JP6030246B2 - 銅精錬スラグを減少させる方法および装置 - Google Patents
銅精錬スラグを減少させる方法および装置 Download PDFInfo
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- JP6030246B2 JP6030246B2 JP2015545661A JP2015545661A JP6030246B2 JP 6030246 B2 JP6030246 B2 JP 6030246B2 JP 2015545661 A JP2015545661 A JP 2015545661A JP 2015545661 A JP2015545661 A JP 2015545661A JP 6030246 B2 JP6030246 B2 JP 6030246B2
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- slag
- copper
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0002—Preliminary treatment
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0026—Pyrometallurgy
- C22B15/0028—Smelting or converting
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0026—Pyrometallurgy
- C22B15/0028—Smelting or converting
- C22B15/0047—Smelting or converting flash smelting or converting
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0026—Pyrometallurgy
- C22B15/0054—Slag, slime, speiss, or dross treating
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B14/00—Crucible or pot furnaces
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B3/00—Hearth-type furnaces, e.g. of reverberatory type; Tank furnaces
- F27B3/02—Hearth-type furnaces, e.g. of reverberatory type; Tank furnaces of single-chamber fixed-hearth type
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B3/00—Hearth-type furnaces, e.g. of reverberatory type; Tank furnaces
- F27B3/10—Details, accessories, or equipment peculiar to hearth-type furnaces
- F27B3/20—Arrangements of heating devices
- F27B3/205—Burners
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D3/00—Charging; Discharging; Manipulation of charge
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D3/00—Charging; Discharging; Manipulation of charge
- F27D3/0033—Charging; Discharging; Manipulation of charge charging of particulate material
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D7/00—Forming, maintaining, or circulating atmospheres in heating chambers
- F27D7/02—Supplying steam, vapour, gases, or liquids
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D99/00—Subject matter not provided for in other groups of this subclass
- F27D99/0001—Heating elements or systems
- F27D99/0033—Heating elements or systems using burners
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/04—Working-up slag
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B14/00—Crucible or pot furnaces
- F27B2014/002—Smelting process, e.g. sequences to melt a specific material
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B14/00—Crucible or pot furnaces
- F27B2014/002—Smelting process, e.g. sequences to melt a specific material
- F27B2014/004—Process involving a smelting step, e.g. vaporisation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Manufacture And Refinement Of Metals (AREA)
Description
清浄装置内で、銅精錬溶融スラグ、還元剤および加圧不活性ガスを混合して清浄を行い、それにより清浄スラグを得る工程であって、前記不活性ガスは100kPa乃至800kPaの圧力を有する、工程を備える。
炉本体を備え、前記炉本体は、内部に溶融貯まりを備え、ガスノズル、供給口およびスラグ排出口が設けられており、
前記ガスノズルは、炉本体の側壁に配置され、前記溶融貯まりの中間部分につながっている。
前記不活性ガスは、前記ガスノズルを介して前記清浄装置に導入される。
燃料と助燃剤が前記燃料バーナーに導入される。
炉本体を備え、前記炉本体は、内部に溶融貯まりを備え、ガスノズル、供給口およびスラグ排出口が設けられており、前記ガスノズルは、炉本体の側壁に配置され、前記溶融貯まりの中間部分につながっている。
Claims (7)
- 銅精錬溶融スラグを清浄する方法であって:
清浄装置内で、銅精錬溶融スラグ、還元剤および加圧不活性ガスを混合し、清浄を行い、それにより清浄スラグを得る工程であって、前記不活性ガスは100kPa乃至800kPaの圧力を有する、工程を備え;
銅精錬溶融スラグ中で、酸化された状態の銅は、10重量%乃至20重量%の量であり;
前記清浄装置は、炉本体を備え、複数のガスノズルが前記炉本体の側壁に配置され、前記ガスノズルは、溶融貯まりの溶融物中に沈められ、前記溶融貯まりの中間部分に延び、ここで、前記溶融貯まりの前記中間部分とは、形成されたスラグ層に対応する位置をいい、前記ガスノズルは、前記加圧不活性ガスを前記溶融スラグ中に導入することで、溶融スラグを沸騰させ激しい撹拌を生じさせる力を提供し;
前記還元剤は、FeSとCu 2 Sを含有する銅精鉱であり、前記還元剤中の硫黄成分の前記銅精錬溶融スラグ中の酸素成分に対する質量比は、(0.6〜1.5):1である;
方法。 - 前記清浄装置は、
前記炉本体に配置された供給口およびスラグ排出口をさらに備えることを特徴とする;
請求項1の方法。 - 前記銅精錬溶融スラグと前記還元剤はそれぞれ、ランナを通って前記供給口を介して前記清浄装置に導入され;
前記不活性ガスは、前記ガスノズルを介して前記清浄装置に導入されることを特徴とする;
請求項2の方法。 - 前記炉本体には上部に燃料バーナーが設けられ;
燃料と助燃剤が前記燃料バーナーに導入されることを特徴とする;
請求項3の方法。 - 前記助燃剤は、酸素濃度が95重量%より大きな工業用酸素ガスであることを特徴とする;
請求項4の方法。 - 前記不活性ガスは、窒素ガスであることを特徴とする;
請求項1乃至5のいずれか1項の方法。 - 前記銅精錬溶融スラグは、1050℃乃至1350℃の温度であることを特徴とする; 請求項1乃至5のいずれか1項の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310311055.XA CN103334014B (zh) | 2013-07-23 | 2013-07-23 | 铜冶炼熔融炉渣贫化的方法 |
CN201310311055.X | 2013-07-23 | ||
PCT/CN2014/077950 WO2015010500A1 (zh) | 2013-07-23 | 2014-05-21 | 铜冶炼炉渣贫化方法及装置 |
Publications (2)
Publication Number | Publication Date |
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JP2015537121A JP2015537121A (ja) | 2015-12-24 |
JP6030246B2 true JP6030246B2 (ja) | 2016-11-24 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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JP2015545661A Active JP6030246B2 (ja) | 2013-07-23 | 2014-05-21 | 銅精錬スラグを減少させる方法および装置 |
Country Status (8)
Country | Link |
---|---|
US (1) | US9903005B2 (ja) |
EP (1) | EP3026131B1 (ja) |
JP (1) | JP6030246B2 (ja) |
CN (1) | CN103334014B (ja) |
CL (1) | CL2015001670A1 (ja) |
ES (1) | ES2735333T3 (ja) |
RU (1) | RU2633428C2 (ja) |
WO (1) | WO2015010500A1 (ja) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103334014B (zh) | 2013-07-23 | 2016-01-27 | 阳谷祥光铜业有限公司 | 铜冶炼熔融炉渣贫化的方法 |
CN103388082B (zh) * | 2013-07-23 | 2015-05-20 | 阳谷祥光铜业有限公司 | 粗铜的生产方法及用于粗铜生产的生产装置 |
CN105671325A (zh) * | 2016-03-15 | 2016-06-15 | 东北大学 | 一种铜冶炼渣的贫化处理方法 |
CN109055720B (zh) * | 2018-09-06 | 2019-10-25 | 钢研晟华科技股份有限公司 | 一种基于碱法改性和低温硫化还原的铜渣制备铁粉的方法 |
CN110629036A (zh) * | 2019-08-16 | 2019-12-31 | 中国瑞林工程技术股份有限公司 | 连续炼铜设备及炼铜方法 |
CN115141935A (zh) * | 2021-03-29 | 2022-10-04 | 东北大学 | 一种铜精炼渣贫化方法 |
CN115141938A (zh) * | 2021-03-29 | 2022-10-04 | 东北大学 | 一种利用铜精炼熔渣对铜冶炼熔渣进行贫化的方法 |
CN114836630A (zh) * | 2022-03-29 | 2022-08-02 | 中国恩菲工程技术有限公司 | 铜精矿协同处理含铜危废的方法及*** |
CN115012003B (zh) * | 2022-06-20 | 2024-02-06 | 中南大学 | 一种硫化锑矿熔盐电解连续化生产的方法及装置 |
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GB1458269A (en) * | 1973-03-05 | 1976-12-15 | Kennecott Copper Corp | Process of extracting copper and/or molybdenum from ferro- silicate slag |
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AU509658B2 (en) * | 1978-01-26 | 1980-05-22 | Q-S Oxygen Process Ltd. | Treating liquid slag |
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CN103388082B (zh) | 2013-07-23 | 2015-05-20 | 阳谷祥光铜业有限公司 | 粗铜的生产方法及用于粗铜生产的生产装置 |
CN103334014B (zh) | 2013-07-23 | 2016-01-27 | 阳谷祥光铜业有限公司 | 铜冶炼熔融炉渣贫化的方法 |
-
2013
- 2013-07-23 CN CN201310311055.XA patent/CN103334014B/zh active Active
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2014
- 2014-05-21 JP JP2015545661A patent/JP6030246B2/ja active Active
- 2014-05-21 EP EP14830180.7A patent/EP3026131B1/en active Active
- 2014-05-21 US US14/649,800 patent/US9903005B2/en active Active
- 2014-05-21 WO PCT/CN2014/077950 patent/WO2015010500A1/zh active Application Filing
- 2014-05-21 RU RU2015121634A patent/RU2633428C2/ru active
- 2014-05-21 ES ES14830180T patent/ES2735333T3/es active Active
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Also Published As
Publication number | Publication date |
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JP2015537121A (ja) | 2015-12-24 |
CN103334014A (zh) | 2013-10-02 |
EP3026131B1 (en) | 2019-04-17 |
RU2015121634A (ru) | 2017-08-29 |
CN103334014B (zh) | 2016-01-27 |
US20150307959A1 (en) | 2015-10-29 |
WO2015010500A1 (zh) | 2015-01-29 |
EP3026131A1 (en) | 2016-06-01 |
ES2735333T3 (es) | 2019-12-18 |
EP3026131A4 (en) | 2017-03-15 |
RU2633428C2 (ru) | 2017-10-12 |
CL2015001670A1 (es) | 2016-01-15 |
AU2014295665A1 (en) | 2015-07-02 |
US9903005B2 (en) | 2018-02-27 |
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