JP6030657B2 - 加水分解アシルハライド化合物を調製するためのインサイチュ法 - Google Patents
加水分解アシルハライド化合物を調製するためのインサイチュ法 Download PDFInfo
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- JP6030657B2 JP6030657B2 JP2014533582A JP2014533582A JP6030657B2 JP 6030657 B2 JP6030657 B2 JP 6030657B2 JP 2014533582 A JP2014533582 A JP 2014533582A JP 2014533582 A JP2014533582 A JP 2014533582A JP 6030657 B2 JP6030657 B2 JP 6030657B2
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/58—Preparation of carboxylic acid halides
- C07C51/62—Preparation of carboxylic acid halides by reactions not involving the carboxylic acid halide group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C201/00—Preparation of esters of nitric or nitrous acid or of compounds containing nitro or nitroso groups bound to a carbon skeleton
- C07C201/06—Preparation of nitro compounds
- C07C201/12—Preparation of nitro compounds by reactions not involving the formation of nitro groups
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Description
式(I):
Claims (5)
- 800ppm未満の水溶解度を有する炭化水素またはハロゲン化炭化水素溶媒を含む溶液において、少なくとも1つのアシルハライド官能基およびカルボン酸官能基を含む反応生成物を調製するための方法であって、
前記反応生成物が、前記溶媒において1重量パーセント未満の溶解限度を有し、前記溶液に可溶性であるままに、前記溶媒内のその溶解限度よりも大きいモル濃度に生成され、かつ
前記溶液が、
i)前記溶媒内の水の溶解限度よりも大きいが、前記溶液による水の溶解限度未満のモル濃度の水、
ii)複数のアシルハライド官能基を含む反応体、ここで、当該反応体のモル濃度は、前記溶媒内の当該反応体の溶解限度よりも小さく、かつ当該反応体と水とのモル比は1:2〜1000:1である、および
iii)前記反応体とのモル比が100:1〜1:1000のトリ−ヒドロカルビルホスフェート化合物
〔ここで、前記トリ−ヒドロカルビルホスフェート化合物は、
と組み合わせて少なくとも80v/v%の溶媒を含む、方法。 - 前記反応体および反応生成物が両方とも300amu(ダルトン)未満の分子量を有する、請求項1に記載の方法。
- 前記反応体および反応生成物が両方とも4〜12個の炭素原子を含む、請求項1に記載の方法。
- 前記溶液が、
i)1重量%未満の濃度の水、
ii)10重量%未満の濃度の前記反応体および
iii)10重量%未満の濃度の前記トリ−ヒドロカルビルホスフェート化合物
を含む、請求項1に記載の方法。 - 前記炭化水素溶媒の水溶解度が150ppm未満である、請求項1に記載の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201161540551P | 2011-09-29 | 2011-09-29 | |
US61/540,551 | 2011-09-29 | ||
PCT/US2012/055264 WO2013048762A1 (en) | 2011-09-29 | 2012-09-14 | In-situ method for preparing hydrolyzed acyl halide compound |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2014534180A JP2014534180A (ja) | 2014-12-18 |
JP2014534180A5 JP2014534180A5 (ja) | 2016-07-07 |
JP6030657B2 true JP6030657B2 (ja) | 2016-11-24 |
Family
ID=46964056
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2014533582A Active JP6030657B2 (ja) | 2011-09-29 | 2012-09-14 | 加水分解アシルハライド化合物を調製するためのインサイチュ法 |
Country Status (8)
Country | Link |
---|---|
EP (1) | EP2731925B1 (ja) |
JP (1) | JP6030657B2 (ja) |
KR (1) | KR102004232B1 (ja) |
CN (1) | CN103958452B (ja) |
ES (1) | ES2544308T3 (ja) |
IL (1) | IL231572A0 (ja) |
IN (1) | IN2014CN02226A (ja) |
WO (1) | WO2013048762A1 (ja) |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103328081B (zh) | 2011-01-24 | 2015-08-19 | 陶氏环球技术有限责任公司 | 复合聚酰胺膜 |
CN103764264B (zh) | 2011-08-31 | 2016-11-16 | 陶氏环球技术有限责任公司 | 源自包含胺反应性官能团和含磷官能团的单体的复合聚酰胺膜 |
WO2013048764A1 (en) | 2011-09-29 | 2013-04-04 | Dow Global Technologies Llc | Method for preparing high purity mono-hydrolyzed acyl halide compound |
WO2013103666A1 (en) | 2012-01-06 | 2013-07-11 | Dow Global Technologies Llc | Composite polyamide membrane |
US9610542B2 (en) | 2012-07-19 | 2017-04-04 | Dow Global Technologies Llc | Composite polyamide membrane with increased carboxylic acid functionality |
CN104918687A (zh) | 2013-01-14 | 2015-09-16 | 陶氏环球技术有限责任公司 | 使用非极性溶剂的掺合物经由界面聚合制造复合聚酰胺膜 |
US9895666B2 (en) | 2013-01-14 | 2018-02-20 | Dow Global Technologies Llc | Composite polyamide membrane made using substituted benzamide monomer |
US9289729B2 (en) | 2013-03-16 | 2016-03-22 | Dow Global Technologies Llc | Composite polyamide membrane derived from carboxylic acid containing acyl halide monomer |
US9051227B2 (en) | 2013-03-16 | 2015-06-09 | Dow Global Technologies Llc | In-situ method for preparing hydrolyzed acyl halide compound |
US9051417B2 (en) | 2013-03-16 | 2015-06-09 | Dow Global Technologies Llc | Method for solubilizing carboxylic acid-containing compound in hydrocarbon solvent |
CN105163837B (zh) | 2013-05-03 | 2017-05-10 | 陶氏环球技术有限责任公司 | 衍生自脂肪族非环状叔胺化合物的复合聚酰胺膜 |
EP3077089B1 (en) | 2013-12-02 | 2018-02-28 | Dow Global Technologies LLC | Method of forming a composite polyamide membrane treated with dihyroxyaryl compounds and nitrous acid |
EP3077088B1 (en) | 2013-12-02 | 2017-12-27 | Dow Global Technologies LLC | Method for forming a composite polyamide membrane post treated with nitrious acid |
KR102289354B1 (ko) | 2014-01-09 | 2021-08-12 | 다우 글로벌 테크놀로지스 엘엘씨 | 높은 산 함량 및 낮은 아조 함량을 갖는 복합 폴리아미드 막 |
CN105848765B (zh) | 2014-01-09 | 2020-02-14 | 陶氏环球技术有限责任公司 | 具有优选偶氮含量的复合聚酰胺膜 |
CN105899283A (zh) | 2014-01-09 | 2016-08-24 | 陶氏环球技术有限责任公司 | 具有偶氮含量和高酸含量的复合聚酰胺膜 |
JP2017513703A (ja) | 2014-04-28 | 2017-06-01 | ダウ グローバル テクノロジーズ エルエルシー | 亜硝酸で後処理される複合ポリアミド膜 |
US9943810B2 (en) | 2014-05-14 | 2018-04-17 | Dow Global Technologies Llc | Composite polyamide membrane post-treated with nitrous acid |
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Publication number | Priority date | Publication date | Assignee | Title |
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DE3001293A1 (de) * | 1980-01-11 | 1981-07-16 | Schering Ag Berlin Und Bergkamen, 1000 Berlin | Ionische 5-c-substitiuerte 2,4,6-trijod-isophtalsaeure-derivete |
JPS5913754A (ja) * | 1982-07-14 | 1984-01-24 | Kuraray Co Ltd | 新規なアミド化合物 |
US5736371A (en) * | 1991-06-04 | 1998-04-07 | A Et S Biovecteurs | Biodegradable particulate vector for transporting molecules having biological activity |
FR2677249B1 (fr) * | 1991-06-04 | 1995-03-17 | Biovecteurs As | Vecteur particulaire biodegradable et procede de synthese. |
-
2012
- 2012-09-14 EP EP12766790.5A patent/EP2731925B1/en active Active
- 2012-09-14 JP JP2014533582A patent/JP6030657B2/ja active Active
- 2012-09-14 IN IN2226CHN2014 patent/IN2014CN02226A/en unknown
- 2012-09-14 KR KR1020147011508A patent/KR102004232B1/ko active IP Right Grant
- 2012-09-14 ES ES12766790.5T patent/ES2544308T3/es active Active
- 2012-09-14 WO PCT/US2012/055264 patent/WO2013048762A1/en active Application Filing
- 2012-09-14 CN CN201280045493.XA patent/CN103958452B/zh active Active
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2014
- 2014-03-18 IL IL231572A patent/IL231572A0/en active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
IL231572A0 (en) | 2014-04-30 |
ES2544308T3 (es) | 2015-08-28 |
CN103958452B (zh) | 2016-01-20 |
CN103958452A (zh) | 2014-07-30 |
IN2014CN02226A (ja) | 2015-06-12 |
EP2731925A1 (en) | 2014-05-21 |
KR102004232B1 (ko) | 2019-07-26 |
KR20140069317A (ko) | 2014-06-09 |
WO2013048762A1 (en) | 2013-04-04 |
EP2731925B1 (en) | 2015-07-08 |
JP2014534180A (ja) | 2014-12-18 |
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