JP6316162B2 - 生物によって再生可能な相変化インク - Google Patents
生物によって再生可能な相変化インク Download PDFInfo
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- JP6316162B2 JP6316162B2 JP2014205651A JP2014205651A JP6316162B2 JP 6316162 B2 JP6316162 B2 JP 6316162B2 JP 2014205651 A JP2014205651 A JP 2014205651A JP 2014205651 A JP2014205651 A JP 2014205651A JP 6316162 B2 JP6316162 B2 JP 6316162B2
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- phase change
- change ink
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- 239000011874 heated mixture Substances 0.000 description 1
- 238000003384 imaging method Methods 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- SXQCTESRRZBPHJ-UHFFFAOYSA-M lissamine rhodamine Chemical compound [Na+].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=C(S([O-])(=O)=O)C=C1S([O-])(=O)=O SXQCTESRRZBPHJ-UHFFFAOYSA-M 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000696 magnetic material Substances 0.000 description 1
- 239000002122 magnetic nanoparticle Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000816 matrix-assisted laser desorption--ionisation Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- NRZWYNLTFLDQQX-UHFFFAOYSA-N p-tert-Amylphenol Chemical compound CCC(C)(C)C1=CC=C(O)C=C1 NRZWYNLTFLDQQX-UHFFFAOYSA-N 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000988 sulfur dye Substances 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-O tributylazanium Chemical compound CCCC[NH+](CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-O 0.000 description 1
- 239000000984 vat dye Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 235000019235 yellow 2G Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
- C08K5/18—Amines; Quaternary ammonium compounds with aromatically bound amino groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/20—Carboxylic acid amides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3415—Five-membered rings
- C08K5/3417—Five-membered rings condensed with carbocyclic rings
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/32—Inkjet printing inks characterised by colouring agents
- C09D11/322—Pigment inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/32—Inkjet printing inks characterised by colouring agents
- C09D11/324—Inkjet printing inks characterised by colouring agents containing carbon black
- C09D11/326—Inkjet printing inks characterised by colouring agents containing carbon black characterised by the pigment dispersant
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/32—Inkjet printing inks characterised by colouring agents
- C09D11/328—Inkjet printing inks characterised by colouring agents characterised by dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/34—Hot-melt inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Ink Jet (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Description
表2に列挙した生物によって再生可能なアモルファス化合物と、表3に列挙した結晶性化合物との混合物を用い、インクを配合した。以下の表4は、調製されたインク配合物を示す。
(インク実施例1)
30mLの褐色瓶に、以下のものを以下の順序で入れた。3.92gのジドコシルテレフタレート(表3の化合物3、78.4重量%)および0.98gのSylvatac RE 40(表1に示す商業的なアモルファスバインダー)。この材料を140℃で溶融し、磁気攪拌棒を用い、30分間攪拌した後、溶融した混合物に、0.1gのKeyplast Solvent blue 101染料(2重量%、Keystoneから購入)を加えた。このインクを140℃でさらに1時間攪拌し、アルミニウム皿に注ぎ、室温まで冷却した。このインクのレオロジーを測定し、図2に示す。
(インク実施例2)
インク実施例2をインク実施例1と同じ手順を用いて製造するが、但し、ジステアリルテレフタレート(DST)を、ジドコシルテレフタレートの代わりに使用した。レオロジーを測定し、表4に示す。
(インク実施例3)
(顔料濃縮物の手順)
ビーカーに、72gのDST、40gのアミン系分散剤(本明細書に参考として組み込まれる米国特許第7,973,186号に記載される特注の分散剤)および8gのSunFlo SFD−B124相乗剤を入れた。この溶液を130℃で30分間攪拌し、40グラムのCyan B4G顔料を加え、130℃でさらに1時間攪拌した。これを、顔料を濡らす段階と呼ぶ。次いで、この混合物を、1800gの1/8インチステンレスショットの入った100mLのアトライタ容器に移した。この混合物を130℃、350RPMで24時間攪拌した。次いで、顔料濃縮物をショットからふるい分けし、粒径を測定した。
50mLビーカーに、1.33gの顔料濃縮物、6.75gのDSTおよび1.91gのSylvatac RE 40を加えた。次いで、この混合物を130℃で2時間攪拌し、皿に注いで凍結(固化)させた。次いで、レオロジーを測定し、結果を表4に示す。
インク実施例4−6をインク実施例3と同じ手順を用いて製造したが、但し、表4に示す他のアモルファスバインダーをSylvatac RE 40の代わりに使用した。次いで、レオロジーを測定し、結果を表4に示す。
図2は、新しいインク実施例3のサンプルと、熟成した実施例3のサンプルのレオロジーを示す。インクのレオロジーは、オーブン中、高温で7日間熟成しても変化しなかった。インク4〜6は、非常に低い粘度を有しており、120℃未満で吐出することができる。
改変したXerox Phaser 8860プリンタを用い、Digital Color Elite Gloss、120gsm(DCEG)にインク実施例3〜6を印刷し、基材から簡単には除去することができない堅牢性の高い画像を作成した。垂直方向から約15°の角度に湾曲した先端を有する引っ掻き用/丸い指状部を用い、528gの重量を加えつつ、約13mm/sの速度で画像の上を引っ掻いたとき、インク実施例3および4を用いて製造された画像からは、インクが目に見えるほど除去されなかった。インク実施例5および6から製造された画像は、インクの一部が除去された。引っ掻き用/丸い指状の先端は、旋盤で丸め、先端を切断した、曲率半径が約12mmの小片に似た形である。画像の一部を、Duplo D−590折り目作成機で、XEROX Business 4200(75gsm)の前面とともに折り曲げ、折り曲げたときの皺と折り曲げたときの裏移りを評価した。インク実施例3および4から得た画像は、裏移りを示さず、インク実施例5および6は、一部が裏移りした。インク実施例3および4は、低Tgアモルファスバインダーを用いて製造し、インク実施例5および6は、高Tgアモルファスバインダーを用いて製造した。Tgが高くなるにつれて、画像の堅牢性は悪くなる。
Claims (18)
- 結晶性成分と;
芳香族ロジンエステルであるアモルファス成分と;
を含む相変化インクであって、
前記芳香族ロジンエステルは、
、およびこれらの混合物からなる群から選択され、着色剤を更に含むか又は含まない相変化インク。 - 顔料、染料、及びこれらの混合物からなる群より選択される着色剤を更に含む、請求項1に記載の相変化インク。
- 前記アモルファス成分および前記結晶性成分は、生物によって再生可能な内容物(bio−renewable content)を少なくとも80重量%含む、請求項1に記載の相変化インク。
- 生物によって再生可能な内容物(bio−renewable content)を少なくとも70重量%含む、請求項1に記載の相変化インク。
- 前記結晶性成分は、ジステアリルテレフタレート、ジドコシルテレフタレート、およびこれらの混合物からなる群から選択される、請求項1に記載の相変化インク。
- 前記結晶性成分は、相変化インクの合計重量の60重量%〜95重量%の量で存在する、請求項1に記載の相変化インク。
- 前記アモルファス成分は、相変化インクの合計重量の5重量%〜40重量%の量で存在する、請求項1に記載の相変化インク。
- 結晶性/アモルファス比が60:40〜95:5である、請求項1に記載の相変化インク。
- 前記結晶性成分は140℃の温度での粘度が12cP未満である、請求項1に記載の相変化インク。
- 前記アモルファス成分はTgが−10℃〜30℃である、請求項1に記載の相変化インク。
- 前記アモルファス成分はオーブン中、140℃で5日間熟成させても粘度が実質的に上昇しない、請求項1に記載の相変化インク。
- 100〜140℃の吐出範囲での粘度が1〜22cPである、請求項1に記載の相変化インク。
- 室温での粘度が106cPよりも大きい、請求項1に記載の相変化インク。
- 分散剤、相乗剤、酸化防止剤、すべりおよびレベリング剤、清澄剤、粘度調整剤、接着剤、可塑剤、及びこれらの混合物からなる群より選択される添加剤を更に含む、請求項1に記載の相変化インク。
- 結晶性成分と;
芳香族ロジンエステルであるアモルファス成分と;
顔料と;
顔料分散剤と、
を含む相変化インクであって、
前記芳香族ロジンエステルは、
、およびこれらの混合物からなる群から選択される、相変化インク。 - 前記顔料分散剤は下記式IIの構造を有するアミン系分散剤である、請求項15に記載の相変化インク。
〔式中、xは1〜10であり、yは10〜10,000である。〕 - 平均粒子サイズが50nm〜400nmである、請求項15に記載の相変化インク。
- 結晶性成分と;
芳香族ロジンエステルであるアモルファス成分と;
着色剤と;
を含む相変化インクであって、前記アモルファス成分及び前記結晶性成分は生物によって再生可能な内容物(bio−renewable content)を少なくとも80重量%含む、相変化インクであって、
前記芳香族ロジンエステルは、
、およびこれらの混合物からなる群より選択される、相変化インク。
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US14/053,601 US9120943B2 (en) | 2013-10-15 | 2013-10-15 | Bio-renewable phase change inks |
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JP2015078363A5 JP2015078363A5 (ja) | 2017-11-16 |
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KR101318708B1 (ko) * | 2010-12-15 | 2013-10-16 | 에스케이이노베이션 주식회사 | 폴리프로필렌카보네이트를 이용한 로토그라비아 핫멜트 잉크 조성물 |
US8500896B2 (en) | 2011-04-27 | 2013-08-06 | Xerox Corporation | Solid ink compositions comprising amorphous esters of tartaric acid |
CN104024348A (zh) * | 2012-01-06 | 2014-09-03 | 奥西-技术有限公司 | 热熔墨水组合物、制备热熔墨水组合物的方法及其用途 |
US8741043B2 (en) * | 2012-04-26 | 2014-06-03 | Xerox Corporation | Bio-renewable fast crystallizing phase change inks |
US9062226B2 (en) * | 2012-11-19 | 2015-06-23 | Xerox Corporation | Compositions of pigment concentrates in phase change inks |
US8778069B2 (en) * | 2012-11-19 | 2014-07-15 | Xerox Corporation | Phase change inks containing oligomeric rosin esters |
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CN104559477B (zh) | 2017-09-08 |
KR102131461B1 (ko) | 2020-07-08 |
KR20150044380A (ko) | 2015-04-24 |
RU2659969C2 (ru) | 2018-07-04 |
JP2015078363A (ja) | 2015-04-23 |
US9120943B2 (en) | 2015-09-01 |
CA2867813A1 (en) | 2015-04-15 |
IN2014DE02766A (ja) | 2015-06-26 |
CN104559477A (zh) | 2015-04-29 |
RU2014139140A (ru) | 2016-04-20 |
DE102014219828A1 (de) | 2015-04-16 |
US20150101508A1 (en) | 2015-04-16 |
CA2867813C (en) | 2017-11-28 |
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