JP6118450B1 - Cleaning composition - Google Patents
Cleaning composition Download PDFInfo
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- JP6118450B1 JP6118450B1 JP2016219662A JP2016219662A JP6118450B1 JP 6118450 B1 JP6118450 B1 JP 6118450B1 JP 2016219662 A JP2016219662 A JP 2016219662A JP 2016219662 A JP2016219662 A JP 2016219662A JP 6118450 B1 JP6118450 B1 JP 6118450B1
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- 238000004140 cleaning Methods 0.000 title claims abstract description 68
- 239000000203 mixture Substances 0.000 title claims abstract description 67
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 claims abstract description 33
- ZUBZATZOEPUUQF-UHFFFAOYSA-N isononane Chemical compound CCCCCCC(C)C ZUBZATZOEPUUQF-UHFFFAOYSA-N 0.000 claims abstract description 22
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 claims abstract description 11
- JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 claims abstract description 11
- WZLFPVPRZGTCKP-UHFFFAOYSA-N 1,1,1,3,3-pentafluorobutane Chemical compound CC(F)(F)CC(F)(F)F WZLFPVPRZGTCKP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000002689 soil Substances 0.000 claims description 10
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 claims description 7
- 238000005406 washing Methods 0.000 claims description 7
- 238000001035 drying Methods 0.000 abstract description 13
- 239000003921 oil Substances 0.000 description 25
- 235000019198 oils Nutrition 0.000 description 25
- 239000000976 ink Substances 0.000 description 17
- 239000002480 mineral oil Substances 0.000 description 16
- 235000010446 mineral oil Nutrition 0.000 description 16
- 239000003963 antioxidant agent Substances 0.000 description 10
- -1 3,5-di-t-butyl-4-hydroxyphenyl Chemical group 0.000 description 9
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 9
- 239000002184 metal Substances 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 229910001220 stainless steel Inorganic materials 0.000 description 6
- 239000010935 stainless steel Substances 0.000 description 6
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 6
- 150000001335 aliphatic alkanes Chemical class 0.000 description 5
- 239000003550 marker Substances 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- 238000009835 boiling Methods 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 239000002537 cosmetic Substances 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- CYNYIHKIEHGYOZ-UHFFFAOYSA-N 1-bromopropane Chemical compound CCCBr CYNYIHKIEHGYOZ-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 230000003078 antioxidant effect Effects 0.000 description 3
- 239000002738 chelating agent Substances 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 239000003925 fat Substances 0.000 description 3
- 235000019197 fats Nutrition 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 description 3
- 239000008158 vegetable oil Substances 0.000 description 3
- UYQYTUYNNYZATF-UHFFFAOYSA-N 6-methyl-4,6-bis(octylsulfanylmethyl)cyclohexa-1,3-dien-1-ol Chemical compound CCCCCCCCSCC1=CC=C(O)C(C)(CSCCCCCCCC)C1 UYQYTUYNNYZATF-UHFFFAOYSA-N 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 239000012459 cleaning agent Substances 0.000 description 2
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 210000005224 forefinger Anatomy 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 230000003449 preventive effect Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 210000003813 thumb Anatomy 0.000 description 2
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 description 1
- SLSZYCUCKFSOCN-UHFFFAOYSA-N 1-(difluoromethoxy)-1,1,2,2-tetrafluoroethane Chemical compound FC(F)OC(F)(F)C(F)F SLSZYCUCKFSOCN-UHFFFAOYSA-N 0.000 description 1
- FOUZISDNESEYLX-UHFFFAOYSA-N 2-(2-hydroxyethylazaniumyl)acetate Chemical compound OCCNCC(O)=O FOUZISDNESEYLX-UHFFFAOYSA-N 0.000 description 1
- QSRJVOOOWGXUDY-UHFFFAOYSA-N 2-[2-[2-[3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propanoyloxy]ethoxy]ethoxy]ethyl 3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C)=CC(CCC(=O)OCCOCCOCCOC(=O)CCC=2C=C(C(O)=C(C)C=2)C(C)(C)C)=C1 QSRJVOOOWGXUDY-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QRLSTWVLSWCGBT-UHFFFAOYSA-N 4-((4,6-bis(octylthio)-1,3,5-triazin-2-yl)amino)-2,6-di-tert-butylphenol Chemical compound CCCCCCCCSC1=NC(SCCCCCCCC)=NC(NC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=N1 QRLSTWVLSWCGBT-UHFFFAOYSA-N 0.000 description 1
- BFVOBXSKECUHSW-UHFFFAOYSA-N 4-n,4-n-di(butan-2-yl)benzene-1,4-diamine Chemical compound CCC(C)N(C(C)CC)C1=CC=C(N)C=C1 BFVOBXSKECUHSW-UHFFFAOYSA-N 0.000 description 1
- ZVVFVKJZNVSANF-UHFFFAOYSA-N 6-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]hexyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCCCCCCOC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 ZVVFVKJZNVSANF-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- HKZLKMXGKMSCRW-UHFFFAOYSA-N CCOP(=O)(Cc1cc(c(O)c(c1)C(C)(C)C)C(C)(C)C)OCC.Cc1c(Cc2cc(c(O)c(c2)C(C)(C)C)C(C)(C)C)c(C)c(Cc2cc(c(O)c(c2)C(C)(C)C)C(C)(C)C)c(C)c1Cc1cc(c(O)c(c1)C(C)(C)C)C(C)(C)C Chemical compound CCOP(=O)(Cc1cc(c(O)c(c1)C(C)(C)C)C(C)(C)C)OCC.Cc1c(Cc2cc(c(O)c(c2)C(C)(C)C)C(C)(C)C)c(C)c(Cc2cc(c(O)c(c2)C(C)(C)C)C(C)(C)C)c(C)c1Cc1cc(c(O)c(c1)C(C)(C)C)C(C)(C)C HKZLKMXGKMSCRW-UHFFFAOYSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- 206010007269 Carcinogenicity Diseases 0.000 description 1
- 206010008428 Chemical poisoning Diseases 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- XBPCUCUWBYBCDP-UHFFFAOYSA-N Dicyclohexylamine Chemical compound C1CCCCC1NC1CCCCC1 XBPCUCUWBYBCDP-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical class C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- JYXGIOKAKDAARW-UHFFFAOYSA-N N-(2-hydroxyethyl)iminodiacetic acid Chemical compound OCCN(CC(O)=O)CC(O)=O JYXGIOKAKDAARW-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 235000019485 Safflower oil Nutrition 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- BLXLSQIOCCHAHJ-UHFFFAOYSA-N [2,3,4-tri(nonyl)phenyl] dihydrogen phosphite Chemical compound CCCCCCCCCC1=CC=C(OP(O)O)C(CCCCCCCCC)=C1CCCCCCCCC BLXLSQIOCCHAHJ-UHFFFAOYSA-N 0.000 description 1
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 1
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 230000007670 carcinogenicity Effects 0.000 description 1
- 231100000260 carcinogenicity Toxicity 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 235000005687 corn oil Nutrition 0.000 description 1
- 239000002285 corn oil Substances 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- IOCGMLSHRBHNCM-UHFFFAOYSA-N difluoromethoxy(difluoro)methane Chemical compound FC(F)OC(F)F IOCGMLSHRBHNCM-UHFFFAOYSA-N 0.000 description 1
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical class C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 229910052571 earthenware Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 235000021323 fish oil Nutrition 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003676 hair preparation Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 229960004488 linolenic acid Drugs 0.000 description 1
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- LGOPTUPXVVNJFH-UHFFFAOYSA-N pentadecanethioic s-acid Chemical compound CCCCCCCCCCCCCCC(O)=S LGOPTUPXVVNJFH-UHFFFAOYSA-N 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- 150000004986 phenylenediamines Chemical class 0.000 description 1
- DOIRQSBPFJWKBE-UHFFFAOYSA-N phthalic acid di-n-butyl ester Natural products CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 239000003495 polar organic solvent Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 235000015277 pork Nutrition 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- QEDNBHNWMHJNAB-UHFFFAOYSA-N tris(8-methylnonyl) phosphite Chemical compound CC(C)CCCCCCCOP(OCCCCCCCC(C)C)OCCCCCCCC(C)C QEDNBHNWMHJNAB-UHFFFAOYSA-N 0.000 description 1
- 239000002383 tung oil Substances 0.000 description 1
- 238000004506 ultrasonic cleaning Methods 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 239000010698 whale oil Substances 0.000 description 1
Abstract
【課題】引火性が低く、乾燥性のよい洗浄用組成物を提供すること。【解決手段】本発明は、（Ａ）１，１，１，３，３−ペンタフルオロブタン並びに（Ｂ）ｎ−ヘプタン、イソオクタン及びイソノナンからなる群から選ばれる少なくとも１種を含む、洗浄用組成物に関する。【選択図】なしDisclosed is a cleaning composition having low flammability and good drying properties. The present invention relates to a cleaning composition comprising (A) 1,1,1,3,3-pentafluorobutane and (B) at least one selected from the group consisting of n-heptane, isooctane and isononane. Related to things. [Selection figure] None
Description
本発明は、洗浄用組成物に関する。 The present invention relates to a cleaning composition.
金属加工においては、金属の塗装、メッキ工程の前に脱脂洗浄の工程がある。また、鋼板の鏡面加工には、鉱物油及び油性インクが使用されており、洗浄する必要がある。これらの洗浄には、高い洗浄力と乾燥性が求められるため、従来、ジクロロメタン及びトリクロロエチレンが使用されてきた。しかしながら、前記成分は、発がん性があるため、特別有機溶剤に指定されており、使用が制限されている。
これに対して、ジフルオロメトキシ−ビス（ジフルオロメチルエーテル）又は１，１，２，２−テトラフルオロエチルジフルオロメチルエーテルと、ヘキサン又はペンタンとを配合した共沸性組成物を用いて、油性製品の除去を行うことが知られている（特許文献１）。
In metal processing, there is a degreasing and cleaning step before the metal painting and plating step. Moreover, mineral oil and oil-based ink are used for mirror finishing of a steel plate, and it is necessary to wash it. Since these washings require high detergency and drying properties, dichloromethane and trichlorethylene have been conventionally used. However, since the said component has carcinogenicity, it is designated as a special organic solvent and its use is restricted.
On the other hand, by using an azeotropic composition containing difluoromethoxy-bis (difluoromethyl ether) or 1,1,2,2-tetrafluoroethyl difluoromethyl ether and hexane or pentane, It is known to perform removal (Patent Document 1).
しかしながら、ヘキサン及びペンタンといった炭素数が６以下のアルカン類は、引火点が−２０℃以下と低く、安全性が低い。一方、炭素数が７以上のアルカン類は、引火点が０度付近かそれ以上であるので、炭素数が６以下のアルカンを用いた洗浄用組成物よりも安全性は高まるが、沸点も高くなるため乾燥性が悪くなり、洗浄用組成物が拭取り跡として残るという問題がある。
本発明の課題は、引火性が低く、乾燥性のよい洗浄用組成物を提供することである。
However, alkanes having 6 or less carbon atoms, such as hexane and pentane, have a low flash point of −20 ° C. or less and have low safety. On the other hand, alkanes having 7 or more carbon atoms have a flash point of about 0 ° C. or higher, and thus have higher safety than cleaning compositions using alkanes having 6 or less carbon atoms, but also have a high boiling point. Therefore, there is a problem that the drying property is deteriorated and the cleaning composition remains as a wiping trace.
An object of the present invention is to provide a cleaning composition having low flammability and good drying properties.
本発明は、以下の態様を含む。
［１］（Ａ）１，１，１，３，３−ペンタフルオロブタン並びに（Ｂ）ｎ−ヘプタン、イソオクタン及びイソノナンからなる群から選ばれる少なくとも１種を含む、洗浄用組成物。
［２］（Ａ）及び（Ｂ）の合計１００質量部に対して、（Ｂ）が１７質量部以上５０質量部未満である［１］の洗浄用組成物。
［３］（Ｂ）がｎ−ヘプタン及びイソオクタンからなる群から選ばれる少なくとも１種であって、（Ａ）及び（Ｂ）の合計１００質量部に対して、（Ｂ）が１７〜４９質量部である［２］の洗浄用組成物。
［４］（Ｂ）がイソノナンであって、（Ａ）及び（Ｂ）の合計１００質量部に対して、（Ｂ）が１７〜４２質量部である［２］の洗浄用組成物。
［５］更に、（Ｃ）炭酸ジメチルを含む［１］の洗浄用組成物。
［６］（Ａ）、（Ｂ）及び（Ｃ）の合計１００質量部に対して、（Ｂ）が１３．２６〜３８．２２質量部、（Ｃ）が３．４０〜１０．８０質量部である［５］の洗浄用組成物。
［７］油性汚れ洗浄用である［１］〜［６］の洗浄用組成物。
The present invention includes the following aspects.
[1] A cleaning composition comprising (A) 1,1,1,3,3-pentafluorobutane and (B) at least one selected from the group consisting of n-heptane, isooctane and isononane.
[2] The cleaning composition according to [1], wherein (B) is 17 parts by mass or more and less than 50 parts by mass with respect to 100 parts by mass in total of (A) and (B).
[3] (B) is at least one selected from the group consisting of n-heptane and isooctane, and (B) is 17 to 49 parts by mass with respect to a total of 100 parts by mass of (A) and (B). The cleaning composition according to [2].
[4] The cleaning composition according to [2], wherein (B) is isononane, and (B) is 17 to 42 parts by mass with respect to 100 parts by mass in total of (A) and (B).
[5] The cleaning composition according to [1], further comprising (C) dimethyl carbonate.
[6] (B) is 13.26 to 38.22 parts by mass and (C) is 3.40 to 10.80 parts by mass with respect to a total of 100 parts by mass of (A), (B) and (C). The cleaning composition according to [5].
[7] The cleaning composition according to [1] to [6], which is used for cleaning oily soil.
本発明により、引火性が低く、乾燥性のよい洗浄用組成物を提供することができる。 According to the present invention, a cleaning composition having low flammability and good drying properties can be provided.
［用語の定義］
本明細書において、（Ａ）１，１，１，３，３−ペンタフルオロブタンを、単に（Ａ）と記載する場合がある。（Ｂ）ｎ−ヘプタン、イソオクタン及びイソノナンからなる群から選ばれる少なくとも１種等についても同様である。「拭取り跡」とは、洗浄用組成物の使用により生じた基材のシミや汚れをいう。
[Definition of terms]
In this specification, (A) 1,1,1,3,3-pentafluorobutane may be simply referred to as (A). The same applies to (B) at least one selected from the group consisting of n-heptane, isooctane and isononane. The “wiping trace” refers to a stain or stain on the base material caused by the use of the cleaning composition.
［洗浄用組成物］
洗浄用組成物は、（Ａ）１，１，１，３，３−ペンタフルオロブタン並びに（Ｂ）ｎ−ヘプタン、イソオクタン及びイソノナンからなる群から選ばれる少なくとも１種を含む（以下、これを単に「組成物」ともいう）。
組成物は、油性汚れに対して高い洗浄性を有する。また、引火性が低いため、安全性が高い。さらには、乾燥性がよく、拭取り跡を生じない。
[Cleaning composition]
The cleaning composition contains (A) 1,1,1,3,3-pentafluorobutane and (B) at least one selected from the group consisting of n-heptane, isooctane and isononane (hereinafter referred to simply as “this”). Also referred to as “composition”).
The composition has a high detergency against oily soils. In addition, safety is high due to low flammability. Furthermore, it has good drying properties and does not cause wiping traces.
＜（Ａ）１，１，１，３，３−ペンタフルオロブタン＞
（Ａ）は、１，１，１，３，３−ペンタフルオロブタンである（「３６５ｍｆｃ」とも呼ばれる）。（Ａ）は、沸点が４０℃と低いため、沸点が１００℃付近かそれ以上である（Ｂ）と混合することにより、組成物全体の沸点を下げることができる。その結果、乾燥性が向上するため、洗浄を行なった際に、油性汚れが付着した基材（以下、「被洗浄物」ともいう。）に組成物が残存しにくいので、被洗浄物に拭取り跡が残ることを抑えることができる。
<(A) 1,1,1,3,3-pentafluorobutane>
(A) is 1,1,1,3,3-pentafluorobutane (also referred to as “365mfc”). Since (A) has a low boiling point of 40 ° C., the boiling point of the entire composition can be lowered by mixing with (B) having a boiling point of about 100 ° C. or higher. As a result, the drying property is improved, so that when cleaning is performed, the composition does not easily remain on the base material (hereinafter also referred to as “object to be cleaned”) to which oily dirt adheres. It can suppress that a trace remains.
＜（Ｂ）ｎ−ヘプタン、イソオクタン及びイソノナンからなる群から選ばれる少なくとも１種＞
（Ｂ）は、ｎ−ヘプタン、イソオクタン及びイソノナンからなる群から選ばれる少なくとも１種である。（Ｂ）は、極性が低いため、鉱物油等の極性の低い油性汚れを洗浄する能力が高い。また（Ｂ）は、引火点が０℃付近かそれ以上であるので、炭素数が６以下のアルカン類よりも引火点が高く、危険性が低い。
<(B) at least one selected from the group consisting of n-heptane, isooctane and isononane>
(B) is at least one selected from the group consisting of n-heptane, isooctane and isononane. Since (B) is low in polarity, it has a high ability to clean low-polarity oily dirt such as mineral oil. In addition, (B) has a flash point higher than that of alkanes having 6 or less carbon atoms because its flash point is around 0 ° C. or higher, and is less dangerous.
＜更なる成分＞
組成物は、更に（Ｃ）炭酸ジメチルを含むことが好ましく、また、本発明の効果を損なわない範囲で、（Ｄ）その他の成分を含んでいてもよい。
<Additional ingredients>
The composition preferably further contains (C) dimethyl carbonate, and may contain (D) other components as long as the effects of the present invention are not impaired.
＜＜（Ｃ）炭酸ジメチル＞＞
（Ｃ）は、炭酸ジメチルである。（Ｃ）は、（Ｂ）と極性が異なるため、組成物が更に（Ｃ）を含むと、より広い種類の油性汚れを対象とした洗浄に、組成物を好適に用いることができる。
前記（Ａ）、（Ｂ）及び（Ｃ）は、労働安全衛生法の有機溶剤中毒予防規則に指定された溶剤に該当しない。したがって、（Ａ）及び（Ｂ）、好ましくはさらに（Ｃ）を含む組成物は、人体への影響が少ない。
<< (C) Dimethyl carbonate >>
(C) is dimethyl carbonate. Since (C) has a different polarity from (B), when the composition further contains (C), the composition can be suitably used for washing for a wider variety of oily soils.
Said (A), (B) and (C) do not correspond to the solvent designated in the organic solvent poisoning prevention regulations of the Industrial Safety and Health Law. Therefore, the composition containing (A) and (B), preferably further (C) has little influence on the human body.
＜＜（Ｄ）その他の成分＞＞
（Ｄ）その他の成分として、紫外線吸収剤、酸化防止剤、防錆剤、消泡剤、界面活性剤及びキレート剤からなる群より選択される１種以上が挙げられる。更なる成分は、洗浄剤の分野で慣用されている成分であれば特に限定されず、それぞれ単独で用いることもでき、また複数の混合物として用いることもできる。
<< (D) Other ingredients >>
(D) As another component, 1 or more types selected from the group which consists of a ultraviolet absorber, antioxidant, a rust preventive agent, an antifoamer, surfactant, and a chelating agent are mentioned. The additional component is not particularly limited as long as it is a component commonly used in the field of cleaning agents, and can be used alone or as a mixture.
紫外線吸収剤及び酸化防止剤は、組成物の長期保存等における安定性を向上させる成分である。紫外線吸収剤は、ベンゾトリアゾール系紫外線吸収剤、ベンゾフェノン系紫外線吸収剤、及びヒンダードアミン系紫外線吸収剤が挙げられる。酸化防止剤は、フェノール系酸化防止剤、アミン系酸化防止剤、硫黄系酸化防止剤、及びリン系等酸化防止剤が挙げられる。 The ultraviolet absorber and the antioxidant are components that improve the stability of the composition during long-term storage and the like. Examples of the ultraviolet absorber include a benzotriazole-based ultraviolet absorber, a benzophenone-based ultraviolet absorber, and a hindered amine-based ultraviolet absorber. Examples of the antioxidant include phenolic antioxidants, amine-based antioxidants, sulfur-based antioxidants, and phosphorus-based antioxidants.
フェノール系酸化防止剤は、２，６−ジ−ｔ−ブチル−４−メチルフェノール、トリエチレングリコール−ビス［３−（３−ｔ−ブチル−５−メチル−４−ヒドロキシフェニル）プロピオネート］、１，６−ヘキサンジオール−ビス［３−（３，５−ジ−ｔ−ブチル−４−ヒドロキシフェニル）プロピオネート］、２，４−ビス−（ｎ−オクチルチオ）−６−（４−ヒドロキシ−３，５−ジ−ｔ−ブチルアニリノ）−１，３，５−トリアジン、ペンタエリスリチル−テトラキス［３−（３，５−ジ−ｔ−ブチル−４−ヒドロキシフェニル）プロピオネート］、２，２−チオ−ジエチレンビス［３−（３，５−ジ−ｔ−ブチル−ヒドロキシフェニル）プロピオネート］、オクタドデシル−３−［３，５−ジ−ｔ−ブチル−４−ヒドロキシフェニル］プロピオネート］、Ｎ，Ｎ−ヘキサメチレンビス（３，５−ジ−ｔ−ブチル−４−ヒドロキシ−ヒドロシンナミド）、３，５−ジ−ｔ−ブチル−４−ヒドロキシ−ベンジルフォスフォネート−ジエチルエステル、１，３，５−トリメチル−２，４，６−トリス（３，５−ジ−ｔ−ブチル−４−ヒドロキシベンジル）ベンゼン、２，４−ビス［（オクチルチオ）メチル］−ｏ−クレゾール等が挙げられる。 Phenol antioxidants include 2,6-di-t-butyl-4-methylphenol, triethylene glycol-bis [3- (3-t-butyl-5-methyl-4-hydroxyphenyl) propionate], 1 , 6-hexanediol-bis [3- (3,5-di-t-butyl-4-hydroxyphenyl) propionate], 2,4-bis- (n-octylthio) -6- (4-hydroxy-3, 5-di-t-butylanilino) -1,3,5-triazine, pentaerythrityl-tetrakis [3- (3,5-di-t-butyl-4-hydroxyphenyl) propionate], 2,2-thio- Diethylenebis [3- (3,5-di-t-butyl-hydroxyphenyl) propionate], octadodecyl-3- [3,5-di-t-butyl-4-hydroxypheny ] Propionate], N, N-hexamethylenebis (3,5-di-tert-butyl-4-hydroxy-hydrocinnamide), 3,5-di-tert-butyl-4-hydroxy-benzylphosphonate-diethyl ester 1,3,5-trimethyl-2,4,6-tris (3,5-di-t-butyl-4-hydroxybenzyl) benzene, 2,4-bis [(octylthio) methyl] -o-cresol, etc. Is mentioned.
アミン系酸化防止剤は、アルキル化ジフェニルアミン、トリス−（３，５−ジ−ｔ−ブチル−４−ヒドロキシベンジル）−イソシアヌレート、Ｎ，Ｎ−ジ−ｓｅｃ−ブチル−ｐ−フェニレンジアミン、ｐ−フェニレンジアミン誘導体、１，３，５−トリス（４−ｔ−ブチル−３−ヒドロキシ−２，６−ジメチル）イソシアヌレート等が挙げられる。硫黄系酸化防止剤は、２，４−ビス［（オクチルチオ）メチル］−ｏ−クレゾール、ジラウリル−３，３−チオジプロピオネート、ジミリスチル−３，３−ジオジプロピオネート、ジステアリル−３，３−チオジプロピオネート、ペンタエリスリチルテトラキス（３−ラウリルチオプロピオネート）、ジトリデシル−３，３−チオジプロピオネート、２−メルカプトベンズイミダゾール、ビス［２−メチル−４−（３−ｎ−アルキルチオプロピオニルオキシ）−５−ｔ−ブチルフェニル］スルフィド等が挙げられる。リン系酸化防止剤は、トリス−ノニルフェニルフォスファイト、トリフェニルフォスファイト、トリス（２，４−ジ−ｔ−ブチルフェニル）フォスファイト、トリス（イソデシル）フォスファイト等が挙げられる。 Amine-based antioxidants include alkylated diphenylamine, tris- (3,5-di-t-butyl-4-hydroxybenzyl) -isocyanurate, N, N-di-sec-butyl-p-phenylenediamine, p- Examples include phenylenediamine derivatives and 1,3,5-tris (4-t-butyl-3-hydroxy-2,6-dimethyl) isocyanurate. Sulfur-based antioxidants include 2,4-bis [(octylthio) methyl] -o-cresol, dilauryl-3,3-thiodipropionate, dimyristyl-3,3-diodipropionate, distearyl-3, 3-thiodipropionate, pentaerythrityltetrakis (3-laurylthiopropionate), ditridecyl-3,3-thiodipropionate, 2-mercaptobenzimidazole, bis [2-methyl-4- (3-n -Alkylthiopropionyloxy) -5-tert-butylphenyl] sulfide and the like. Examples of phosphorus antioxidants include tris-nonylphenyl phosphite, triphenyl phosphite, tris (2,4-di-t-butylphenyl) phosphite, and tris (isodecyl) phosphite.
キレート剤は、アミノカルボン酸系のキレート剤が挙げられ、ヒドロキシエチルアミノ酢酸、ヒドロキシエチルイミノ二酢酸、エチレンジアミンテトラ酢酸やそれらの塩等が好ましい。 Examples of the chelating agent include aminocarboxylic acid-based chelating agents, and hydroxyethylaminoacetic acid, hydroxyethyliminodiacetic acid, ethylenediaminetetraacetic acid and salts thereof are preferable.
防錆剤は、シクロヘキシルアミン及びジシクロヘキシルアミンが挙げられる。界面活性剤は、非イオン性界面活性剤が挙げられ、高級アルコールエチレンオキサイド付加物、アルキルフェノールエチレンオキサイド付加物、脂肪酸エチレンオキサイド付加物、高級アルキルアミンエチレンオキサイド付加物、ソルビトール及びソルビタンの脂肪酸エステル、ショ糖脂肪酸エステル、シリコーン系界面活性剤、及びフッ素系界面活性剤等が好ましい。 Examples of the rust preventive include cyclohexylamine and dicyclohexylamine. Examples of the surfactant include nonionic surfactants, and include higher alcohol ethylene oxide adducts, alkylphenol ethylene oxide adducts, fatty acid ethylene oxide adducts, higher alkylamine ethylene oxide adducts, fatty acid esters of sorbitol and sorbitan, Sugar fatty acid esters, silicone surfactants, fluorine surfactants and the like are preferable.
＜組成物の組成＞
組成物における（Ａ）及び（Ｂ）の合計１００質量部に対する（Ｂ）の配合量は、好ましくは１７質量部以上５０質量部未満であり、より好ましくは１７〜４９質量部であり、更に好ましくは１７〜４２質量部である。このような範囲であると、油性汚れに対する洗浄性が優れる。また、洗浄性の観点から、（Ａ）及び（Ｂ）の合計１００質量部に対する（Ｂ）の配合量は、（Ｂ）がｎ−ヘプタン及びイソオクタンからなる群から選ばれる少なくとも１種である場合は、好ましくは１７〜４９質量部であり、（Ｂ）がイソノナンである場合は、好ましくは１７〜４２質量部である。
組成物における（Ａ）、（Ｂ）及び（Ｃ）の合計１００質量部に対する（Ｂ）の配合量は、好ましくは１３．２６〜３８．２２質量部であり、より好ましくは１４〜３８質量部であり、（Ｃ）の配合量は、好ましくは３．４０〜１０．８０質量部であり、より好ましくは４〜１０質量部である。このような範囲であると、油性汚れに対する洗浄性が優れる。
<Composition of composition>
The blending amount of (B) with respect to a total of 100 parts by mass of (A) and (B) in the composition is preferably 17 parts by mass or more and less than 50 parts by mass, more preferably 17 to 49 parts by mass, and still more preferably. Is 17 to 42 parts by mass. In such a range, the cleaning property against oily dirt is excellent. From the viewpoint of detergency, the blending amount of (B) with respect to 100 parts by mass of (A) and (B) is at least one selected from the group consisting of n-heptane and isooctane. Is preferably 17 to 49 parts by mass, and when (B) is isononane, it is preferably 17 to 42 parts by mass.
The blending amount of (B) with respect to 100 parts by mass of (A), (B) and (C) in the composition is preferably 13.26 to 38.22 parts by mass, more preferably 14 to 38 parts by mass. The blending amount of (C) is preferably 3.40 to 10.80 parts by mass, and more preferably 4 to 10 parts by mass. In such a range, the cleaning property against oily dirt is excellent.
＜製造方法＞
組成物の製造方法は特に限定されないが、上述の成分を、公知の方法で、撹拌、混合、溶解、分散等を適宜選択して行なうことによって製造することができる。上述の成分は、市販品を用いることができる。
<Manufacturing method>
Although the manufacturing method of a composition is not specifically limited, It can manufacture by selecting suitably the above-mentioned component by a well-known method, stirring, mixing, melt | dissolution, dispersion | distribution, etc. A commercial item can be used for the above-mentioned component.
＜油性汚れ＞
組成物は、油性汚れの洗浄に用いることが好ましい。油性汚れとしては、非極性成分による油性汚れ、極性成分による油性汚れ、及び極性の異なる複数の成分による油性汚れが挙げられ、より具体的には、鉱物油、非極性有機溶剤といった非極性成分による油性汚れ、植物油脂、動物油脂、極性有機溶剤といった極性成分による油性汚れ、油性インク、化粧品といった極性の異なる複数の成分による油性汚れが挙げられる。
<Oil stain>
The composition is preferably used for cleaning oily soil. Examples of oily stains include oily stains due to nonpolar components, oily stains due to polar components, and oily stains due to multiple components having different polarities, and more specifically, due to nonpolar components such as mineral oil and nonpolar organic solvents. Examples include oily stains due to polar components such as oily stains, vegetable oils, animal fats and oils, and polar organic solvents, and oily stains due to a plurality of components having different polarities such as oil-based inks and cosmetics.
鉱物油としては、特に制限はなく、市販品としてはプーリーSFオイル（出光興産株式会社製）が挙げられる。
植物油脂としては、オリーブ油、アマニ油、キリ油、ゴマ油、サフラワー油、大豆油、ヒマシ油、綿実油、ヤシ油、コーン油及び脱水ヒマシ油等が挙げられる。植物油を構成する脂肪酸は、Ｃ１２〜Ｃ１８の飽和又は不飽和脂肪酸であり、具体的には、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、オレイン酸、リノール酸、リノレン酸、及びエレオステアリン酸等が挙げられる。
動物油脂としては、魚油、鯨油、豚脂、牛脂等が挙げられる。
油性インクは、通常、有機溶剤、染料及び／又は顔料、並びに任意に樹脂を含むが、特に限定されない。
化粧品としては、基礎化粧品、仕上げ化粧品、毛髪用化粧品等が挙げられる。
There is no restriction | limiting in particular as mineral oil, As a commercial item, pulley SF oil (made by Idemitsu Kosan Co., Ltd.) is mentioned.
Examples of vegetable oils include olive oil, linseed oil, tung oil, sesame oil, safflower oil, soybean oil, castor oil, cottonseed oil, coconut oil, corn oil, and dehydrated castor oil. The fatty acids constituting the vegetable oil are C 12 to C 18 saturated or unsaturated fatty acids, specifically, lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, linoleic acid, linolenic acid, and eleo Examples include stearic acid.
Examples of animal fats include fish oil, whale oil, pork fat, and beef tallow.
The oil-based ink usually contains an organic solvent, a dye and / or a pigment, and optionally a resin, but is not particularly limited.
Cosmetics include basic cosmetics, finished cosmetics, hair cosmetics, and the like.
（Ａ）及び（Ｂ）を含む組成物は、非極性成分による油性汚れ、特に鉱物油による油性汚れに好適に用いることができるが、これに限定されない。
（Ａ）、（Ｂ）及び（Ｃ）を含む好ましい態様の組成物は、非極性成分による油性汚れ、極性成分による油性汚れ、及び極性の異なる複数の成分による油性汚れに好適であり、特に油性インクによる油性汚れ及び鉱物油による油性汚れに好適に用いることができる。極性の異なる複数の成分による油性汚れ、特に油性インクによる油性汚れに対して好適に用いられる組成は、前述の通りである。非極性成分による油性汚れ及び極性の異なる複数の成分による油性汚れのいずれにも好適に用いられる組成、特に油性インクによる油性汚れ及び鉱物油による油性汚れのいずれにも好適に用いられる組成は、前述の組成において、（Ｂ）成分及び（Ｃ）成分の合計１００質量部に対する（Ｃ）成分の配合量が２２質量部以下であることが好ましい。
The composition containing (A) and (B) can be suitably used for oily dirt due to nonpolar components, particularly oily dirt due to mineral oil, but is not limited thereto.
The composition of a preferred embodiment containing (A), (B) and (C) is suitable for oily soils due to non-polar components, oily soils due to polar components, and oily soils due to a plurality of components having different polarities. It can be suitably used for oily stains caused by ink and oily stains caused by mineral oil. The composition suitably used for oily stains caused by a plurality of components having different polarities, particularly oily stains caused by oil-based inks, is as described above. The composition preferably used for both oil-based stains due to non-polar components and oil-based stains due to a plurality of components having different polarities, particularly the composition preferably used for both oil-based stains due to oil-based inks and oil-based stains due to mineral oil. It is preferable that the compounding quantity of (C) component with respect to a total of 100 mass parts of (B) component and (C) component is 22 mass parts or less.
＜洗浄方法＞
組成物を用いた洗浄方法は、被洗浄物を洗浄するため方法であって、組成物を被洗浄物と接触させることを含む。
基材は、特に制限されないが、金属、繊維、ガラス、陶器、プラスチック等が挙げられ、これらの中でも、加工の際に油性汚れを除去する要請がある金属が好ましい。
洗浄方法において、組成物を被洗浄物に接触させることにより、基材に付着した油性汚れは、基材から除去される。なお、油性汚れが塵、埃等の固形の汚れを含む場合、この固形の汚れは、油性汚れの除去と同時に除去され得る。
<Washing method>
The cleaning method using the composition is a method for cleaning an object to be cleaned, and includes bringing the composition into contact with the object to be cleaned.
The substrate is not particularly limited, and examples thereof include metals, fibers, glass, earthenware, and plastics. Among these, metals that are required to remove oily dirt during processing are preferable.
In the cleaning method, the oily soil adhered to the substrate is removed from the substrate by bringing the composition into contact with the object to be cleaned. In addition, when oily dirt contains solid dirt, such as dust and dust, this solid dirt can be removed simultaneously with the removal of oily dirt.
組成物と、被洗浄物とを接触させるための方法としては、特に制限はなく、例えば、手拭き洗浄、浸漬洗浄（液相洗浄）、スプレー洗浄、超音波洗浄、蒸気洗浄（気相洗浄）が挙げられるが、手拭き洗浄が好ましい。手拭き洗浄は、通常、組成物を染み込ませた紙、布等を、油性汚れが付着した領域に接触させながら手でこすることにより、又は組成物を染み込ませた紙、布等を、油性汚れが付着した領域に接触させながら板や棒を介して手でこすることにより行う。油性汚れが油性インクによるものである場合は、組成物を染み込ませた紙、布等を、平らな板を介して手でこすると、溝のように拭取り跡が生じることを抑制することができる。組成物及び被洗浄物の接触時間に相当する洗浄時間は、基材から油性汚れを除去できる時間であれば特に制限されない。例えば、洗浄時間は、１０秒〜２時間であってもよい。 The method for bringing the composition into contact with the object to be cleaned is not particularly limited, and examples include hand-wiping cleaning, immersion cleaning (liquid phase cleaning), spray cleaning, ultrasonic cleaning, and vapor cleaning (vapor phase cleaning). Although mention is made, hand-wiping cleaning is preferable. Manual cleaning is usually performed by rubbing the paper, cloth, etc., soaked with the composition, with the hand in contact with the area where the oily dirt is adhered, or with oil-stained paper, cloth, etc., soaked with the composition. This is done by rubbing with a hand through a plate or a rod while making contact with the area where the material adheres. If the oily stain is due to oil-based ink, rubbing the paper, cloth, etc. soaked with the composition with a hand through a flat plate can suppress the occurrence of wiping marks like grooves. it can. The cleaning time corresponding to the contact time of the composition and the object to be cleaned is not particularly limited as long as the oily soil can be removed from the substrate. For example, the cleaning time may be 10 seconds to 2 hours.
実施例で用いた成分は、以下の通りである。
３６５ｍｆｃ：１，１，１，３，３−ペンタフルオロブタン
実施例１〜１３、１６及び１７並びに参考例１４及び１５の洗浄用組成物は、それぞれ、各成分を表２〜６の配合量で混合することにより調製した。
The components used in the examples are as follows.
365 mfc: 1,1,1,3,3-pentafluorobutane Examples 1 to 13, 16 and 17 and cleaning compositions of Reference Examples 14 and 15 were each mixed in the amounts shown in Tables 2 to 6, respectively. Prepared by mixing.
＜（Ａ）鉱物油洗浄試験＞
実施例１〜１３並びに参考例１４及び１５の洗浄用組成物を用いて、洗浄性試験を以下の通り行い、下記評価基準に基づき評価した。結果を表２〜５に示す。
（１）洗浄試験サンプル１の作成
ＳＵＳ４３０のステンレス鋼（縦５０ｍｍ、横５０ｍｍ、厚さ０．５ｍｍ）を、１−ブロモプロパンに１０分以上浸漬した後、乾燥することにより洗浄した。洗浄後の前記ステンレス鋼の表面の縦１５ｍｍ、横３０ｍｍの領域に、鉱物油（プーリーSFオイル：出光興産株式会社製）である鉱物油を丸筆３号（馬毛）を用いて塗布し、洗浄試験サンプル１とした。
<(A) Mineral oil cleaning test>
Using the cleaning compositions of Examples 1 to 13 and Reference Examples 14 and 15, a detergency test was performed as follows and evaluated based on the following evaluation criteria. The results are shown in Tables 2-5.
(1) Preparation of cleaning test sample 1 SUS430 stainless steel (length 50 mm, width 50 mm, thickness 0.5 mm) was immersed in 1-bromopropane for 10 minutes or more and then washed by drying. Applying mineral oil (pulley SF oil: manufactured by Idemitsu Kosan Co., Ltd.) mineral oil to the area of 15 mm in length and 30 mm in width on the surface of the stainless steel after washing using round brush No. 3 (horse hair), A cleaning test sample 1 was obtained.
（２）洗浄試験
２枚重ねのティッシュペーパー（王子ネピア株式会社製）１組を、縦６５ｍｍ、横７２ｍｍの大きさにしたものを、四つ折りにして各実施例の洗浄用組成物を染み込ませ、それを親指と人差し指で１回絞った。
洗浄試験サンプル１の鉱物油が塗布された領域に、前記洗浄用組成物を染み込ませたティッシュペーパーの半分を接触させて手でこすることにより拭いた後、もう一度その領域にティッシュペーパーの残りの半分を接触させて手でこすることにより拭いた。
(2) Cleaning test Two sets of tissue paper (made by Oji Napier Co., Ltd.), one set of 65 mm in length and 72 mm in width, are folded in four and soaked with the cleaning composition of each example. I squeezed it once with my thumb and forefinger.
The area of the cleaning test sample 1 coated with mineral oil is wiped by touching half of the tissue paper soaked with the cleaning composition and rubbing by hand, and then the remaining tissue paper is again applied to the area. Wipe by touching half and rubbing by hand.
（３）評価
洗浄試験後、洗浄試験サンプル１の鉱物油が洗浄されたか否かを目視観察し、以下の基準で評価した。
○：鉱物油の残渣がなく、かつ拭取り跡が残らない。
×：鉱物油の残渣がある、及び／又は拭取り跡が残る。
(3) Evaluation After the cleaning test, whether or not the mineral oil of the cleaning test sample 1 was cleaned was visually observed and evaluated according to the following criteria.
○: There is no residue of mineral oil and no wiping traces remain.
X: There exists a residue of mineral oil and / or a wiping trace remains.
＜（Ｂ）油性インク洗浄試験＞
実施例１６及び１７の洗浄用組成物を用いて洗浄性試験を以下の通り行い、下記評価基準に基づき評価した。結果を表６に示す。
（１）洗浄試験サンプル２の作成
ＳＵＳ４３０のステンレス鋼（縦５０ｍｍ、横５０ｍｍ、厚さ０．５ｍｍ）を、１−ブロモプロパンに１０分以上浸漬した後、乾燥することにより洗浄した。洗浄後の前記ステンレス鋼の表面の縦３０ｍｍ、横１０ｍｍの領域に、油性インク（サクラマーカー極太ＳＧ７ 黒：株式会社サクラクレパス製）を１回塗布した後、５分間室温で放置して乾燥させた。２枚重ねのティッシュペーパー（王子ネピア株式会社製）１組で塗布した領域を拭いても、油性マーカーのインキがティッシュペーパーに付着しないことを確認して、洗浄試験サンプル２とした。
<(B) Oil-based ink cleaning test>
Detergency tests were performed as follows using the cleaning compositions of Examples 16 and 17 and evaluated based on the following evaluation criteria. The results are shown in Table 6.
(1) Preparation of cleaning test sample 2 SUS430 stainless steel (length 50 mm, width 50 mm, thickness 0.5 mm) was immersed in 1-bromopropane for 10 minutes or more and then washed by drying. An oil-based ink (Sakura Marker Extra Thick SG7 Black: manufactured by Sakura Crepas Co., Ltd.) was applied once to a 30 mm long and 10 mm wide area on the surface of the stainless steel after washing, and then allowed to dry at room temperature for 5 minutes. . It was confirmed that the oil marker marker ink did not adhere to the tissue paper even when the region coated with one set of two layers of tissue paper (manufactured by Oji Napier Co., Ltd.) was wiped.
（２）洗浄試験サンプル３の作成
ＳＵＳ４３０のステンレス鋼（縦５０ｍｍ、横２５ｍｍ、厚さ０．５ｍｍ）を、１−ブロモプロパンに１０分以上浸漬した後、乾燥することにより洗浄した。洗浄後の前記ステンレス鋼の表面の縦３０ｍｍ、横８ｍｍの領域に、油性インク（ハイマッキー 黒 太字側：ゼブラ株式会社製）を２回塗布した後、５分間室温で放置して乾燥させた。２枚重ねのティッシュペーパー（王子ネピア株式会社製）１組で塗布した領域を拭いても、油性マーカーのインキがティッシュペーパーに付着しないことを確認して、洗浄試験サンプル３とした。
(2) Preparation of cleaning test sample 3 SUS430 stainless steel (length 50 mm, width 25 mm, thickness 0.5 mm) was immersed in 1-bromopropane for 10 minutes or more and then washed by drying. Oil-based ink (Himacky black bold side: manufactured by Zebra Co., Ltd.) was applied twice to a 30 mm long and 8 mm wide area on the surface of the stainless steel after washing, and then allowed to dry at room temperature for 5 minutes. It was confirmed that the oil marker marker ink did not adhere to the tissue paper even when the region coated with one set of two layers of tissue paper (manufactured by Oji Napier Co., Ltd.) was wiped.
（３）洗浄試験
２枚重ねのティッシュペーパー（王子ネピア株式会社製）１組を、縦５０ｍｍ、横５０ｍｍの大きさにしたものを、四つ折りにして各実施例の洗浄用組成物を染み込ませ、それを親指と人差し指で１回絞った。
洗浄試験サンプル２及び３の油性インクが塗布された領域に、前記洗浄用組成物を染み込ませたティッシュペーパーを接触させてポリプロピレン板を介して手でこすることにより３回拭いた。
(3) Cleaning test Two sets of tissue paper (made by Oji Napier Co., Ltd.), one set of 50 mm in length and 50 mm in width, are folded in four and soaked with the cleaning composition of each example. I squeezed it once with my thumb and forefinger.
The region where the oil-based inks of the cleaning test samples 2 and 3 were applied was wiped three times by bringing the tissue paper soaked with the cleaning composition into contact with the region and rubbing it manually through a polypropylene plate.
（４）評価
洗浄試験後、洗浄試験サンプル２及び３の油性インクが洗浄されたか否かを目視観察し、以下の基準で評価した。
○：油性インクの残渣がなく、かつ拭取り跡が残らない。
×：油性インクの残渣がある、及び／又は拭取り跡が残る。
(4) Evaluation After the cleaning test, whether the oil-based inks of the cleaning test samples 2 and 3 were cleaned was visually observed and evaluated according to the following criteria.
◯: There is no residue of oil-based ink and no wiping traces remain.
X: There is a residue of oil-based ink and / or a wiping trace remains.
表１によれば、ｎ−ヘプタン、イソオクタン及びイソノナンは、引火点が０℃付近又はそれ以上であり、ペンタン及びヘキサンよりもはるかに引火点が高く、安全性が高い。その上、表２〜４によれば、前記引火点の高いアルカン類を含む本発明の組成物は、金属表面に付着した鉱物油の汚れに対し、高い洗浄力を示した。また拭取り跡も残らなかったため乾燥性も良好であった。
また、表５によれば、さらに炭酸ジメチルを含む参考例の組成物は、金属表面に付着した鉱物油の汚れに対し、高い洗浄力を示した。また拭取り跡も残らなかったため乾燥性も良好であった。表６によれば、さらに炭酸ジメチルを含む好ましい態様の本発明の組成物は、金属表面に付着した油性インクの汚れに対し、高い洗浄力を示した。また拭取り跡も残らなかったため乾燥性も良好であった。
According to Table 1, n-heptane, isooctane and isononane have a flash point of around 0 ° C. or higher, and have a much higher flash point than pentane and hexane, and are highly safe. Moreover, according to Tables 2 to 4, the composition of the present invention containing alkanes having a high flash point showed a high detergency against soiling of mineral oil adhering to the metal surface. Moreover, since no wiping trace was left, the drying property was good.
Moreover, according to Table 5, the composition of the reference example further containing dimethyl carbonate showed a high detergency against soiling of mineral oil adhering to the metal surface. Moreover, since no wiping trace was left, the drying property was good. According to Table 6, the composition of the present invention of a preferred embodiment further containing dimethyl carbonate showed high detergency against oil-based ink stains adhering to the metal surface. Moreover, since no wiping trace was left, the drying property was good.
本発明の組成物は、油性汚れの付着した基材から油性汚れを除去するための洗浄剤として産業上極めて有用である。 The composition of the present invention is extremely useful industrially as a cleaning agent for removing oily dirt from a substrate to which oily dirt is adhered.
Claims (7)
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| CN115537832A (en) * | 2022-08-31 | 2022-12-30 | 深圳市鑫承诺环保产业股份有限公司 | Hydrocarbon cleaning agent for cleaning surface of metal piece and preparation method thereof |
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| JP6647269B2 (en) * | 2017-12-21 | 2020-02-14 | 株式会社Ｅｎｅｏｓサンエナジー | Solvent composition |
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