JP5652725B2 - 透明膜形成用インクジェット組成物及びその製造方法 - Google Patents
透明膜形成用インクジェット組成物及びその製造方法 Download PDFInfo
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Classifications
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/20—Filters
- G02B5/22—Absorbing filters
- G02B5/223—Absorbing filters containing organic substances, e.g. dyes, inks or pigments
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
- C08G59/32—Epoxy compounds containing three or more epoxy groups
- C08G59/3209—Epoxy compounds containing three or more epoxy groups obtained by polymerisation of unsaturated mono-epoxy compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/062—Copolymers with monomers not covered by C09D133/06
- C09D133/068—Copolymers with monomers not covered by C09D133/06 containing glycidyl groups
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/20—Filters
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- Life Sciences & Earth Sciences (AREA)
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- Chemical Kinetics & Catalysis (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Ink Jet (AREA)
Description
Claims (15)
- (a)エポキシ基を含有するバインダーポリマーと、(b)下記化学式2の化合物と、(c)溶媒と、を含み、
前記(a)エポキシ基を含有するバインダーポリマーは、エポキシ基を有するモノマーとエポキシ基を有するアクリル系モノマー、側鎖にエチレン性二重結合を有するアクリル系モノマー、(メタ)アクリル酸エステルモノマー、スチレンモノマー及びエチレン性不飽和結合を含むシラン単量体からなる群より選択された1種以上の物質との共重合体を含み、
前記(a)エポキシ基を有するバインダーポリマー及び(b)化学式2の化合物の固形分含量が全体の透明膜形成用インクジェット組成物の総固形分含量に対して95から99重量%である、透明膜形成用インクジェット組成物。
前記式において、R 4 からR 9 は、それぞれ独立的に炭素数1から30の線型または分枝型アルキルと、炭素数1から30の線型または分枝型アルコキシと、炭素数3から30の線型または分枝型アリルと、炭素数2から30の線型または分枝型アルケニルと、炭素数2から30の線型または分枝型ビニルと、エーテル基(−CH 2 OR)、アルコール基(−CH 2 OH)、置換または非置換された炭素数3から20のシクロアルキルと、置換または非置換された炭素数6から40のアリールと、置換または非置換された炭素数7から15のアラルキル(aralkyl)と、炭化水素に置換または非置換された炭素数7から15のアルキルアリール(alkylaryl)からなる群より選択される。 - 前記透明膜形成用インクジェット組成物の総重量に対して(a)エポキシ基を含有するバインダーポリマー1から40重量%と、(b)化学式2のメラミン化合物1から40重量%と、(c)溶媒40から90重量%と、を含む、請求項1に記載の透明膜形成用インクジェット組成物。
- 前記インクジェット組成物は、3次元網構造を有する、請求項1又は2に記載の透明膜形成用インクジェット組成物。
- 前記透明膜形成用インクジェット組成物は、インクジェット工程用に用いられる、請求項1から3の何れか1項に記載の透明膜形成用インクジェット組成物。
- 前記共重合体は、前記エポキシ基を有するモノマーの含量が全体の共重合体を基準に5から50重量%である、請求項1から4のいずれか1項に記載の透明膜形成用インクジェット組成物。
- 前記(a)エポキシ基を含有するバインダーポリマーの重量平均分子量は、1、000から100、000である、請求項1から5の何れか1項に記載の透明膜形成用インクジェット組成物。
- 前記(c)溶媒は、沸点が150から250℃である、請求項1から6の何れか1項に記載の透明膜形成用インクジェット組成物。
- 前記透明膜形成用インクジェット組成物の粘度は、8から16cPである、請求項1から7の何れか1項に記載の透明膜形成用インクジェット組成物。
- 前記(a)エポキシ基を含有するバインダーポリマーと(b)化学式2のメラミン化合物との重量比は1:0.5から1:2である、請求項1から8の何れか1項に記載の透明膜形成用インクジェット組成物。
- (a)エポキシ基を含有するバインダーポリマーと、(b)下記化学式2のメラミン化合物と、(c)溶媒と、を混合する段階を含み、
前記(a)エポキシ基を含有するバインダーポリマーは、エポキシ基を有するモノマーとエポキシ基を有するアクリル系モノマー、側鎖にエチレン性二重結合を有するアクリル系モノマー、(メタ)アクリル酸エステルモノマー、スチレンモノマー及びエチレン性不飽和結合を含むシラン単量体からなる群より選択された1種以上の物質との共重合体を含み、
前記(a)エポキシ基を有するバインダーポリマー及び(b)化学式2の化合物の固形分含量が全体の透明膜形成用インクジェット組成物の総固形分含量に対して95から99重量%である、
透明膜形成用インクジェット組成物の製造方法。
前記式において、R 4 からR 9 は、それぞれ独立的に炭素数1から30の線型または分枝型アルキルと、炭素数1から30の線型または分枝型アルコキシと、炭素数3から30の線型または分枝型アリルと、炭素数2から30の線型または分枝型アルケニルと、炭素数2から30の線型または分枝型ビニルと、エーテル基(−CH 2 OR)、アルコール基(−CH 2 OH)、置換または非置換された炭素数3から20のシクロアルキルと、置換または非置換された炭素数6から40のアリールと、置換または非置換された炭素数7から15のアラルキル(aralkyl)と、炭化水素に置換または非置換された炭素数7から15のアルキルアリール(alkylaryl)からなる群より選択される。 - 請求項1から9の何れか一項に記載の透明膜形成用インクジェット組成物を用いて形成される、透明膜。
- 前記透明膜は、380から780nmにおける光透過度が硬化後に98%である、請求項11に記載の透明膜。
- 請求項1から9の何れか一項に記載の透明膜形成用インクジェット組成物でインクジェット法を用いて透明膜を形成する段階を含む、透明膜の製造方法。
- 請求項11または12に記載の透明膜をオーバーコートとして含む、電子素子。
- 請求項11または12に記載の透明膜をホワイトパターンとして含む、カラーフィルター。
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