyl 2-methyl-2-propylpentanoate Chemical compound CCCC(C)(CCC)C(=O)OC=C HTBDFCHXYGXXSD-UHFFFAOYSA-N 0.000 claims 1
- BTFFUEGVQBZTMY-UHFFFAOYSA-N ethenyl 3-methylbutanoate Chemical compound CC(C)CC(=O)OC=C BTFFUEGVQBZTMY-UHFFFAOYSA-N 0.000 claims 1
- QQZBNCQYXOBPDL-UHFFFAOYSA-N ethenyl 4-ethyl-4-methyloctanoate Chemical compound CCCCC(C)(CC)CCC(=O)OC=C QQZBNCQYXOBPDL-UHFFFAOYSA-N 0.000 claims 1
- GLVVKKSPKXTQRB-UHFFFAOYSA-N ethenyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC=C GLVVKKSPKXTQRB-UHFFFAOYSA-N 0.000 claims 1
- BLZSRIYYOIZLJL-UHFFFAOYSA-N ethenyl pentanoate Chemical compound CCCCC(=O)OC=C BLZSRIYYOIZLJL-UHFFFAOYSA-N 0.000 claims 1
- 125000001153 fluoro group Chemical group F* 0.000 claims 1
- 150000003463 sulfur Chemical class 0.000 claims 1
- 239000006185 dispersion Substances 0.000 description 32
- 239000000047 product Substances 0.000 description 30
- 238000006116 polymerization reaction Methods 0.000 description 24
- 229920000642 polymer Polymers 0.000 description 22
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 21
- 239000003999 initiator Substances 0.000 description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 17
- 239000002245 particle Substances 0.000 description 16
- 238000006243 chemical reaction Methods 0.000 description 13
- 230000008569 process Effects 0.000 description 12
- 239000000460 chlorine Substances 0.000 description 11
- 239000004094 surface-active agent Substances 0.000 description 10
- 239000002904 solvent Substances 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- 230000004888 barrier function Effects 0.000 description 8
- 238000009826 distribution Methods 0.000 description 8
- 150000003254 radicals Chemical class 0.000 description 8
- 239000003921 oil Substances 0.000 description 7
- 238000004537 pulping Methods 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000008367 deionised water Substances 0.000 description 6
- 229910021641 deionized water Inorganic materials 0.000 description 6
- 239000012966 redox initiator Substances 0.000 description 6
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 6
- 239000002023 wood Substances 0.000 description 6
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 5
- 235000011613 Pinus brutia Nutrition 0.000 description 5
- 241000018646 Pinus brutia Species 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 239000010408 film Substances 0.000 description 5
- 230000000977 initiatory effect Effects 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 5
- 229920001897 terpolymer Polymers 0.000 description 5
- 238000007792 addition Methods 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- WBZKQQHYRPRKNJ-UHFFFAOYSA-L disulfite Chemical compound [O-]S(=O)S([O-])(=O)=O WBZKQQHYRPRKNJ-UHFFFAOYSA-L 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 229920002313 fluoropolymer Polymers 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 235000013334 alcoholic beverage Nutrition 0.000 description 3
- 239000003945 anionic surfactant Substances 0.000 description 3
- 239000012736 aqueous medium Substances 0.000 description 3
- 239000003638 chemical reducing agent Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000002537 cosmetic Substances 0.000 description 3
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- 235000013305 food Nutrition 0.000 description 3
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- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000007800 oxidant agent Substances 0.000 description 3
- 238000004806 packaging method and process Methods 0.000 description 3
- 239000002304 perfume Substances 0.000 description 3
- 150000002978 peroxides Chemical class 0.000 description 3
- 235000019505 tobacco product Nutrition 0.000 description 3
- 229910052723 transition metal Inorganic materials 0.000 description 3
- 150000003624 transition metals Chemical class 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 241000208140 Acer Species 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- 241000218657 Picea Species 0.000 description 2
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 2
- 229920002522 Wood fibre Polymers 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 2
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 2
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- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
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- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 2
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- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
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- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 2
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- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 2
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- KHXKESCWFMPTFT-UHFFFAOYSA-N 1,1,1,2,2,3,3-heptafluoro-3-(1,2,2-trifluoroethenoxy)propane Chemical compound FC(F)=C(F)OC(F)(F)C(F)(F)C(F)(F)F KHXKESCWFMPTFT-UHFFFAOYSA-N 0.000 description 1
- LFMIQNJMJJKICW-UHFFFAOYSA-N 1,1,2-trichloro-2-fluoroethene Chemical group FC(Cl)=C(Cl)Cl LFMIQNJMJJKICW-UHFFFAOYSA-N 0.000 description 1
- BZPCMSSQHRAJCC-UHFFFAOYSA-N 1,2,3,3,4,4,5,5,5-nonafluoro-1-(1,2,3,3,4,4,5,5,5-nonafluoropent-1-enoxy)pent-1-ene Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)=C(F)OC(F)=C(F)C(F)(F)C(F)(F)C(F)(F)F BZPCMSSQHRAJCC-UHFFFAOYSA-N 0.000 description 1
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- KTHXOYWHJBTQNC-UHFFFAOYSA-N 2-methyl-2-propylpentanoic acid Chemical compound CCCC(C)(C(O)=O)CCC KTHXOYWHJBTQNC-UHFFFAOYSA-N 0.000 description 1
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- 230000000996 additive effect Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- 239000001099 ammonium carbonate Substances 0.000 description 1
- 235000012501 ammonium carbonate Nutrition 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000012874 anionic emulsifier Substances 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- GEWYFWXMYWWLHW-UHFFFAOYSA-N azanium;octanoate Chemical class [NH4+].CCCCCCCC([O-])=O GEWYFWXMYWWLHW-UHFFFAOYSA-N 0.000 description 1
- 239000010905 bagasse Substances 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- GWYFCOCPABKNJV-UHFFFAOYSA-N beta-methyl-butyric acid Natural products CC(C)CC(O)=O GWYFCOCPABKNJV-UHFFFAOYSA-N 0.000 description 1
- 230000002902 bimodal effect Effects 0.000 description 1
- KVNRLNFWIYMESJ-UHFFFAOYSA-N butyronitrile Chemical compound CCCC#N KVNRLNFWIYMESJ-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 239000000701 coagulant Substances 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 239000012933 diacyl peroxide Substances 0.000 description 1
- 238000000502 dialysis Methods 0.000 description 1
- QDGONURINHVBEW-UHFFFAOYSA-N dichlorodifluoroethylene Chemical group FC(F)=C(Cl)Cl QDGONURINHVBEW-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 229920000840 ethylene tetrafluoroethylene copolymer Polymers 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000008394 flocculating agent Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 229940093915 gynecological organic acid Drugs 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 150000002432 hydroperoxides Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- SURQXAFEQWPFPV-UHFFFAOYSA-L iron(2+) sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Fe+2].[O-]S([O-])(=O)=O SURQXAFEQWPFPV-UHFFFAOYSA-L 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- AHSBSUVHXDIAEY-UHFFFAOYSA-K manganese(iii) acetate Chemical compound [Mn+3].CC([O-])=O.CC([O-])=O.CC([O-])=O AHSBSUVHXDIAEY-UHFFFAOYSA-K 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- UJMWVICAENGCRF-UHFFFAOYSA-N oxygen difluoride Chemical class FOF UJMWVICAENGCRF-UHFFFAOYSA-N 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 238000009512 pharmaceutical packaging Methods 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920002493 poly(chlorotrifluoroethylene) Polymers 0.000 description 1
- 239000005023 polychlorotrifluoroethylene (PCTFE) polymer Substances 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229940001584 sodium metabisulfite Drugs 0.000 description 1
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical class [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 125000001273 sulfonato group Chemical class [O-]S(*)(=O)=O 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000006276 transfer reaction Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/12—Coatings without pigments applied as a solution using water as the only solvent, e.g. in the presence of acid or alkaline compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/16—Sizing or water-repelling agents
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/3154—Of fluorinated addition polymer from unsaturated monomers
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Paper (AREA)
- Paints Or Removers (AREA)
Description
本開示は、その全内容が参照により本明細書に援用される2012年9月24日に出願された米国特許仮出願番号第61/704,956号の優先権の利益を主張するものである。
CTFE/VDF/プロピオン酸ビニルターポリマー分散体の作製
80.1重量%のクロロトリフルオロエチレン、16.5重量%のフッ化ビニリデン、および3.4重量%のプロピオン酸ビニルを有するCTFE/VDF/プロピオン酸ビニルターポリマー分散体を作製した。このポリマーを作製するために、3ガロンのガラス裏打ちオートクレーブに、1.57ガロンの脱イオン水を充填し、次に窒素を注入して酸素を除去した。次に、オートクレーブに、585gのCTFEおよび116グラムのVDFを充填し、19℃(66.2°F)まで加熱した。ターシャリーブチルヒドロペルオキシド(TBHP)の70%水溶液の5.7Gを、脱イオン水で35.7mLにさらに希釈した。4.4グラムのメタ亜硫酸水素ナトリウム(MBS)および0.9グラムの硫酸第一鉄七水和物も、脱イオン水で35.7mLに希釈した。次に、これら2つの溶液を別々に、10分間掛けてオートクレーブに添加し、重合を開始した。オートクレーブ内の温度を、重合全体を通して19〜20℃に維持した。TBHP(142mLの脱イオン水中20.6g)およびMBS(142.8mLの脱イオン水中16.8g)から成る2つの別々の溶液をゆっくり添加することにより重合を継続した。25分間の重合後、108.4mLのプロピオン酸ビニルを、CTFEおよびVDFの消費速度に等しい速度にて、重合を通してオートクレーブ中にポンプ注入した。CTFEおよびVDFの初期チャージの消費後、追加のCTFEおよびVDFを、4時間にわたってオートクレーブに添加し、反応器圧を50〜160psigに維持した。圧力維持のために添加したCTFEおよびVDFの合計量は、それぞれ、4222グラムおよび837グラムのVDFである。すべてのモノマーの消費後(圧力は<90psigに低下)、オートクレーブを解放し、31.2重量%のポリマー固形分を含有する水性ターポリマー分散体の2ガロンを得た。
実施例1からの分散体を用いた紙のコーティング
実施例1で得た分散体へ、2.0重量%(分散体の重量に基づいて)のCapstone FS‐32フルオロ界面活性剤(デュポン製)を添加し、充分に混合した。次に、この混合物を、ラミネート紙(オランダ、コールデンホーブ(Coldenhove)製)上に、マルチパスを用いて室温でコーティングし、紙の両面に1.5ミルの厚さのコーティングを得た。コート紙の合計厚さは、4.9ミルに対応する。コーティングごとに、コート紙を80℃のエアオーブンで乾燥した。次に、このコート紙を、40℃および相対湿度70%でのMOCON試験に掛け、0.0929グラム/100インチ2‐日の水蒸気透過率を得た。このコート紙を175℃(約350°F)に加熱すると、それ自体がヒートシールされ、シールを破壊しようとする試みは紙が裂ける結果となり、シールが保持されたままであることが示される。
Claims (9)
- 木材パルプから得られるセルロース系繊維材料からなる紙または紙製品の基材、及び
前記基材の少なくとも1つの面上に適用されたコポリマーからなるコポリマーコーティング、からなるコート基材であって、
前記コポリマーは、式:
CX2CYA
のコモノマーユニットを少なくとも2つ有し、
式中、各Xは、独立して、H、Cl、およびFから成る群より選択され、Yは、H、Cl、F、O(CZ2)nCZ3、(CZ2)nCZ3、(OCZ2CZ2)nCZ3、および(O(CZ2)n)nCZ3から成る群より選択され、ここで、各nは、独立して、約1から約12であり、各Zは、独立して、H、Cl、およびFから成る群より選択され、ならびに、Aは、H、Cl、およびFから成る群より選択され、但し、少なくとも1つのコモノマーユニットにおいて、A、Y、およびXまたはいずれかのZのうちの少なくとも1つは、Clであり、
前記コポリマーは、アルキルビニルエステル、酸およびそれらの硫黄類似体、ならびに非ハロゲン化アルファ‐オレフィン、ならびにこれらの混合物から成る群より選択されるモノマーをさらに含み、
前記コポリマーは、約2,000,000から約20,000,000ダルトンの重量平均分子量を有し、
前記セルロース系繊維材料は、乾燥され、紙シートまたはボール紙の形態とされたセルロース系繊維パルプを含み、
前記コポリマーコーティングは、前記基材の少なくとも1つの面上に、前記基材の前記少なくとも1つの面から前記基材の他方の面への水分の通過を抑制するコーティング厚を有する、
コート基材。 - 前記コポリマーが、クロロトリフルオロエチレン、フルオロトリクロロエチレン、1,1‐ジクロロジフルオロエチレン、1,2‐ジクロロジフルオロエチレンのシスおよびトランス異性体、1‐クロロ‐1‐フルオロエチレン、1‐クロロ‐2,2‐ジフルオロエチレン、塩化ビニリデン、塩化ビニル、トリクロロエチレン、パークロロフルオロエーテル、パークロロフルオロジオキソール、及び、これらの混合物から成る群より選択される少なくとも1つのコモノマーを含む、請求項1に記載のコート基材。
- 前記コポリマーが、少なくとも1つのフッ素化モノマーと共重合されたクロロフルオロ‐オレフィンを含み、
前記クロロフルオロ‐オレフィンが、クロロトリフルオロエチレン、フルオロトリクロロエチレン、1,1‐ジクロロジフルオロエチレン、1,2‐ジクロロジフルオロエチレンのシスおよびトランス異性体、1‐クロロ‐1‐フルオロエチレン、及び1‐クロロ‐2,2‐ジフルオロエチレンから成る群より選択される、
請求項2に記載のコート基材。 - 前記フッ素化モノマーが、フッ化ビニリデン、ヘキサフルオロプロピレン、テトラフルオロエチレン、フッ化ビニル、トリフルオロエチレン、フッ素化アルキルビニルエーテル、パーフッ素化アルキルビニルエーテル、1,2‐ジフルオロエチレン、フッ素化アルファ‐オレフィン、パーフルオロジオキソール、およびこれらの混合物から成る群より選択される、請求項3に記載のコート基材。
- 前記コポリマーが、フッ化ビニリデン、ヘキサフルオロプロピレン、テトラフルオロエチレン、フッ化ビニル、トリフルオロエチレン、フッ素化アルキルビニルエーテル、パーフッ素化アルキルビニルエーテル、およびこれらの混合物から成る群より選択されるフッ素化モノマーと共重合されたクロロトリフルオロエチレンを含む、請求項4に記載のコート基材。
- 前記コポリマーが、フッ素化アルファオレフィンをさらに含む、請求項5に記載のコート基材。
- 前記コポリマーが、少なくとも1つのフルオロ‐オレフィンおよび少なくとも1つのアルキルビニルエステルと共重合されたクロロトリフルオロエチレンを含む、請求項5に記載のコート基材。
- 前記アルキルビニルエステルが、プロピオン酸ビニル、酢酸ビニル、酪酸ビニル、イソ酪酸ビニル、ヘキサン酸ビニル、ステアリン酸ビニル、ネオノナン酸エテニルエステル、バーサチック酸ビニルエステル、吉草酸ビニルエステル、カプロン酸ビニルエステル、ラウリン酸ビニルエステル、イソ吉草酸ビニルエステル、2‐エチルヘキサン酸ビニルエステル、2,2‐ジメチルオクタン酸ビニルエステル、2‐メチル‐2‐プロピルペンタン酸ビニルエステル、4‐メチル‐4‐ブチルヘキサン酸ビニルエステル、およびネオ酸(neo acids)のビニルエステル、ならびにこれらの混合物から成る群より選択される、請求項7に記載のコート基材。
- 前記クロロフルオロ‐オレフィンが、クロロトリフルオロエチレンであり、前記フルオロ‐オレフィンが、フッ化ビニリデンであり、および前記ビニルエステルが、プロピオン酸ビニルである、請求項8に記載のコート基材。
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US13/834,800 US20140087195A1 (en) | 2012-09-24 | 2013-03-15 | Chlorofluoropolymer coated substrates and methods for producing the same |
US13/834,800 | 2013-03-15 | ||
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US10435580B2 (en) | 2015-11-20 | 2019-10-08 | Honeywell International Inc. | Gloss retentive fluorocopolymers for coating applications |
US20190002656A1 (en) * | 2015-08-26 | 2019-01-03 | Bemis Company, Inc. | Anti-Scalping Pharmaceutical Packaging Film |
US11015005B2 (en) | 2015-11-20 | 2021-05-25 | Honeywell International Inc. | Fluorocopolymers for coating applications |
JP6683884B2 (ja) * | 2016-07-27 | 2020-04-22 | ハネウェル・インターナショナル・インコーポレーテッドHoneywell International Inc. | フィルム層及びその形成方法 |
CN110869400A (zh) * | 2017-05-12 | 2020-03-06 | 霍尼韦尔国际公司 | 基于三氟氯乙烯和氯乙烯的共聚物和三元共聚物及其用途 |
KR102328470B1 (ko) * | 2017-05-12 | 2021-11-18 | 허니웰 인터내셔날 인코포레이티드 | 클로로트리플루오로에틸렌와 비닐 염화물에 기초한 공중합체와 3량체 및 그의 용도 |
KR102512161B1 (ko) * | 2022-05-02 | 2023-03-22 | (주)미지건설 | 자기치유 및 균열저감형 초속경 시멘트 모르타르 조성물 및 표면보호 코팅제를 이용한 콘크리트 구조물의 보수공법 |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3531441A (en) * | 1966-03-01 | 1970-09-29 | Du Pont | Interpolymers of vinyl fluoride |
US3449305A (en) * | 1966-03-01 | 1969-06-10 | Du Pont | Interpolymers of vinylidene fluoride |
US3839144A (en) * | 1970-09-21 | 1974-10-01 | W Lounden | Paper having 60{14 97 percent hydrated cellulosic fibers and 3{14 40 percent unhydrated cellulosic fibers |
JPS6067517A (ja) * | 1983-09-21 | 1985-04-17 | Daikin Ind Ltd | 含フッ素共重合体 |
US4581412A (en) * | 1983-09-21 | 1986-04-08 | Daikin Kogyo Co., Ltd. | Coating composition of vinylidene fluoride copolymer and acrylic polymer |
JPS61261367A (ja) * | 1985-05-15 | 1986-11-19 | Dainippon Ink & Chem Inc | エマルジヨン塗料用組成物 |
DE3688000T2 (de) * | 1985-05-16 | 1993-10-21 | Chemfab Corp | Ein Fluorpolymer enthaltende biegsame Verbundlaminate. |
GB8713362D0 (en) * | 1987-06-08 | 1987-07-15 | Ici Plc | Fluorocopolymer compositions |
US4808467A (en) * | 1987-09-15 | 1989-02-28 | James River Corporation Of Virginia | High strength hydroentangled nonwoven fabric |
JP3087286B2 (ja) * | 1990-05-22 | 2000-09-11 | ダイキン工業株式会社 | フッ化ビニリデン共重合体およびそれを含有した硬化用組成物 |
US5776842A (en) * | 1994-06-23 | 1998-07-07 | Cellresin Technologies, Llc | Cellulosic web with a contaminant barrier or trap |
FR2737228B1 (fr) * | 1995-07-24 | 1997-09-05 | Sibille Dalle | Papier sulfurise couche et son procede de fabrication |
US5612416A (en) * | 1995-10-10 | 1997-03-18 | Ppg Industries, Inc. | Unsaturated hydroxy diester copolymers and their use in coating compositions |
US6369178B1 (en) | 1998-12-23 | 2002-04-09 | Alliedsignal Inc. | Poly (chlorotrifluoroethylene/vinylidenefluoride/vinylester) copolymers with excellent long-term ultraviolet light resistance |
US6494328B1 (en) * | 2000-08-23 | 2002-12-17 | L&P Property Management Company | Modular gravity feed dispenser unit |
AU2003235863A1 (en) * | 2002-05-10 | 2003-11-11 | Daikin Industries, Ltd. | Surfactant and dispersion aid each comprising graft fluoropolymer |
CA2703595A1 (en) * | 2010-05-12 | 2011-11-12 | Rajan Ahluwalia | Process for producing recycled paper |
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US20140087195A1 (en) | 2014-03-27 |
EP2898147A1 (en) | 2015-07-29 |
CA2884590C (en) | 2021-08-24 |
JP2015530495A (ja) | 2015-10-15 |
KR20150058235A (ko) | 2015-05-28 |
WO2014046954A1 (en) | 2014-03-27 |
CA2884590A1 (en) | 2014-03-27 |
EP2898147A4 (en) | 2016-05-04 |
MX2015003521A (es) | 2015-07-17 |
KR102257643B1 (ko) | 2021-06-01 |
CN104641040A (zh) | 2015-05-20 |
BR112015006244A2 (pt) | 2017-07-04 |
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