JP5653423B2 - アルミナ及びジルコニアに基づく焼結製品 - Google Patents
アルミナ及びジルコニアに基づく焼結製品 Download PDFInfo
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- JP5653423B2 JP5653423B2 JP2012513720A JP2012513720A JP5653423B2 JP 5653423 B2 JP5653423 B2 JP 5653423B2 JP 2012513720 A JP2012513720 A JP 2012513720A JP 2012513720 A JP2012513720 A JP 2012513720A JP 5653423 B2 JP5653423 B2 JP 5653423B2
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- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 title claims description 48
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 title claims description 12
- 239000002245 particle Substances 0.000 claims description 123
- 239000000203 mixture Substances 0.000 claims description 50
- 238000005245 sintering Methods 0.000 claims description 40
- 239000000843 powder Substances 0.000 claims description 36
- 239000000654 additive Substances 0.000 claims description 35
- 230000000996 additive effect Effects 0.000 claims description 33
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims description 30
- 239000011324 bead Substances 0.000 claims description 25
- 239000011572 manganese Substances 0.000 claims description 25
- 238000000034 method Methods 0.000 claims description 24
- 238000000227 grinding Methods 0.000 claims description 13
- 239000002243 precursor Substances 0.000 claims description 12
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 11
- 239000012535 impurity Substances 0.000 claims description 9
- 238000004458 analytical method Methods 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 6
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 claims description 4
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 claims description 4
- 238000002441 X-ray diffraction Methods 0.000 claims description 3
- 238000001513 hot isostatic pressing Methods 0.000 claims description 3
- 238000005266 casting Methods 0.000 claims description 2
- 230000003796 beauty Effects 0.000 claims 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 26
- 239000000292 calcium oxide Substances 0.000 description 26
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 19
- 239000000725 suspension Substances 0.000 description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 239000003349 gelling agent Substances 0.000 description 10
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 9
- 229910021193 La 2 O 3 Inorganic materials 0.000 description 9
- 235000013980 iron oxide Nutrition 0.000 description 8
- 239000007787 solid Substances 0.000 description 8
- 239000005751 Copper oxide Substances 0.000 description 7
- 229910000431 copper oxide Inorganic materials 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 238000005259 measurement Methods 0.000 description 7
- 229910003447 praseodymium oxide Inorganic materials 0.000 description 7
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc oxide Inorganic materials [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 7
- FGUUSXIOTUKUDN-IBGZPJMESA-N C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 Chemical compound C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 FGUUSXIOTUKUDN-IBGZPJMESA-N 0.000 description 6
- 239000002270 dispersing agent Substances 0.000 description 6
- MMKQUGHLEMYQSG-UHFFFAOYSA-N oxygen(2-);praseodymium(3+) Chemical compound [O-2].[O-2].[O-2].[Pr+3].[Pr+3] MMKQUGHLEMYQSG-UHFFFAOYSA-N 0.000 description 6
- 239000010949 copper Substances 0.000 description 5
- 229910001697 hibonite Inorganic materials 0.000 description 5
- 229910052748 manganese Inorganic materials 0.000 description 5
- 239000007858 starting material Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 4
- 229910017493 Nd 2 O 3 Inorganic materials 0.000 description 4
- 229910052684 Cerium Inorganic materials 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 239000012736 aqueous medium Substances 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000003792 electrolyte Substances 0.000 description 3
- 229910000449 hafnium oxide Inorganic materials 0.000 description 3
- WIHZLLGSGQNAGK-UHFFFAOYSA-N hafnium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Hf+4] WIHZLLGSGQNAGK-UHFFFAOYSA-N 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000003607 modifier Substances 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical group O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
- 229910052779 Neodymium Inorganic materials 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000003006 anti-agglomeration agent Substances 0.000 description 2
- 239000003125 aqueous solvent Substances 0.000 description 2
- 239000007900 aqueous suspension Substances 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 2
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 description 2
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Inorganic materials [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 2
- 229910000420 cerium oxide Inorganic materials 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000004676 glycans Polymers 0.000 description 2
- 229910052746 lanthanum Inorganic materials 0.000 description 2
- 239000002609 medium Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 2
- -1 oxynitrides Chemical class 0.000 description 2
- 229910002077 partially stabilized zirconia Inorganic materials 0.000 description 2
- 239000011802 pulverized particle Substances 0.000 description 2
- 238000007873 sieving Methods 0.000 description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 2
- 229910010271 silicon carbide Inorganic materials 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 229910052712 strontium Inorganic materials 0.000 description 2
- IATRAKWUXMZMIY-UHFFFAOYSA-N strontium oxide Inorganic materials [O-2].[Sr+2] IATRAKWUXMZMIY-UHFFFAOYSA-N 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- 229910018404 Al2 O3 Inorganic materials 0.000 description 1
- 238000004438 BET method Methods 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910052777 Praseodymium Inorganic materials 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- HEAFLBOWLRRIHV-UHFFFAOYSA-N [Na].[P] Chemical compound [Na].[P] HEAFLBOWLRRIHV-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 229940072056 alginate Drugs 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 230000002744 anti-aggregatory effect Effects 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 125000003262 carboxylic acid ester group Chemical group [H]C([H])([*:2])OC(=O)C([H])([H])[*:1] 0.000 description 1
- 150000001733 carboxylic acid esters Chemical class 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical group OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 230000002706 hydrostatic effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000867 polyelectrolyte Polymers 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 150000004804 polysaccharides Polymers 0.000 description 1
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000001812 pycnometry Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001603 reducing effect Effects 0.000 description 1
- 238000004626 scanning electron microscopy Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 238000003980 solgel method Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
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Description
重量百分率として:
・CeO2とY2O3によって部分的に安定化されたZrO2:100%への残部;
・Al2O3:10〜60%;
・CaO、酸化マンガン、ZnO、La2O3、酸化プラセオジム、SrO、酸化銅、Nd2O3、BaO、酸化鉄及びそれらの混合物から選択される添加剤:0.2%〜6%;
・ただしCaOの量は2%より少ない;
・不純物:<2%;
・CeO2とY2O3は、ZrO2とCeO2とY2O3の合計に基づくモル百分率で、
・CeO2:6モル%〜11モル%;及び
・Y2O3:0.5モル%〜2モル%;
であるような量で存在する:
該粒子は1300℃より高い焼結温度にて焼結することによって得られ、該焼結温度は
(C1)添加剤がCaOであるとき、又は、
(C2)CeO2モル含有量が10%〜11%の範囲にあるときは
1400℃より高い、好ましくは1425℃より高い。
b)上記粉体から懸濁物を調製し、懸濁物の組成は、段階f)の最後で、本発明の焼結粒子に一致する組成を有する焼結粒子を得るように適合されている。
c)懸濁物の滴を硬化して、未焼成粒子を形成する。
d)洗浄する。
e)乾燥する。
f)1300℃超の焼結温度で焼結して、焼結粒子を得る。
焼結温度は
(C’1)懸濁物が、Mn、Zn、Cu、Pr、Nd、Sr、La、Ba、またはFeの化合物を含まない、つまり焼結粒子中の添加剤がCaOである、あるいは、
(C’2)懸濁物が、段階f)の最後で得られた焼結粒子のCeO2モル含有量がZrO2、CeO2、及びY2O3の合計に基づくモル百分率で10〜11%の範囲にあるなら、1400℃超であり、好ましくは1425℃超である。
用語「粒子」は、粉体中にある固体物質の一つの個体を意味する。
T=100×(A細長いグレイン)/(A細長いグレイン+AAl2o3+AZro2) (1)
・ヒボナイト型相の<110>反射に相当するピーク(ICDDファイルNo38−0470)の、及び
・マグネトプランバイト型相の<107>反射に相当するピーク(ICDDファイルNo04−0704)の
X線回折図にて測定された面積の合計である。
・固形分に基づく重量百分率で0〜10%の量の分散剤。
・固形分に基づく重量百分率で0〜3%の量の粘度安定剤、又は凝集防止剤。
・固形分に基づく重量百分率で0〜3%の量の表面張力変更剤。
・固形分に基づく重量百分率で0〜2%の量のゲル化剤。
分散剤または凝集防止剤として、ナトリウムまたはアンモニウムポリメタクリレート群、ナトリウムまたはアンモニウムポリアクリレート群、ポリアクリル酸群(アンモニウムまたはナトリウム塩)、または、その他の高分子電解質、クエン酸塩群、例えばアンモニウム、リン酸ナトリウム群、及びカルボン酸エステル群、
表面張力変更剤として、ある脂肪族アルコールのような有機溶媒、及び、
ゲル化剤として、天然多糖群のいずれかである。
焼結粒子の密度はヘリウムピクノメトリ法(AccuPyc 1330、マイクロメリティクス(商標)社製)により測定された。
100(m0−m)/m0
・プラネタリー摩耗が3%に等しいかそれ未満であり、かつ、
・密度が4.5g/cm3〜5.9g/cm3の範囲にあるときに、
粉砕収率とプラネタリー摩耗の間に良い妥協があると考える。
Claims (26)
- 最小粒径と最大粒径の比が0.6超であり、以下の化学分析を有する焼結粒子
重量百分率として:
・Al2O3:10〜60%;
・CaOである添加剤、及び、酸化マンガン、SrO、BaO及びそれらの混合物から選択される第二の添加剤:0.2%〜6%;
・ただしCaOの量は2%より少ない;
・不純物:<2%;
・CeO 2 とY 2 O 3 で部分的に安定化されたZrO 2 :焼結粒子の重量を100%とした残りの量;
・ジルコニアはCeO2とY2O3で安定化されており、CeO2とY2O3は、ZrO2とCeO2とY2O3の合計に基づくモル百分率で
・CeO2:6モル%〜11モル%;及び
・Y2O3:0.5モル%〜2モル%;
となるようなモル量で含まれる;
・該粒子は、酸化マンガン、及び/又はSrO、及び/又はBaO、及び/又は前記酸化物の前駆体粒子を含む粒子混合物を、1300℃より高い焼結温度にて焼結することによって得られ、該焼結温度は、CeO2モル含有量が10%〜11%の範囲にあれば、1400℃より高い。 - CeO2モル含有量が10%未満かつ7%超である、請求項1に記載の焼結粒子。
- CeO2モル含有量が9.5%未満かつ8.5%超である、請求項2に記載の焼結粒子。
- Y2O3モル含有量が1.2%未満かつ0.8%超である、請求項1〜3のいずれか1項に記載の焼結粒子。
- アルミナAl2O3含有量が酸化物に基づく重量百分率で15%超かつ55%未満である、請求項1〜4のいずれか1項に記載の焼結粒子。
- アルミナAl2O3含有量が酸化物に基づく重量百分率で20%超かつ40%未満である、請求項5に記載の焼結粒子。
- 添加剤がCaO及び、MnO、MnO2、Mn2O3、Mn3O4 、SrO及びそれらの混合物から選択される第二の添加剤を含む、請求項1〜6のいずれか1項に記載の焼結粒子。
- 添加剤がCaO及び、MnO、Mn3O4及びそれらの混合物から選択される第二の添加剤を含む、請求項7に記載の焼結粒子。
- CaOの量が、酸化物に基づく重量百分率で0.3%超である、請求項1〜8のいずれか1項に記載の焼結粒子。
- 第二の添加剤の量が、酸化物に基づく重量百分率で0.1%超である、請求項1〜9のいずれか1項に記載の焼結粒子。
- 添加剤含有量が酸化物に基づく重量百分率で0.4%超かつ5%未満である、請求項1〜10のいずれか1項に記載の焼結粒子。
- 添加剤の量が酸化物に基づく重量百分率で0.5%超かつ1%未満である、請求項11に記載の焼結粒子。
- 添加剤の量が酸化物に基づく重量百分率で4%未満である、請求項1〜12のいずれか1項に記載の焼結粒子。
- 添加剤がCaOを含有し、該CaOの量が酸化物に基づく重量百分率で0.3%超かつ1.5%未満である、請求項1〜13のいずれか1項に記載の焼結粒子。
- 不純物の量が1%未満である、請求項1〜14のいずれか1項に記載の焼結粒子。
- 0.7超の球形度を有するビーズ状である、請求項1〜15のいずれか1項に記載の焼結粒子。
- 細長い形状を有するグレインを含有し、X線回折で測定された細長い形状を有するグレインの量が0.05%〜5%の範囲にある、請求項1〜16のいずれか1項に記載の焼結粒子。
- ジルコニアの80体積%超が正方晶相にある、請求項1〜17のいずれか1項に記載の焼結粒子。
- ドリップキャスティング工程を含む方法によって製造された、請求項1〜18のいずれか1項に記載の焼結粒子。
- 少なくとも焼結工程が終わる前に、熱間静圧圧縮成形(HIP)を含まない方法によって製造された、請求項1〜19のいずれか1項に記載の焼結粒子。
- 粒子混合物を焼結することによって製造された、請求項1〜20のいずれか1項に記載の焼結粒子であって、該粒子混合物が、ZrO 2 粉体、Al 2 O 3 粉体、CeO 2 粉体、CaO粉体、酸化マンガン粉体、及び/又はSrO粉体、及び/又はBaO粉体、及び/又は前記酸化物の前駆体粉体を含み、及び、Y 2 O 3 を、酸化イットリウム粉体及び/または酸化イットリウムの前駆体の形で、又は酸化イットリウムで部分的に安定化されたジルコニアの形で含む、焼結粒子。
- 粒子混合物であって、ZrO2、Al2O3、CeO2、Y2O3 、CaO、及び/又は酸化マンガン及び/又はSrO及び/又はBaO及び/又は前記酸化物の前駆体粒子を、該粒子混合物を焼結することによって請求項1〜21のいずれか1項に記載の焼結粒子が得られるような割合で含有する、粒子混合物。
- メジアン径が1μm未満である、請求項22に記載の粒子混合物。
- メジアン径が0.3μm未満である、請求項23に記載の粒子混合物。
- 請求項1〜21のいずれか1項に記載の焼結粒子、又は請求項22〜24のいずれか1項に記載の粒子混合物から製造された焼結粒子を含む粉砕機。
- 請求項1〜21のいずれか1項に記載の焼結粒子、又は請求項22〜24のいずれか1項に記載の粒子混合物から製造された焼結粒子を粉砕媒体として使用する方法。
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PCT/IB2010/052447 WO2010140121A1 (fr) | 2009-06-03 | 2010-06-01 | Produit fritte a base d'alumine et de zircone |
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US8614001B2 (en) | 2013-12-24 |
SI2438029T1 (sl) | 2014-01-31 |
FR2946337B1 (fr) | 2011-08-05 |
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CN105777087A (zh) | 2016-07-20 |
RU2011148477A (ru) | 2013-07-20 |
AU2010255358A1 (en) | 2011-12-15 |
CN102459124A (zh) | 2012-05-16 |
CA2763679A1 (fr) | 2010-12-09 |
EP2438029A1 (fr) | 2012-04-11 |
WO2010140121A1 (fr) | 2010-12-09 |
JP2012528782A (ja) | 2012-11-15 |
FR2946337A1 (fr) | 2010-12-10 |
CA2763679C (fr) | 2018-08-07 |
KR101702603B1 (ko) | 2017-02-03 |
EP2438029B1 (fr) | 2013-10-23 |
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AU2010255358B2 (en) | 2014-04-24 |
US20120082849A1 (en) | 2012-04-05 |
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