JP5814265B2 - 無水日焼け防止処方物用の自己適応ポリマー - Google Patents
無水日焼け防止処方物用の自己適応ポリマー Download PDFInfo
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- JP5814265B2 JP5814265B2 JP2012552098A JP2012552098A JP5814265B2 JP 5814265 B2 JP5814265 B2 JP 5814265B2 JP 2012552098 A JP2012552098 A JP 2012552098A JP 2012552098 A JP2012552098 A JP 2012552098A JP 5814265 B2 JP5814265 B2 JP 5814265B2
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
- A61K8/8182—Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/35—Ketones, e.g. benzophenone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8164—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers, e.g. poly (methyl vinyl ether-co-maleic anhydride)
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/90—Block copolymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/91—Graft copolymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
- A61K2800/31—Anhydrous
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Description
本出願は、2010年2月4日付け出願の米国特許仮出願第61/301,469号および2010年2月4日付け出願の米国特許仮出願第61/301,453号の利益を主張し、当該仮出願の全内容をここに参照して援用する。
本発明は、自己適応ポリマーを対象とし、より詳細には無水日焼け防止処方物に用いる自己適応ポリマーを対象とする。他の態様によれば、本発明はまた、日焼け防止組成物または一定のSPF値を必要とする他の組成物を対象とし、当該組成物はそのSPF値をブーストするポリマーを含む。
1.ポリマーの分子量
2.当該ポリマーのモノマーの組成と種類
3.ポリマー全体にわたるモノマーの分布
4.使用する日焼け防止処方物におけるポリマーの溶解性とその残留相
5.ポリマーの電荷密度
γSV=γSL+γLVcosθ
ポリマーのブースト有無による処方物を調製した。これら処方物を以下に示す。これら処方物の吸光度を以下の手順に従い体外で測定した。
1.処方物の標準量(0.8mg/cm2)をPMMAプレート上に塗布し、均一に広げて均一な膜を得た。
2.何らかの測定を行う前に、プレートを15分間平衡になるまで放置した。
3.プレートをlabsphere(DRA-CA-30I)を備えた紫外分光計(Varian 300 UV-VIS)で測定した。
4.透過率スペクトルが生じ、吸収スペクトルに変換した。
5.体外での吸収の増大は、通常SPF値の増大に変換される太陽光線保護の増大に関連する。
Claims (13)
- サンケア剤と、
自己適応ポリマーとを含み、
前記自己適応ポリマーは、ビニルピロリドン(VP)/ビニルカプロラクタム/ジメチルアミノプロピルメタクリルアミド(DMAPA)アクリレートコポリマーであり、
水との接触後に疎水性の増大を示す、紫外光からの皮膚保護用無水組成物であり、
前記自己適応ポリマーが、前記組成物の総重量の0.5重量%〜3.0重量%である、紫外光からの皮膚保護用無水組成物。 - 前記サンケア剤が、UV−A日焼け防止剤、UV−B日焼け防止剤、物理的サンブロッカーおよびそれらの組み合わせからなる群より選択される請求項1に記載の組成物。
- 前記サンケア剤が、アヴォベンゾン、ベンゾフェノン−3、p−アミノ安息香酸(PABA)、カンファーベンズアルコニウムメチル硫酸塩、フェニルベンズイミダゾールスルホン酸、テレフタリデンジカンファースルホン酸、ベンジリデンカンファースルホン酸、オクトクリレン、ポリアクリルアミドメチルベンジリデンカンファー、エチルヘキシルメトキシシンナメート、ポリエチレングリコール(PEG)−25 PABA、イソアミル−p−メトキシシンナメート、エチルヘキシルトリアゾン、ドロメトリゾールトリシロキサン、ジエチルヘキシルブタミドトリアゾン、4−メチルベンジリデンカンファー、3−ベンジリデンカンファー、サリチル酸エチルヘキシル、エチルヘキシルジメチルPABA、ベンゾフェノン−4、ベンゾフェノン−5、メチレンビス−ベンズトリアゾイルテトラメチルブチルフェノール、フェニルジベンズイミダゾールテトラスルホン酸二ナトリウム、ビス−エチルヘキシルオキシフェノールメトキシフェノールトリアジン、ポリシリコーン15、酸化セリウム、酸化クロム、酸化コバルト、酸化鉄、赤色ペトロラタム、シリコーン処理二酸化チタン、二酸化チタン、酸化亜鉛および酸化ジルコニウムならびにこれらの酸、塩、エステル、誘導体および組み合わせからなる群より選択される請求項1に記載の組成物。
- 少なくとも10のSPFを有する請求項1に記載の組成物。
- 前記1種以上のサンケア剤が、組成物の総重量の1重量%〜50重量%の量で存在する請求項1に記載の組成物。
- 前記ポリマーが、組成物の総重量の0.5重量%〜2重量%である請求項1に記載の組成物。
- 前記組成物が、無水溶媒を含む請求項1に記載の組成物。
- 前記組成物が、10%未満の水を含む請求項1に記載の組成物。
- 前記組成物が、水を含まない請求項8に記載の組成物。
- 前記組成物が、浸水後に少なくとも5°の接触角の増大を示す請求項1に記載の組成物。
- 前記組成物が、前記ポリマーを含まない対照組成物と比較して少なくとも50%のSPF値のブーストの増大を示す請求項1に記載の組成物。
- 皮膚感触添加剤、保湿剤、塗膜形成剤、耐水剤、pH調節剤、キレート剤、乳化剤、防腐剤およびこれらの組み合わせからなる群より選択される1種以上の追加成分をさらに含む請求項1に記載の組成物。
- 噴霧可能な組成物の形態である請求項1に記載の組成物。
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US30145310P | 2010-02-04 | 2010-02-04 | |
US30146910P | 2010-02-04 | 2010-02-04 | |
US61/301,469 | 2010-02-04 | ||
US61/301,453 | 2010-02-04 | ||
PCT/US2011/023701 WO2011097448A1 (en) | 2010-02-04 | 2011-02-04 | Self adapting polymers for anhydrous sunscreen formulations |
Publications (2)
Publication Number | Publication Date |
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JP2013518898A JP2013518898A (ja) | 2013-05-23 |
JP5814265B2 true JP5814265B2 (ja) | 2015-11-17 |
Family
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Application Number | Title | Priority Date | Filing Date |
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JP2012552098A Active JP5814265B2 (ja) | 2010-02-04 | 2011-02-04 | 無水日焼け防止処方物用の自己適応ポリマー |
Country Status (10)
Country | Link |
---|---|
US (1) | US10729625B2 (ja) |
EP (1) | EP2531168B1 (ja) |
JP (1) | JP5814265B2 (ja) |
KR (1) | KR20120112849A (ja) |
CN (1) | CN102781404B (ja) |
AU (1) | AU2011212859B2 (ja) |
BR (1) | BR112012019631B1 (ja) |
CA (1) | CA2788691C (ja) |
MX (1) | MX351010B (ja) |
WO (1) | WO2011097448A1 (ja) |
Families Citing this family (8)
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US8697035B2 (en) | 2010-07-14 | 2014-04-15 | Neutrogena Corporation | Skin care compositions |
US20130078201A1 (en) * | 2011-09-28 | 2013-03-28 | Susan Daly | Topical sunscreen compositions |
WO2014152096A1 (en) * | 2013-03-15 | 2014-09-25 | Suncare Research Laboratories, Llc | In vitro determination of sunscreen protection based on image analysis of sunscreens applied to skin |
US10092494B2 (en) * | 2015-09-14 | 2018-10-09 | Edgewell Personal Care Brands, Llc. | Sunscreen compositions with improved water resistance of UVA sunscreen active agents |
JP6883943B2 (ja) * | 2015-12-14 | 2021-06-09 | 花王株式会社 | 評価方法、評価装置及びプログラム |
BR112020018029A2 (pt) | 2018-04-05 | 2020-12-22 | Beiersdorf Ag | Composição cosmética para pré-condicionamento da pele |
KR102073635B1 (ko) * | 2018-07-23 | 2020-02-06 | 주식회사 초이스엔텍 | 에탄올을 포함하는 자외선 차단용 화장료 조성물 |
KR102313519B1 (ko) * | 2020-06-03 | 2021-10-15 | 주식회사 엘지생활건강 | 열과 자외선에 의해 자외선 차단 효율이 상승하는 자외선 차단용 화장료 조성물 |
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US5026540A (en) * | 1987-06-04 | 1991-06-25 | Chesebrough-Pond's Usa Co. | Sunscreen composition |
US5558071A (en) * | 1994-03-07 | 1996-09-24 | Combustion Electromagnetics, Inc. | Ignition system power converter and controller |
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IL134830A0 (en) * | 2000-03-01 | 2001-05-20 | Chay 13 Medical Res Group N V | Peptides and immunostimulatory and anti-bacterial pharmaceutical compositions containing them |
CA2402733A1 (en) * | 2000-03-14 | 2001-09-20 | Burkhard Goke | Effects of glucagon-like peptide-1 (7-36) on antro-pyloro-duodenal motility |
US6706674B2 (en) * | 2001-01-17 | 2004-03-16 | The Andrew Jergens Company | Nonaqueous hair styling composition and method of use |
US6436376B1 (en) | 2001-02-26 | 2002-08-20 | Societe L'oreal S.A. | Enhanced SPF UV-sunscreen/tricontanyl PVP photoprotecting (sprayable) formulations |
EP1245240A1 (en) * | 2001-03-30 | 2002-10-02 | The Procter & Gamble Company | Skin-compatible hydrogel adhesives and personal care products containing them |
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EP2054017B1 (en) | 2006-08-24 | 2011-10-12 | Unilever PLC | Photostable cosmetic compositions |
US8461129B2 (en) * | 2006-09-25 | 2013-06-11 | Archer Daniels Midland Company | Superabsorbent surface-treated carboxyalkylated polysaccharides and process for producing same |
US9149664B2 (en) * | 2007-01-31 | 2015-10-06 | Akzo Nobel N.V. | Sunscreen compositions |
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US20090035234A1 (en) * | 2007-07-31 | 2009-02-05 | Kimberly-Clark Worldwide, Inc. | Continuous spray sunscreen compositions |
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CN102164579B (zh) * | 2008-09-25 | 2014-10-15 | 赛福伦公司 | 苯达莫司汀的液体配制品 |
US20100272658A1 (en) * | 2009-04-27 | 2010-10-28 | Akzo Nobel Chemicals International B.V. | Enhanced efficiency of sunscreen compositions |
DE102009020553A1 (de) * | 2009-05-08 | 2010-11-11 | Henkel Ag & Co. Kgaa | Polymerkombination aus mindestens zwei verschiedenen N-Vinylpyrrolidon/N-Vinylcaprolactam-Copolymeren für glanzgebende kosmetische Haarbehandlungsmittel |
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- 2011-02-04 CN CN201180012143.9A patent/CN102781404B/zh active Active
- 2011-02-04 WO PCT/US2011/023701 patent/WO2011097448A1/en active Application Filing
- 2011-02-04 CA CA2788691A patent/CA2788691C/en active Active
- 2011-02-04 US US13/575,530 patent/US10729625B2/en active Active
- 2011-02-04 AU AU2011212859A patent/AU2011212859B2/en active Active
- 2011-02-04 EP EP11740402.0A patent/EP2531168B1/en active Active
- 2011-02-04 KR KR1020127022745A patent/KR20120112849A/ko not_active Application Discontinuation
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Also Published As
Publication number | Publication date |
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KR20120112849A (ko) | 2012-10-11 |
MX2012008868A (es) | 2012-08-31 |
BR112012019631A2 (pt) | 2018-06-19 |
AU2011212859B2 (en) | 2014-05-08 |
CN102781404B (zh) | 2014-08-27 |
US20130243703A1 (en) | 2013-09-19 |
CA2788691C (en) | 2017-11-07 |
MX351010B (es) | 2017-09-28 |
EP2531168A4 (en) | 2015-12-09 |
EP2531168B1 (en) | 2019-10-30 |
CN102781404A (zh) | 2012-11-14 |
US10729625B2 (en) | 2020-08-04 |
AU2011212859A1 (en) | 2012-08-23 |
EP2531168A1 (en) | 2012-12-12 |
BR112012019631B1 (pt) | 2019-04-30 |
JP2013518898A (ja) | 2013-05-23 |
WO2011097448A1 (en) | 2011-08-11 |
CA2788691A1 (en) | 2011-08-11 |
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