JP6297161B2 - 同位体比の測定方法 - Google Patents
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- 238000000691 measurement method Methods 0.000 title 1
- 238000005259 measurement Methods 0.000 claims description 225
- 238000000034 method Methods 0.000 claims description 68
- 239000003570 air Substances 0.000 claims description 28
- 238000012937 correction Methods 0.000 claims description 20
- 230000008859 change Effects 0.000 claims description 8
- 239000012080 ambient air Substances 0.000 claims description 4
- 230000000155 isotopic effect Effects 0.000 claims description 4
- FGUUSXIOTUKUDN-IBGZPJMESA-N C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 Chemical compound C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 FGUUSXIOTUKUDN-IBGZPJMESA-N 0.000 claims description 3
- 238000012544 monitoring process Methods 0.000 claims description 3
- 238000004590 computer program Methods 0.000 claims description 2
- 239000007789 gas Substances 0.000 description 231
- 230000008569 process Effects 0.000 description 14
- 239000012159 carrier gas Substances 0.000 description 13
- 230000003287 optical effect Effects 0.000 description 12
- 238000004458 analytical method Methods 0.000 description 10
- 238000002156 mixing Methods 0.000 description 10
- 239000012895 dilution Substances 0.000 description 9
- 238000010790 dilution Methods 0.000 description 9
- 238000010586 diagram Methods 0.000 description 5
- 238000004949 mass spectrometry Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 241000894007 species Species 0.000 description 5
- 238000004611 spectroscopical analysis Methods 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 4
- 230000003595 spectral effect Effects 0.000 description 4
- 239000012491 analyte Substances 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 238000005194 fractionation Methods 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000007865 diluting Methods 0.000 description 2
- 239000001307 helium Substances 0.000 description 2
- 229910052734 helium Inorganic materials 0.000 description 2
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000012552 review Methods 0.000 description 2
- 239000012898 sample dilution Substances 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 230000003434 inspiratory effect Effects 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 238000002307 isotope ratio mass spectrometry Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
Classifications
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/27—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands using photo-electric detection ; circuits for computing concentration
- G01N21/274—Calibration, base line adjustment, drift correction
- G01N21/276—Calibration, base line adjustment, drift correction with alternation of sample and standard in optical path
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/0004—Gaseous mixtures, e.g. polluted air
- G01N33/0006—Calibrating gas analysers
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/0004—Gaseous mixtures, e.g. polluted air
- G01N33/0009—General constructional details of gas analysers, e.g. portable test equipment
- G01N33/0027—General constructional details of gas analysers, e.g. portable test equipment concerning the detector
- G01N33/0036—General constructional details of gas analysers, e.g. portable test equipment concerning the detector specially adapted to detect a particular component
- G01N33/004—CO or CO2
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J49/00—Particle spectrometers or separator tubes
- H01J49/0009—Calibration of the apparatus
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
- G01N21/35—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
- G01N21/3504—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light for analysing gases, e.g. multi-gas analysis
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- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- General Physics & Mathematics (AREA)
- General Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Combustion & Propulsion (AREA)
- Food Science & Technology (AREA)
- Medicinal Chemistry (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Mathematical Physics (AREA)
- Theoretical Computer Science (AREA)
- Other Investigation Or Analysis Of Materials By Electrical Means (AREA)
- Investigating Or Analysing Materials By Optical Means (AREA)
Description
Claims (22)
- 同位体比分光器内で連続試料の同位体比を測定する方法であって、
a)前記分光器内で、ある測定期間
b)前記測定期間
c)前記測定された試料濃度と、
d)前記分光器内で、前記整合された基準ガス濃度
e)対応する基準ガス濃度
f)複数の較正された同位体比及び複数の試料ガス濃度測定値を決定することであって、前記複数の較正された同位体比及び前記複数の試料ガス濃度測定値の各々が、それぞれの異なる時間に対するものである、決定することと、を含む、前記方法。 - ある特定の測定期間
前記複数の較正された同位体比及び前記複数の試料ガス濃度測定値を決定する前記ステップf)が、各測定期間
- 前記ある特定の測定期間
- 前記分光器内で前記測定期間
- 前記分光器内で前記基準ガス濃度
- ステップa)の前に、
前記測定期間
前記測定期間
- 前記選択された先行する基準ガス濃度
前記選択された先行する基準ガス濃度
前記基準ガス濃度
- 前記選択された先行する基準ガス濃度
- 先行する基準ガス濃度
- 前記測定期間
- 前記測定期間
- 前記測定期間
- 前記測定期間
前記測定期間
- 前記分光器内で前記測定期間
前記測定期間
前記それぞれの試料同位体比に関するそれぞれの試料特性を特定することと、
前記特定されたそれぞれの試料特性に関する前記基準ガスのそれぞれの同位体比を決定することと、
前記基準ガスの前記決定されたそれぞれの同位体比を使用して、前記それぞれの試料同位体比を較正することと、を含む、請求項13に記載の前記方法。 - 前記それぞれの試料同位体比に関する前記それぞれの試料特性が、前記それぞれの試料同位体比に関するそれぞれの試料濃度を含む、請求項14に記載の前記方法。
- 前記特定されたそれぞれの試料特性に関する前記基準ガスのそれぞれの同位体比を決定する前記ステップが、前記先行する基準ガス濃度
- 前記それぞれの試料同位体比に関する前記それぞれの試料特性が、前記それぞれの試料同位体比に関するそれぞれの試料測定時間を含む、請求項14〜16のいずれか一項に記載の前記方法。
- 前記特定されたそれぞれの試料特性に関する前記基準ガスのそれぞれの同位体比を決定する前記ステップが、前記先行する基準期間
- 前記連続試料が、周囲空気、開放空気源、プラントチャンバ、及びガス監視入力のうちの1つ以上から誘導される、請求項1〜18のいずれか一項に記載の前記方法。
- プロセッサによって操作されると請求項1〜19のいずれか一項に記載の前記方法を実施するように構成される、コンピュータプログラム。
- 以下のステップに従って動作するように前記同位体比分光器を制御するように構成される、連続試料同位体比分光器のための制御器であって、
前記ステップは、
a)前記分光器内で、ある測定期間
b)前記測定期間
c)前記測定された試料濃度と、
d)前記分光器内で、前記整合された基準ガス濃度
e)対応する基準ガス濃度
f)複数の較正された同位体比及び複数の試料ガス濃度測定値を決定することであって、前記複数の較正された同位体比及び前記複数の試料ガス濃度測定値の各々が、それぞれの異なる時間に対するものである、決定することと、を含む、制御器。 - 連続試料を受け入れるように構成され、かつ請求項21に記載の前記制御器を備える、同位体比分光器。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1319875.9A GB2520086B (en) | 2013-11-11 | 2013-11-11 | Method of measuring isotope ratio |
GB1319875.9 | 2013-11-11 | ||
PCT/EP2014/074188 WO2015067806A1 (en) | 2013-11-11 | 2014-11-10 | Method of measuring isotope ratio |
Publications (2)
Publication Number | Publication Date |
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JP2016535859A JP2016535859A (ja) | 2016-11-17 |
JP6297161B2 true JP6297161B2 (ja) | 2018-03-20 |
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US (1) | US9874513B2 (ja) |
EP (1) | EP3069370B1 (ja) |
JP (1) | JP6297161B2 (ja) |
CN (1) | CN105659354B (ja) |
GB (1) | GB2520086B (ja) |
WO (1) | WO2015067806A1 (ja) |
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Publication number | Priority date | Publication date | Assignee | Title |
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EP3279922A4 (en) * | 2015-04-01 | 2018-10-31 | China Institute of Atomic Energy | Accelerator mass spectrometry device for simultaneously measuring isotopes |
US10330592B2 (en) * | 2017-07-21 | 2019-06-25 | Serguei Koulikov | Laser absorption spectroscopy isotopic gas analyzer |
EP3608941B1 (en) | 2018-08-07 | 2023-11-22 | Thermo Fisher Scientific (Bremen) GmbH | Isotope ratio measurement |
FI130881B1 (fi) * | 2020-03-03 | 2024-05-07 | Teknologian Tutkimuskeskus Vtt Oy | Menetelmä isotooppikäyttönormaalikaasun valmistamiseksi, menetelmä isotooppisuhteen määrittämiseksi näytteessä ja grafiitin käyttö hiili- ja/tai happi-isotooppikäyttönormaalikaasun valmistamiseksi |
CN112198263A (zh) * | 2020-11-09 | 2021-01-08 | 北京普瑞亿科科技有限公司 | 一种快速单体同位素分析*** |
CN113339703B (zh) * | 2021-07-07 | 2022-03-08 | 中国科学院地质与地球物理研究所 | 一种供气调节装置、He气同位素分析***及分析方法 |
CN118130598A (zh) * | 2024-04-30 | 2024-06-04 | 云南商测质量检验技术服务有限公司 | 一种食品中二氧化硫测定方法及*** |
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US4866270A (en) * | 1987-09-02 | 1989-09-12 | Vg Instruments Group Limited | Method and apparatus for the determination of isotopic composition |
DE3932838C2 (de) * | 1989-09-30 | 1996-03-07 | Hartmann & Braun Ag | Nichtdispersiver Infrarot-Gasanalysator |
JP2947737B2 (ja) * | 1995-10-09 | 1999-09-13 | 大塚製薬株式会社 | 同位体ガス分光測定方法及び測定装置 |
CN1138978C (zh) * | 1995-10-09 | 2004-02-18 | 大冢制药株式会社 | 测定同位素气体的光谱学方法及其仪器 |
DE19714903A1 (de) * | 1997-04-10 | 1998-10-29 | Hartmann & Braun Gmbh & Co Kg | Verfahren zur Kalibrierung von NDIR-Spektrometern |
US6656127B1 (en) | 1999-06-08 | 2003-12-02 | Oridion Breathid Ltd. | Breath test apparatus and methods |
EP1781464A1 (en) * | 2004-07-02 | 2007-05-09 | Dennis Coleman | Hydrocarbon preparation system |
US7928369B2 (en) * | 2006-03-31 | 2011-04-19 | Thermo Fisher Scientific (Bremen) Gmbh | Device for the analysis of isotope ratios |
KR101699286B1 (ko) * | 2009-02-02 | 2017-01-24 | 플래너테리 이미션즈 매니지먼트 | 온실가스 유출입량을 모니터하기 위한 복합 시스템 |
CN101936964B (zh) * | 2010-07-29 | 2012-10-03 | 中国科学院兰州地质研究所 | 混合气体中硫化氢硫同位素的gc-irms直接测定法 |
CN102175641B (zh) | 2010-12-10 | 2013-03-20 | 中国科学院安徽光学精密机械研究所 | 基于中红外量子级联激光器直接吸收光谱法的痕量气体检测装置及方法 |
CN109596782A (zh) * | 2013-04-15 | 2019-04-09 | 塞莫费雪科学(不来梅)有限公司 | 用于同位素比分析仪的进气***和确定同位素比的方法 |
GB2513120B (en) * | 2013-04-15 | 2015-09-09 | Thermo Fisher Scient Bremen | Method of determining an isotope ratio |
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2013
- 2013-11-11 GB GB1319875.9A patent/GB2520086B/en active Active
-
2014
- 2014-11-10 US US15/035,736 patent/US9874513B2/en active Active
- 2014-11-10 CN CN201480056911.4A patent/CN105659354B/zh active Active
- 2014-11-10 JP JP2016552694A patent/JP6297161B2/ja active Active
- 2014-11-10 EP EP14796101.5A patent/EP3069370B1/en active Active
- 2014-11-10 WO PCT/EP2014/074188 patent/WO2015067806A1/en active Application Filing
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Publication number | Publication date |
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WO2015067806A1 (en) | 2015-05-14 |
US9874513B2 (en) | 2018-01-23 |
GB2520086A (en) | 2015-05-13 |
GB2520086B (en) | 2020-02-19 |
EP3069370A1 (en) | 2016-09-21 |
JP2016535859A (ja) | 2016-11-17 |
US20160266031A1 (en) | 2016-09-15 |
GB201319875D0 (en) | 2013-12-25 |
CN105659354B (zh) | 2017-10-10 |
EP3069370B1 (en) | 2021-06-23 |
CN105659354A (zh) | 2016-06-08 |
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