JP6034294B2 - 注射器具 - Google Patents
注射器具 Download PDFInfo
- Publication number
- JP6034294B2 JP6034294B2 JP2013537213A JP2013537213A JP6034294B2 JP 6034294 B2 JP6034294 B2 JP 6034294B2 JP 2013537213 A JP2013537213 A JP 2013537213A JP 2013537213 A JP2013537213 A JP 2013537213A JP 6034294 B2 JP6034294 B2 JP 6034294B2
- Authority
- JP
- Japan
- Prior art keywords
- housing
- spring
- drive
- injection device
- drive spring
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 238000002347 injection Methods 0.000 title claims description 12
- 239000007924 injection Substances 0.000 title claims description 12
- 239000003814 drug Substances 0.000 claims description 8
- 230000000295 complement effect Effects 0.000 claims description 6
- 229940079593 drug Drugs 0.000 claims description 6
- 238000010586 diagram Methods 0.000 description 7
- 238000000034 method Methods 0.000 description 5
- 230000000284 resting effect Effects 0.000 description 3
- 230000036316 preload Effects 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 1
- POIUWJQBRNEFGX-XAMSXPGMSA-N cathelicidin Chemical compound C([C@@H](C(=O)N[C@@H](CCCNC(N)=N)C(=O)N[C@@H](CCCCN)C(=O)N[C@@H](CO)C(=O)N[C@@H](CCCCN)C(=O)N[C@@H](CCC(O)=O)C(=O)N[C@@H](CCCCN)C(=O)N[C@@H]([C@@H](C)CC)C(=O)NCC(=O)N[C@@H](CCCCN)C(=O)N[C@@H](CCC(O)=O)C(=O)N[C@@H](CC=1C=CC=CC=1)C(=O)N[C@@H](CCCCN)C(=O)N[C@@H](CCCNC(N)=N)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](C(C)C)C(=O)N[C@@H](CCC(N)=O)C(=O)N[C@@H](CCCNC(N)=N)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CCCCN)C(=O)N[C@@H](CC(O)=O)C(=O)N[C@@H](CC=1C=CC=CC=1)C(=O)N[C@@H](CC(C)C)C(=O)N[C@@H](CCCNC(N)=N)C(=O)N[C@@H](CC(N)=O)C(=O)N[C@@H](CC(C)C)C(=O)N[C@@H](C(C)C)C(=O)N1[C@@H](CCC1)C(=O)N[C@@H](CCCNC(N)=N)C(=O)N[C@@H]([C@@H](C)O)C(=O)N[C@@H](CCC(O)=O)C(=O)N[C@@H](CO)C(O)=O)NC(=O)[C@H](CC=1C=CC=CC=1)NC(=O)[C@H](CC(O)=O)NC(=O)CNC(=O)[C@H](CC(C)C)NC(=O)[C@@H](N)CC(C)C)C1=CC=CC=C1 POIUWJQBRNEFGX-XAMSXPGMSA-N 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 238000007373 indentation Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229940090048 pen injector Drugs 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M5/00—Devices for bringing media into the body in a subcutaneous, intra-vascular or intramuscular way; Accessories therefor, e.g. filling or cleaning devices, arm-rests
- A61M5/178—Syringes
- A61M5/31—Details
- A61M5/315—Pistons; Piston-rods; Guiding, blocking or restricting the movement of the rod or piston; Appliances on the rod for facilitating dosing ; Dosing mechanisms
- A61M5/31565—Administration mechanisms, i.e. constructional features, modes of administering a dose
- A61M5/31576—Constructional features or modes of drive mechanisms for piston rods
- A61M5/31583—Constructional features or modes of drive mechanisms for piston rods based on rotational translation, i.e. movement of piston rod is caused by relative rotation between the user activated actuator and the piston rod
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M5/00—Devices for bringing media into the body in a subcutaneous, intra-vascular or intramuscular way; Accessories therefor, e.g. filling or cleaning devices, arm-rests
- A61M5/178—Syringes
- A61M5/20—Automatic syringes, e.g. with automatically actuated piston rod, with automatic needle injection, filling automatically
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M5/00—Devices for bringing media into the body in a subcutaneous, intra-vascular or intramuscular way; Accessories therefor, e.g. filling or cleaning devices, arm-rests
- A61M5/178—Syringes
- A61M5/24—Ampoule syringes, i.e. syringes with needle for use in combination with replaceable ampoules or carpules, e.g. automatic
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M5/00—Devices for bringing media into the body in a subcutaneous, intra-vascular or intramuscular way; Accessories therefor, e.g. filling or cleaning devices, arm-rests
- A61M5/178—Syringes
- A61M5/31—Details
- A61M5/315—Pistons; Piston-rods; Guiding, blocking or restricting the movement of the rod or piston; Appliances on the rod for facilitating dosing ; Dosing mechanisms
- A61M5/31533—Dosing mechanisms, i.e. setting a dose
- A61M5/31545—Setting modes for dosing
- A61M5/31548—Mechanically operated dose setting member
- A61M5/3155—Mechanically operated dose setting member by rotational movement of dose setting member, e.g. during setting or filling of a syringe
- A61M5/31553—Mechanically operated dose setting member by rotational movement of dose setting member, e.g. during setting or filling of a syringe without axial movement of dose setting member
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M5/00—Devices for bringing media into the body in a subcutaneous, intra-vascular or intramuscular way; Accessories therefor, e.g. filling or cleaning devices, arm-rests
- A61M5/178—Syringes
- A61M5/24—Ampoule syringes, i.e. syringes with needle for use in combination with replaceable ampoules or carpules, e.g. automatic
- A61M2005/2403—Ampoule inserted into the ampoule holder
- A61M2005/2407—Ampoule inserted into the ampoule holder from the rear
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M5/00—Devices for bringing media into the body in a subcutaneous, intra-vascular or intramuscular way; Accessories therefor, e.g. filling or cleaning devices, arm-rests
- A61M5/178—Syringes
- A61M5/24—Ampoule syringes, i.e. syringes with needle for use in combination with replaceable ampoules or carpules, e.g. automatic
- A61M2005/2485—Ampoule holder connected to rest of syringe
- A61M2005/2488—Ampoule holder connected to rest of syringe via rotation, e.g. threads or bayonet
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M5/00—Devices for bringing media into the body in a subcutaneous, intra-vascular or intramuscular way; Accessories therefor, e.g. filling or cleaning devices, arm-rests
- A61M5/178—Syringes
- A61M5/24—Ampoule syringes, i.e. syringes with needle for use in combination with replaceable ampoules or carpules, e.g. automatic
- A61M2005/2485—Ampoule holder connected to rest of syringe
- A61M2005/2492—Ampoule holder connected to rest of syringe via snap connection
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M2207/00—Methods of manufacture, assembly or production
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M5/00—Devices for bringing media into the body in a subcutaneous, intra-vascular or intramuscular way; Accessories therefor, e.g. filling or cleaning devices, arm-rests
- A61M5/178—Syringes
- A61M5/31—Details
- A61M5/315—Pistons; Piston-rods; Guiding, blocking or restricting the movement of the rod or piston; Appliances on the rod for facilitating dosing ; Dosing mechanisms
- A61M5/31533—Dosing mechanisms, i.e. setting a dose
- A61M5/31545—Setting modes for dosing
- A61M5/31548—Mechanically operated dose setting member
- A61M5/3156—Mechanically operated dose setting member using volume steps only adjustable in discrete intervals, i.e. individually distinct intervals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49826—Assembling or joining
Landscapes
- Health & Medical Sciences (AREA)
- Vascular Medicine (AREA)
- Engineering & Computer Science (AREA)
- Anesthesiology (AREA)
- Biomedical Technology (AREA)
- Heart & Thoracic Surgery (AREA)
- Hematology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Infusion, Injection, And Reservoir Apparatuses (AREA)
Description
使用時に薬剤のシリンジ又はカートリッジを収容するためのハウジングと、
使用時に調節可能なプレセット量だけ回転して、上記シリンジ又はカートリッジから対応する量の薬剤を搾り出す、回転式の駆動軸と、
一端領域は上記駆動軸に対して固定され、他端領域は、使用時に回転可能に係合されるように構成された上記バネと上記ハウジングとについてのそれぞれの相補的な構造によって固定され、係合後は同じ向きにさらに回転しないように構成されている、ねじり駆動バネと
を備える注射器具が提供される。
使用時に薬剤のシリンジ又はカートリッジを収容するためのハウジングと、
上記ハウジング内に配置され、用量設定手順中にバネの力に抗して第1の方向に安静位からプレセットされた角度位置まで回転し、次いで上記駆動軸が解放されてその安静位に戻るときに使用時に搾り出す用量の大きさを決定する、バネで駆動する回転式の駆動軸を含む、駆動機構と
を備える注射器具であって、
上記駆動軸の逆方向への角運動を制限するための停止装置であって、上記ハウジング内に角運動のために取り付けられた中間部材を含み、上記中間部材が上記ハウジングのアバットメント表面と協働するための第1のアバットメント表面と、上記駆動軸のアバットメント表面と協働するための第2のアバットメント表面とを有し、これにより安静位を超えた逆方向への回転が防止される、停止配置を特徴とする、注射器具
が提供される。
Claims (4)
- 薬剤のシリンジ又はカートリッジ(14)を収容するためのハウジング(10)と、
使用時に調節可能なプレセット量だけ回転して、前記シリンジ又はカートリッジから対応する量の薬剤を搾り出す、回転式の駆動軸(20)と、
一端領域が前記駆動軸(20)に対して固定されている駆動バネ(24)と、
前記駆動バネ(24)の他端領域に設けられている接続金具(44)と、
を備え、
前記ハウジングは、後方のドライブハウジング部分の内側の前端を有し、前記内側の前端には環状の端壁(48)が設けられており、その裏面からは前記接続金具(44)のフランジに対して離間している多数のラグ(50)が突出しており、
前記接続金具は、前記駆動バネの他端領域が前記ハウジング(10)に導入されて、前記駆動バネと前記ハウジングとが互いに対して回転する際に、前記接続金具を前記ラグと係合させることにより前記ハウジングのシート(48、50)と回転せずに係合するように構成されている、注射器具。 - 前記接続金具は、つば部(44)を備え、前記つば部と前記シート(48、50)とが、前記シートに対する前記つば部の単一の相対角度位置でのみ完全に係合できるように構成されている、請求項1に記載の注射器具。
- 請求項1に記載の注射器具であって、
前記ハウジングはシートを含み、
前記駆動バネ(24)の前記他端領域は、前記駆動バネと前記ハウジングとについてのそれぞれの相補的な構造によって前記ハウジングのシートと回転せずに係合する、ように構成され、
前記相補的な構造は、使用時に回転可能に係合するように構成され、係合後は同じ向きにさらに回転しないように構成されている、注射器具。 - 請求項1に記載の注射器具であって、
前記駆動バネ(24)は、その他端領域に、前記ハウジングに付随する開口部又はスロットを通り、前記ハウジングの協働部分の周りで引っかけて、前記ハウジングに対して前記バネを固定する構造を有する、注射器具。
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US41110010P | 2010-11-08 | 2010-11-08 | |
GBGB1018827.4A GB201018827D0 (en) | 2010-11-08 | 2010-11-08 | Injection device |
US61/411,100 | 2010-11-08 | ||
GB1018827.4 | 2010-11-08 | ||
PCT/GB2011/052175 WO2012063061A2 (en) | 2010-11-08 | 2011-11-08 | Injection device |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2013542801A JP2013542801A (ja) | 2013-11-28 |
JP6034294B2 true JP6034294B2 (ja) | 2016-11-30 |
Family
ID=43414514
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2013537213A Active JP6034294B2 (ja) | 2010-11-08 | 2011-11-08 | 注射器具 |
Country Status (9)
Country | Link |
---|---|
US (1) | US9381307B2 (ja) |
EP (1) | EP2637718B1 (ja) |
JP (1) | JP6034294B2 (ja) |
CN (1) | CN103249441B (ja) |
BR (1) | BR112013011443A2 (ja) |
DK (1) | DK2637718T3 (ja) |
GB (1) | GB201018827D0 (ja) |
MX (1) | MX349529B (ja) |
WO (1) | WO2012063061A2 (ja) |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB201018827D0 (en) | 2010-11-08 | 2010-12-22 | Owen Mumford Ltd | Injection device |
GB2501897B (en) | 2012-05-09 | 2014-09-03 | Owen Mumford Ltd | Injection devices |
WO2014170177A1 (en) * | 2013-04-18 | 2014-10-23 | Novo Nordisk A/S | Fixation of a torsion spring |
US10864328B2 (en) | 2013-09-03 | 2020-12-15 | Sanofi | Drive mechanism for a drug delivery device |
US20160193420A1 (en) * | 2013-09-03 | 2016-07-07 | Sanofi | Drive mechanism for a drug delivery device |
TW201603850A (zh) * | 2014-07-01 | 2016-02-01 | 賽諾菲公司 | 藥物輸送裝置及其製造方法 |
TW201603847A (zh) * | 2014-07-01 | 2016-02-01 | 賽諾菲公司 | 注射裝置及組裝方法 |
CN106794311A (zh) | 2014-10-08 | 2017-05-31 | 诺和诺德股份有限公司 | 用于注射装置的扭力弹簧和包括这种扭力弹簧的注射装置 |
TW201622762A (zh) | 2014-10-09 | 2016-07-01 | 賽諾菲公司 | 插件及具有該插件的藥物輸送裝置 |
AR102190A1 (es) * | 2014-10-09 | 2017-02-08 | Sanofi Sa | Dispositivo de administración de fármacos |
WO2016146448A1 (en) * | 2015-03-19 | 2016-09-22 | Carebay Europe Ltd | Dose setting mechanism and medicament delivery device comprising the dose setting mechanism |
WO2017055492A1 (en) * | 2015-10-01 | 2017-04-06 | Novo Nordisk A/S | Torsion spring fixation in automatic drug delivery device |
PL414382A1 (pl) | 2015-10-15 | 2017-04-24 | Copernicus Spółka Z Ograniczoną Odpowiedzialnością | Mechanizm nastawczy, w szczególności do dozowania |
CH712146A2 (de) | 2016-02-23 | 2017-08-31 | Tecpharma Licensing Ag | Injektionsvorrichtung mit einem distal eines Dosiseinstellglieds angebrachten Betätigungsglied zur Auslösung der Produktausschüttung. |
US20180015224A1 (en) | 2016-07-13 | 2018-01-18 | California Institute Of Technology | Dampers and Methods for Performing Measurements in an Autoinjector |
CN111447961A (zh) * | 2017-12-04 | 2020-07-24 | 诺和诺德股份有限公司 | 用于基于扭转弹簧的装置的弹簧应变机构 |
US11110227B2 (en) * | 2018-11-09 | 2021-09-07 | Cheryl Muise | Method and apparatus for injecting fluids |
USD1009565S1 (en) | 2021-10-26 | 2024-01-02 | Eric Campos | Shot glass |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB8809115D0 (en) | 1988-04-18 | 1988-05-18 | Turner R C | Syringes |
ES2334046T3 (es) * | 2004-10-21 | 2010-03-04 | Novo Nordisk A/S | Mecanismo de disminucion para pluma regulable. |
PL1819382T3 (pl) | 2004-10-21 | 2010-03-31 | Novo Nordisk As | Urządzenie wstrzykujące ze sprężyną skrętną i obrotowym wskaźnikiem |
DK1843809T3 (en) | 2005-01-21 | 2017-07-31 | Novo Nordisk As | AUTOMATIC INJECTION DEVICE WITH A TOP TRANSMISSION MECHANISM |
PL208660B1 (pl) | 2005-05-25 | 2011-05-31 | Kappa Medilab Społka Z Ograniczoną Odpowiedzialnością | Automatyczny aplikator, zwłaszcza do insuliny |
GB0524604D0 (en) * | 2005-12-02 | 2006-01-11 | Owen Mumford Ltd | Injection method and apparatus |
DE102006038103B4 (de) | 2006-08-14 | 2017-02-23 | Tecpharma Licensing Ag | Injektionsvorrichtung mit variabler Gewindeführung |
MX2009001777A (es) * | 2006-08-18 | 2009-05-22 | Shl Group Ab | Dispositivo para suministrar medicamento que comprende un mecanismo de libracion de presion. |
CN101641126B (zh) * | 2007-03-23 | 2014-06-04 | 诺沃-诺迪斯克有限公司 | 包括锁定螺母的注射装置 |
EP2164544A1 (en) * | 2007-07-06 | 2010-03-24 | Novo Nordisk A/S | Automatic injection device |
DE102007053743A1 (de) * | 2007-11-12 | 2009-06-10 | Tecpharma Licensing Ag | Drehbare Führungshülse mit überspannungsgesicherter Feder |
GB2463034B (en) * | 2008-08-28 | 2012-11-07 | Owen Mumford Ltd | Autoinjection devices |
JP5324654B2 (ja) | 2008-09-09 | 2013-10-23 | エス・ホー・エル・グループ・アクチボラゲット | 薬剤送達装置 |
CN102448525B (zh) | 2009-04-03 | 2014-12-17 | Shl集团有限责任公司 | 药物递送装置 |
ES2443951T3 (es) | 2009-07-08 | 2014-02-21 | Novo Nordisk A/S | Dispositivo de inyección con protección contra congelación |
PL215310B1 (pl) | 2009-10-30 | 2013-11-29 | Kappa Medilab Spolka Z Ograniczona Odpowiedzialnoscia | Automatyczny aplikator, zwlaszcza do insuliny |
GB201018827D0 (en) | 2010-11-08 | 2010-12-22 | Owen Mumford Ltd | Injection device |
GB2501897B (en) | 2012-05-09 | 2014-09-03 | Owen Mumford Ltd | Injection devices |
-
2010
- 2010-11-08 GB GBGB1018827.4A patent/GB201018827D0/en not_active Ceased
-
2011
- 2011-11-08 JP JP2013537213A patent/JP6034294B2/ja active Active
- 2011-11-08 MX MX2013005159A patent/MX349529B/es active IP Right Grant
- 2011-11-08 DK DK11785060.2T patent/DK2637718T3/en active
- 2011-11-08 CN CN201180053435.7A patent/CN103249441B/zh active Active
- 2011-11-08 US US13/883,879 patent/US9381307B2/en active Active
- 2011-11-08 BR BR112013011443A patent/BR112013011443A2/pt not_active IP Right Cessation
- 2011-11-08 EP EP11785060.2A patent/EP2637718B1/en active Active
- 2011-11-08 WO PCT/GB2011/052175 patent/WO2012063061A2/en active Application Filing
Also Published As
Publication number | Publication date |
---|---|
US9381307B2 (en) | 2016-07-05 |
US20130281943A1 (en) | 2013-10-24 |
WO2012063061A9 (en) | 2013-06-06 |
EP2637718A2 (en) | 2013-09-18 |
GB201018827D0 (en) | 2010-12-22 |
WO2012063061A3 (en) | 2012-07-05 |
DK2637718T3 (en) | 2018-06-06 |
EP2637718B1 (en) | 2018-02-21 |
BR112013011443A2 (pt) | 2017-10-31 |
WO2012063061A2 (en) | 2012-05-18 |
JP2013542801A (ja) | 2013-11-28 |
MX349529B (es) | 2017-08-02 |
CN103249441B (zh) | 2016-06-29 |
CN103249441A (zh) | 2013-08-14 |
MX2013005159A (es) | 2013-05-28 |
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