JP5721243B2 - 脱酸素性プラスチック材料 - Google Patents
脱酸素性プラスチック材料 Download PDFInfo
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- JP5721243B2 JP5721243B2 JP2013517063A JP2013517063A JP5721243B2 JP 5721243 B2 JP5721243 B2 JP 5721243B2 JP 2013517063 A JP2013517063 A JP 2013517063A JP 2013517063 A JP2013517063 A JP 2013517063A JP 5721243 B2 JP5721243 B2 JP 5721243B2
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- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims description 4
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- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical class CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 description 1
- 239000004147 Sorbitan trioleate Substances 0.000 description 1
- PRXRUNOAOLTIEF-ADSICKODSA-N Sorbitan trioleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCC\C=C/CCCCCCCC PRXRUNOAOLTIEF-ADSICKODSA-N 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- LWZFANDGMFTDAV-BURFUSLBSA-N [(2r)-2-[(2r,3r,4s)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] dodecanoate Chemical class CCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O LWZFANDGMFTDAV-BURFUSLBSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical class [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- 235000013405 beer Nutrition 0.000 description 1
- 230000006399 behavior Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000001588 bifunctional effect Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 229940106691 bisphenol a Drugs 0.000 description 1
- QNRMTGGDHLBXQZ-UHFFFAOYSA-N buta-1,2-diene Chemical class CC=C=C QNRMTGGDHLBXQZ-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- ZIXVIWRPMFITIT-UHFFFAOYSA-N cadmium lead Chemical compound [Cd].[Pb] ZIXVIWRPMFITIT-UHFFFAOYSA-N 0.000 description 1
- 235000012241 calcium silicate Nutrition 0.000 description 1
- SHZIWNPUGXLXDT-UHFFFAOYSA-N caproic acid ethyl ester Natural products CCCCCC(=O)OCC SHZIWNPUGXLXDT-UHFFFAOYSA-N 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 235000014171 carbonated beverage Nutrition 0.000 description 1
- 235000012174 carbonated soft drink Nutrition 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 125000006297 carbonyl amino group Chemical group [H]N([*:2])C([*:1])=O 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical class [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000001032 cobalt pigment Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- QYQADNCHXSEGJT-UHFFFAOYSA-N cyclohexane-1,1-dicarboxylate;hydron Chemical compound OC(=O)C1(C(O)=O)CCCCC1 QYQADNCHXSEGJT-UHFFFAOYSA-N 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 150000001982 diacylglycerols Chemical class 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- PPSZHCXTGRHULJ-UHFFFAOYSA-N dioxazine Chemical compound O1ON=CC=C1 PPSZHCXTGRHULJ-UHFFFAOYSA-N 0.000 description 1
- TVIDDXQYHWJXFK-UHFFFAOYSA-N dodecanedioic acid Chemical compound OC(=O)CCCCCCCCCCC(O)=O TVIDDXQYHWJXFK-UHFFFAOYSA-N 0.000 description 1
- LRJHYQLNLMGEPR-UHFFFAOYSA-N ethyl n,n-di(propan-2-yl)carbamate Chemical compound CCOC(=O)N(C(C)C)C(C)C LRJHYQLNLMGEPR-UHFFFAOYSA-N 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- ANSXAPJVJOKRDJ-UHFFFAOYSA-N furo[3,4-f][2]benzofuran-1,3,5,7-tetrone Chemical compound C1=C2C(=O)OC(=O)C2=CC2=C1C(=O)OC2=O ANSXAPJVJOKRDJ-UHFFFAOYSA-N 0.000 description 1
- 125000003827 glycol group Chemical group 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-M hexadecanoate Chemical compound CCCCCCCCCCCCCCCC([O-])=O IPCSVZSSVZVIGE-UHFFFAOYSA-M 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 235000013980 iron oxide Nutrition 0.000 description 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
- 150000003951 lactams Chemical class 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000001035 lead pigment Substances 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000010128 melt processing Methods 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 description 1
- ABMFBCRYHDZLRD-UHFFFAOYSA-N naphthalene-1,4-dicarboxylic acid Chemical compound C1=CC=C2C(C(=O)O)=CC=C(C(O)=O)C2=C1 ABMFBCRYHDZLRD-UHFFFAOYSA-N 0.000 description 1
- 125000005609 naphthenate group Chemical group 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- YCWSUKQGVSGXJO-NTUHNPAUSA-N nifuroxazide Chemical group C1=CC(O)=CC=C1C(=O)N\N=C\C1=CC=C([N+]([O-])=O)O1 YCWSUKQGVSGXJO-NTUHNPAUSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-M oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC([O-])=O ZQPPMHVWECSIRJ-KTKRTIGZSA-M 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 1
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 1
- 239000000825 pharmaceutical preparation Substances 0.000 description 1
- 229940127557 pharmaceutical product Drugs 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 229920005644 polyethylene terephthalate glycol copolymer Polymers 0.000 description 1
- 229920000223 polyglycerol Chemical class 0.000 description 1
- 229920006123 polyhexamethylene isophthalamide Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- FYNROBRQIVCIQF-UHFFFAOYSA-N pyrrolo[3,2-b]pyrrole-5,6-dione Chemical compound C1=CN=C2C(=O)C(=O)N=C21 FYNROBRQIVCIQF-UHFFFAOYSA-N 0.000 description 1
- IZMJMCDDWKSTTK-UHFFFAOYSA-N quinoline yellow Chemical compound C1=CC=CC2=NC(C3C(C4=CC=CC=C4C3=O)=O)=CC=C21 IZMJMCDDWKSTTK-UHFFFAOYSA-N 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 238000003303 reheating Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 235000019351 sodium silicates Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229940035044 sorbitan monolaurate Drugs 0.000 description 1
- 235000019337 sorbitan trioleate Nutrition 0.000 description 1
- 229960000391 sorbitan trioleate Drugs 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 229940014800 succinic anhydride Drugs 0.000 description 1
- 150000003445 sucroses Chemical class 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- JOUDBUYBGJYFFP-FOCLMDBBSA-N thioindigo Chemical compound S\1C2=CC=CC=C2C(=O)C/1=C1/C(=O)C2=CC=CC=C2S1 JOUDBUYBGJYFFP-FOCLMDBBSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 1
- 238000007666 vacuum forming Methods 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/12—Polyester-amides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/101—Esters; Ether-esters of monocarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/1355—Elemental metal containing [e.g., substrate, foil, film, coating, etc.]
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Containers Having Bodies Formed In One Piece (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Description
成分Aはポリエステルであり、
成分Bはポリアミドであり、
成分Cは遷移金属触媒であり、
成分Dは、パラフィン、植物油、ポリアルキレングリコール、ポリオールのエステル、アルコキシレート及びこれらの物質の混合物からなる群から選択される有機化合物である。
− 好ましい合成有機顔料は、アゾもしくはジスアゾ顔料、レーキ化アゾもしくはジスアゾ顔料または多環式顔料、特に好ましくはフタロシアニン、ジケトピロロピロール、キナクリドン、ペリレン、ジオキサジン、アントラキノン、チオインディゴ、ジアリールもしくはキノフタロン顔料であり;
− 好ましい合成無機顔料は、金属酸化物、混合酸化物、硫酸アルミニウム類、クロメート類、金属粉末、真珠光沢顔料(マイカ)、発光着色料、酸化チタン類、カドニウム鉛顔料、酸化鉄類、カーボンブラック、シリケート類、チタン酸ニッケル類、コバルト顔料または三価クロム類であり;
− フィラー及びナノサイズフィラー、好ましくはシリカ、ゼオライト類、シリケート類、特に好ましくケイ酸アルミニウム類、ケイ酸ナトリウム、ケイ酸カルシウム類、チョークまたはタルク;金属水和物;
− 助剤、好ましくは酸捕捉剤、加工助剤、カップリング剤、滑剤、ステアレート類、発泡剤、多価アルコール、成核剤、または酸化防止剤、例えばステアレート類、または酸化物、例えば酸化マグネシウム;
− 酸化防止剤、好ましくは一次もしくは二次酸化防止剤;
− 帯電防止剤;
− ポリエステル/ポリアミドブレンドのための相溶化剤;
UV吸収剤、スリップ剤、曇り防止剤、縮合防止剤、懸濁安定剤、ブロッキング防止剤、ワックス、及びこれらの物質の混合物、
からなる群から選択される。
− 80〜98.9重量%の成分A;
− 1〜10重量%の成分B;
− 0.0001〜0.8重量%の成分C;
− 0.01〜2重量%の成分D;
− 0〜18.9899%、好ましくは0〜18重量%の成分E;
を含み、より好ましくは
− 90〜98重量%の成分A;
− 1〜7重量%の成分B;
− 0.001〜0.5重量%の成分C;
− 0.1〜2重量%の成分D;
− 0〜8.899重量%の成分E;
を含み、ここで重量%は、それぞれ組成物Zの総重量を基準とし、そして成分A、B、C、D及びEの重量%は常に合計して100%である。
− 包装品中に最初に存在する酸素の量、
− 脱酸素性が無い時の該包装品中への酸素侵入速度、及び
− 包装品の意図された保存可能期間、
に大きく依存する。
ここで、所与の脱酸素性組成物及び/または所与の物品について、
Xは、100日間の観察期間にわたって測定した最大酸素含有量と定義され、
tmaxは、物品の形成及びそれの充填から、酸素含有量Xがその最大値に到達するまでに経過する時間と定義され、
Yは、その或る脱酸素性組成物に特有の脱酸素効率及び誘導の程度の目安を与える。
製品の特性は、他に記載が無ければ、次の方法で測定する:
密度の値は、ASTM D792に従い測定する(g/cm3)。
典型的な炭酸飲料保存可能期間試験のために、(i)窒素循環グローブボックス内で、500ml容積のボトルに、上部空間(headspace)が10mlとなるまで脱酸素水を満たし(ここでボトル内の水の酸素濃度は、十分に50ppb未満となるレベルに安定化された)、(ii)2.8ボリュームの炭酸濃度(すなわち、水1cm3あたりに溶解されたガス量が2.8cm3)までCO2で炭酸化し、次いで蓋をする。次いで、ボトルの空き上部空間中の酸素濃度の測定を、非破壊型酸素測定センサー及びFibox(登録商標)トランスミッタを用いて行う。データは、同じ組成の少なくとも二つのボトルについて、一定の時間間隔で及び100日間の時間フレームにわたって、並行して集める。各々のサンプルボトルについて、或る時間での酸素侵入を、その時に測定された酸素含有量と、時間0で測定した酸素濃度との差として計算する。次いで、酸素侵入を、各々の組成物について測定したサンプルボトルの数で平均し、次いで時間に対してプロットする。
成分A1:
1.35〜1.45g/cm3の密度及び0.74〜0.78dl/gの固有粘度(ASTM D3236−88)を有するポリエチレンテレフタレート(PET)
成分A2:
1.28〜1.32g/cm3の密度及び0.90〜1.00dl/gの固有粘度(ASTM D3236−88)を有するポリブチレンテレフタレート(PBT)
成分B1:
1.20〜1.30g/cm3の密度及び(275℃/0.325kgで測定して)2g/10分のMFRを有するポリ(m−キシリレンアジパミド)(MXD6)
成分C1:
ステアリン酸コバルト(コバルト濃度9.5%)
成分C2:
ネオデカン酸コバルト(コバルト濃度20.5%)
成分D1:
20℃で0.98〜1.02g/cm3の密度及び最大220mgKOH/gのヒドロキシル価(DIN53240)を有するソルビタンモノオレエート
成分D2:
15℃で0.85〜0.88g/cm3の密度及び40℃で66〜74mm2/sの粘度(ASTM D445)を有するホワイトミネラルオイル
成分E1:
24〜29mgKOH/gの酸価(ASTM D664)及び200℃で7000〜9500mPascal.sのICIコーン&プレート溶融粘度(ASTM D4287)を有するイソフタル酸変性ポリエチレンテレフタレート
各成分を、230℃の温度でLeistritz(登録商標)ZSE18HP押出機で互いにホモジナイズして、固形マスターバッチMB1、MB2、MB7及びMB8を得た。液状マスターバッチMB3〜MB6は、Cowlesミキサー中で、意図した加熱無しに各成分を15分間攪拌することによって得た。表1に詳細を示す。
成分A1を160℃で7時間乾燥し、次いで他の成分を表2に記載の比率でホモジナイズ及び混合した。得られたコンパウンドCO1〜CO10を、2ステップISBMプロセスを介して500mlボトルの製造に使用した。先ず、23gのプリフォームを射出成形機Arburg(登録商標)420C 1000−150で作製し、次いで室温に冷却し、その後、Sidel(登録商標)SBO−1で延伸ブロー成形ステップを行った。
X・tmax=Y
に従い、組成物CO1〜CO10は、異なる脱酸素性能を明らかに示し、ここで本発明の組成物CO2、CO5、CO6、CO7、CO8及びCO9にはより低いY値が記録された。低いY値は、良好な脱酸素性能及び短縮された誘導時間の両方を示す。表4に各々の組成物の詳細を記す。
Claims (12)
- 成分A、B、CおよびDを含む組成物Zを含むプラスチック材料であって、
成分Aは、ポリエチレンテレフタレート、シクロヘキサンジメタノール/ポリエチレンテレフタレートコポリマー、ポリエチレンナフタレート、ポリブチレンテレフタレート、およびこれらの混合物からなる群から選択されるポリエステルであり、
成分Bは、ポリ(m−キシリレンアジパミド)、ポリ(ヘキサメチレンイソフタルアミド)、ポリ(ヘキサメチレンアジパミド−co−イソフタルアミド)、ポリ(ヘキサメチレンアジパミド−co−テレフタルアミド)、ポリ(ヘキサメチレンイソフタルアミド−co−テレフタルアミド)、ポリ(ヘキサメチレンアジパミド)、ポリ(カプロラクタム)、ポリ(ヘキサメチレンアジパミド)−co−カプロラクタム、およびこれらの混合物からなる群から選択されるポリアミドであり、
成分Cは、オレイン酸コバルト、プロピオン酸コバルト、ステアリン酸コバルト、ネオデカン酸コバルト、およびこれらの混合物からなる群から選択される遷移金属触媒であり、
成分Dは、パラフィン、植物油、ポリオールのエステル、およびこれらの物質の混合物からなる群から選択される有機化合物である、
前記プラスチック材料。 - 成分Dが周囲温度および大気圧下に液状である、請求項1に記載のプラスチック材料。
- 組成物Zが更に成分Eを含み、成分Eが、
着色剤、フィラー、酸捕捉剤、加工助剤、カップリング剤、滑剤、ステアレート、発泡剤、多価アルコール、成核剤、酸化防止剤、帯電防止剤、ポリエステル/ポリアミドブレンド用の相溶化剤、UV吸収剤、スリップ剤、曇り防止剤、縮合防止剤、懸濁安定剤、ブロッキング防止剤、ワックス、およびこれらの物質の混合物からなる群から選択される、請求項1又は2に記載のプラスチック材料。 - 組成物Zが、
− 80〜98.9重量%の成分A;
− 1〜10重量%の成分B;
− 0.0001〜0.8重量%の成分C;
− 0.01〜2重量%の成分D;
− 0〜18.9899重量%の成分E;
を含み、ここで重量%は、組成物Zの総重量を基準とし、成分A、B、C、DおよびEの重量%は常に合計して100%である、
請求項1〜3のいずれか一つに記載のプラスチック材料。 - 成形されたプラスチック物品の形態である、請求項1〜4のいずれか一つに記載のプラスチック材料。
- 成形されたプラスチック物品が容器、シートまたはフィルムである、請求項5に記載のプラスチック材料。
- 食品、飲料、化粧料、医薬品、またはパーソナルケア用品の包装に使用するための、請求項5または6に記載のプラスチック材料。
- 容器がボトルである、請求項6または7に記載のプラスチック材料。
- 成分A、B、C、D、および任意にEが、互いに物理的に混合され、そして成形プロセスに付されることを特徴とする、請求項1〜8のいずれか一つに記載のプラスチック材料の製造方法。
- 混合が、押出、混練、ミリングまたはカレンダリングを含む、請求項9に記載の方法。
- 成形プロセスが、ブロー成形、射出成形、射出および延伸ブロー成形、押出ブロー成形、圧縮成形、圧縮、延伸ブロー成形、キャストまたはフィルム押出を含む、請求項9または10に記載の方法。
- 第一のステップにおいて、成分C、D、任意におよびEを互い中に予備分散し、そして一つまたはそれ以上の続くステップにおいて、成分AおよびBに添加する、請求項9〜11のいずれか一つに記載の方法。
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