JP6190239B2 - 洗浄剤組成物 - Google Patents
洗浄剤組成物 Download PDFInfo
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- JP6190239B2 JP6190239B2 JP2013214881A JP2013214881A JP6190239B2 JP 6190239 B2 JP6190239 B2 JP 6190239B2 JP 2013214881 A JP2013214881 A JP 2013214881A JP 2013214881 A JP2013214881 A JP 2013214881A JP 6190239 B2 JP6190239 B2 JP 6190239B2
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- 239000000203 mixture Substances 0.000 title claims description 38
- 238000004140 cleaning Methods 0.000 title claims description 32
- 150000004665 fatty acids Chemical class 0.000 claims description 31
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 25
- 239000000194 fatty acid Substances 0.000 claims description 25
- 229930195729 fatty acid Natural products 0.000 claims description 25
- -1 polyoxyethylene Polymers 0.000 claims description 12
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 claims description 10
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 9
- 239000003599 detergent Substances 0.000 claims description 9
- 150000003839 salts Chemical class 0.000 claims description 8
- 150000005846 sugar alcohols Polymers 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 239000012528 membrane Substances 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 4
- 229910001413 alkali metal ion Inorganic materials 0.000 claims description 3
- HLERILKGMXJNBU-UHFFFAOYSA-N norvaline betaine Chemical compound CCCC(C([O-])=O)[N+](C)(C)C HLERILKGMXJNBU-UHFFFAOYSA-N 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims 2
- 239000006260 foam Substances 0.000 description 37
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 12
- 230000007794 irritation Effects 0.000 description 12
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 10
- 210000004877 mucosa Anatomy 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 9
- 238000011156 evaluation Methods 0.000 description 9
- 229960003237 betaine Drugs 0.000 description 6
- 239000000284 extract Substances 0.000 description 6
- 239000003346 palm kernel oil Substances 0.000 description 6
- 235000019865 palm kernel oil Nutrition 0.000 description 6
- 210000004379 membrane Anatomy 0.000 description 5
- 239000002453 shampoo Substances 0.000 description 5
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 239000005639 Lauric acid Substances 0.000 description 4
- 229920002472 Starch Polymers 0.000 description 4
- 239000012459 cleaning agent Substances 0.000 description 4
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 4
- 238000005187 foaming Methods 0.000 description 4
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 4
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 4
- 239000008213 purified water Substances 0.000 description 4
- 235000019698 starch Nutrition 0.000 description 4
- 239000008107 starch Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 241000972773 Aulopiformes Species 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 231100000017 mucous membrane irritation Toxicity 0.000 description 3
- 235000019515 salmon Nutrition 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- 229940058015 1,3-butylene glycol Drugs 0.000 description 2
- GYSCBCSGKXNZRH-UHFFFAOYSA-N 1-benzothiophene-2-carboxamide Chemical compound C1=CC=C2SC(C(=O)N)=CC2=C1 GYSCBCSGKXNZRH-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- 235000021357 Behenic acid Nutrition 0.000 description 2
- 241000238424 Crustacea Species 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N Decanoic acid Natural products CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 2
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 2
- DUKURNFHYQXCJG-UHFFFAOYSA-N Lewis A pentasaccharide Natural products OC1C(O)C(O)C(C)OC1OC1C(OC2C(C(O)C(O)C(CO)O2)O)C(NC(C)=O)C(OC2C(C(OC3C(OC(O)C(O)C3O)CO)OC(CO)C2O)O)OC1CO DUKURNFHYQXCJG-UHFFFAOYSA-N 0.000 description 2
- QZXSMBBFBXPQHI-UHFFFAOYSA-N N-(dodecanoyl)ethanolamine Chemical compound CCCCCCCCCCCC(=O)NCCO QZXSMBBFBXPQHI-UHFFFAOYSA-N 0.000 description 2
- OVRNDRQMDRJTHS-FMDGEEDCSA-N N-acetyl-beta-D-glucosamine Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O OVRNDRQMDRJTHS-FMDGEEDCSA-N 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- 235000021314 Palmitic acid Nutrition 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 2
- 229940116226 behenic acid Drugs 0.000 description 2
- 235000019437 butane-1,3-diol Nutrition 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 239000000306 component Substances 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 229940124274 edetate disodium Drugs 0.000 description 2
- 230000002255 enzymatic effect Effects 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 2
- 229950006780 n-acetylglucosamine Drugs 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 235000021313 oleic acid Nutrition 0.000 description 2
- 210000001672 ovary Anatomy 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 2
- 235000010234 sodium benzoate Nutrition 0.000 description 2
- 239000004299 sodium benzoate Substances 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 230000000638 stimulation Effects 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 2
- 244000144730 Amygdalus persica Species 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- 102000008186 Collagen Human genes 0.000 description 1
- 108010035532 Collagen Proteins 0.000 description 1
- 244000061508 Eriobotrya japonica Species 0.000 description 1
- 235000009008 Eriobotrya japonica Nutrition 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 235000018330 Macadamia integrifolia Nutrition 0.000 description 1
- 240000000912 Macadamia tetraphylla Species 0.000 description 1
- 235000003800 Macadamia tetraphylla Nutrition 0.000 description 1
- 240000002853 Nelumbo nucifera Species 0.000 description 1
- 235000006508 Nelumbo nucifera Nutrition 0.000 description 1
- 235000006510 Nelumbo pentapetala Nutrition 0.000 description 1
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 1
- 235000006040 Prunus persica var persica Nutrition 0.000 description 1
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
- 229920002385 Sodium hyaluronate Polymers 0.000 description 1
- 235000018936 Vitellaria paradoxa Nutrition 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229940110456 cocoa butter Drugs 0.000 description 1
- 235000019868 cocoa butter Nutrition 0.000 description 1
- 229920001436 collagen Polymers 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 229940105990 diglycerin Drugs 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- 229940113120 dipropylene glycol Drugs 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 229960005150 glycerol Drugs 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 210000004400 mucous membrane Anatomy 0.000 description 1
- 239000010466 nut oil Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229910001414 potassium ion Inorganic materials 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 229940010747 sodium hyaluronate Drugs 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- YWIVKILSMZOHHF-QJZPQSOGSA-N sodium;(2s,3s,4s,5r,6r)-6-[(2s,3r,4r,5s,6r)-3-acetamido-2-[(2s,3s,4r,5r,6r)-6-[(2r,3r,4r,5s,6r)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2- Chemical compound [Na+].CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 YWIVKILSMZOHHF-QJZPQSOGSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- PUVAFTRIIUSGLK-UHFFFAOYSA-M trimethyl(oxiran-2-ylmethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CC1CO1 PUVAFTRIIUSGLK-UHFFFAOYSA-M 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
- 239000009538 yokuinin Substances 0.000 description 1
Landscapes
- Cosmetics (AREA)
Description
実施例、比較例の洗浄剤組成物を精製水で十倍に希釈し、パネルメンバー10名の眼にスポイトで一滴滴下し、刺激の有無について官能評価を行った。各洗浄剤組成物の評価基準は下記の通りである。
(評価基準)
◎・・・パネルメンバー8名以上が刺激を感じなかった。
○・・・パネルメンバー6名以上8名未満が刺激を感じなかった。
△・・・パネルメンバー3名以上6名未満が刺激を感じなかった。
×・・・パネルメンバーのうち刺激を感じなかったのが3名未満。
実施例、比較例の洗浄剤組成物を泡吐出容器から吐出させ、泡の状態についてパネルメンバー10名が目視による評価を行った。各洗浄剤組成物の評価基準は下記の通りである。(評価基準)
◎・・・パネルメンバー8名以上が泡は均質であると評価した。
○・・・パネルメンバー6名以上8名未満が泡は均質であると評価した。
△・・・パネルメンバー3名以上6名未満が泡は均質であると評価した。
×・・・パネルメンバーのうち泡は均質であると評価したのが3名未満。
実施例、比較例の洗浄剤組成物を泡吐出容器10個に充填し、泡を1回吐出させた後、そのまま25℃、40%の相対湿度に調節した恒温恒湿室内に2日間放置した。その後、再度吐出操作を行ない、目詰まりを確認した。各洗浄剤組成物の評価基準は下記の通りである。
(評価基準)
◎・・・泡吐出容器8個以上が目詰まりを起こさなかった。
○・・・泡吐出容器6個以上8個未満が目詰まりを起こさなかった。
△・・・泡吐出容器3個以上6個未満が目詰まりを起こさなかった。
×・・・泡吐出容器が目詰まりを起こさなかったのは3個未満。
表1、2に示した処方の洗浄料組成物を調整し、前記各試験を実施した。その結果を表1、2に併せて示す。各成分の配合量の単位は質量%である。
(質量%)
1.スルホコハク酸ポリオキシエチレンラウロイル
エタノールアミド二ナトリウム(5E.O.) 10.0
2.パーム核油脂肪酸アミドプロピルベタイン 5.0
3.ジプロピレングリコール 10.0
4.グリセリン 5.0
5.精製水 20.0
6.塩化グリシジルトリメチルアンモニウム
ヒドロキシエチルセルロース 0.1
7.安息香酸ナトリウム 0.2
8.エデト酸二ナトリウム 0.1
9.ビワ葉抽出液 0.1
10.桃葉抽出液 0.1
11.加水分解サケ卵巣膜抽出液 0.1
12.塩水湖水塩 0.01
13.酵素分解デンプン水素添加物 0.1
14.甲殻類由来アセチルグルコサミン 0.01
15.マカデミアナッツ油脂肪酸フィトステリル 0.01
16.乳酸球菌発酵ヒアルロン酸ナトリウム 0.1
17.鱈浮袋由来水溶性コラーゲン 0.1
18.精製水 残 余
成分5に成分6を加え、分散させながら80℃まで加温、それに成分7、8を加え溶解させた。その後、残りの成分を加え混合分散し、室温まで冷却した。
(質量%)
1.スルホコハク酸ポリオキシエチレンラウロイル
エタノールアミド二ナトリウム(5E.O.) 15.0
2.パーム核油脂肪酸アミドプロピルベタイン 8.0
3.ジプロピレングリコール 10.0
4.1,3−ブチレングリコール 5.0
5.安息香酸ナトリウム 0.2
6.エデト酸二ナトリウム 0.1
7.レモン抽出液 0.1
8.ハス種子乳酸菌発酵液 0.1
9.加水分解サケ卵巣膜抽出液 0.1
10.ヨクイニンエキス 0.1
11.酵素分解デンプン水素添加物 0.1
12.甲殻類由来アセチルグルコサミン 0.1
13.カカオ脂 0.01
14.シア脂 0.01
15.精製水 to100
成分15に成分1〜12を混合分散し、それに成分13、14を加温溶解したものを加え分散させた。
Claims (1)
- 下記成分(A)〜(C)を含有し、かつ成分(A)と成分(B)の配合量合計が洗浄剤組成物総量に対して15質量%以上であり、かつ成分(A)と成分(B)の配合量合計と成分(C)の配合量の比 ((A)+(B))/(C)が1.0以下である、ノンガスタイプ容器内の多孔質膜を通り泡状で吐出されることを特徴とする洗浄剤組成物。
(A)下記一般式(I)で表されるスルホコハク酸ポリオキシエチレン脂肪酸エタノールアミド塩 3〜20質量%
(B)下記一般式(II)で表される脂肪酸アミドプロピルベタイン 1〜10質量%
(C)常温、常圧で液状の多価アルコール 15〜30質量%
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2013214881A JP6190239B2 (ja) | 2013-10-15 | 2013-10-15 | 洗浄剤組成物 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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JP2013214881A JP6190239B2 (ja) | 2013-10-15 | 2013-10-15 | 洗浄剤組成物 |
Publications (2)
Publication Number | Publication Date |
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JP2015078139A JP2015078139A (ja) | 2015-04-23 |
JP6190239B2 true JP6190239B2 (ja) | 2017-08-30 |
Family
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Application Number | Title | Priority Date | Filing Date |
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JP2013214881A Active JP6190239B2 (ja) | 2013-10-15 | 2013-10-15 | 洗浄剤組成物 |
Country Status (1)
Country | Link |
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JP (1) | JP6190239B2 (ja) |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101790368B (zh) * | 2007-08-30 | 2012-04-25 | 狮王株式会社 | 皮肤清洗剂及使用该皮肤清洗剂的皮肤清洗方法 |
JP5680399B2 (ja) * | 2009-12-22 | 2015-03-04 | ライオン株式会社 | 皮膚洗浄料 |
JP5748681B2 (ja) * | 2012-01-31 | 2015-07-15 | 株式会社マンダム | 透明液状洗浄料 |
-
2013
- 2013-10-15 JP JP2013214881A patent/JP6190239B2/ja active Active
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Publication number | Publication date |
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