JP5655890B2 - スラグ系注入材及びその注入工法 - Google Patents
スラグ系注入材及びその注入工法 Download PDFInfo
- Publication number
- JP5655890B2 JP5655890B2 JP2013107978A JP2013107978A JP5655890B2 JP 5655890 B2 JP5655890 B2 JP 5655890B2 JP 2013107978 A JP2013107978 A JP 2013107978A JP 2013107978 A JP2013107978 A JP 2013107978A JP 5655890 B2 JP5655890 B2 JP 5655890B2
- Authority
- JP
- Japan
- Prior art keywords
- fine powder
- injection material
- mass
- slag
- blast furnace
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000002347 injection Methods 0.000 title claims description 99
- 239000007924 injection Substances 0.000 title claims description 99
- 239000000463 material Substances 0.000 title claims description 99
- 239000002893 slag Substances 0.000 title claims description 57
- 238000000034 method Methods 0.000 title description 20
- 239000000843 powder Substances 0.000 claims description 87
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 35
- 239000000920 calcium hydroxide Substances 0.000 claims description 35
- 235000011116 calcium hydroxide Nutrition 0.000 claims description 35
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 35
- 239000002270 dispersing agent Substances 0.000 claims description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 24
- 239000002245 particle Substances 0.000 claims description 23
- 229910052910 alkali metal silicate Inorganic materials 0.000 claims description 20
- 238000010521 absorption reaction Methods 0.000 claims description 18
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 15
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 12
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 9
- 229920000570 polyether Polymers 0.000 claims description 9
- 238000000862 absorption spectrum Methods 0.000 claims description 8
- 238000010276 construction Methods 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 6
- 235000012239 silicon dioxide Nutrition 0.000 claims description 6
- 159000000000 sodium salts Chemical class 0.000 claims description 6
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 5
- 101000878457 Macrocallista nimbosa FMRFamide Proteins 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- 125000001033 ether group Chemical group 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 claims description 3
- 238000002513 implantation Methods 0.000 claims 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 22
- 230000035699 permeability Effects 0.000 description 15
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 14
- 235000019353 potassium silicate Nutrition 0.000 description 12
- 239000004576 sand Substances 0.000 description 12
- 230000035515 penetration Effects 0.000 description 11
- 238000005259 measurement Methods 0.000 description 10
- 238000001879 gelation Methods 0.000 description 9
- 239000002689 soil Substances 0.000 description 8
- 239000000499 gel Substances 0.000 description 7
- 238000007711 solidification Methods 0.000 description 7
- 230000008023 solidification Effects 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 238000002156 mixing Methods 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 239000000725 suspension Substances 0.000 description 6
- 238000009826 distribution Methods 0.000 description 5
- 230000007774 longterm Effects 0.000 description 5
- 238000000926 separation method Methods 0.000 description 5
- 239000000377 silicon dioxide Substances 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 239000004568 cement Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 230000006872 improvement Effects 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 238000001507 sample dispersion Methods 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 239000002609 medium Substances 0.000 description 3
- 229920003169 water-soluble polymer Polymers 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000002612 dispersion medium Substances 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 230000008595 infiltration Effects 0.000 description 2
- 238000001764 infiltration Methods 0.000 description 2
- 238000012417 linear regression Methods 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000005728 strengthening Methods 0.000 description 2
- 238000002834 transmittance Methods 0.000 description 2
- 239000011398 Portland cement Substances 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- -1 alkali metal salts Chemical class 0.000 description 1
- 229910001583 allophane Inorganic materials 0.000 description 1
- 230000003466 anti-cipated effect Effects 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 229920001222 biopolymer Polymers 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 1
- XFWJKVMFIVXPKK-UHFFFAOYSA-N calcium;oxido(oxo)alumane Chemical compound [Ca+2].[O-][Al]=O.[O-][Al]=O XFWJKVMFIVXPKK-UHFFFAOYSA-N 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011362 coarse particle Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000009430 construction management Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 238000009775 high-speed stirring Methods 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 125000005624 silicic acid group Chemical class 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
Images
Landscapes
- Consolidation Of Soil By Introduction Of Solidifying Substances Into Soil (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Soil Conditioners And Soil-Stabilizing Materials (AREA)
Description
使用した材料は次のとおりである。
(1)高炉スラグ微粉末:通過体積百分率95%粒子径4.3μm、ブレーン比表面積15100cm2/g、塩基度1.88
(2)消石灰微粉末:通過体積百分率95%粒子径4.1μm
(3)ケイ酸アルカリ:JIS K 1408−1966「けい酸ナトリウム」に規定の3号品(SiO2濃度29%)
(4)分散剤:カルボキシル基含有ポリエーテル系分散剤(固形分量33質量%、赤外線吸収スペクトルの相対強度比α=0.63、β=1.09)
(1)注入材の調製
高炉スラグ微粉末の質量と消石灰微粉末の質量の比を93:7、注入材中の分散剤を約0.7質量%(溶液基準)に固定し、水の質量と高炉スラグ微粉末及び消石灰微粉末の合計質量の比を8:1及び12:1とし、表1及び2に示すようにケイ酸アルカリの量を変動させて、実施例1〜4及び比較例1〜2の注入材を調製した。注入材は、1バッチ当たりの出来上がり容積を1Lとして、所定量の分散剤、高炉スラグ微粉末及び消石灰微粉末、ケイ酸アルカリの順に加え、ジューサーミキサ(松下電器社製、MX‐915C)で1分間高速攪拌(15000rpm)して調製した。
調製した注入材を、円筒形容器(直径9cm、高さ9cm、内容積400ml、粉砕媒体無し)に入れ、ボールミル架台にセットして室温(23℃)で低速回転(23rpm)した。所定の時間に達した時点で、注入材粘度(みかけ粘度)をB型粘度計(株式会社トキメック製デジタル粘度計DVL−BII形、23℃、回転数60rpm、BLアダプター使用)で測定し、次の測定まで再び低速回転した。これらの結果を表1〜2に示す。
上記材料を使用し、高炉スラグ微粉末の質量と消石灰微粉末の質量との比を93:7とし、表3及び4に示すように、水の質量と高炉スラグ微粉末及び消石灰微粉末の合計質量との比(表3及び4中の質量比)、分散剤及びケイ酸アルカリの量を変動させて、実施例1、4〜6及び比較例3の注入材を調製し、注入材を珪砂(宇部珪砂7号、細粒土分24%)と練り混ぜ、塩化ビニル製の円筒容器(内径Φ5cm×10cm)に流し込み、23℃の恒温室で封緘養生した。所定材齢経過後、脱型して一軸圧縮強さを測定した。なお、混合珪砂充填時の間隙率は約50%であったので、その間隙相当容積の注入材を加えた。結果を表3〜4に示した。
Claims (6)
- 高炉スラグ微粉末、消石灰微粉末、ケイ酸のナトリウム塩、主鎖を形成するメチル基又はメチレン基をもち、カルボキシ金属塩を主鎖中にもち、かつ脂肪族エーテル基の側鎖をもつカルボキシル基含有ポリエーテル系分散剤及び水を含有してなる1液型のスラグ系注入材であって、注入材中、ケイ酸のナトリウム塩がSiO2濃度にして0.07〜0.37質量%、カルボキシル基含有ポリエーテル系分散剤が0.25〜0.74質量%であり、
高炉スラグ微粉末の質量と消石灰微粉末の質量との比が85:15〜96:4であり、かつ水の質量と高炉スラグ微粉末及び消石灰微粉末の合計質量との比が12:1以下であり、
高炉スラグ微粉末及び消石灰微粉末が、それぞれ通過体積百分率95%の粒子径が12.0μm以下の粉末である、1液型のスラグ系注入材。 - 前記カルボキシル基含有ポリエーテル系分散剤が、赤外吸収スペクトルの相対強度比α[(1560〜1600cm −1 付近に出現する吸収ピークAの強度)/(2850〜2960cm −1 付近に出現する吸収ピークBの強度)]が0.25〜0.80であり、かつ赤外吸収スペクトルの相対強度比β[(1090〜1130cm −1 付近に出現する吸収ピークCの強度)/(2850〜2960cm −1 付近に出現する吸収ピークBの強度)]が0.40〜1.30である、請求項1記載の1液型のスラグ系注入材。
- 高炉スラグ微粉末の質量と消石灰微粉末の質量との比が90:10〜95:5である、請求項1又は2記載の1液型のスラグ系注入材。
- 注入材中、ケイ酸アルカリがSiO2濃度にして0.07〜0.32質量%である、請求項1〜3のいずれか1項記載の1液型のスラグ系注入材。
- 注入材中、ケイ酸アルカリがSiO2濃度にして0.09〜0.28質量%である、請求項1〜4のいずれか1項記載の1液型スラグ系注入材。
- 請求項1〜5のいずれか1項記載の1液型のスラグ系注入材を地盤に注入する注入工法。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2013107978A JP5655890B2 (ja) | 2013-05-22 | 2013-05-22 | スラグ系注入材及びその注入工法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2013107978A JP5655890B2 (ja) | 2013-05-22 | 2013-05-22 | スラグ系注入材及びその注入工法 |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2007158753A Division JP5277570B2 (ja) | 2007-06-15 | 2007-06-15 | スラグ系注入材及びその注入工法 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2013213216A JP2013213216A (ja) | 2013-10-17 |
JP5655890B2 true JP5655890B2 (ja) | 2015-01-21 |
Family
ID=49586782
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2013107978A Active JP5655890B2 (ja) | 2013-05-22 | 2013-05-22 | スラグ系注入材及びその注入工法 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP5655890B2 (ja) |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5949283A (ja) * | 1982-09-14 | 1984-03-21 | Shimoda Gijutsu Kenkyusho:Kk | スラグと石灰を用いた水ガラス系グラウト材 |
JPH10168451A (ja) * | 1996-12-13 | 1998-06-23 | Mitsui Chem Inc | 懸濁型グラウト剤とそれを用いた地盤注入固結法 |
JPH10168452A (ja) * | 1996-12-13 | 1998-06-23 | Mitsui Chem Inc | 水ガラス系懸濁型グラウト剤とそれを用いた地盤注入固 結法 |
JPH11228959A (ja) * | 1998-02-10 | 1999-08-24 | Mitsui Chem Inc | 懸濁型グラウト剤 |
JP5277570B2 (ja) * | 2007-06-15 | 2013-08-28 | 宇部興産株式会社 | スラグ系注入材及びその注入工法 |
-
2013
- 2013-05-22 JP JP2013107978A patent/JP5655890B2/ja active Active
Also Published As
Publication number | Publication date |
---|---|
JP2013213216A (ja) | 2013-10-17 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP7444306B2 (ja) | 硬化材、硬化材液、土質安定用薬液、該薬液の製造方法、及び地盤安定化工法 | |
JP5936949B2 (ja) | 水中不分離性コンクリート | |
CN106517957A (zh) | 一种普通强度高弹性模量混凝土及其制备方法 | |
JP5500828B2 (ja) | 土壌固化材 | |
JP5277570B2 (ja) | スラグ系注入材及びその注入工法 | |
JP6122647B2 (ja) | 液体急結剤、それを用いたセメント組成物および吹付け工法 | |
JP5189274B2 (ja) | 地盤注入材及びそれを用いた地盤注入工法 | |
JP2020090622A (ja) | 硬化材、硬化材液、土質安定用薬液、該薬液の製造方法、及び地盤安定化工法 | |
JP4976803B2 (ja) | グラウト組成物およびそれを用いたグラウト材料 | |
CN106747146A (zh) | 一种水下抗分散水泥基灌浆料及其制备方法 | |
JP5655890B2 (ja) | スラグ系注入材及びその注入工法 | |
JP5689224B2 (ja) | 注入材及び注入工法 | |
JPH1161125A (ja) | 地盤注入材 | |
JP5769198B2 (ja) | 地盤注入用水硬性セメント組成物およびそれを用いた地盤改良工法 | |
JP6033664B2 (ja) | 液体急結剤およびその製造方法、それを用いたセメント組成物および吹付け工法 | |
JP4627153B2 (ja) | 懸濁型地盤改良材及びその製造方法 | |
JP5810602B2 (ja) | 懸濁グラウト薬液の製造方法 | |
JP5717945B2 (ja) | 注入材料、注入材及び注入工法 | |
JP5196990B2 (ja) | 土質安定用薬液 | |
JP5818077B2 (ja) | 懸濁グラウト薬液 | |
JP6300365B2 (ja) | 水中不分離性速硬コンクリートおよびその製造方法 | |
JP2012140522A (ja) | 注入材 | |
JP4172762B2 (ja) | 粘性土用硬化材組成物 | |
JPH0867876A (ja) | 地盤注入用薬液 | |
JP2008285597A (ja) | 高圧噴射攪拌施工用混和剤 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A132 Effective date: 20140805 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20140930 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20141028 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20141110 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 5655890 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
S533 | Written request for registration of change of name |
Free format text: JAPANESE INTERMEDIATE CODE: R313533 |
|
S111 | Request for change of ownership or part of ownership |
Free format text: JAPANESE INTERMEDIATE CODE: R313111 |
|
R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |