JP6105938B2 - ナトリウム電池 - Google Patents
ナトリウム電池 Download PDFInfo
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- JP6105938B2 JP6105938B2 JP2013000762A JP2013000762A JP6105938B2 JP 6105938 B2 JP6105938 B2 JP 6105938B2 JP 2013000762 A JP2013000762 A JP 2013000762A JP 2013000762 A JP2013000762 A JP 2013000762A JP 6105938 B2 JP6105938 B2 JP 6105938B2
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- Prior art keywords
- weight percent
- oxide
- sodium
- glass
- sealing glass
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 title claims description 38
- 239000011734 sodium Substances 0.000 title claims description 38
- 229910052708 sodium Inorganic materials 0.000 title claims description 38
- 239000005394 sealing glass Substances 0.000 claims description 96
- 239000000203 mixture Substances 0.000 claims description 68
- 239000011521 glass Substances 0.000 claims description 58
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 claims description 32
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 25
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 24
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 23
- 229910052810 boron oxide Inorganic materials 0.000 claims description 19
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims description 19
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 16
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 16
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 15
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 14
- IATRAKWUXMZMIY-UHFFFAOYSA-N strontium oxide Chemical compound [O-2].[Sr+2] IATRAKWUXMZMIY-UHFFFAOYSA-N 0.000 claims description 12
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 11
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 9
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 9
- 239000000292 calcium oxide Substances 0.000 claims description 9
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 9
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 9
- 230000009477 glass transition Effects 0.000 claims description 8
- 229910001507 metal halide Inorganic materials 0.000 claims description 7
- 229910000873 Beta-alumina solid electrolyte Inorganic materials 0.000 claims description 6
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical class [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 claims description 6
- 150000002500 ions Chemical group 0.000 claims description 6
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 claims description 5
- 150000004820 halides Chemical class 0.000 description 23
- 239000000919 ceramic Substances 0.000 description 19
- 230000007797 corrosion Effects 0.000 description 17
- 238000005260 corrosion Methods 0.000 description 17
- 239000000843 powder Substances 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 8
- 239000002775 capsule Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 6
- 239000006060 molten glass Substances 0.000 description 6
- 238000007789 sealing Methods 0.000 description 6
- 239000000377 silicon dioxide Substances 0.000 description 5
- 229910001220 stainless steel Inorganic materials 0.000 description 5
- 239000010935 stainless steel Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 235000012239 silicon dioxide Nutrition 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 229910004298 SiO 2 Inorganic materials 0.000 description 3
- BNOODXBBXFZASF-UHFFFAOYSA-N [Na].[S] Chemical compound [Na].[S] BNOODXBBXFZASF-UHFFFAOYSA-N 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 238000004146 energy storage Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 description 2
- IVORCBKUUYGUOL-UHFFFAOYSA-N 1-ethynyl-2,4-dimethoxybenzene Chemical compound COC1=CC=C(C#C)C(OC)=C1 IVORCBKUUYGUOL-UHFFFAOYSA-N 0.000 description 1
- 229910016523 CuKa Inorganic materials 0.000 description 1
- 241001427367 Gardena Species 0.000 description 1
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000010405 anode material Substances 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000010406 cathode material Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000004320 controlled atmosphere Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000004031 devitrification Methods 0.000 description 1
- ZSFZQNSWHYVSDP-UHFFFAOYSA-G dialuminum;sodium;heptachloride Chemical compound [Na+].[Al+3].[Al+3].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-] ZSFZQNSWHYVSDP-UHFFFAOYSA-G 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012777 electrically insulating material Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000156 glass melt Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- MOWNZPNSYMGTMD-UHFFFAOYSA-N oxidoboron Chemical class O=[B] MOWNZPNSYMGTMD-UHFFFAOYSA-N 0.000 description 1
- RPMPQTVHEJVLCR-UHFFFAOYSA-N pentaaluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3] RPMPQTVHEJVLCR-UHFFFAOYSA-N 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 229910001404 rare earth metal oxide Inorganic materials 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229910052594 sapphire Inorganic materials 0.000 description 1
- 239000010980 sapphire Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- -1 tetrachloroaluminate Chemical compound 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
- 239000002043 β-alumina solid electrolyte Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/12—Silica-free oxide glass compositions
- C03C3/14—Silica-free oxide glass compositions containing boron
- C03C3/145—Silica-free oxide glass compositions containing boron containing aluminium or beryllium
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/12—Silica-free oxide glass compositions
- C03C3/23—Silica-free oxide glass compositions containing halogen and at least one oxide, e.g. oxide of boron
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/20—Compositions for glass with special properties for chemical resistant glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/24—Fusion seal compositions being frit compositions having non-frit additions, i.e. for use as seals between dissimilar materials, e.g. glass and metal; Glass solders
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B37/00—Joining burned ceramic articles with other burned ceramic articles or other articles by heating
- C04B37/003—Joining burned ceramic articles with other burned ceramic articles or other articles by heating by means of an interlayer consisting of a combination of materials selected from glass, or ceramic material with metals, metal oxides or metal salts
- C04B37/005—Joining burned ceramic articles with other burned ceramic articles or other articles by heating by means of an interlayer consisting of a combination of materials selected from glass, or ceramic material with metals, metal oxides or metal salts consisting of glass or ceramic material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/36—Accumulators not provided for in groups H01M10/05-H01M10/34
- H01M10/39—Accumulators not provided for in groups H01M10/05-H01M10/34 working at high temperature
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/36—Accumulators not provided for in groups H01M10/05-H01M10/34
- H01M10/39—Accumulators not provided for in groups H01M10/05-H01M10/34 working at high temperature
- H01M10/3909—Sodium-sulfur cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/36—Accumulators not provided for in groups H01M10/05-H01M10/34
- H01M10/39—Accumulators not provided for in groups H01M10/05-H01M10/34 working at high temperature
- H01M10/3909—Sodium-sulfur cells
- H01M10/3963—Sealing means between the solid electrolyte and holders
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
- C04B2237/02—Aspects relating to interlayers, e.g. used to join ceramic articles with other articles by heating
- C04B2237/10—Glass interlayers, e.g. frit or flux
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
- C04B2237/30—Composition of layers of ceramic laminates or of ceramic or metallic articles to be joined by heating, e.g. Si substrates
- C04B2237/32—Ceramic
- C04B2237/34—Oxidic
- C04B2237/343—Alumina or aluminates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
- C04B2237/50—Processing aspects relating to ceramic laminates or to the joining of ceramic articles with other articles by heating
- C04B2237/76—Forming laminates or joined articles comprising at least one member in the form other than a sheet or disc, e.g. two tubes or a tube and a sheet or disc
- C04B2237/765—Forming laminates or joined articles comprising at least one member in the form other than a sheet or disc, e.g. two tubes or a tube and a sheet or disc at least one member being a tube
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Geochemistry & Mineralogy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Electrochemistry (AREA)
- Ceramic Engineering (AREA)
- Structural Engineering (AREA)
- Glass Compositions (AREA)
- Secondary Cells (AREA)
Description
[実施例]
以下の実施例は単に例示的なものであり、特許請求される発明の範囲に対するいかなる限定とも解釈されるべきでない。特に明記しない限り、すべての成分は、Alpha Aesar, Inc.(Ward Hill、Massachusetts)、Sigma Aldrich(St.Louis、Missouri)、Spectrum Chemical Mfg.Corp.(Gardena、California)などの一般的な化学製品供給業者から市販され得る。
[実施例1]
3つの封着ガラス組成物(試料1〜3)は、表1に示す量の酸化アルミニウム(99.99%、Inframat)、酸化ホウ素(99%、Sigma−Aldrich)、酸化バリウム(97%、Sigma−Aldrich)および酸化ジルコニウム(99%、Sigma−Aldrich)を混合することによって調製した。酸化物成分は、ボールミルにより十分混合した。ボールミルにかけた混合物は、白金るつぼに入れ、空気雰囲気中、約1650℃の温度で約10分間ガラス溶融炉で溶融させ、溶融ガラスを得た。溶融ガラスを室温の空気中で2枚のステンレス鋼板の間で急冷し塊にした。急冷したガラス塊は、約10時間かけてそのガラス転移温度未満で焼きなまし、その後、ガラス塊を粉砕することでガラスフリットにした。次に、結合する2つのセラミック部の間の隙間にガラスフリットを適用し、約1000℃まで加熱し、ガラスシールを形成した。
比較例
比較試料は、実施例1で上記したプロセスと同様のプロセスを用いて、46重量%の二酸化ケイ素、25重量%の酸化ホウ素、10重量%のアルミナ、4重量%の酸化ナトリウム、3重量%の酸化カルシウム、6重量%の酸化バリウムおよび6重量%の酸化ストロンチウムを混合することによって調製した。
20 セパレータチューブ
30 セルケース
40 アノードチャンバ
50 カソードチャンバ
60 絶縁セラミックカラー
70 上端
80 カソード集電体アセンブリ
90 キャップ構造
100 ガラスシール
110 下部
120 上部
Claims (9)
- 30質量パーセントから40質量パーセントの範囲の量で存在する酸化ホウ素と、
20質量パーセントから40質量パーセントの範囲の量で存在する酸化アルミニウムと、
10質量パーセントから35質量パーセントの範囲の量で存在する酸化バリウムと、
13質量パーセントから20質量パーセントの範囲の量で存在する酸化ジルコニウムと、
を含み、
酸化ケイ素および酸化チタンを実質的に含まない、
封着ガラス組成物を組み込んだナトリウム電池。 - 前記ガラス組成物が、前記ナトリウム電池の第1の部品と第2の部品を結合するガラスシールを提供する、請求項1に記載のナトリウム電池。
- 前記第1の部品がイオン伝導性セパレータであり、前記第2の部品が電気絶縁カラーである、請求項2に記載のナトリウム電池。
- 前記第1の部品がβ−アルミナを含み、前記第2の部品がα−アルミナを含む、請求項2に記載のナトリウム電池。
- 前記ガラス組成物が、酸化ナトリウム、酸化カルシウム、酸化ストロンチウム、酸化ナトリウム、酸化イットリウム、またはそれらの組み合わせを含む、請求項1から4のいずれかに記載のナトリウム電池。
- 前記封着ガラス組成物のガラス転移温度が、500℃から700℃の範囲である、請求項1から5のいずれかに記載のナトリウム電池。
- 前記封着ガラス組成物の作業温度が、700℃から1200℃の範囲である、請求項1から5のいずれかに記載のナトリウム電池。
- ナトリウム金属ハロゲン化物電池の形態である、請求項1から7のいずれかに記載のナトリウム電池。
- 30質量パーセントから40質量パーセントの範囲の量で存在する酸化ホウ素と、
20質量パーセントから40質量パーセントの範囲の量で存在する酸化アルミニウムと、
10質量パーセントから35質量パーセントの範囲の量で存在する酸化バリウムと、
13質量パーセントから20質量パーセントの範囲の量で存在する酸化ジルコニウムと、
から実質的に成る封着ガラス組成物を組み込んだナトリウム電池。
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US13/354,101 US9067818B2 (en) | 2012-01-19 | 2012-01-19 | Sealing glass composition and article |
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CN111018351B (zh) * | 2019-12-06 | 2022-03-01 | 西安赛尔电子材料科技有限公司 | 热电池用钛与可伐合金封接玻璃材料及制备方法和应用 |
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Family Cites Families (35)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL38224C (ja) | 1932-04-12 | |||
BE513407A (ja) | 1951-08-15 | |||
FR1336602A (fr) | 1961-10-27 | 1963-08-30 | Ass Elect Ind | Procédé de fabrication d'un verre résistant à l'attaque des vapeurs de métaux alcalins |
US3275358A (en) * | 1963-03-14 | 1966-09-27 | Gen Electric | Glass-to-metal and glass-to-ceramic seals |
US3544330A (en) | 1967-04-24 | 1970-12-01 | Du Pont | Glasses and capacitor dielectric compositions made therefrom |
US3678178A (en) * | 1971-11-18 | 1972-07-18 | Bell Telephone Labor Inc | High temperature compression seal terminal |
US3970464A (en) | 1975-02-10 | 1976-07-20 | Owens-Illinois, Inc. | Silica-free, alkali metal-free and lead-free sealing glasses |
US4190500A (en) | 1978-06-19 | 1980-02-26 | E. I. Du Pont De Nemours And Company | Sodium ion conducting sodium aluminum borate glasses |
US4341849A (en) | 1978-10-24 | 1982-07-27 | General Electric Company | Sodium resistant sealing glasses and sodium-sulfur cells sealed with said glasses |
US4291107A (en) * | 1979-04-19 | 1981-09-22 | Chloride Silent Power Limited | Glass seals for sealing beta-alumina in electro-chemical cells or other energy conversion devices, glasses for use in such seals and cells or other energy conversion devices with such seals |
GB2048237B (en) | 1979-04-19 | 1983-01-12 | Chloride Silent Power Ltd | Glass for sealing beta-alumina in electrochemical cells |
DE3033130A1 (de) | 1980-09-03 | 1982-04-01 | Brown, Boveri & Cie Ag, 6800 Mannheim | Elektrochemische speicherzelle |
US4347295A (en) | 1980-10-09 | 1982-08-31 | Corning Glass Works | Sealing glasses for electrochemical, electrical, electronic, and optical applications |
GB2178589B (en) | 1985-05-21 | 1988-08-17 | Chloride Silent Power Ltd | Composite ceramic structure for use in a sodium sulphur cell |
GB8613796D0 (en) * | 1986-06-06 | 1986-07-09 | Lilliwyte Sa | Electrochemical cell |
US5015530A (en) | 1988-01-21 | 1991-05-14 | The Unites States Of America As Represetned By The United States Department Of Energy | High expansion, lithium corrosion resistant sealing glasses |
US5104738A (en) | 1988-06-01 | 1992-04-14 | The United States Of America As Represented By The United States Department Of Energy | Sealing glasses for titanium and titanium alloys |
US5194337A (en) * | 1990-05-18 | 1993-03-16 | Ngk Insulators, Ltd. | Glass joint body and method of manufacturing the same |
JPH04175271A (ja) * | 1990-07-04 | 1992-06-23 | Ngk Insulators Ltd | ガラス接合体およびその製造法 |
US5158840A (en) | 1991-03-11 | 1992-10-27 | Hughes Aircraft Company | Glass sealing materials for sodium-sulfur batteries and batteries made therewith |
US5134044A (en) | 1991-03-11 | 1992-07-28 | Hughes Aircraft Company | Glass-graphite bonding system for sodium-sulphur batteries and batteries made therefrom |
US5320915A (en) | 1992-12-11 | 1994-06-14 | Hughes Aircraft Company | Glass sealing of electrochemical storage cell structures |
US5478663A (en) | 1994-03-22 | 1995-12-26 | International Fuel Cells Corporation | Edge seals for molten carbonate fuel cell stacks |
JPH09283175A (ja) * | 1996-04-10 | 1997-10-31 | Mitsubishi Heavy Ind Ltd | ナトリウム/溶融塩二次電池 |
JPH09326261A (ja) * | 1996-06-06 | 1997-12-16 | Hitachi Ltd | 高温型二次電池用ガラス材料及びガラス接合体 |
US5693580A (en) | 1996-09-13 | 1997-12-02 | Sandia Corporation | Titanium sealing glasses and seals formed therefrom |
JPH11147733A (ja) | 1997-09-08 | 1999-06-02 | Asahi Glass Co Ltd | ガラス組成物 |
WO2003061034A1 (en) | 2002-01-09 | 2003-07-24 | Alfred E. Mann Foundation For Scientific Research | Hermetic seals for lithium-ion batteries |
US7897530B2 (en) * | 2008-01-14 | 2011-03-01 | Atomic Energy Council-Institute Of Nuclear Energy Research | Glass-ceramic sealant for planar solid oxide fuel cells |
US8603659B2 (en) * | 2008-10-03 | 2013-12-10 | General Electric Company | Sealing glass composition and article |
US8043986B2 (en) * | 2008-11-13 | 2011-10-25 | General Electric Company | Sealing glass composition, method and article |
US8034457B2 (en) | 2008-11-13 | 2011-10-11 | Jian Wu | Seal structure and associated method |
US8334053B2 (en) | 2009-01-09 | 2012-12-18 | General Electric Company | Seal structure and associated method |
US8343661B2 (en) | 2009-11-04 | 2013-01-01 | General Electric Company | Cathode compositions comprising Zn and chalcogenide and energy storage cell comprising same |
DE102010013293A1 (de) * | 2010-03-29 | 2011-09-29 | Schott Ag | Komponenten für Batteriezellen mit anorganischen Bestandteilen geringer thermischer Leitfähigkeit |
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KR102009796B1 (ko) | 2019-08-13 |
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US9067818B2 (en) | 2015-06-30 |
US20130189568A1 (en) | 2013-07-25 |
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