JP6122633B2 - Hair cosmetics - Google Patents
Hair cosmetics Download PDFInfo
- Publication number
- JP6122633B2 JP6122633B2 JP2012277979A JP2012277979A JP6122633B2 JP 6122633 B2 JP6122633 B2 JP 6122633B2 JP 2012277979 A JP2012277979 A JP 2012277979A JP 2012277979 A JP2012277979 A JP 2012277979A JP 6122633 B2 JP6122633 B2 JP 6122633B2
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- JP
- Japan
- Prior art keywords
- acid
- hair
- hair cosmetic
- weight
- oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000003676 hair preparation Substances 0.000 title description 14
- 210000004209 hair Anatomy 0.000 claims description 99
- 239000000203 mixture Substances 0.000 claims description 61
- 239000002537 cosmetic Substances 0.000 claims description 52
- 239000003921 oil Substances 0.000 claims description 36
- 239000002736 nonionic surfactant Substances 0.000 claims description 32
- -1 polyethylene Polymers 0.000 claims description 31
- 239000002253 acid Substances 0.000 claims description 25
- 102000008186 Collagen Human genes 0.000 claims description 21
- 108010035532 Collagen Proteins 0.000 claims description 21
- 229920001436 collagen Polymers 0.000 claims description 20
- 239000003093 cationic surfactant Substances 0.000 claims description 19
- 229920006317 cationic polymer Polymers 0.000 claims description 18
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 claims description 17
- 239000007788 liquid Substances 0.000 claims description 12
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 11
- 239000004359 castor oil Substances 0.000 claims description 11
- 235000019438 castor oil Nutrition 0.000 claims description 11
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 11
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 10
- 229920001577 copolymer Polymers 0.000 claims description 9
- 235000011837 pasties Nutrition 0.000 claims description 9
- 238000011282 treatment Methods 0.000 claims description 9
- OYINQIKIQCNQOX-UHFFFAOYSA-M 2-hydroxybutyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCC(O)C[N+](C)(C)C OYINQIKIQCNQOX-UHFFFAOYSA-M 0.000 claims description 8
- 244000007835 Cyamopsis tetragonoloba Species 0.000 claims description 8
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 claims description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 7
- 125000005456 glyceride group Chemical group 0.000 claims description 7
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 7
- 229920000642 polymer Polymers 0.000 claims description 7
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 6
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 5
- 235000011187 glycerol Nutrition 0.000 claims description 5
- ASKIVFGGGGIGKH-UHFFFAOYSA-N 2,3-dihydroxypropyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(O)CO ASKIVFGGGGIGKH-UHFFFAOYSA-N 0.000 claims description 4
- 235000021355 Stearic acid Nutrition 0.000 claims description 4
- NCHJGQKLPRTMAO-XWVZOOPGSA-N [(2R)-2-[(2R,3R,4S)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NCHJGQKLPRTMAO-XWVZOOPGSA-N 0.000 claims description 4
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 claims description 4
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 4
- 229940105297 polyglyceryl-2 diisostearate Drugs 0.000 claims description 4
- 239000008117 stearic acid Substances 0.000 claims description 4
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 3
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 claims description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 3
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 claims description 3
- 229920006322 acrylamide copolymer Polymers 0.000 claims description 3
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 3
- 239000001630 malic acid Substances 0.000 claims description 3
- 235000011090 malic acid Nutrition 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- 239000001593 sorbitan monooleate Substances 0.000 claims description 3
- 229940035049 sorbitan monooleate Drugs 0.000 claims description 3
- 235000011069 sorbitan monooleate Nutrition 0.000 claims description 3
- AVBJHQDHVYGQLS-AWEZNQCLSA-N (2s)-2-(dodecanoylamino)pentanedioic acid Chemical compound CCCCCCCCCCCC(=O)N[C@H](C(O)=O)CCC(O)=O AVBJHQDHVYGQLS-AWEZNQCLSA-N 0.000 claims description 2
- QTNHIWWMGWTVJH-VOKNKEOFSA-N (Z)-octadec-9-enoic acid propane-1,2,3-triol Chemical compound OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O QTNHIWWMGWTVJH-VOKNKEOFSA-N 0.000 claims description 2
- JNAYPSWVMNJOPQ-UHFFFAOYSA-N 2,3-bis(16-methylheptadecanoyloxy)propyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCC(C)C)COC(=O)CCCCCCCCCCCCCCC(C)C JNAYPSWVMNJOPQ-UHFFFAOYSA-N 0.000 claims description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 2
- 229920002472 Starch Polymers 0.000 claims description 2
- YIOJGTBNHQAVBO-UHFFFAOYSA-N dimethyl-bis(prop-2-enyl)azanium Chemical compound C=CC[N+](C)(C)CC=C YIOJGTBNHQAVBO-UHFFFAOYSA-N 0.000 claims description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 239000000600 sorbitol Substances 0.000 claims description 2
- 239000008107 starch Substances 0.000 claims description 2
- 235000019698 starch Nutrition 0.000 claims description 2
- DTPCFIHYWYONMD-UHFFFAOYSA-N decaethylene glycol Polymers OCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO DTPCFIHYWYONMD-UHFFFAOYSA-N 0.000 claims 2
- RZRNAYUHWVFMIP-KTKRTIGZSA-N 1-oleoylglycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-KTKRTIGZSA-N 0.000 claims 1
- 229960001777 castor oil Drugs 0.000 claims 1
- RZRNAYUHWVFMIP-HXUWFJFHSA-N glycerol monolinoleate Natural products CCCCCCCCC=CCCCCCCCC(=O)OC[C@H](O)CO RZRNAYUHWVFMIP-HXUWFJFHSA-N 0.000 claims 1
- 229940074096 monoolein Drugs 0.000 claims 1
- 229940098385 triisostearin Drugs 0.000 claims 1
- 235000019198 oils Nutrition 0.000 description 33
- 229920001296 polysiloxane Polymers 0.000 description 29
- 230000000694 effects Effects 0.000 description 17
- 230000000052 comparative effect Effects 0.000 description 10
- 238000000034 method Methods 0.000 description 10
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 8
- 235000014113 dietary fatty acids Nutrition 0.000 description 7
- 239000000194 fatty acid Substances 0.000 description 7
- 229930195729 fatty acid Natural products 0.000 description 7
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 7
- 238000011156 evaluation Methods 0.000 description 6
- 150000004665 fatty acids Chemical class 0.000 description 6
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 6
- 230000001953 sensory effect Effects 0.000 description 6
- 238000001035 drying Methods 0.000 description 5
- 230000007774 longterm Effects 0.000 description 5
- 230000002688 persistence Effects 0.000 description 5
- 238000000926 separation method Methods 0.000 description 5
- 238000013112 stability test Methods 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 239000004264 Petrolatum Substances 0.000 description 4
- 230000005856 abnormality Effects 0.000 description 4
- 239000004205 dimethyl polysiloxane Substances 0.000 description 4
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 229940066842 petrolatum Drugs 0.000 description 4
- 235000019271 petrolatum Nutrition 0.000 description 4
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 3
- WWZKQHOCKIZLMA-UHFFFAOYSA-N Caprylic acid Natural products CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 235000019485 Safflower oil Nutrition 0.000 description 3
- 235000019486 Sunflower oil Nutrition 0.000 description 3
- HGKOWIQVWAQWDS-UHFFFAOYSA-N bis(16-methylheptadecyl) 2-hydroxybutanedioate Chemical compound CC(C)CCCCCCCCCCCCCCCOC(=O)CC(O)C(=O)OCCCCCCCCCCCCCCCC(C)C HGKOWIQVWAQWDS-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 235000019864 coconut oil Nutrition 0.000 description 3
- 239000003240 coconut oil Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000004043 dyeing Methods 0.000 description 3
- 239000000118 hair dye Substances 0.000 description 3
- 239000002932 luster Substances 0.000 description 3
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 3
- 235000005713 safflower oil Nutrition 0.000 description 3
- 239000003813 safflower oil Substances 0.000 description 3
- 235000003441 saturated fatty acids Nutrition 0.000 description 3
- 150000004671 saturated fatty acids Chemical class 0.000 description 3
- 229940032094 squalane Drugs 0.000 description 3
- 239000002600 sunflower oil Substances 0.000 description 3
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 2
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- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 1
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Landscapes
- Cosmetics (AREA)
Description
本発明は、毛髪化粧料、特にヘアコンディショナー、ヘアリンス、又はヘアトリートメントとして用いるのに適した毛髪化粧料に関する。本発明によれば、髪の乾燥後のさらさら感、しなやかさ、艶(ツヤ)、においの持続性、及び地肌の潤いに優れた毛髪化粧料を得ることができる。 The present invention relates to a hair cosmetic, particularly a hair cosmetic suitable for use as a hair conditioner, hair rinse or hair treatment. ADVANTAGE OF THE INVENTION According to this invention, the hair cosmetics excellent in the dry feeling after hair drying, suppleness, luster (luster), the persistence of an odor, and the moisture of the background can be obtained.
毛髪をシャンプー等で洗髪した後には、一般的に、艶や指通りが悪くなるために、リンス、ヘアコンディショナー、トリートメント等の毛髪化粧料が用いられている。
このような毛髪化粧料には、通常、第四級アンモニウム塩型カチオン性界面活性剤が配合されている。第四級アンモニウム塩型カチオン性界面活性剤は、毛髪に対して柔軟性や帯電防止効果を付与する効果を有する。
In general, after the hair is washed with shampoo or the like, the gloss and finger passage are deteriorated, so that hair cosmetics such as rinses, hair conditioners and treatments are used.
Such hair cosmetics usually contain a quaternary ammonium salt type cationic surfactant. The quaternary ammonium salt type cationic surfactant has an effect of imparting flexibility and antistatic effect to the hair.
例えば、特許文献1には第四級アンモニウム塩型カチオン性界面活性剤、3−メチル−1,3−ブタンジオール、及びワセリンを配合し、仕上がり後の毛髪のしっとり感、及び柔らかさに優れた洗い流し用の毛髪化粧料が開示されている。また、特許文献2には、エーテル型カチオン界面活性剤(第四級アンモニウム塩)、及びワセリンを配合し、毛髪の柔軟性、滑らかさ、平滑性、及びしっとり感に優れる毛髪化粧料が開示されている。更に、特許文献3には、多糖類、第三級アミン及び高級アルコールを配合し、まとまり感、及び滑り感を付与することのできる毛髪化粧料が開示されている。また、髪を乾燥させた後のさらさら感を得るために、シリコーン又はシリコーン誘導体を配合させた毛髪化粧料も提案されている(特許文献4)。 For example, Patent Document 1 contains a quaternary ammonium salt type cationic surfactant, 3-methyl-1,3-butanediol, and petrolatum, and is excellent in the moist feeling and softness of the finished hair. A hair cosmetic for rinsing is disclosed. Patent Document 2 discloses a hair cosmetic composition that is blended with an ether type cationic surfactant (quaternary ammonium salt) and petrolatum and is excellent in hair flexibility, smoothness, smoothness, and moist feeling. ing. Further, Patent Document 3 discloses a hair cosmetic that can be blended with a polysaccharide, a tertiary amine, and a higher alcohol to give a sense of unity and a slipperiness. In addition, a hair cosmetic containing silicone or a silicone derivative has been proposed in order to obtain a smooth feeling after the hair is dried (Patent Document 4).
しかしながら、前記の特許文献1及び2に記載の毛髪化粧料は、現在求められているレベルの十分なしっとり感、及びなめらかさが得られているとは言い難い。また、特許文献3に記載の毛髪化粧料は、べたつき及びハリ感が認められ、十分な毛髪の柔軟性は得られない。
従って、使用時における滑らかさ、指通り、及び洗い流しのし易さ、並びに使用後の毛髪のさらさら感、しっとり感、柔らかさ、滑らかさ、艶、及び櫛通り等の優れた、使用性が良い毛髪化粧料が望まれていた。更に、近年は、紫外線の影響、ドライヤーの過熱などにより、毛髪を痛めている人も多く、これらの毛髪に対しても改善効果を有する毛髪化粧料も求められていた。
本発明の目的は、現在の毛髪化粧料における、使用時の感触(滑らかさ、指通り、及び洗い流しのし易さなど)、使用後の仕上がり感(さらさら感、しなやかさ、しっとり感、柔らかさ、滑らかさ、艶、においの持続性、及び櫛通りなど)及び地肌の潤い感が向上した毛髪化粧料を提供することである。
また、染毛料を使用する場合に、シリコーンが毛髪に付着していると毛髪の染まりが悪くなることが知られている。従って、最近はシリコーン及びシリコーン誘導体が含まれていないノンシリコーン毛髪化粧料が開発されている。しかしながら、シリコーンの含まれていない毛髪化粧料は、髪を乾燥させた後のさらさら感が得られない。
従って、本発明の別の目的は、シリコーン又はシリコーン誘導体を含まなくても、乾燥後のさらさら感に優れた毛髪化粧料を提供することである。
However, it is difficult to say that the hair cosmetics described in Patent Documents 1 and 2 have a sufficiently moist feeling and smoothness that are currently required. Further, the hair cosmetic described in Patent Document 3 has stickiness and firmness, and sufficient hair flexibility cannot be obtained.
Therefore, it has excellent usability, such as smoothness during use, easy fingering, and easy washing, as well as smoothness, moistness, softness, smoothness, gloss, and combing of the hair after use. Hair cosmetics were desired. Furthermore, in recent years, there are many people who hurt hair due to the influence of ultraviolet rays, overheating of a dryer, etc., and hair cosmetics having an improvement effect on these hairs have also been demanded.
The object of the present invention is to feel at the time of use (smoothness, easy to pass through, and easy to wash away), finish feeling after use (smoothness, suppleness, moistness, softness) in the present hair cosmetics. , Smoothness, gloss, odor persistence, combing, etc.) and a moisturizing feeling of the background.
Moreover, when using a hair dye, it is known that the hair dye | stain will worsen if silicone has adhered to hair. Therefore, recently, non-silicone hair cosmetics that do not contain silicone and silicone derivatives have been developed. However, hair cosmetics that do not contain silicone do not provide a smooth feeling after the hair has been dried.
Accordingly, another object of the present invention is to provide a hair cosmetic that is excellent in the dry feeling after drying without containing silicone or silicone derivatives.
本発明者は、前記の課題を解決するため、鋭意研究した結果、驚くべきことに、カチオン性界面活性剤、特定の非イオン性界面活性剤、油分成分、及びカチオン性ポリマーを含み、且つカチオン性界面活性剤(a)と非イオン性界面活性剤(b)との重量比(a)/(b)を、2〜45とすることにより、使用時の滑らかさ、指通りの良さ、及び洗い流しのし易さ、並びに使用後の毛髪のさらさら感、しなやかさ、しっとり感、柔らかさ、滑らかさ、艶、においの持続性、地肌の潤い、及び櫛通りに優れた毛髪化粧料を得ることができることを見出した。特に、本発明は、前記の特徴を有することにより、使用後の毛髪のさらさら感、しなやかさ、においの持続性が優れ、髪に優れた艶(ツヤ)を与え、更には地肌に潤いを与えることができるものである。
本発明は、こうした知見に基づくものである。
従って、本発明は、
[1](a)カチオン性界面活性剤を1〜10重量%、(b)HLB値が7以下であり、且つ常温で液状又はペースト状の非イオン性界面活性剤を0.1〜5重量%、(c)油性成分を1〜20重量%、及び(d)カチオン性ポリマーを0.1〜5重量%を含み、成分(a)及び(b)の重量比(a)/(b)の値が2〜45であることを特徴とする毛髪化粧料、
[2]非イオン界面活性剤が、ジポリヒドロキシステアリン酸ポリエチレングリコール−30、セスキイソステアリン酸ソルビタン、ジイソステアリン酸ポリグリセリル−2、モノイソステアリン酸グリセリド、ポリオキシエチレン(7)硬化ヒマシ油、モノオレイン酸ソルビタン、トリイソステアリン酸ポリオキシエチレン(10)グリセリン、トリイソステアリン酸ポリオキシエチレン(10)硬化ヒマシ油、ラウロイルグルタミン酸ポリオキシエチレン(2)オクチルドデシルエーテルジエステル、ジイソステアリン酸グリセリド,ジオレイン酸グリセリド、モノイソステアリン酸ソルビタン、モノオレイン酸プロピレングリコール、ペンタオレイン酸デカグリセリン、デカオレイン酸デカグリセリン、(ステアリン酸/リンゴ酸)グリセリド、及びイソステアリン酸ポリオキシエチレン(3)ソルビットからなる群から選択される1つ以上の非イオン性界面活性剤である、[1]に記載の毛髪化粧料、
[3]アシル化加水分解コラーゲンを、更に含む[1]又は[2]に記載の毛髪化粧料、
[4]前記油性成分が、1000mPa・s/25℃以上の高粘性油分を含む、[1]〜[3]のいずれかに記載の毛髪化粧料、
[5]前記カチオン性ポリマーが、塩化ヒドロキシエチルセルロースジメチルジアリルアンモニウム、塩化O−[2−ヒドロキシ−3−(トリメチルアンモニオ)プロピル]ヒドロキシエチルセルロース、グアーヒドロキシプロピルトリモニウムクロリド、ヒドロキシプロピルグアーヒドロキシプロピルトリモニウムクロリド、塩化ヒドロキシプロピルトリモニウムデンプン、ジメチルジアリルアンモニウム・アクリルアミド共重合体、ビニルピロリドン・メチルビニルイミダゾリウム共重合体、アクリルアミド・アクリル酸・塩化ジメチルジアリルアンモニウム共重合体;ポリ塩化ジメチルメチレンピペリジニウムからなる群から選択される少なくとも1つ以上のカチオン化ポリマーである、[1]〜[4]のいずれかに記載の毛髪化粧料、及び
[6]毛髪化粧料がリンス、コンディショナー、又はトリートメントである、[1]〜[5]のいずれかに記載の毛髪化粧料、
に関する。
As a result of intensive studies to solve the above problems, the present inventor surprisingly includes a cationic surfactant, a specific nonionic surfactant, an oil component, and a cationic polymer. By setting the weight ratio (a) / (b) of the surfactant (a) to the nonionic surfactant (b) to 2 to 45, smoothness during use, good fingering, and Easily rinse away, and after use, the hair feels smooth, supple, moist, soft, smooth, glossy, odor persistence, moisturizing the skin, and a hair cosmetic that is excellent in combing. I found out that I can. In particular, the present invention has the above-mentioned characteristics, so that the hair feels smooth, supple, and smelly after use, gives the hair an excellent luster, and further moisturizes the background. It is something that can be done.
The present invention is based on these findings.
Therefore, the present invention
[1] (a) 1 to 10% by weight of a cationic surfactant, (b) 0.1 to 5% by weight of a nonionic surfactant that is HLB value of 7 or less and is liquid or pasty at room temperature %, (C) 1 to 20% by weight of oil component, and (d) 0.1 to 5% by weight of cationic polymer, the weight ratio of components (a) and (b) (a) / (b) Hair cosmetics characterized by a value of 2 to 45,
[2] The nonionic surfactant is polyethylene glycol-30 dipolyhydroxystearate, sorbitan sesquiisostearate, polyglyceryl-2 diisostearate, glyceryl monoisostearate, polyoxyethylene (7) hydrogenated castor oil, sorbitan monooleate , Polyisoethylene stearate (10) glycerin, polyoxyethylene triisostearate (10) hydrogenated castor oil, polyoxyethylene lauroyl glutamate (2) octyldodecyl ether diester, glyceryl diisostearate, glyceride dioleate, sorbitan monoisostearate , Propylene glycol monooleate, decaglycerin pentaoleate, decaglycerin dekaoleate, (stearic acid / malic acid) g Ceilidh, and isostearic acid polyoxyethylene (3) is one or more non-ionic surfactant selected from the group consisting of sorbitol, hair cosmetic according to [1],
[3] The hair cosmetic composition according to [1] or [2], further comprising acylated hydrolyzed collagen,
[4] The hair cosmetic composition according to any one of [1] to [3], wherein the oil component contains a high-viscosity oil component of 1000 mPa · s / 25 ° C. or higher.
[5] The cationic polymer is hydroxyethyl cellulose dimethyl diallylammonium chloride, O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethyl cellulose, guar hydroxypropyltrimonium chloride, hydroxypropyl guar hydroxypropyltrimonium. Chloride, hydroxypropyltrimonium chloride starch, dimethyldiallylammonium / acrylamide copolymer, vinylpyrrolidone / methylvinylimidazolium copolymer, acrylamide / acrylic acid / dimethyldiallylammonium chloride copolymer; polydimethylmethylenepiperidinium The hair cosmetic composition according to any one of [1] to [4], which is at least one cationized polymer selected from the group consisting of: Beauty [6] The hair cosmetic composition is a rinse, conditioner, or treatments, [1] The hair cosmetic composition according to any one of to [5],
About.
本発明の毛髪化粧料によれば、特に使用後の毛髪のさらさら感、及びしなやかさが優れているものである。また、本発明の毛髪化粧料によれば、髪に優れた艶(ツヤ)を与えることが可能であり、においの持続性に優れ、更に地肌に優れた潤いを与えることが可能である。また、健常な毛髪ばかりでなく、痛んだ毛髪にも十分な使用満足感を与えることができる。 According to the hair cosmetic composition of the present invention, the smoothness and suppleness of the hair after use are particularly excellent. Moreover, according to the hair cosmetic composition of the present invention, it is possible to give the hair an excellent gloss, excellent odor persistence, and an excellent moisture to the background. Moreover, sufficient use satisfaction can be given not only to healthy hair but also to damaged hair.
また前記のように、染毛料を使用する場合、シリコーンが毛髪に付着していると毛髪の染まりが悪くなる。従って、髪を染色する場合、シリコーンやシリコーン誘導体が含まれていないノンシリコーン毛髪化粧料を使用する人も増えてきている。本発明の毛髪化粧料によれば、シリコーン及びシリコーン誘導体を含まないでも、乾燥後のさらさら感に優れた毛髪化粧料を提供することができる。 In addition, as described above, when a hair dye is used, hair dyeing becomes worse if silicone is attached to the hair. Therefore, when dyeing hair, an increasing number of people use non-silicone hair cosmetics that do not contain silicone or silicone derivatives. According to the hair cosmetic composition of the present invention, it is possible to provide a hair cosmetic composition that is excellent in the dry feeling after drying without containing silicone and silicone derivatives.
本発明の毛髪化粧料は、(a)カチオン性界面活性剤を1〜10重量%、(b)HLB値が7以下であり、且つ常温で液状又はペースト状の非イオン性界面活性剤を0.1〜5重量%、(c)油性成分を1〜20重量%、及び(d)カチオン性ポリマーを0.1〜5重量%を含み、成分(a)及び(b)の重量比(a)/(b)の値が2〜45である。 The hair cosmetic composition of the present invention has (a) 1-10% by weight of a cationic surfactant, (b) an HLB value of 7 or less, and 0% of a liquid or pasty nonionic surfactant at room temperature. 0.1 to 5% by weight, (c) 1 to 20% by weight of oil component, and (d) 0.1 to 5% by weight of cationic polymer, the weight ratio of components (a) and (b) (a ) / (B) is 2 to 45.
《カチオン性界面活性剤:成分(a)》
本発明の毛髪化粧料は、カチオン性界面活性剤を1〜10重量%含む。カチオン性界面活性剤は、毛髪の柔軟性を維持する効果、及び帯電防止性を付与する効果を有している。更に、カチオン性界面活性剤は、毛髪化粧料の乳化状態を維持する効果も有している。
<< Cationic surfactant: Component (a) >>
The hair cosmetic composition of the present invention contains 1 to 10% by weight of a cationic surfactant. Cationic surfactants have the effect of maintaining the flexibility of the hair and the effect of imparting antistatic properties. Furthermore, the cationic surfactant has an effect of maintaining the emulsified state of the hair cosmetic.
本発明の毛髪化粧料に含まれるカチオン性界面活性剤は、特に限定されるものではないが、例えば、脂肪酸アミドアミン塩、モノアルキル型4級アンモニウム塩、ジアルキル型4級アンモニウム塩、ベンザルコニウム型4級アンモニウム、及びエチル硫酸ラノリン脂肪酸アミノプロピルエチルジメチルアンモニウムを挙げることができる。脂肪酸アミドアミン塩としては、例えば、ベヘナミドプロピルジメチルアミン、ステアリン酸ジエチルアミノエチルアミド、ステアリン酸ジメチルアミノプロピルアミドを挙げることができる。モノアルキル型4級アンモニウム塩としては、例えば、塩化ラウリルトリメチルアンモニウム、塩化セチルトリメチルアンモニウム(セトリモニウムクロリド)、塩化ステアリルトリメチルアンモニウム、塩化ベヘニルトリメチルアンモニウム、臭化ラウリルトリメチルアンモニウム、臭化セチルトリメチルアンモニウム、及び臭化ステアリルトリメチルアンモニウム、塩化アルキルトリメチルアンモニウム(ベヘントリモニウムクロリド)、塩を挙げることができる。ジアルキル型4級アンモニウム塩としては、例えば、塩化ジステアリルジメチルアンモニウム、塩化ジココイルジメチルアンモニウム、及び塩化ジセチルジメチルアンモニウムを挙げることができる。ベンザルコニウム型4級アンモニウムとしては、例えば、塩化ベンザルコニウム、及び塩化ステアリルジメチルベンジルアンモニウムを挙げることができる。本発明の毛髪化粧料は、これらの1種又は2種以上のカチオン性界面活性剤を含むことができる。 The cationic surfactant contained in the hair cosmetic composition of the present invention is not particularly limited, and examples thereof include fatty acid amidoamine salts, monoalkyl quaternary ammonium salts, dialkyl quaternary ammonium salts, and benzalkonium types. Mention may be made of quaternary ammonium and ethyl lanolin sulfate fatty acid aminopropylethyldimethylammonium. Examples of fatty acid amidoamine salts include behenamidopropyl dimethylamine, stearic acid diethylaminoethylamide, and stearic acid dimethylaminopropylamide. Examples of monoalkyl quaternary ammonium salts include lauryl trimethyl ammonium chloride, cetyl trimethyl ammonium chloride (cetrimonium chloride), stearyl trimethyl ammonium chloride, behenyl trimethyl ammonium chloride, lauryl trimethyl ammonium bromide, cetyl trimethyl ammonium bromide, and Examples include stearyltrimethylammonium bromide, alkyltrimethylammonium chloride (behentrimonium chloride), and salts. Examples of the dialkyl type quaternary ammonium salt include distearyldimethylammonium chloride, dicocoyldimethylammonium chloride, and dicetyldimethylammonium chloride. Examples of the benzalkonium-type quaternary ammonium include benzalkonium chloride and stearyldimethylbenzylammonium chloride. The hair cosmetic composition of the present invention can contain one or more of these cationic surfactants.
本発明の毛髪化粧料に含まれるカチオン性界面活性剤の含有量は、1〜10重量%であれば特に限定されるものではないが、好ましくは1〜8重量%であり、より好ましくは2〜6重量%であり、最も好ましくは2.5〜5.5重量%である。カチオン性界面活性剤の含有量が1%未満であると毛髪をやわらかく、かつ、しなやかにする効果が得られないことがあり、含有量が10%を超えると皮膚安全性面で好ましくない。 The content of the cationic surfactant contained in the hair cosmetic composition of the present invention is not particularly limited as long as it is 1 to 10% by weight, preferably 1 to 8% by weight, and more preferably 2%. -6% by weight, most preferably 2.5-5.5% by weight. If the content of the cationic surfactant is less than 1%, the effect of softening and suppleening the hair may not be obtained, and if the content exceeds 10%, it is not preferable in terms of skin safety.
《非イオン性界面活性剤:成分(b)》
本発明の毛髪化粧料はHLB値が7以下であり、且つ常温で液状又はペースト状の非イオン性界面活性剤を0.1〜5重量%含む。
<< Nonionic Surfactant: Component (b) >>
The hair cosmetic composition of the present invention has an HLB value of 7 or less and contains 0.1 to 5% by weight of a nonionic surfactant that is liquid or pasty at room temperature.
本発明の毛髪化粧料に用いる非イオン界面活性剤は、常温で液状又はペースト状である。本明細書において、液状とは液体の状態のものを意味し、ペースト状とは流動性のある半固形の状態を意味する。また、本明細書において「常温」とは、20℃±5℃を意味する。従って、常温で液状又はペースト状の非イオン性界面活性剤とは、15℃〜25℃において、液体の状態又は流動性のある半固形の状態の非イオン性界面活性剤である。本発明に用いる非イオン性界面活性剤の融点は、15℃以上、又は15℃近辺にあるものが多いと考えられる。常温で液状又はペースト状であることによって、毛髪の感触が良く、特に、毛髪に艶を与える効果に優れている。また、このような効果は、シリコーンを含まない場合に顕著に現れる。 The nonionic surfactant used for the hair cosmetic composition of the present invention is liquid or pasty at normal temperature. In this specification, liquid means a liquid state, and paste means a fluid semi-solid state. In the present specification, “normal temperature” means 20 ° C. ± 5 ° C. Accordingly, the nonionic surfactant that is liquid or pasty at room temperature is a nonionic surfactant in a liquid state or a fluid semisolid state at 15 ° C to 25 ° C. It is considered that many nonionic surfactants used in the present invention have a melting point of 15 ° C. or more or around 15 ° C. By being liquid or pasty at normal temperature, the hair feels good, and in particular, it has an excellent effect of glossing the hair. Moreover, such an effect appears notably when silicone is not included.
本発明の毛髪化粧料に用いる非イオン性界面活性剤のHLBは7以下であれば限定されるものではない。HLBが7を超えると髪のさらさら感やしなやかさが得られないことがある。一方、HLBが7以下であることにより、髪のさらさら感やしなやかさが得られるが、特にシリコーンを含まない場合にこのような効果が顕著である。
非イオン性界面活性剤のHLBの計算方法としては、グリフィン法、ディビス法、アトラス法、又は川上法などがあるが、本明細書におけるHLBはグリフィン法により計算されてものを用いる。グリフィン法によるHLBは以下の式によって、計算することができる。
HLB=20×(親水部分の分子量/全体の分子量)
グリフィン法以外に、標準試料にHLBを決定したい非イオン性界面活性剤を添加して、乳化し実験的に決定する方法を用いてもよい。
The HLB of the nonionic surfactant used in the hair cosmetic composition of the present invention is not limited as long as it is 7 or less. If the HLB exceeds 7, the hair may not be smooth and supple. On the other hand, when the HLB is 7 or less, a smooth and supple feel of hair can be obtained, but such an effect is particularly remarkable when silicone is not included.
As a method for calculating the HLB of the nonionic surfactant, there are the Griffin method, the Divis method, the Atlas method, the Kawakami method, and the like. The HLB in this specification is calculated by the Griffin method. The HLB by the Griffin method can be calculated by the following equation.
HLB = 20 × (molecular weight of hydrophilic portion / total molecular weight)
In addition to the Griffin method, a method may be used in which a nonionic surfactant whose HLB is to be determined is added to a standard sample, emulsified and experimentally determined.
本発明の毛髪化粧料に用いる非イオン性界面活性剤は、前記の物性を有する限り限定されるものではないが、例えば、セスキイソステアリン酸ソルビタン(HLB:4.0)、ジポリヒドロキシステアリン酸PEG−30(HLB:5.5)、ジイソステアリン酸ポリグリセリル−2(HLB:4.1)、モノイソステアリン酸グリセリド(HLB:4.0)、POE(7)硬化ヒマシ油(HLB:5.9)、モノオレイン酸ソルビタン(HLB:4.3)、トリイソステアリン酸POE(10)グリセリン(HLB:5.1)、トリイソステアリン酸POE(10)硬化ヒマシ油(HLB:3.6)、ラウロイルグルタミン酸POE(2)オクチルドデシルエーテルジエステル(HLB:4.0)、ジイソステアリン酸グリセリド,ジオレイン酸グリセリド、モノイソステアリン酸ソルビタン、モノオレイン酸プロピレングリコール、ジイソステアリンジグリセリン、ペンタオレイン酸デカグリセリン、デカオレイン酸デカグリセリン、(ステアリン酸/リンゴ酸)グリセリド、イソステアリン酸POE(3)ソルビットを挙げることができる。特には、ジポリヒドロキシステアリン酸PEG−30、モノイソステアリン酸ソルビタン、セスキイソステアリン酸ソルビタン、及びジイソステアリン酸ポリグリセリル−2が好ましい。 The nonionic surfactant used in the hair cosmetic composition of the present invention is not limited as long as it has the above-mentioned physical properties. For example, sorbitan sesquiisostearate (HLB: 4.0), PEG dipolyhydroxystearate -30 (HLB: 5.5), polyglyceryl-2 diisostearate (HLB: 4.1), monoisostearic acid glyceride (HLB: 4.0), POE (7) hydrogenated castor oil (HLB: 5.9), Sorbitan monooleate (HLB: 4.3), triisostearic acid POE (10) glycerin (HLB: 5.1), triisostearic acid POE (10) hydrogenated castor oil (HLB: 3.6), lauroyl glutamic acid POE ( 2) Octyldodecyl ether diester (HLB: 4.0), diisostearic acid glyceride, dioleo Examples include acid glyceride, sorbitan monoisostearate, propylene glycol monooleate, diisostearate diglycerin, pentaoleic acid decaglycerin, dekaoleic acid decaglycerin, (stearic acid / malic acid) glyceride, and isostearic acid POE (3) sorbit. it can. In particular, PEG-30 dipolyhydroxystearate, sorbitan monoisostearate, sorbitan sesquiisostearate, and polyglyceryl-2 diisostearate are preferred.
本発明の毛髪化粧料に含まれる非イオン性界面活性剤の含有量は、0.1〜5重量%であれば特に限定されるものではないが、好ましくは0.1〜4.5重量%であり、より好ましくは0.1〜4重量%であり、最も好ましくは0.1〜3.5重量%である。非イオン性界面活性剤の含有量が0.1%未満であるとさらさら感やしなやかさが得られないことがあり、含有量が5%を超えると油性成分が分離し、安定性の問題が生じることがある。 The content of the nonionic surfactant contained in the hair cosmetic composition of the present invention is not particularly limited as long as it is 0.1 to 5% by weight, preferably 0.1 to 4.5% by weight. More preferably, it is 0.1 to 4% by weight, and most preferably 0.1 to 3.5% by weight. If the content of the nonionic surfactant is less than 0.1%, a smooth feeling or suppleness may not be obtained. If the content exceeds 5%, the oily component is separated, which causes a problem of stability. May occur.
《成分(a)と成分(b)の比》
本発明の毛髪化粧料におけるカチオン性界面活性剤(成分(a))と、非イオン性界面活性剤(成分(b))との重量比(a)/(b)は、2〜45である限りにおいて限定されないが、より好ましくは2〜43である。(a)/(b)の重量比が2〜45であることによって、使用後の毛髪のさらさら感に優れ、髪に優れた艶(ツヤ)を与えることができる。
<< Ratio of component (a) to component (b) >>
The weight ratio (a) / (b) between the cationic surfactant (component (a)) and the nonionic surfactant (component (b)) in the hair cosmetic composition of the present invention is 2 to 45. Although it does not limit in limitation, More preferably, it is 2-43. When the weight ratio of (a) / (b) is 2 to 45, the hair has a smooth feeling after use, and the hair can be given a gloss (shine).
《油性成分:成分(c)》
本発明の毛髪化粧料は、油性成分を1〜20重量%含む。前記油性成分は、特に限定されるものではなく、エステル油、炭化水素油、動植物油、脂肪族アルコール、高級脂肪酸、シリコーン又はシリコーン誘導体を挙げることができる。本発明の毛髪化粧料は、これらの油性成分に含まれるものを1種又は2種以上混合して用いることができる。
<< Oil component: Component (c) >>
The hair cosmetic composition of the present invention contains 1 to 20% by weight of an oily component. The oil component is not particularly limited, and examples thereof include ester oils, hydrocarbon oils, animal and vegetable oils, aliphatic alcohols, higher fatty acids, silicones, and silicone derivatives. The hair cosmetic composition of the present invention can be used alone or in combination of two or more of those oily ingredients.
前記エステル油としては、例えばミリスチン酸イソプロピル、ミリスチン酸ブチル、パルミチン酸イソプロピル、ステアリン酸ブチル、ステアリン酸エチル、オレイン酸エチル、リノール酸エチル、リノール酸イソプロピル、カプリル酸セチル、ラウリン酸ヘキシル、ミリスチン酸デシル、ミリスチン酸ミリスチル、ミリスチン酸セチル、パルミチン酸セチル、ステアリン酸ステアリル、オレイン酸デシル、オレイン酸オレイル、リシノール酸セチル、ラウリン酸イソステアリル、ミリスチン酸イソトリデシル、ミリスチン酸2−ヘキシルデシル、ミリスチン酸イソステアリル、ミリスチン酸2−オクチルドデシル、パルミチン酸2−エチルヘキシル、パルミチン酸2−ヘキシルデシル、パルミチン酸イソステアリル、ステアリン酸2−エチルヘキシル、ステアリン酸2−ヘキシルデシル、オレイン酸イソデシル、オレイン酸2−オクチルドデシル、リシノール酸2−オクチルドデシル、イソステアリン酸エチル、イソステアリン酸イソプロピル、2−エチルヘキサン酸セチル、2−エチルヘキサン酸セトステアリル、2−エチルヘキサン酸ステアリル、イソステアリン酸ヘキシル、ジ2−エチルヘキサン酸エチレングリコール、ジオレイン酸エチレングリコール、ジカプリル酸プロピレングリコール、ジ(カプリル・カプリン酸)プロピレングリコール、ジカプリン酸プロピレングリコール、ジオレイン酸プロピレングリコール、ジカプリン酸ネオペンチルグリコール、ジ2−エチルヘキサン酸ネオペンチルグリコール、トリカプリル酸グリセリル、トリ2−エチルヘキサン酸グリセリル、トリ(カプリル・カプリン酸)グリセリル、トリウンデシル酸グリセリル、トリイソパルミチン酸グリセリル、トリイソステアリン酸グリセリル、トリ2−エチルヘキサン酸トリメチロールプロパン、トリイソステアリン酸トリメチロールプロパン、テトラ2−エチルヘキサン酸ペンタエリスリトール、テトラミリスチン酸ペンタエリスリトール、テトライソステアリン酸ペンタエリスリトール、ジペンタエリトリット脂肪酸エステル(1)、ネオペンタン酸2−オクチルドデシル、2−エチルヘキサン酸2−ヘキシルデシル、2−エチルヘキサン酸イソステアリル、イソノナン酸2−エチルヘキシル、ジメチルオクタン酸2−ヘキシルデシル、ジメチルオクタン酸2−オクチルドデシル、イソパルミチン酸2−エチルヘキシル、イソステアリン酸2−ヘキシルデシル、イソステアリン酸イソステアリル、イソステアリン酸2−オクチルドデシル、乳酸ラウリル、乳酸ミリスチル、乳酸セチル、乳酸2−オクチルドデシル、クエン酸トリエチル、クエン酸アセチルトリエチル、クエン酸アセチルトリブチル、クエン酸トリ2−エチルヘキシル、クエン酸トリイソセチル、クエン酸トリ2−オクチルドデシル、リンゴ酸ジイソステアリル、ヒドロキシステアリン酸2−エチルヘキシル、コハク酸ジ2−エチルヘキシル、アジピン酸ジイソプロピル、アジピン酸ジイソブチル、アジピン酸ジ2−エチルヘキシル、セバシン酸ジエチル、セバシン酸ジイソプロピル、セバシン酸ジ2−エチルヘキシル、セバシン酸ジブチルオクチル、ステアリン酸コレステリル、イソステアリン酸コレステリル、ヒドロキシステアリン酸コレステリル、オレイン酸コレステリル、オレイン酸ジヒドロコレステリル、イソステアリン酸フィトステリル、オレイン酸フィトステリル、12−ステアロイルヒドロキシステアリン酸イソセチル、12−ステアロイルヒドロキシステアリン酸ステアリル、又は12−ステアロイルヒドロキシステアリン酸イソステアリル、等を挙げることができる。 Examples of the ester oil include isopropyl myristate, butyl myristate, isopropyl palmitate, butyl stearate, ethyl stearate, ethyl oleate, ethyl linoleate, isopropyl linoleate, cetyl caprylate, hexyl laurate, decyl myristate. , Myristyl myristate, cetyl myristate, cetyl palmitate, stearyl stearate, decyl oleate, oleyl oleate, cetyl ricinoleate, isostearyl laurate, isotridecyl myristate, 2-hexyldecyl myristate, isostearyl myristate, 2-octyldodecyl myristate, 2-ethylhexyl palmitate, 2-hexyldecyl palmitate, isostearyl palmitate, 2-ethyl stearate Hexyl, 2-hexyldecyl stearate, isodecyl oleate, 2-octyldodecyl oleate, 2-octyldodecyl ricinoleate, ethyl isostearate, isopropyl isostearate, cetyl 2-ethylhexanoate, cetostearyl 2-ethylhexanoate, Stearyl 2-ethylhexanoate, hexyl isostearate, ethylene glycol di-2-ethylhexanoate, ethylene glycol dioleate, propylene glycol dicaprylate, propylene glycol di (capryl / capric acid), propylene glycol dicaprate, propylene glycol dioleate, Neopentyl glycol dicaprate, neopentyl glycol di-2-ethylhexanoate, glyceryl tricaprylate, tri-2-ethylhexanoic acid Seryl, tri (caprylic / capric) glyceryl, glyceryl triundecylate, glyceryl triisopalmitate, glyceryl triisostearate, tri-2-ethylhexanoic acid trimethylolpropane, triisostearic acid trimethylolpropane, tetra-2-ethylhexanoic acid penta Erythritol, pentaerythritol tetramyristate, pentaerythritol tetraisostearate, dipentaerythritol fatty acid ester (1), 2-octyldodecyl neopentanoate, 2-hexyldecyl 2-ethylhexanoate, isostearyl 2-ethylhexanoate, isononane 2-ethylhexyl acid, 2-hexyldecyl dimethyloctanoate, 2-octyldecyl dimethyloctanoate, 2-ethylhexyl isopalmitate, 2-hexyldecyl sostearate, isostearyl isostearate, 2-octyldodecyl isostearate, lauryl lactate, myristyl lactate, cetyl lactate, 2-octyl dodecyl lactate, triethyl citrate, acetyl triethyl citrate, acetyl tributyl citrate, citrate Tri-2-ethylhexyl acid, triisocetyl citrate, tri-2-octyldodecyl citrate, diisostearyl malate, 2-ethylhexyl hydroxystearate, di-2-ethylhexyl succinate, diisopropyl adipate, diisobutyl adipate, di2 adipate -Ethylhexyl, diethyl sebacate, diisopropyl sebacate, di-2-ethylhexyl sebacate, dibutyloctyl sebacate, cholesteryl stearate, isostearic acid Lesteryl, cholesteryl hydroxystearate, cholesteryl oleate, dihydrocholesteryl oleate, phytosteryl isostearate, phytosteryl oleate, isocetyl 12-stearoylhydroxystearate, stearyl 12-stearoylhydroxystearate, or isostearyl 12-stearoylhydroxystearate Etc.
前記炭化水素油としては、オゾケライト、α−オレフィンオリゴマー、軽質イソパラフィン、軽質流動イソパラフィン、合成スクワラン、植物性スクワラン、スクワラン、セレシン、パラフィン、ポリエチレン末、ポリブテン、流動イソパラフィン、流動パラフィン、スクワレン、プリスタン、ワセリン、又はマイクロクリスタリンワックスを挙げることができる。 Examples of the hydrocarbon oil include ozokerite, α-olefin oligomer, light isoparaffin, light liquid isoparaffin, synthetic squalane, vegetable squalane, squalane, ceresin, paraffin, polyethylene powder, polybutene, liquid isoparaffin, liquid paraffin, squalene, pristane, petrolatum. Or microcrystalline waxes.
前記動植物油としては、例えばアボガド油、トウモロコシ油、月見草油、パーシック油、サザンカ油、ヒマシ油、サフラワー油、シナモン油、アーモンド油、大豆油、大豆胚芽油、菜種油、高オレイン酸菜種油、コーン油、ゴマ油、シソ油、亜麻仁油、落花生油、紅花油、高オレイン酸紅花油、ひまわり油、ミッドオレイックひまわり油、高オレイン酸ひまわり油、綿実油、ブドウ種子油、マカデミアナッツ油、ヘーゼルナッツ油、カボチャ種子油、クルミ油、椿油、茶実油、エゴマ油、ボラージ油、オリーブ油、米糠油、小麦胚芽油、パーム油、パーム核油、ヤシ油、カカオ脂、卵黄油、ミンク油、牛脂、豚脂、ラード、鶏脂、乳脂、魚油、アザラシ油、及び藻類油、並びにそれらの分別油、硬化油、及びエステル交換油を挙げることができる。 Examples of the animal and vegetable oils include avocado oil, corn oil, evening primrose oil, persic oil, sasanqua oil, castor oil, safflower oil, cinnamon oil, almond oil, soybean oil, soybean germ oil, rapeseed oil, oleic rapeseed oil, corn Oil, sesame oil, perilla oil, flaxseed oil, peanut oil, safflower oil, high oleic safflower oil, sunflower oil, mid oleic sunflower oil, high oleic sunflower oil, cottonseed oil, grape seed oil, macadamia nut oil, hazelnut oil, pumpkin Seed oil, walnut oil, coconut oil, tea seed oil, sesame oil, borage oil, olive oil, rice bran oil, wheat germ oil, palm oil, palm kernel oil, coconut oil, cocoa butter, egg yolk oil, mink oil, beef tallow , Lard, chicken fat, milk fat, fish oil, seal oil, and algal oil, and fractionated oils, hydrogenated oils, and transesterified oils thereof. That.
前記脂肪族アルコールとしては、直鎖状の飽和アルコール(例えば、ラウリルアルコール、ミリスチルアルコール、セチルアルコール、ステアリルアルコール、又はベヘニルアルコール)、分岐状の飽和アルコール(例えば、イソステアリルアルコール、又はオクチルドデカノール)、又は不飽和アルコール(例えば、オレイルアルコール)などの炭素数が12〜22のアルコール(いわゆる高級アルコール)を挙げることができる。 Examples of the aliphatic alcohol include linear saturated alcohols (for example, lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, or behenyl alcohol), branched saturated alcohols (for example, isostearyl alcohol, or octyldodecanol), Alternatively, an alcohol having 12 to 22 carbon atoms (a so-called higher alcohol) such as an unsaturated alcohol (for example, oleyl alcohol) can be used.
前記高級脂肪酸としては、直鎖状の飽和脂肪酸(例えば、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ベヘニン酸、12−ヒドロキシステアリン酸)、分岐状の飽和脂肪酸(例えば、イソステアリン酸)、不飽和脂肪酸(例えば、オレイン酸、リノール酸、リノレイン酸、ウンデシレン酸、エイコサペンタエン酸、ドコサヘキサエン酸)、トール酸、ラノリン酸などを挙げることができる。 Examples of the higher fatty acids include linear saturated fatty acids (for example, lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, 12-hydroxystearic acid), branched saturated fatty acids (for example, isostearic acid), Saturated fatty acids (for example, oleic acid, linoleic acid, linolenic acid, undecylenic acid, eicosapentaenoic acid, docosahexaenoic acid), tolic acid, lanolinic acid and the like can be mentioned.
前記油性成分の含有量は、1〜20重量%である限り、特に限定されるものではないが、好ましくは2〜18重量%であり、より好ましくは3〜15重量%であり、最も好ましくは4〜12重量%である。油性成分の含有量が1%未満であると毛髪に艶を与える効果が十分でなく、地肌の潤いが得られないことがある。また、含有量が20%を超えるとべたつき感を感じることがある。 The content of the oil component is not particularly limited as long as it is 1 to 20% by weight, but is preferably 2 to 18% by weight, more preferably 3 to 15% by weight, and most preferably 4 to 12% by weight. When the content of the oil component is less than 1%, the effect of glossing the hair is not sufficient, and the moisture of the background may not be obtained. Moreover, when content exceeds 20%, a sticky feeling may be felt.
前記シリコーン又はシリコーン誘導体としては、メチルポリシロキサン、ジメチルシロキサン、ジメチルポリシロキサン、メチルフェニルポリシロキサン、メチルハイドロジェンポリシロキサン、メチルアミノプロピルシロキサン、アミノエチルアミノプロピルメチルシロキサン、シリコーンゴム、オクタメチルトリシロキサン、デカメチルテトラシロキサン、ドデカメチルポリシロキサン、高重合メチルポリシロキサン、オクタメチルシクロテトラシロキサン、デカメチルシクロペンタシロキサン、デカメチルポリシロキサン、又はメチル(アミノプロピル)シロキサンを挙げることができる。シリコーン又はシリコーン誘導体を含むことによって、髪を乾燥させた後のさらさら感を得ることができる。しかしながら、本発明の毛髪化粧料においては、シリコーン又はシリコーン誘導体を含まない場合でも、十分な乾燥後のさらさら感を得ることができる。この本発明の効果は、限定されるわけではないが、特にはHLB値が7以下であり、且つ常温で液状又はペースト状の非イオン性界面活性剤を0.1〜5重量%含み、そしてカチオン性ポリマーを0.1〜5重量%含むことによって得ることができると考えられる。 Examples of the silicone or silicone derivative include methylpolysiloxane, dimethylsiloxane, dimethylpolysiloxane, methylphenylpolysiloxane, methylhydrogenpolysiloxane, methylaminopropylsiloxane, aminoethylaminopropylmethylsiloxane, silicone rubber, octamethyltrisiloxane, Mention may be made of decamethyltetrasiloxane, dodecamethylpolysiloxane, highly polymerized methylpolysiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, decamethylpolysiloxane, or methyl (aminopropyl) siloxane. By including the silicone or the silicone derivative, it is possible to obtain a dry feeling after the hair is dried. However, in the hair cosmetic composition of the present invention, even when silicone or a silicone derivative is not included, a sufficient dry feeling after drying can be obtained. The effect of the present invention is not particularly limited, and in particular has an HLB value of 7 or less, and contains 0.1 to 5% by weight of a nonionic surfactant that is liquid or pasty at room temperature, and It is considered that it can be obtained by containing 0.1 to 5% by weight of a cationic polymer.
(1000mPa・s/25℃以上の高粘性油分)
本発明の毛髪化粧料に含まれる油性成分として、好ましくは1000mPa・s/25℃以上の粘度を有する高粘性油分を含む。本明細書において、高粘性油分とは25℃における粘度が1000mPa・s以上の油分を意味し、液状でもペースト状でもよい。本明細書において、粘度はBL型粘度計ロータ3号、12rpmの測定条件で測定した値を意味する。
(1000 mPa · s / 25 ° C or higher highly viscous oil)
The oily component contained in the hair cosmetic composition of the present invention preferably contains a highly viscous oil component having a viscosity of 1000 mPa · s / 25 ° C. or higher. In the present specification, the high-viscosity oil component means an oil component having a viscosity at 25 ° C. of 1000 mPa · s or more and may be liquid or pasty. In this specification, a viscosity means the value measured on BL type viscometer rotor No. 3, measurement conditions of 12 rpm.
具体的には高粘性油分として、例えば、リンゴ酸ジイソステアリル、イソステアリン酸ジペンタエリスチリル、ヘキサイソノナン酸ジペンタエリスチリル、デカイソステアリン酸ポリグリセリル−10、水添ポリイソブテン、水添ポリブテン、高重合度ジメチルポリシロキサン、(イソステアリン酸ポリグリセリル−2/ダイマージリノール酸)コポリマー、(イソノナン酸ポリグリセリル−2/ダイマージリノール酸)コポリマー、(ジグリセリン/ジリノール酸/ヒドロキシステアリン酸)コポリマー、ダイマージリノール酸水添ヒマシ油、イソステアリン酸水添ヒマシ油、テトライソステアリン酸スクロース、ラノリン、ワセリン等を挙げることができ、本発明の毛髪化粧料は、これらの油分の1種又は2種以上を含むことができる。これらの高粘性油分を含むことによって、より髪がしなやかで艶やかになり、優れた地肌の潤い感を得ることができる。 Specifically, as a highly viscous oil component, for example, diisostearyl malate, dipentaerythryl isostearate, dipentaerythryl hexaisononanoate, polyglyceryl-10 decaisostearate, hydrogenated polyisobutene, hydrogenated polybutene, high polymerization degree Dimethylpolysiloxane, (polyglyceryl-2 isostearate / dimerlinolinic acid) copolymer, (polyglyceryl-2 isononanoate / dimerlinolinic acid) copolymer, (diglycerin / dilinoleic acid / hydroxystearic acid) copolymer, dimerlinoleic acid water There may be mentioned castor oil, isostearic acid hydrogenated castor oil, sucrose tetraisostearate, lanolin, petrolatum and the like, and the hair cosmetic composition of the present invention may contain one or more of these oils. By containing these high-viscosity oils, the hair becomes more supple and glossy, and an excellent moist feeling of the background can be obtained.
高粘性油分の含有量は、0.2〜5重量%である限り、特に限定されるものではないが、好ましくは0.5〜4重量%であり、より好ましくは1〜3重量%であり、最も好ましくは1.5〜2.5重量%である。高粘性油分の含有量が0.2%未満であると髪のしなやかさや艶、地肌の潤いが得られないことがあり、含有量が5%を超えるとべたつき感を感じることがある。 The content of the highly viscous oil is not particularly limited as long as it is 0.2 to 5% by weight, but is preferably 0.5 to 4% by weight, more preferably 1 to 3% by weight. Most preferably, it is 1.5 to 2.5% by weight. If the content of the high-viscosity oil is less than 0.2%, the suppleness and gloss of the hair and the moisture of the background may not be obtained, and if the content exceeds 5%, a sticky feeling may be felt.
《カチオン性ポリマー:成分(d)》
本発明の毛髪化粧料は、カチオン性ポリマーを0.1〜5重量%含む。カチオン性ポリマーとは陽イオン化する置換基を有する高分子である。陽イオン化する置換基としてはアミノ基、又はアンモニウム基を挙げることができる。カチオン性ポリマーは、通常、毛髪に滑り性を付与し、毛髪をぱさつかせない効果を得ることができるため、シャンプーに含まれることが多い。本発明の毛髪化粧料においては、前記のように特定の物性の非イオン性界面活性剤、油性成分、及びカチオン性ポリマーを含むことによって、髪のさらさら感を得ることができると考えられる。
<< Cationic polymer: Component (d) >>
The hair cosmetic composition of the present invention contains 0.1 to 5% by weight of a cationic polymer. The cationic polymer is a polymer having a cationizing substituent. Examples of the cationizing substituent include an amino group and an ammonium group. Cationic polymers are usually included in shampoos because they can impart slipperiness to the hair and have the effect of preventing hair from being crushed. In the hair cosmetic composition of the present invention, it is considered that the hair feel of hair can be obtained by including a nonionic surfactant having specific physical properties, an oily component, and a cationic polymer as described above.
カチオン性ポリマーは、半合成カチオン化ポリマー、合成カチオン化ポリマー等に分類される。半合成カチオン化ポリマーとしては、例えば、ポリクオタニウム−4(塩化ヒドロキシエチルセルロースジメチルジアリルアンモニウム)、ポリクオタニウム10(塩化O−[2−ヒドロキシ−3−(トリメチルアンモニオ)プロピル]ヒドロキシエチルセルロース)等のカチオン化セルロース;グアーヒドロキシプロピルトリモニウムクロリド、ヒドロキシプロピルグアーヒドロキシプロピルトリモニウムクロリド等のカチオン化グアーガム;塩化ヒドロキシプロピルトリモニウムデンプン等のカチオン化デンプン;が挙げられる。また、合成カチオン化ポリマーとしては、例えば、ポリクオタニウム−7、ポリクオタニウム−52等の塩化ジメチルジアリルアンモニウム・アクリルアミド共重合体;ポリクオタニウム−16等のビニルピロリドン・メチルビニルイミダゾリウム共重合体;ポリクオタニウム−39等のアクリルアミド・アクリル酸・塩化ジメチルジアリルアンモニウム共重合体;ポリ塩化ジメチルメチレンピペリジニウム;が挙げられる。 Cationic polymers are classified into semi-synthetic cationized polymers, synthetic cationized polymers and the like. Examples of semi-synthetic cationized polymers include cationized celluloses such as polyquaternium-4 (hydroxyethylcellulose dimethyldiallylammonium chloride) and polyquaternium 10 (O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose chloride). Cationized guar gums such as guar hydroxypropyltrimonium chloride, hydroxypropyl guar hydroxypropyltrimonium chloride; cationized starches such as hydroxypropyltrimonium chloride; Examples of the synthetic cationized polymer include dimethyldiallylammonium chloride / acrylamide copolymer such as polyquaternium-7 and polyquaternium-52; vinylpyrrolidone / methylvinylimidazolium copolymer such as polyquaternium-16; polyquaternium-39 and the like. And acrylamide / acrylic acid / dimethyldiallylammonium chloride copolymer; polydimethylmethylenepiperidinium chloride.
カチオン性ポリマーの含有量は、0.1〜5重量%である限り、特に限定されるものではないが、好ましくは0.15〜4重量%であり、より好ましくは0.2〜3.5重量%であり、最も好ましくは0.25〜3重量%である。カチオン性ポリマーの含有量が0.1%未満であると髪のしなやかさが得られないことがあり、含有量が5%を超えると髪にべたつき感やごわつき感を感じることがある。 The content of the cationic polymer is not particularly limited as long as it is 0.1 to 5% by weight, but is preferably 0.15 to 4% by weight, more preferably 0.2 to 3.5%. % By weight, most preferably 0.25 to 3% by weight. If the content of the cationic polymer is less than 0.1%, the hair may not be supple, and if the content exceeds 5%, the hair may feel sticky or stiff.
《アシル化加水分解コラーゲン:成分(e)》
本発明の本発明の毛髪化粧料は、更にアシル化加水分解コラーゲンを含むことが好ましい。アシル化加水分解コラーゲンを含むことによって、髪のさらさら感が得られ、毛髪に艶を与える効果が得られる。これらの効果は前記成分(b)の非イオン性界面活性剤と併用することにより、増加するものである。
<< Acylated hydrolyzed collagen: component (e) >>
The hair cosmetic composition of the present invention of the present invention preferably further contains acylated hydrolyzed collagen. By including acylated hydrolyzed collagen, the hair feels smooth and the effect of glossing the hair is obtained. These effects increase when used in combination with the nonionic surfactant of component (b).
アシル化加水分解コラーゲンは、コラーゲンタンパク質を酸、アルカリ、酵素又はこれらの組み合わせにより加水分解して得られるペプチド又はペプチド混合物(平均分子量1000未満)と炭素数10〜25の直鎖又は分枝鎖を有する脂肪族カルボン酸との縮合物、あるいはこれら縮合物の混合物である。アシル化加水分解コラーゲンは、医薬部外品原料規格(厚生省薬務局審査課監修、1991年6月15日、薬事日報社発行)に記載されている。アシル化加水分解コラーゲンとして、例えばミリストイル化加水分解コラーゲン、パルミトイル化加水分解コラーゲン、ステアロイル化加水分解コラーゲン、イソステアロイル化加水分解コラーゲン、オレオイル化加水分解コラーゲン、ウンデシレノイル化加水分解コラーゲン、ラウロイル化加水分解コラーゲン又はヤシ油脂肪酸と加水分解コラーゲンとの縮合物等を挙げることができる。本発明の毛髪化粧料は、これらのアシル化加水分解コラーゲンを1種以上含むことができる。
アシル化加水分解コラーゲンの含有量は、特に限定されるものではないが、好ましくは0.1〜2重量%であり、より好ましくは0.1〜1.5重量%であり、最も好ましくは0.2〜1.0重量%である。
Acylated hydrolyzed collagen is a peptide or peptide mixture (average molecular weight less than 1000) obtained by hydrolyzing collagen protein with acid, alkali, enzyme or a combination thereof, and a linear or branched chain having 10 to 25 carbon atoms. A condensate with an aliphatic carboxylic acid or a mixture of these condensates. Acylated hydrolyzed collagen is described in the quasi-drug raw material standard (supervised by the Pharmaceutical Affairs Bureau, Ministry of Health and Welfare, issued on June 15, 1991, published by Yakuji Nippo). Examples of acylated hydrolyzed collagen include myristoylated hydrolyzed collagen, palmitoylated hydrolyzed collagen, stearoylated hydrolyzed collagen, isostearoylated hydrolyzed collagen, oleoyl hydrolyzed collagen, undecylenoylated hydrolyzed collagen, lauroyl hydrolyzed Examples thereof include condensates of collagen or coconut oil fatty acid and hydrolyzed collagen. The hair cosmetic composition of the present invention can contain one or more of these acylated hydrolyzed collagens.
The content of acylated hydrolyzed collagen is not particularly limited, but is preferably 0.1 to 2% by weight, more preferably 0.1 to 1.5% by weight, and most preferably 0. .2 to 1.0% by weight.
《その他の成分:成分(f)》
本発明の毛髪化粧料は、本発明の効果を阻害しない限りにおいて、その他の成分を含むことができる。その他の成分としては、保湿剤(例えば、トリメチルグリシン、濃グリセリン、ソルビット、キシリトール、ヒアルロン酸、ピロリドンカルボン酸ナトリウム、セラミド類、加水分解ケラチン)、着色剤(例えば、顔料、又は色素)、粘度調整剤(例えば、メチルセルロース、ポリエチレングリコール)、乳化剤(例えば、モノステアリン酸グリセリン)、パール光沢付与剤(例えば、ジステアリン酸グリコール、又はジステアリン酸エチレングリコール)、塩類(例えば、塩化ナトリウム)、植物エキス類、防腐剤、ビタミン剤、香料、紫外線吸収剤、抗酸化剤、湿潤剤、キレート剤、pH調整剤(例えば、クエン酸、又は酒石酸)水を含むことができる。
<< Other ingredients: ingredient (f) >>
The hair cosmetic composition of the present invention can contain other components as long as the effects of the present invention are not impaired. Other ingredients include humectants (eg, trimethyl glycine, concentrated glycerin, sorbit, xylitol, hyaluronic acid, sodium pyrrolidone carboxylate, ceramides, hydrolyzed keratin), colorants (eg, pigments or dyes), viscosity adjustment Agents (for example, methylcellulose, polyethylene glycol), emulsifiers (for example, glyceryl monostearate), pearlescent agents (for example, glycol distearate or ethylene glycol distearate), salts (for example, sodium chloride), plant extracts, Preservatives, vitamins, fragrances, UV absorbers, antioxidants, wetting agents, chelating agents, pH adjuster (eg, citric acid or tartaric acid) water can be included.
《毛髪化粧料》
本発明の毛髪化粧料としては、リンス、コンディショナー、又はトリートメントを挙げることができる。
《Hair cosmetics》
As the hair cosmetic composition of the present invention, there may be mentioned a rinse, a conditioner or a treatment.
以下、実施例によって本発明を具体的に説明するが、これらは本発明の範囲を限定するものではない。
後述の実施例及び比較例によって得られた毛髪化粧料の評価は、以下の「長期安定性試験」及び「使用性試験(感応試験)」により行った。
EXAMPLES Hereinafter, the present invention will be specifically described by way of examples, but these do not limit the scope of the present invention.
Evaluation of hair cosmetics obtained in Examples and Comparative Examples described later was performed by the following “long-term stability test” and “usability test (sensitivity test)”.
《長期安定性試験》
得られた透明クレンジング化粧料を、0℃、25℃(室温)、40℃の各温度条件下において1ヶ月保存し、目視により分離などの外観変化、粘度変化の有無を確認し、以下の基準にて評価した。また、5℃と45℃との温度変化を1日2サイクル行い、1ヶ月保存し、同様に以下の基準で評価した。なお、◎及び○と評価されたものは、実用上十分な安定性を示すものである。
◎:外観変化、粘度変化、又は分離等の異常は全く認められない。
○:外観変化、粘度変化、又は分離等の異常が僅かに認められる。
△:外観変化、粘度変化、又は分離等の異常が認められる。
×:外観変化、粘度変化、又は分離等の異常が著しい。
<Long-term stability test>
The obtained transparent cleansing cosmetic is stored for 1 month under each temperature condition of 0 ° C., 25 ° C. (room temperature) and 40 ° C., and visually confirmed for appearance changes such as separation and viscosity changes, the following criteria Evaluated. Moreover, the temperature change with 5 degreeC and 45 degreeC was performed 2 cycles a day, and it preserve | saved for 1 month, and evaluated similarly on the following references | standards. Note that those evaluated as ○ and ◯ show practically sufficient stability.
A: No abnormality such as change in appearance, change in viscosity, or separation is observed.
○: Abnormality such as change in appearance, change in viscosity, or separation is slightly observed.
Δ: Abnormality such as change in appearance, change in viscosity, or separation is observed.
X: Abnormalities such as change in appearance, change in viscosity, or separation are significant.
《使用性(官能評価)》
使用性については、被験者20名の官能試験により行った。
シャンプー後に、実施例又は比較例で得られたリンス、コンディショナー、又はトリートメントを使用し、「使用中」(指どおり、きしみ、ぬるつき)、並びに髪を乾燥後の「さらさら感」、「しなやかさ」、「艶(ツヤ)」、「においの持続性」及び「地肌の潤い」について評価を行った。
◎(とても良い):15〜20名が、優れているという評価を行った。
○(良い):10〜14名が、優れているという評価を行った。
△(普通):5〜9名が、優れているという評価を行った。
×(悪い):0〜4名が、優れているという評価を行った。
<< Usability (sensory evaluation) >>
About usability, it carried out by the sensory test of 20 test subjects.
After shampooing, use the rinse, conditioner, or treatment obtained in the examples or comparative examples, and “in use” (following fingers, squeaks, and sliminess), as well as “dry feeling” and “smoothness” after drying the hair ”,“ Glossy ”,“ Odor persistence ”and“ Moisture of the skin ”were evaluated.
◎ (Very good) 15-20 people evaluated it as excellent.
○ (Good): 10 to 14 people evaluated that they were excellent.
Δ (Normal): 5 to 9 people evaluated that they were excellent.
X (Bad): 0 to 4 people evaluated that it was excellent.
《実施例1:リンス》
表1に示す組成の各成分(化合物)を、75℃にて、溶解させた。得られた混合物を室温まで冷却して、リンスを得た。得られたリンスについて、前記「長期安定性試験」、及び「使用性(官能評価)」の評価を行った。結果を表1に示す。
なお、成分(b)の非イオン界面活性剤としてセスキイソステアリン酸ソルビタン(HLB4.0)(コスモール182V:日清オイリオ社製)を用いた。また、成分(d)のカチオン性ポリマーとして、ポリクオタニウム−39(マーコートプラス3330:Lubrizol社製)を用いた。
Example 1: Rinse
Each component (compound) having the composition shown in Table 1 was dissolved at 75 ° C. The resulting mixture was cooled to room temperature to obtain a rinse. The obtained rinse was evaluated for the “long-term stability test” and “usability (sensory evaluation)”. The results are shown in Table 1.
In addition, sorbitan sesquiisostearate (HLB4.0) (Cosmol 182V: Nisshin Oilio Co., Ltd.) was used as the nonionic surfactant of component (b). In addition, Polyquaternium-39 (Mercoat Plus 3330: manufactured by Lubrizol) was used as the cationic polymer of component (d).
《実施例2:リンス》
成分(b)のセスキイソステアリン酸ソルビタンに代えて、ジポリヒドロキシステアリン酸PEG−30(HLB5.5)(シスロールDPHS−SO−(AP):クローダジャパン社製)を使用し、実施例1の操作を繰り返した。組成及び結果を表1に示す。
<< Example 2: Rinse >>
The operation of Example 1 was carried out using PEG-30 (HLB5.5) dipolyhydroxystearate (HLB5.5) (manufactured by Croda Japan) instead of sorbitan sesquiisostearate as the component (b). Was repeated. The composition and results are shown in Table 1.
《比較例1:リンス》
成分(b)のセスキイソステアリン酸ソルビタンに代えて、HLBが7を超えている非イオン性界面活性剤として、トリイソステアリン酸POE(40)硬化ヒマシ油(HLB8.4)(EMALEX RWIS−340:日本エマルジョン社製)を使用し、実施例1の操作を繰り返した。組成及び結果を表1に示す。
<< Comparative Example 1: Rinse >>
Instead of sorbitan sesquiisostearate as component (b), triisostearic acid POE (40) hydrogenated castor oil (HLB8.4) (EMALEX RWIS-340: Japan) as a nonionic surfactant having an HLB exceeding 7 The operation of Example 1 was repeated using Emulsion). The composition and results are shown in Table 1.
《比較例2:リンス》
成分(d)のポリクオタニウム−39を添加せずに、実施例2の操作を繰り返した。組成及び結果を表1に示す。
<< Comparative Example 2: Rinse >>
The procedure of Example 2 was repeated without adding the component (d) polyquaternium-39. The composition and results are shown in Table 1.
《比較例3:リンス》
ジポリヒドロキシステアリン酸PEG−30に代えて、HLBが7を超えている非イオン性界面活性剤として、イソステアリン酸PPEG−20ソルビタン(HLB15.0)(NIKKOL TI10V:日光ケミカルズ社製)を使用し、比較例2の操作を繰り返した。組成及び結果を表1に示す。
<< Comparative Example 3: Rinse >>
In place of dipolyhydroxystearic acid PEG-30, PPEG-20 sorbitan isostearate (HLB15.0) (NIKKOL TI10V: manufactured by Nikko Chemicals) is used as a nonionic surfactant having an HLB exceeding 7. The operation of Comparative Example 2 was repeated. The composition and results are shown in Table 1.
《実施例3:コンディショナー》
表2に示す組成の各成分(化合物)を、75℃にて、溶解させた。得られた混合物を室温まで冷却して、コンディショナーを得た。得られたコンディショナーについて、前記「長期安定性試験」、及び「使用性(官能評価)」の評価を行った。結果を表2に示す。
なお、成分(b)の非イオン界面活性剤として、ジポリヒドロキシステアリン酸PEG−30(HLB5.5)(シスロールDPHS−SO−(AP):クローダジャパン社製)を用いた。また、成分(d)のカチオン性ポリマーとして、ポリクオタニウム−10(カチナールHC−200:東邦化学工業社製)を用いた。
<< Example 3: Conditioner >>
Each component (compound) having the composition shown in Table 2 was dissolved at 75 ° C. The resulting mixture was cooled to room temperature to obtain a conditioner. The obtained conditioner was evaluated for the “long-term stability test” and “usability (sensory evaluation)”. The results are shown in Table 2.
In addition, dipolyhydroxystearic acid PEG-30 (HLB5.5) (cis roll DPHS-SO- (AP): the product made by a Croda Japan company) was used as a nonionic surfactant of a component (b). Moreover, polyquaternium-10 (Catinal HC-200: manufactured by Toho Chemical Industry Co., Ltd.) was used as the cationic polymer of the component (d).
《実施例4:コンディショナー》
成分(e)のアシル化加水分解コラーゲンとして、イソステアロイル加水分解コラーゲン(プロモイスEU−118(IS):成和化成社製)を添加して、実施例3の操作を繰り返した。組成及び結果を表2に示す。
<< Example 4: Conditioner >>
As the acylated hydrolyzed collagen of component (e), isostearoyl hydrolyzed collagen (Promois EU-118 (IS): manufactured by Seiwa Kasei Co., Ltd.) was added, and the operation of Example 3 was repeated. The composition and results are shown in Table 2.
《実施例5:コンディショナー》
表2に示す実施例5の組成で、実施例3の操作を繰り返した。組成及び結果を表2に示す。
<< Example 5: Conditioner >>
The operation of Example 3 was repeated with the composition of Example 5 shown in Table 2. The composition and results are shown in Table 2.
《実施例6:コンディショナー》
表2に示す実施例6の組成で、実施例3の操作を繰り返した。組成及び結果を表2に示す。
<< Example 6: Conditioner >>
The operation of Example 3 was repeated with the composition of Example 6 shown in Table 2. The composition and results are shown in Table 2.
《比較例4:コンディショナー》
表2に示す比較例3の組成で、実施例3の操作を繰り返した。カチオン性界面活性剤(a)/非イオン性界面活性剤(b)の重量比を50とした。組成及び結果を表2に示す。
<< Comparative Example 4: Conditioner >>
The operation of Example 3 was repeated with the composition of Comparative Example 3 shown in Table 2. The weight ratio of cationic surfactant (a) / nonionic surfactant (b) was 50. The composition and results are shown in Table 2.
《比較例5:コンディショナー》
表2に示す比較例4の組成で、実施例3の操作を繰り返した。カチオン性界面活性剤(a)/非イオン性界面活性剤(b)の重量比を1.82とした。組成及び結果を表2に示す。
<< Comparative Example 5: Conditioner >>
The operation of Example 3 was repeated with the composition of Comparative Example 4 shown in Table 2. The weight ratio of the cationic surfactant (a) / nonionic surfactant (b) was 1.82. The composition and results are shown in Table 2.
《実施例7:トリートメント》
表3に示す組成の各成分(化合物)を、75℃にて、溶解させた。得られた混合物を室温まで冷却して、トリートメントを得た。得られたトリートメントについて、前記「長期安定性試験」、使用性(官能評価)」及び「さらさら感(官能評価)」を行った。結果を表3に示す。
なお、成分(b)の非イオン界面活性剤として、ジイソステアリン酸ポリグリセリル−2(HLB4.1)(コスモール42V:日清オイリオ社製)、及びジポリヒドロキシステアリン酸PEG−30(HLB5.5)(シスロールDPHS−SO−(AP):クローダジャパン社製)を用いた。また、成分(d)のカチオン性ポリマーとして、グアーヒドロキシプロピルトリモニウムクロリト(ラボールガムCG−M:DSP五協フード&ケミカル社製)を用いた。また、成分(c)のジメチコンはシリコーンであり、アミノプロピルジメチコンは、シリコーン誘導体である。
<< Example 7: Treatment >>
Each component (compound) having the composition shown in Table 3 was dissolved at 75 ° C. The resulting mixture was cooled to room temperature to obtain a treatment. The obtained treatment was subjected to the “long-term stability test”, usability (sensory evaluation) and “smooth feeling (sensory evaluation)”. The results are shown in Table 3.
In addition, as a nonionic surfactant of a component (b), diisostearate polyglyceryl-2 (HLB4.1) (Cosmol 42V: Nisshin Oilio Co., Ltd.) and dipolyhydroxystearic acid PEG-30 (HLB5.5) ( Cisrol DPHS-SO- (AP): manufactured by Croda Japan Co., Ltd.) was used. In addition, guar hydroxypropyltrimonium chloride (Labor gum CG-M: manufactured by DSP Gokyo Food & Chemical Co., Ltd.) was used as the cationic polymer of component (d). The component (c) dimethicone is silicone, and aminopropyl dimethicone is a silicone derivative.
《実施例8》
表3に示す実施例8の組成で、実施例7の操作を繰り返した。組成及び結果を表3に示す。シリコーン誘導体を含んでないが、十分に本発明の効果が得られている。
Example 8
The operation of Example 7 was repeated with the composition of Example 8 shown in Table 3. The composition and results are shown in Table 3. Although the silicone derivative is not included, the effect of the present invention is sufficiently obtained.
《実施例9》
表3に示す実施例9の組成で、実施例7の操作を繰り返した。組成及び結果を表3に示す。成分(c)の高粘性油分として、リンゴ酸ジイソステアリル(2000mPa・s/25℃)(コスモール222:日清オイリオ社製)を用いた。
Example 9
The operation of Example 7 was repeated with the composition of Example 9 shown in Table 3. The composition and results are shown in Table 3. As the highly viscous oil component (c), diisostearyl malate (2000 mPa · s / 25 ° C.) (Cosmol 222: manufactured by Nisshin Oilio Co., Ltd.) was used.
《実施例10》
表3に示す実施例10の組成で、実施例7の操作を繰り返した。組成及び結果を表3に示す。成分(c)の高粘性油分として、イソステアリン酸水添ヒマシ油(29000Pa・s/25℃)(リソカスタMIS:高級アルコール工業社製)を用いた。
Example 10
The operation of Example 7 was repeated with the composition of Example 10 shown in Table 3. The composition and results are shown in Table 3. As a highly viscous oil component (c), isostearic acid hydrogenated castor oil (29000 Pa · s / 25 ° C.) (Risocasta MIS: manufactured by Higher Alcohol Industry Co., Ltd.) was used.
本発明の毛髪化粧料は、製剤の安定性や安全性に優れている。また、使用時の滑らかさ、指通りの良さ、及び洗い流しのし易さ、使用後の毛髪のさらさら感、しっとり感、柔らかさ、滑らかさ、艶、櫛通りの良さが優れている。特に、ノンシリコーンの毛髪化粧料としての優れたさらさら感を示し、染色前の毛髪化粧料として効果的に使用することができる。 The hair cosmetic composition of the present invention is excellent in the stability and safety of the preparation. Moreover, the smoothness at the time of use, the goodness of fingering, and the ease of washing off, the smoothness of the hair after use, moistness, softness, smoothness, gloss, and the goodness of combing are excellent. In particular, it exhibits an excellent dry feeling as a non-silicone hair cosmetic and can be effectively used as a hair cosmetic before dyeing.
Claims (6)
(b)HLB値が7以下であり、且つ常温で液状又はペースト状の非イオン性界面活性剤を0.1〜5重量%、
(c)油性成分を1〜20重量%、及び
(d)カチオン性ポリマーを0.1〜5重量%
を含み、成分(a)及び(b)の重量比(a)/(b)の値が2〜45であることを特徴とする毛髪化粧料。 (A) 1-10% by weight of a cationic surfactant,
(B) 0.1 to 5% by weight of a nonionic surfactant that has an HLB value of 7 or less and is liquid or pasty at room temperature,
(C) 1 to 20% by weight of oil component and (d) 0.1 to 5% by weight of cationic polymer
And a weight ratio (a) / (b) of the components (a) and (b) is 2 to 45.
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