JP5731492B2 - 蒸着コーティングを用いて製造された疎水性材料及びその応用 - Google Patents
蒸着コーティングを用いて製造された疎水性材料及びその応用 Download PDFInfo
- Publication number
- JP5731492B2 JP5731492B2 JP2012514954A JP2012514954A JP5731492B2 JP 5731492 B2 JP5731492 B2 JP 5731492B2 JP 2012514954 A JP2012514954 A JP 2012514954A JP 2012514954 A JP2012514954 A JP 2012514954A JP 5731492 B2 JP5731492 B2 JP 5731492B2
- Authority
- JP
- Japan
- Prior art keywords
- silicone
- hydrophobic material
- producing
- natural mineral
- hydrophobic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000463 material Substances 0.000 title claims description 47
- 230000002209 hydrophobic effect Effects 0.000 title claims description 45
- 238000000576 coating method Methods 0.000 title claims description 38
- 238000007740 vapor deposition Methods 0.000 title claims description 22
- 239000011248 coating agent Substances 0.000 title claims description 20
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 64
- 239000011707 mineral Substances 0.000 claims description 64
- 229920001296 polysiloxane Polymers 0.000 claims description 46
- 229920002379 silicone rubber Polymers 0.000 claims description 34
- 239000004945 silicone rubber Substances 0.000 claims description 33
- 229910001562 pearlite Inorganic materials 0.000 claims description 27
- 235000019362 perlite Nutrition 0.000 claims description 23
- 239000010451 perlite Substances 0.000 claims description 22
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 20
- -1 polysiloxane Polymers 0.000 claims description 19
- 239000002210 silicon-based material Substances 0.000 claims description 18
- 239000010455 vermiculite Substances 0.000 claims description 17
- 229910052902 vermiculite Inorganic materials 0.000 claims description 17
- 235000019354 vermiculite Nutrition 0.000 claims description 17
- 238000010438 heat treatment Methods 0.000 claims description 16
- 238000004519 manufacturing process Methods 0.000 claims description 16
- 239000008262 pumice Substances 0.000 claims description 13
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 238000004132 cross linking Methods 0.000 claims description 5
- 238000000151 deposition Methods 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- 235000012239 silicon dioxide Nutrition 0.000 claims description 5
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 3
- 229910021536 Zeolite Inorganic materials 0.000 claims description 3
- 150000004645 aluminates Chemical class 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 3
- 239000010457 zeolite Substances 0.000 claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
- 239000000440 bentonite Substances 0.000 claims description 2
- 229910000278 bentonite Inorganic materials 0.000 claims description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 2
- 239000003054 catalyst Substances 0.000 claims description 2
- 238000001816 cooling Methods 0.000 claims description 2
- 238000005520 cutting process Methods 0.000 claims description 2
- 238000005229 chemical vapour deposition Methods 0.000 claims 1
- 238000005240 physical vapour deposition Methods 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 51
- 239000003921 oil Substances 0.000 description 40
- 235000019198 oils Nutrition 0.000 description 40
- 239000002245 particle Substances 0.000 description 31
- 238000000034 method Methods 0.000 description 25
- 239000010410 layer Substances 0.000 description 19
- 239000000843 powder Substances 0.000 description 18
- 239000004205 dimethyl polysiloxane Substances 0.000 description 14
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 10
- 239000000839 emulsion Substances 0.000 description 7
- 239000011148 porous material Substances 0.000 description 7
- 239000008158 vegetable oil Substances 0.000 description 7
- 239000004567 concrete Substances 0.000 description 6
- 239000010440 gypsum Substances 0.000 description 6
- 229910052602 gypsum Inorganic materials 0.000 description 6
- 239000005909 Kieselgur Substances 0.000 description 5
- 239000004035 construction material Substances 0.000 description 5
- 239000011521 glass Substances 0.000 description 5
- 235000015112 vegetable and seed oil Nutrition 0.000 description 5
- 239000010775 animal oil Substances 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- 230000002940 repellent Effects 0.000 description 4
- 239000005871 repellent Substances 0.000 description 4
- 239000008399 tap water Substances 0.000 description 4
- 235000020679 tap water Nutrition 0.000 description 4
- 230000002745 absorbent Effects 0.000 description 3
- 239000002250 absorbent Substances 0.000 description 3
- 239000004927 clay Substances 0.000 description 3
- 239000011247 coating layer Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 239000000806 elastomer Substances 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 239000008206 lipophilic material Substances 0.000 description 3
- 150000004706 metal oxides Chemical class 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000004570 mortar (masonry) Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 230000008901 benefit Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000003776 cleavage reaction Methods 0.000 description 2
- 239000010779 crude oil Substances 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000007667 floating Methods 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 239000003350 kerosene Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 229920005573 silicon-containing polymer Polymers 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 239000002569 water oil cream Substances 0.000 description 2
- 230000004580 weight loss Effects 0.000 description 2
- 241000195493 Cryptophyta Species 0.000 description 1
- 206010067482 No adverse event Diseases 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 239000004965 Silica aerogel Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000012237 artificial material Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000011362 coarse particle Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000006837 decompression Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 239000010437 gem Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 210000003097 mucus Anatomy 0.000 description 1
- 239000000346 nonvolatile oil Substances 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 125000005625 siliconate group Chemical group 0.000 description 1
- 229920006268 silicone film Polymers 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- CCEKAJIANROZEO-UHFFFAOYSA-N sulfluramid Chemical group CCNS(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F CCEKAJIANROZEO-UHFFFAOYSA-N 0.000 description 1
- 239000013077 target material Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 238000005019 vapor deposition process Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/48—Macromolecular compounds
- C04B41/488—Other macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D17/00—Separation of liquids, not provided for elsewhere, e.g. by thermal diffusion
- B01D17/02—Separation of non-miscible liquids
- B01D17/04—Breaking emulsions
- B01D17/048—Breaking emulsions by changing the state of aggregation
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
- C23C28/34—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D17/00—Separation of liquids, not provided for elsewhere, e.g. by thermal diffusion
- B01D17/02—Separation of non-miscible liquids
- B01D17/04—Breaking emulsions
- B01D17/045—Breaking emulsions with coalescers
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/288—Treatment of water, waste water, or sewage by sorption using composite sorbents, e.g. coated, impregnated, multi-layered
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/68—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
- C02F1/681—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water by addition of solid materials for removing an oily layer on water
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/02—Treatment
- C04B20/04—Heat treatment
- C04B20/06—Expanding clay, perlite, vermiculite or like granular materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/10—Coating or impregnating
- C04B20/1051—Organo-metallic compounds; Organo-silicon compounds, e.g. bentone
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/4584—Coating or impregnating of particulate or fibrous ceramic material
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/10—Glass or silica
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
- C23C16/42—Silicides
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/32—Hydrocarbons, e.g. oil
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/32—Nature of the water, waste water, sewage or sludge to be treated from the food or foodstuff industry, e.g. brewery waste waters
- C02F2103/322—Nature of the water, waste water, sewage or sludge to be treated from the food or foodstuff industry, e.g. brewery waste waters from vegetable oil production, e.g. olive oil production
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
- Y10T428/249967—Inorganic matrix in void-containing component
- Y10T428/249969—Of silicon-containing material [e.g., glass, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/263—Coating layer not in excess of 5 mils thick or equivalent
- Y10T428/264—Up to 3 mils
- Y10T428/265—1 mil or less
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31652—Of asbestos
- Y10T428/31663—As siloxane, silicone or silane
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Hydrology & Water Resources (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Paints Or Removers (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Aftertreatments Of Artificial And Natural Stones (AREA)
Description
約十グラム(10g)のDow Corning's Sylgard(登録商標)184パートA及び1gのパートBをビニール製容器内で混ぜ、硬化するまで室温に約48時間放置した。硬化シリコーンゴムはビニール製容器から取り除かれ、各々約1gの重さの小さな片に切断される。その後、硬化シリコーンゴム1g及び粒径が3mmから6mmの膨張パーライト1gを、カバーされたガラス板の中に入れ、これを加熱炉内でデジタルサーモメータを用いて約250℃で、約10分間加熱してサンプルAを作成し、約30分間加熱してサンプルBを作成し、約60分間加熱してサンプルCを作成する。三つのサンプルは、約100mlの水道水中に約5分間沈められ、水から取り出される。水に沈められる前及び水から取り出された後にサンプルの重さを測定し、増加した重さがサンプルに保持された水を示す。サンプルAは約20%増加し、サンプルB及びCは約5%増加したことが観測された。同じセットの実験において別の回では増加した重さがわずかに変化した。
例1で作成された硬化シリコーンゴムを用いる。1gのPDMS及びさまざまな量の膨張パーライトをカバーされたガラス容器にそれぞれ入れ、約250℃で約30分間加熱した。サンプルAは1gのパーライトを有する。サンプルBは2gのパーライトを有し、サンプルCは5gのパーライトを有する。コーティングされたパーライトA、B及びCの間で水分保持能力に大きな差はみられなかった。
例1で作成された硬化シリコーンゴムを用いる。約1gのPDMS及び1gの膨張パーライトをカバーされたガラス容器にそれぞれ入れ、異なる温度で約30分間加熱した。サンプルAは100℃で加熱した。サンプルBは150℃で加熱した。サンプルCは200℃で加熱した。サンプルDは250℃で加熱した。サンプルEは300℃で加熱した。サンプルFは350℃で加熱した。サンプルGは400℃で加熱した。7つのサンプルを、約100mlの水道水に5分間沈め、水から取り出した。サンプルの重さを水に沈められる前と水から取り出した後で測定し、増加した重さがサンプルに保持された水を示す。サンプルAは約250%増加し、サンプルBは約210%増加し、サンプルCは約130%増加し、サンプルD,E、F及びGは約5%から10%増加した。さらに、サンプルE及びFで用いられたPDMSは30分後に摩耗の兆候を示し、サンプルGに用いられたPDMSはすぐに摩滅した。
例1で製造された硬化シリコーンゴム及び細かくすり潰された珪藻土粉末を用いる。硬化シリコーンゴム及びすり潰された珪藻土粉末を約250℃で30分間加熱する。コーティングされた珪藻土粉末を100mlの水道水に入れ、かき混ぜた。コーティングされた粉末と水の混合は目視で確認されなかった。コーティングされた粉末を水面に約一カ月放置した後も、粉末と水の混合は観測されなかった。
この例では、コーティングされた膨張パーライトの油吸収性を実証する。水道水10mlと植物油0.5mlを24mlのガラス製薬瓶の中で混ぜて油−水エマルションを作成する。目視による効果の観測を容易にするために油を青色溶剤で染める。薬瓶を30秒間力強く振る。その後、エマルションの表面に例2で作成されたコーティングされた膨張パーライト粒子を0.2g入れる。再び薬瓶を30秒間振る。ほとんどの油がシリコーンでコーティングされた膨張パーライトにより吸収され、目視で確認したところ水中に青色の痕跡はなかった。油にまみれた膨張パーライトは依然として水面上に浮いていた。
コーティングされたパーライトの代わりにシリコーンでコーティングされた軽石粉末を使用する以外は、例5と同じである。軽石粉末はほとんどの油を吸収し、凝集して大きな塊となり、水の底に沈んだ。
例5の油にまみれたパーライト粒子を水から取り除き、室温で乾燥した後、99.9%エタノール10mlが入った薬瓶の中に入れる。パーライトから油が解放されてエタノールの底に沈んだ。パーライト粒子はその後エタノールから除去し、60℃で乾燥した。得られたパーライトは依然として疎水性及び親油性の特徴を示した。
例2で作成されたシリコーンゴムでコーティングされたパーライト粒子二グラム(2g)を、直径5cmのこし器に入れ、コレクタをこし器の下に置いた。例5で作成された油−水エマルションをコーティングされたパーライトの上に注いだ。こし器の下のコレクタにより収集された水には、油の痕跡は目視で確認されなかった。
Claims (8)
- 疎水性材料の製造方法において、
パーライト又はバーミキュライトを含む多孔質天然鉱物を準備する工程と、
ポリシロキサンの加硫処理された網状構造を含むシリコーン系材料を準備する工程と、
前記シリコーン系材料を密閉容器内で加熱して前記シリコーン系材料の蒸気分子を放出させる工程と、
前記シリコーン系材料の前記蒸気分子を堆積させることにより前記天然鉱物の表面上に疎水性材料の層を形成する工程と、を含み、
前記製造方法が、触媒又は硬化剤の非存在下で行われ、
前記シリコーン系材料を加熱する工程が架橋反応を引き起こし、
前記シリコーン系材料を加熱する工程が切断反応を引き起こす
ことを特徴とする疎水性材料の製造方法。 - 前記シリコーン系材料は、次の天然鉱物へのコーティングに再使用することができ、前記シリコーン系材料が再生シリコーンゴムであることを特徴とする請求項1に記載の疎水性材料の製造方法。
- 前記シリコーン系材料を加熱する工程が、100℃以上400℃以下の所定温度に加熱することを特徴とする請求項1又は2に記載の疎水性材料の製造方法。
- 前記シリコーン系材料を加熱する工程が、蒸着時の圧力が0.5気圧以上2気圧以下となるよう加熱することを特徴とする請求項3に記載の疎水性材料の製造方法。
- 前記パーライト又はバーミキュライトを含む天然鉱物を準備する工程が、
前記パーライト又はバーミキュライトを含む天然鉱物を加熱炉内で760℃以上980℃以下の温度に加熱して膨張させる工程と、
膨張した前記天然鉱物を空気圧でサイクロン分級機に運ぶ工程と、
分級された前記天然鉱物を収集装置で収集する工程と、
前記分級された天然鉱物を100℃以上400℃以下の温度に冷却する工程と、を含む
ことを特徴とする請求項1〜4の何れか一項に記載の疎水性材料の製造方法。 - 前記蒸気分子を堆積させる工程が、物理的蒸着、化学的蒸着及びプラズマ蒸着のうちの少なくとも一つを含むことを特徴とする請求項1〜5の何れか一項に記載の疎水性材料の製造方法。
- 前記多孔質天然鉱物が、軽石、珪藻岩、ベントナイト及びゼオライトのうちの少なくとも一つを含むことを特徴とする請求項1〜6の何れか一項に記載の疎水性材料の製造方法。
- 前記多孔質天然鉱物が、二酸化ケイ素、酸化アルミニウム、ケイ酸塩、アルミン酸塩及び炭酸塩のうちの少なくとも一つから構成されることを特徴とする請求項1〜7の何れか一項に記載の疎水性材料の製造方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/480,598 US8673393B2 (en) | 2009-06-08 | 2009-06-08 | Hydrophobic materials made by vapor deposition coating and applications thereof |
US12/480,598 | 2009-06-08 | ||
PCT/US2010/027693 WO2010144167A1 (en) | 2009-06-08 | 2010-03-17 | Hydrophobic materials made by vapor deposition coating and applications thereof |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2012529420A JP2012529420A (ja) | 2012-11-22 |
JP2012529420A5 JP2012529420A5 (ja) | 2013-05-02 |
JP5731492B2 true JP5731492B2 (ja) | 2015-06-10 |
Family
ID=43309151
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2012514954A Active JP5731492B2 (ja) | 2009-06-08 | 2010-03-17 | 蒸着コーティングを用いて製造された疎水性材料及びその応用 |
Country Status (6)
Country | Link |
---|---|
US (2) | US8673393B2 (ja) |
EP (1) | EP2440402A4 (ja) |
JP (1) | JP5731492B2 (ja) |
KR (1) | KR20120044967A (ja) |
CN (2) | CN102448719B (ja) |
WO (1) | WO2010144167A1 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101579143B1 (ko) * | 2015-09-21 | 2015-12-23 | 케이알엠건설 주식회사 | 친환경 그라우트 조성물과 이를 이용한 그라우팅 시공공법 |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9811130B2 (en) | 2011-09-12 | 2017-11-07 | The Boeing Company | Power management control system |
KR101462726B1 (ko) * | 2012-10-05 | 2014-11-21 | 성균관대학교산학협력단 | 분말 입자 또는 섬유 표면에 실리콘-탄소 복합체가 코팅된 것을 특징으로 하는 기름 및 유기물 제거용 초소수성 분말입자 또는 섬유 |
KR101486058B1 (ko) * | 2013-05-27 | 2015-01-23 | 박종길 | 수지조성물 및 이의 제조방법 |
JP2016012638A (ja) * | 2014-06-27 | 2016-01-21 | パナソニックIpマネジメント株式会社 | 太陽電池モジュールの製造方法、透光基板の製造方法及び太陽電池モジュール |
CN104927771B (zh) * | 2015-06-15 | 2017-06-30 | 安徽联合安全科技有限公司 | 一种延长环保融雪剂发挥融雪作用时间的方法 |
JP2019529606A (ja) * | 2016-09-08 | 2019-10-17 | モアハウス スクール オブ メディスンMorehouse School Of Medicine | 洗浄組成物、その製造および使用方法 |
US10604729B2 (en) | 2016-09-08 | 2020-03-31 | Morehouse School Of Medicine | Liquid loading composition, method of making and use thereof |
NO345092B1 (no) * | 2017-03-17 | 2020-09-28 | M Vest Water As | Fremgangsmåte for fremstilling og anvendelse av produkt for fjerning av forurensing i vann |
NO345142B1 (no) * | 2017-03-17 | 2020-10-19 | M Vest Water As | Et oljekoaliserende granulert medieprodukt, og fremgangsmåte for fremstilling og anvendelse av et slikt produkt |
KR20190030261A (ko) * | 2017-09-13 | 2019-03-22 | 국민대학교산학협력단 | 유분 부착 방지를 위한 환풍기 및 이의 제조 방법 |
US20190169444A1 (en) * | 2017-12-04 | 2019-06-06 | Applied Materials, Inc. | Anti-wetting coating |
CN108553693A (zh) * | 2018-05-17 | 2018-09-21 | 江汉大学 | 抗革兰氏阳性菌涂层的制备方法及包含涂层的医疗器械 |
KR101957367B1 (ko) * | 2018-10-04 | 2019-03-13 | 신우산업주식회사 | 상하수도용 내구성 강화 합성수지관 제조방법 |
JP7308040B2 (ja) * | 2018-12-26 | 2023-07-13 | 三菱瓦斯化学株式会社 | 無機多孔質体よりなる油吸着剤、及びその製造方法 |
CN109824269A (zh) * | 2019-03-27 | 2019-05-31 | 蔡连和 | 一种硅藻釉料及利用硅藻釉料制造硅藻釉砖的方法 |
US11921259B2 (en) * | 2019-04-17 | 2024-03-05 | Apple Inc. | Oleophobic coatings for glass structures in electronic devices |
CN110586050A (zh) * | 2019-09-18 | 2019-12-20 | 天津大学 | 用于VOCs吸附的疏水Y分子筛及其制备方法 |
CN114504844B (zh) * | 2020-10-28 | 2023-08-08 | 中国石油化工股份有限公司 | 一种聚结材料及其制备方法和除油方法 |
CN114477194B (zh) * | 2022-01-18 | 2023-09-05 | 中国科学院工程热物理研究所 | 基于化学气相沉积制备疏水性二氧化硅气凝胶的方法 |
Family Cites Families (37)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2040818A (en) * | 1932-07-29 | 1936-05-19 | Johns Manville | Coated diatomaceous earth product and method of making the same |
DE1195220B (de) | 1964-11-13 | 1965-06-16 | Perlite G M B H Deutsche | Verwendung von Perlite zum Aufsaugen von auf Wasser schwimmendem OEl |
US3447789A (en) | 1967-05-31 | 1969-06-03 | Chemrock Corp | Portable perlite handling apparatus and method |
US3630891A (en) | 1969-02-28 | 1971-12-28 | Conwed Corp | Method of removing oil from the surface of water |
US4022152A (en) * | 1969-03-29 | 1977-05-10 | Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler | Apparatus for making particulate materials, particularly oxides, hydrophobic |
US3562153A (en) | 1970-02-05 | 1971-02-09 | Cabot Corp | Oil absorbent compositions |
US3696051A (en) | 1970-10-01 | 1972-10-03 | Gulf Research Development Co | Method of removing oil from the surface of water and composition therefor |
US4011175A (en) | 1973-09-28 | 1977-03-08 | Paul Preus | Composition for separating hydrocarbons from water |
JPS5275682A (en) | 1975-12-19 | 1977-06-24 | Agency Of Ind Science & Technol | Oil adsorbent |
US4175159A (en) | 1978-07-31 | 1979-11-20 | General Electric Company | Silicone emulsions for treating silicate particulate matter |
US4255489A (en) | 1979-03-12 | 1981-03-10 | Grefco, Inc. | Perlite filler |
US4525388A (en) * | 1983-12-23 | 1985-06-25 | Usg Corporation | Process for expanding and coating perlite |
JPS61268763A (ja) * | 1984-11-26 | 1986-11-28 | Shiseido Co Ltd | 処理粉体の製造方法 |
DE3684836D1 (de) | 1985-07-29 | 1992-05-21 | Shiseido Co Ltd | Mit silikonpolymer ueberzogenes pulver oder teilchenfoermiges material. |
US4686253A (en) * | 1986-02-20 | 1987-08-11 | United States Gypsum Company | Lightweight joint compound having improved paintability |
US5037557A (en) | 1989-09-12 | 1991-08-06 | General Electric Company | Treated silica for oil absorption |
US5035804A (en) | 1990-09-17 | 1991-07-30 | Clnzall Corporation | Oil spill water treatment |
US5571768A (en) * | 1992-03-12 | 1996-11-05 | Mobil Oil Corporation | Zeolite functionalized with organosiliceous groups |
JPH0641728A (ja) * | 1992-07-22 | 1994-02-15 | Mitsui Eng & Shipbuild Co Ltd | 撥水性被膜の形成方法 |
US5302570A (en) | 1992-11-02 | 1994-04-12 | Enviro-Clean Alaska, Inc. | Environmental product capable of absorbing oil from the surface of water, and process |
US5348760A (en) | 1993-10-12 | 1994-09-20 | Aluminum Company Of America | Surface treated ceramic powders |
WO1998053921A1 (de) * | 1997-05-28 | 1998-12-03 | Global Surface Aktiengesellschaft | Verfahren zum beschichten einer oberfläche |
CN1201796A (zh) * | 1997-06-06 | 1998-12-16 | 吴世维 | 硅橡胶边角废料裂解生产有机硅环体的方法 |
US6045877A (en) * | 1997-07-28 | 2000-04-04 | Massachusetts Institute Of Technology | Pyrolytic chemical vapor deposition of silicone films |
US5939141A (en) * | 1997-08-11 | 1999-08-17 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Waterproof silicone coatings of thermal insulation and vaporization method |
DE19752659A1 (de) | 1997-11-27 | 1999-06-24 | Wacker Chemie Gmbh | Organosiliciumverbindungenhaltige hydrophobierende Pulver enthaltende Baustoffmassen |
US5964934A (en) * | 1997-12-18 | 1999-10-12 | Usg Interiors, Inc. | Acoustical tile containing treated perlite |
JP2002241695A (ja) * | 2000-12-15 | 2002-08-28 | Dow Corning Toray Silicone Co Ltd | 撥水性シリコーンコーティング剤組成物 |
WO2003038143A1 (en) | 2001-10-30 | 2003-05-08 | Massachusetts Institute Of Technology | Fluorocarbon-organosilicon copolymers and coatings prepared by hot-filament chemical vapor deposition |
US20040242729A1 (en) * | 2003-05-30 | 2004-12-02 | 3M Innovative Properties Company | Stabilized particle dispersions containing surface-modified inorganic nanoparticles |
US7344783B2 (en) * | 2003-07-09 | 2008-03-18 | Shell Oil Company | Durable hydrophobic surface coatings using silicone resins |
JP4319878B2 (ja) * | 2003-09-17 | 2009-08-26 | 電気化学工業株式会社 | アルミナセメント組成物及び不定形耐火物の製造方法 |
CN1316058C (zh) * | 2005-03-24 | 2007-05-16 | 上海交通大学 | 溅射TiO2使聚合物微流芯片表面改性的方法 |
JP2007131827A (ja) * | 2005-10-12 | 2007-05-31 | Adeka Corp | 外装材用添加剤及び該添加剤を含有してなる外装材 |
MY144611A (en) * | 2006-07-07 | 2011-10-14 | Seema Ajay Ranka | Methods of treating surfaces with ionic organosilicon compositions |
WO2008034806A1 (en) * | 2006-09-18 | 2008-03-27 | Dow Corning Corporation | Fillers, pigments and mineral powders treated with organopolysiloxanes |
WO2008116122A1 (en) * | 2007-03-22 | 2008-09-25 | World Minerals, Inc. | Mineral ore expanion using microwave energy |
-
2009
- 2009-06-08 US US12/480,598 patent/US8673393B2/en not_active Expired - Fee Related
-
2010
- 2010-03-17 CN CN201080023147.2A patent/CN102448719B/zh not_active Expired - Fee Related
- 2010-03-17 CN CN201410309141.1A patent/CN104085141A/zh active Pending
- 2010-03-17 EP EP10786522.2A patent/EP2440402A4/en not_active Withdrawn
- 2010-03-17 WO PCT/US2010/027693 patent/WO2010144167A1/en active Application Filing
- 2010-03-17 JP JP2012514954A patent/JP5731492B2/ja active Active
- 2010-03-17 KR KR20127000391A patent/KR20120044967A/ko not_active Application Discontinuation
-
2014
- 2014-02-04 US US14/171,985 patent/US20140147655A1/en not_active Abandoned
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101579143B1 (ko) * | 2015-09-21 | 2015-12-23 | 케이알엠건설 주식회사 | 친환경 그라우트 조성물과 이를 이용한 그라우팅 시공공법 |
Also Published As
Publication number | Publication date |
---|---|
CN104085141A (zh) | 2014-10-08 |
US8673393B2 (en) | 2014-03-18 |
US20140147655A1 (en) | 2014-05-29 |
EP2440402A1 (en) | 2012-04-18 |
JP2012529420A (ja) | 2012-11-22 |
US20120292256A1 (en) | 2012-11-22 |
KR20120044967A (ko) | 2012-05-08 |
WO2010144167A1 (en) | 2010-12-16 |
CN102448719B (zh) | 2014-07-09 |
EP2440402A4 (en) | 2016-05-25 |
CN102448719A (zh) | 2012-05-09 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5731492B2 (ja) | 蒸着コーティングを用いて製造された疎水性材料及びその応用 | |
Dong et al. | Simple fabrication of concrete with remarkable self-cleaning ability, robust superhydrophobicity, tailored porosity, and highly thermal and sound insulation | |
Ge et al. | Advanced sorbents for oil‐spill cleanup: recent advances and future perspectives | |
Hao et al. | Developing superhydrophobic rock wool for high-viscosity oil/water separation | |
Khosravi et al. | Synthesis of a novel highly oleophilic and highly hydrophobic sponge for rapid oil spill cleanup | |
Zhai et al. | Durable super-hydrophobic PDMS@ SiO2@ WS2 sponge for efficient oil/water separation in complex marine environment | |
Pang et al. | Inner superhydrophobic materials based on waste fly ash: Microstructural morphology of microetching effects | |
Jiang et al. | Superhydrophobic aerogel membrane with integrated functions of biopolymers for efficient oil/water separation | |
He et al. | Design of stable super-hydrophobic/super-oleophilic 3D carbon fiber felt decorated with Fe3O4 nanoparticles: Facial strategy, magnetic drive and continuous oil/water separation in harsh environments | |
Zhang et al. | Robust and durable superhydrophobic polyurethane sponge for oil/water separation | |
KR20200094974A (ko) | 소수성 흡수체 및 이의 제조방법 | |
CN112169375B (zh) | 用于含油污水处理的超亲水-水下超疏油颗粒及其制备和应用方法 | |
He et al. | Facile preparation of robust superhydrophobic/superoleophilic TiO2-decorated polyvinyl alcohol sponge for efficient oil/water separation | |
JP2010524823A5 (ja) | ||
Bi et al. | Lotus-seedpod-bioinspired 3D superhydrophobic diatomite porous ceramics comodified by graphene and carbon nanobelts | |
Bi et al. | Facile preparation of reduced GO modified porous ceramics with hierarchical pore structure as a highly efficient and durable sorbent material | |
Jin et al. | 3D-printed controllable gradient pore superwetting structures for high temperature efficient oil-water separation | |
Zulfiqar et al. | Renewable adsorbent for the separation of surfactant-stabilized oil in water emulsions based on nanostructured sawdust | |
Sam et al. | Robust, self-healing, superhydrophobic fabric for efficient oil/water emulsion separation | |
Zhou et al. | An effective method for improving the permeation flux of a ceramic membrane: Single-matrix spherical ceramic membrane | |
Yang et al. | Superhydrophobic/superoleophilic modified melamine sponge for oil/water separation | |
Mosayebi et al. | Fabrication of highly hydrophobic sand@ soot with core–shell structure and large-scale production possibility for oil/water separation | |
Biesuz et al. | Polymer-derived Si3N4 nanofelts as a novel oil spills clean-up architecture | |
Guo et al. | The fabrication of 3D porous PDMS sponge for Oil and organic solvent absorption | |
CN107312196A (zh) | 超疏水海绵材料及其制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20130314 |
|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20130314 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20140117 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20140225 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20140414 |
|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20140924 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20150121 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A821 Effective date: 20150121 |
|
A911 | Transfer to examiner for re-examination before appeal (zenchi) |
Free format text: JAPANESE INTERMEDIATE CODE: A911 Effective date: 20150212 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20150310 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20150409 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 5731492 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |