JP5554007B2 - 泡沫状皮膚塗布剤 - Google Patents
泡沫状皮膚塗布剤 Download PDFInfo
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- JP5554007B2 JP5554007B2 JP2009097344A JP2009097344A JP5554007B2 JP 5554007 B2 JP5554007 B2 JP 5554007B2 JP 2009097344 A JP2009097344 A JP 2009097344A JP 2009097344 A JP2009097344 A JP 2009097344A JP 5554007 B2 JP5554007 B2 JP 5554007B2
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- Prior art keywords
- mpa
- mass
- foam
- carbon dioxide
- skin
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Landscapes
- Cosmetics (AREA)
Description
すなわち、本発明は、次の成分(A)〜(E)を含有し、耐圧容器内の内圧が25℃で0.7MPa未満となるように充填してなる泡沫状皮膚塗布剤を提供するものである。
(A)N−アシルアミノ酸又はその塩 0.1〜20質量%、
(B)(メタ)アクリル酸系高分子、
(C)多糖類系高分子、
(D)二酸化炭素、及び
(E)炭素数が3〜5の炭化水素から選ばれる混合物であり、前記混合物中に35℃における蒸気圧0.1MPa以上0.5MPa未満の飽和炭化水素が70〜100質量%含まれる炭化水素混合物 0.1〜3質量%。
また、アシル基は、泡質、泡もち、低温安定性の観点から炭素数8〜18の飽和又は不飽和の直鎖又は分岐鎖を有するものが好ましく、このようなアシル基としては、例えばカプロイル基、カプリロイル基、カプリノイル基、ラウロイル基、ミリストイル基、パルミトイル基、ステアロイル基、イソステアロイル基、オレオイル基、リノレオイル基、ココイル基(ヤシ油脂肪酸アシル基)、パーム油脂肪酸アシル基、パーム核油脂肪酸アシル基、牛脂脂肪酸アシル基、直鎖及び分岐合成脂肪酸アシル基等が挙げられる。このうち泡もち及び安定性の観点から、ラウロイル基、ミリストイル基、ココイル基が好ましい。
このうち、起泡性と低温安定性の観点から、N−ラウロイルグルタミン酸ナトリウム、N−ラウロイルグルタミン酸カリウム、N−ミリストイルグルタミン酸ナトリウム、N−ミリストイルグルタミン酸カリウム、N−ココイルグルタミン酸ナトリウム、N−ココイルグルタミン酸カリウムが好ましい。
(メタ)アクリル酸系高分子は、1種又は2種以上を併用することができ、その含有量は容器内組成物全量中に0.01〜5質量%が好ましく、特に0.05〜3質量%が好ましい。
炭素数3〜5の炭化水素混合物の好ましい形態としては、炭素数5の炭化水素をE1、炭素数4の炭化水素をE2、炭素数3の炭化水素をE3とした場合、E1:E2:E3(質量比)が0〜75:15〜100:0〜30の組成、さらに0〜75:20〜99:0.1〜3の組成、特に0〜50:49〜99:0.5〜1の組成の炭化水素混合物が好ましい。また、E2の含有量は、容器内の全組成物中に0.1〜3質量%、さらに0.1〜2質量%、特に0.3〜1.5質量%含有するのが好ましい。
(1)泡安定性評価1(25℃)
25℃で1週間保存後に、皮膚上に3cmφとなるように泡を噴射し、2分間保持して評価した。
○:泡を形成し、2分間保つ
△:泡を形成するが、だれてしまう
×:泡を形成しない
低温(5℃)で6ヶ月保存後に、容器を取り出して25℃に戻してから皮膚上に3cmφとなるように泡を噴射し、2分間保持して評価した。
○:液の分離がなく、泡を形成して2分間保つ
△:N−アシルアミノ酸類の析出が認められ、泡がだれ易い
×:泡を形成しない
前腕部に3cmφとなるように泡を噴射し、2分間保持後に泡を拭き取って、皮膚の状態(皮膚紅潮)を目視で観察した。
◎:はっきりと紅潮を認める
○:紅潮を認める
△:微かに紅潮を認める
×:紅潮を認めない
原液の粘度は、BM型粘度計(東機産業(株))を用いて、測定温度を25℃とし、ロータNo.2、30r/min、1分間の測定条件により測定した。
pHメータ((株)堀場製作所製F−52)を用いて、測定温度を25℃として測定した。
25℃雰囲気下で泡を噴射し、二酸化炭素濃度を測定した。炭酸ガス測定器は、Orion社製、二酸化炭素電極モデル9502BNを用いた。
*2:ノルマルブタン:イソブタン:プロパン=40:16:44質量%
*3:アミソフトCS−11(F)(味の素株式会社)
*4:アミソフトCK−11(F)(味の素株式会社)
*5:PEMULEN TR−1(Lubrizol Advanced Materials, Inc.)
*6:カーボポール981(Lubrizol Advanced Materials, Inc.)
*7:ケルデント(大日本住友製薬株式会社)
*8:メトローズ 60SH−4000(信越化学工業株式会社)
*9:HECダイセル SE850(ダイセル化学工業株式会社)
*10:マイドール10(花王株式会社)
*11:サンソフトM−12J(太陽化学株式会社)
その結果、本発明品の実施例1、4及び5のいずれも0.7MPa未満の内圧に二酸化炭素を高濃度に溶存しており、皮膚紅潮も十分であるとともに、25℃での泡安定性は良好であった。一方、5℃の泡安定性評価2の低温長期保存後においては、トリメチルグリシンを含む実施例1が、これを含まない実施例4及び5に比べて泡質および液性の観点で特に優れていた。ただし、実施例4及び5の泡のたれは少なかった。
*3:アミソフトCS−11(F)(味の素株式会社)
*4:アミソフトMS−11(味の素株式会社)
*5:アミノフォーマーFLDS−L(旭化成ケミカルズ株式会社)
*6:アミライトACS−12(味の素株式会社)
*7:PEMULEN TR−1(Lubrizol Advanced Materials, Inc.)
*8:カーボポール981(Lubrizol Advanced Materials, Inc.)
*9:ケルデント(大日本住友製薬株式会社)
*10:メトローズ60SH−4000(信越化学工業株式会社)
*11:HECダイセルSE850(ダイセル化学工業株式会社)
*12:マイドール10(花王株式会社)
*13:サンソフトM−12J(太陽化学株式会社)
Claims (7)
- 次の成分(A)〜(E)を含有する泡沫状皮膚塗布剤であって、成分(E)に含まれる炭素数が4の炭化水素を泡沫状皮膚塗布剤中に0.3〜3質量%含有し、成分(D)と(E)との質量比(D:E)が35:65〜95:5であり、かつ、耐圧容器内の内圧が25℃で0.7MPa未満となるように充填してなる泡沫状皮膚塗布剤。
(A)N−アシルアミノ酸又はその塩 0.5〜20質量%、
(B)(メタ)アクリル酸系高分子、
(C)多糖類系高分子、
(D)二酸化炭素、及び
(E)炭素数が3〜5の炭化水素から選ばれる混合物であり、前記混合物中に35℃における蒸気圧0.1MPa以上0.5MPa未満の飽和炭化水素が70〜100質量%含まれる炭化水素混合物 0.1〜3質量%。 - 成分(A)、(B)及び(C)を含有する原液と、成分(D)及び(E)を耐圧容器内の内圧が25℃で0.7MPa未満となるように封入して得られるものである請求項1記載の泡沫状皮膚塗布剤。
- 前記耐圧容器内の液体中に溶存する二酸化炭素の量が500〜25,000ppmである請求項1又は2記載の泡沫状皮膚塗布剤。
- さらに、原液に(F)トリメチルグリシンを含有する請求項1〜3のいずれか1項記載の泡沫状皮膚塗布剤。
- 原液のpHが2.5〜7である請求項1〜4のいずれか1項記載の泡沫状皮膚塗布剤。
- 前記耐圧容器内の液体の粘度が100〜500,000mPa・sである請求項1〜5のいずれか1項記載の泡沫状皮膚塗布剤。
- 前記耐圧容器より噴射して形成した泡沫を、皮膚上に拡げることにより使用するためのものである請求項1〜6のいずれか1項記載の泡沫状皮膚塗布剤。
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JP5671118B1 (ja) * | 2013-10-09 | 2015-02-18 | 近代化学株式会社 | 有害動物の忌避用発泡性組成物 |
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JP7120803B2 (ja) * | 2018-05-15 | 2022-08-17 | 東洋エアゾール工業株式会社 | フォーム形成エアゾール組成物 |
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