JP5530638B2 - Aqueous detergent composition and article cleaning method - Google Patents
Aqueous detergent composition and article cleaning method Download PDFInfo
- Publication number
- JP5530638B2 JP5530638B2 JP2009021912A JP2009021912A JP5530638B2 JP 5530638 B2 JP5530638 B2 JP 5530638B2 JP 2009021912 A JP2009021912 A JP 2009021912A JP 2009021912 A JP2009021912 A JP 2009021912A JP 5530638 B2 JP5530638 B2 JP 5530638B2
- Authority
- JP
- Japan
- Prior art keywords
- article
- ether
- water
- cleaning
- cleaning composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000004140 cleaning Methods 0.000 title claims description 53
- 239000000203 mixture Substances 0.000 title claims description 25
- 238000000034 method Methods 0.000 title claims description 17
- 239000003599 detergent Substances 0.000 title claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 34
- 239000000356 contaminant Substances 0.000 claims description 16
- 239000007921 spray Substances 0.000 claims description 11
- 238000007664 blowing Methods 0.000 claims description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- 239000002904 solvent Substances 0.000 claims description 9
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 8
- 238000005507 spraying Methods 0.000 claims description 5
- XYVAYAJYLWYJJN-UHFFFAOYSA-N 2-(2-propoxypropoxy)propan-1-ol Chemical group CCCOC(C)COC(C)CO XYVAYAJYLWYJJN-UHFFFAOYSA-N 0.000 claims description 4
- 239000004094 surface-active agent Substances 0.000 claims description 4
- 239000002888 zwitterionic surfactant Substances 0.000 claims description 4
- RYNQKSJRFHJZTK-UHFFFAOYSA-N (3-methoxy-3-methylbutyl) acetate Chemical compound COC(C)(C)CCOC(C)=O RYNQKSJRFHJZTK-UHFFFAOYSA-N 0.000 claims description 3
- CUVLMZNMSPJDON-UHFFFAOYSA-N 1-(1-butoxypropan-2-yloxy)propan-2-ol Chemical compound CCCCOCC(C)OCC(C)O CUVLMZNMSPJDON-UHFFFAOYSA-N 0.000 claims description 3
- GDXHBFHOEYVPED-UHFFFAOYSA-N 1-(2-butoxyethoxy)butane Chemical compound CCCCOCCOCCCC GDXHBFHOEYVPED-UHFFFAOYSA-N 0.000 claims description 3
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 claims description 3
- IBLKWZIFZMJLFL-UHFFFAOYSA-N 1-phenoxypropan-2-ol Chemical compound CC(O)COC1=CC=CC=C1 IBLKWZIFZMJLFL-UHFFFAOYSA-N 0.000 claims description 3
- VXQBJTKSVGFQOL-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethyl acetate Chemical compound CCCCOCCOCCOC(C)=O VXQBJTKSVGFQOL-UHFFFAOYSA-N 0.000 claims description 3
- JDSQBDGCMUXRBM-UHFFFAOYSA-N 2-[2-(2-butoxypropoxy)propoxy]propan-1-ol Chemical compound CCCCOC(C)COC(C)COC(C)CO JDSQBDGCMUXRBM-UHFFFAOYSA-N 0.000 claims description 3
- CRWNQZTZTZWPOF-UHFFFAOYSA-N 2-methyl-4-phenylpyridine Chemical compound C1=NC(C)=CC(C=2C=CC=CC=2)=C1 CRWNQZTZTZWPOF-UHFFFAOYSA-N 0.000 claims description 3
- 239000003945 anionic surfactant Substances 0.000 claims description 3
- UYAAVKFHBMJOJZ-UHFFFAOYSA-N diimidazo[1,3-b:1',3'-e]pyrazine-5,10-dione Chemical compound O=C1C2=CN=CN2C(=O)C2=CN=CN12 UYAAVKFHBMJOJZ-UHFFFAOYSA-N 0.000 claims description 3
- 229940116423 propylene glycol diacetate Drugs 0.000 claims description 3
- UPGSWASWQBLSKZ-UHFFFAOYSA-N 2-hexoxyethanol Chemical compound CCCCCCOCCO UPGSWASWQBLSKZ-UHFFFAOYSA-N 0.000 claims description 2
- 125000002091 cationic group Chemical group 0.000 claims description 2
- 238000011109 contamination Methods 0.000 claims description 2
- 239000000839 emulsion Substances 0.000 claims description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- 238000004090 dissolution Methods 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- 150000002430 hydrocarbons Chemical class 0.000 claims 1
- 239000012459 cleaning agent Substances 0.000 description 53
- 238000002347 injection Methods 0.000 description 12
- 239000007924 injection Substances 0.000 description 12
- 238000001035 drying Methods 0.000 description 11
- 230000000694 effects Effects 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 238000010998 test method Methods 0.000 description 7
- 230000001804 emulsifying effect Effects 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 239000003921 oil Substances 0.000 description 6
- 239000003093 cationic surfactant Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 4
- 239000003208 petroleum Substances 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 150000003973 alkyl amines Chemical class 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000003209 petroleum derivative Substances 0.000 description 3
- 239000011550 stock solution Substances 0.000 description 3
- 230000000007 visual effect Effects 0.000 description 3
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 229960003237 betaine Drugs 0.000 description 2
- 238000005238 degreasing Methods 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000010711 gasoline engine oil Substances 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 229960005323 phenoxyethanol Drugs 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000005871 repellent Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- BPIUIOXAFBGMNB-UHFFFAOYSA-N 1-hexoxyhexane Chemical compound CCCCCCOCCCCCC BPIUIOXAFBGMNB-UHFFFAOYSA-N 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- RAXXELZNTBOGNW-UHFFFAOYSA-O Imidazolium Chemical compound C1=C[NH+]=CN1 RAXXELZNTBOGNW-UHFFFAOYSA-O 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 230000000274 adsorptive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 229940064004 antiseptic throat preparations Drugs 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000010960 cold rolled steel Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000010705 motor oil Substances 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- -1 polyoxyethylene Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 239000012855 volatile organic compound Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
- Cleaning By Liquid Or Steam (AREA)
Description
本発明は、車両などの各種物品の洗浄に使用する水系洗浄剤組成物（以下単に「洗浄剤」という場合がある）および洗浄方法に関し、特に自動車、鉄道車両などのブレーキ、エンジン、モーターなどの金属、ゴム、プラスチックなどから構成される物品表面を、迅速かつ安全に洗浄することができる洗浄剤および洗浄方法に関する。 The present invention relates to a water-based cleaning composition (hereinafter sometimes simply referred to as “cleaning agent”) and a cleaning method used for cleaning various articles such as vehicles, and more particularly to brakes, engines, motors, and the like of automobiles and railway vehicles. The present invention relates to a cleaning agent and a cleaning method capable of quickly and safely cleaning the surface of an article made of metal, rubber, plastic or the like.
例えば、自動車の点検および整備において、ブレーキ装置やエンジン周りに揮発性の石油系溶剤をスプレーすることにより、ブレーキダストやエンジンオイルなどの汚れを除去することが行われている。この方法では、石油系溶剤の溶解性と揮発性により、スプレーすることのみで、迅速に洗浄および乾燥を行うことができる。しかし、揮発性の石油系溶剤は、常温での引火性を有するため火災の危険性を伴い、また、揮発性有機化合物のため、作業者などへの人体的悪影響や環境的悪影響も懸念され、取り扱い上制約を受けている。 For example, in the inspection and maintenance of automobiles, dirt such as brake dust and engine oil is removed by spraying a volatile petroleum solvent around the brake device and the engine. In this method, due to the solubility and volatility of petroleum-based solvents, cleaning and drying can be performed quickly only by spraying. However, volatile petroleum solvents are flammable at room temperature, which is associated with fire hazards, and because of volatile organic compounds, there are concerns about adverse effects on human health and the environment on workers. There are restrictions on handling.
また、引火性、人体影響、環境影響を考慮した水系洗浄剤が提案されている（特許文献１）。特許文献１には、アルカリイオン水と陰イオン系、非イオン系界面活性剤のいずれか一種類以上と水相溶性溶媒からなる洗浄剤が開示されている。該洗浄剤を用いて物品を洗浄する場合、洗浄後不揮発性の洗浄剤成分が物品表面に残留するため、再度、水やアルコールなどによる濯ぎ工程が必要となり、作業性の低下を招いてしまう。また、物品表面における残留物を削減するために、希薄な水系洗浄剤を使用した場合、十分な洗浄性が得られず、さらに、成分中の水の揮発性が低いことから、洗浄後の乾燥性が悪く、ウエスなどでのふき取り作業が必要となり、やはり作業性の低下を招くという問題があった。 In addition, an aqueous cleaning agent has been proposed in consideration of flammability, human body influence, and environmental influence (Patent Document 1). Patent Document 1 discloses a cleaning agent comprising an alkaline ionized water, at least one of an anionic or nonionic surfactant and a water-compatible solvent. When an article is cleaned using the cleaning agent, a non-volatile cleaning agent component remains on the surface of the article after cleaning, so that a rinsing step with water, alcohol, or the like is required again, resulting in a decrease in workability. In addition, in order to reduce the residue on the surface of the article, when using a dilute water-based cleaning agent, sufficient cleaning properties cannot be obtained, and furthermore, since the volatility of water in the components is low, drying after cleaning is performed. There is a problem that the workability is poor, and wiping work with a waste cloth or the like is necessary, which also causes a decrease in workability.
上述した従来の石油系および水系洗浄剤は、引火性、人体影響、環境影響、洗浄性、成分残留による仕上がり不良、被洗浄物品の腐食などのいずれかの問題があり、また、特許文献１では、これらの問題は低減されているものの、洗浄剤の乾燥性が十分ではなく、乾燥性改善のためアルコール、アセトンなどを配合したものでも、本発明が目的とする効果を得るには至らないものである。 The conventional petroleum-based and water-based cleaning agents described above have any one of problems such as flammability, human body influence, environmental influence, cleanability, poor finish due to residual components, and corrosion of articles to be cleaned. Although these problems have been reduced, the drying property of the cleaning agent is not sufficient, and even when blended with alcohol, acetone or the like for improving the drying property, the intended effect of the present invention is not obtained. It is.
従って、本発明の目的は、車両などの各種物品の洗浄において、洗浄剤の引火性による危険が無く、被洗浄物品を腐食させずに、迅速かつ良好な洗浄性と仕上がり状態を得ることができる洗浄剤および洗浄方法を提供することである。 Accordingly, an object of the present invention is to provide a quick and good cleanability and finished state without the danger of the flammability of the cleaning agent in cleaning various articles such as vehicles and without corroding the article to be cleaned. It is to provide a cleaning agent and a cleaning method.
上記目的は以下の本発明によって達成される。すなわち、本発明は、水系洗浄剤組成物を被洗浄物品表面にスプレー付与し、前記水系洗浄剤組成物の水膜中に汚染物を溶解および／または乳化させる工程と、エアブローして前記汚染物が溶解および／または乳化している前記水系洗浄剤組成物を吹き飛ばして乾燥した表面を有する物品を得る工程とからなる物品の洗浄方法に用いられる水系洗浄剤組成物であって、カチオン系界面活性剤および／または両性イオン系界面活性剤を０．０５〜３．０３質量％（Ｉ）と、水に対する溶解度が２０質量％以下であるグリコールエーテル０．５０〜５．０５質量％（II）と、水９１．９２〜９９．４５質量％（III）とを含み（但し、アニオン系界面活性剤を含むものを除く）、前記成分（Ｉ）、前記成分（II）、及び前記成分（III）の合計が、１００質量％であることを特徴とする水系洗浄剤組成物を提供する。該水系洗浄剤組成物は、好ましくは自動車もしくは鉄道車両のブレーキ装置、エンジン、またはエンジン周りの部品の洗浄に用いられる。該水系洗浄剤組成物におけるグリコールエーテルとしては、ジプロピレングリコールモノプロピルエーテル、ジプロピレングリコールモノブチルエーテル、プロピレングリコールモノブチルエーテル、プロピレングリコールモノフェニルエーテル、プロピレングリコールジアセテート、トリプロピレングリコールモノブチルエーテル、エチレングリコールモノヘキシルエーテル、エチレングリコールモノフェニルエーテル、エチレングリコールジブチルエーテル、ジエチレングリコールジブチルエーテル、ジエチレングリコールモノブチルエーテルアセテート、および３−メチル−３−メトキシブチルアセテートから選ばれる少なくとも１種であること；さらに石油系炭化水素溶剤を０．５〜５質量％の範囲で含むこと；および洗浄剤の１気圧の状態における引火点が７０℃以上であることが好ましい。なお、本発明における「溶解度」とは、１気圧・２０℃における純水１００質量部中に溶解するグリコールエーテルの質量部を意味する。 The above object is achieved by the present invention described below. That is, the present invention includes a step of spraying an aqueous cleaning composition onto the surface of an article to be cleaned, and dissolving and / or emulsifying contaminants in a water film of the aqueous cleaning composition, An aqueous detergent composition for use in a method for washing an article comprising a step of obtaining an article having a dried surface by blowing off the aqueous detergent composition in which the aqueous solution is dissolved and / or emulsified, comprising a cationic surfactant 0.05 to 3.03 mass% (I) of an agent and / or zwitterionic surfactant and 0.50 to 5.05 mass% (II) of a glycol ether having a solubility in water of 20 mass% or less , water from 91.92 to 99.45 wt% (III) and a containing body (excluding those containing anionic surfactant), the component (I), wherein component (II), and wherein component (III ) Is 1 An aqueous detergent composition characterized by being 00% by mass is provided. The water-based cleaning composition is preferably used for cleaning a brake device, an engine, or parts around the engine of an automobile or a railway vehicle. The glycol ether in the aqueous cleaning composition, dipropylene glycol monopropyl ether, dipropylene glycol monobutyl ether, propylene glycol monobutyl ether, propylene glycol monophenyl ether, propylene glycol diacetate, tripropylene glycol monobutyl ether, ethylene glycol mono At least one selected from hexyl ether, ethylene glycol monophenyl ether, ethylene glycol dibutyl ether, diethylene glycol dibutyl ether, diethylene glycol monobutyl ether acetate, and 3-methyl-3-methoxybutyl acetate; and a petroleum hydrocarbon solvent; Including in the range of 0.5 to 5% by mass; It is preferred flash point in the state at 70 ° C. or higher. The “solubility” in the present invention means a mass part of glycol ether dissolved in 100 parts by mass of pure water at 1 atm and 20 ° C.
また、本発明は、上記本発明の水系洗浄剤組成物を被洗浄物品表面にスプレー付与し、前記水系洗浄剤組成物の水膜中に汚染物を溶解および／または乳化させる工程と、エアブローして汚染物が溶解および／または乳化している前記水系洗浄剤組成物を吹き飛ばして乾燥した表面を有する物品を得る工程とからなることを特徴とする物品の洗浄方法を提供する。 Further, the present invention includes the steps of an aqueous detergent composition of the present invention was spray applied onto cleaned article surface, Ru contaminants dissolved and / or emulsified in water film of the aqueous detergent composition, e Aburo to provide a method of cleaning an article characterized by Rukoto such from the contaminants is obtained an article having a dissolved and / or emulsified by Fukitoba pre Symbol aqueous detergent compositions are dry surface step .
本発明によれば、車両などの各種物品の洗浄において、洗浄剤の引火性による危険が無く、被洗浄物品を腐食させずに、迅速かつ良好な洗浄性と仕上がり状態を得ることができる洗浄剤および洗浄方法を提供することができる。さらに詳しくは、本発明の洗浄剤は、洗浄性と被洗浄物品表面を撥水または水切れ状態とする二つの効果を有しており、スプレー塗布により汚染物質を除去し、続いてエアブローすることにより、撥水または水切れ状態を示した被洗浄物品表面の残留洗浄剤を吹き飛ばすことにより、乾燥され、良好な仕上がり状態を得ることができる。 According to the present invention, in cleaning various articles such as vehicles, there is no danger due to the flammability of the cleaning agent, and the cleaning agent can obtain a quick and good cleaning property and finished state without corroding the article to be cleaned. And a cleaning method can be provided. More specifically, the cleaning agent of the present invention has two effects of making the surface of the article to be cleaned water-repellent or water-removed, removing contaminants by spray application, and then air blowing. By blowing off the residual cleaning agent on the surface of the article to be cleaned that has shown water repellency or running out of water, it is dried and a good finished state can be obtained.
本発明における洗浄原理は定かではないが、本発明者らは以下のように推測する。すなわち、カチオン系および／または両性イオン系界面活性剤の強力な乳化力および吸着力と、水難溶性グリコールエーテルの強い溶解力によって汚染物質が、洗浄剤中に溶解または乳化され、同時に被洗浄物品表面に界面活性剤が吸着し、被洗浄物品表面を撥水性または水切れ状態とする。併せて、これらの界面活性剤が被洗浄物品の表面に吸着することで、被洗浄物品表面の一時的な防錆効果も発揮する。 Although the cleaning principle in the present invention is not clear, the present inventors presume as follows. That is, the contaminants are dissolved or emulsified in the cleaning agent by the strong emulsifying and adsorbing power of the cationic and / or zwitterionic surfactant and the strong dissolving power of the poorly water-soluble glycol ether, and at the same time the surface of the article to be cleaned The surface active agent is adsorbed to the surface of the article to be cleaned, making the surface of the article to be cleaned water-repellent or draining. In addition, these surfactants are adsorbed on the surface of the article to be cleaned, thereby exhibiting a temporary rust prevention effect on the surface of the article to be cleaned.
さらに、洗浄後の被洗浄物品をエアブローすることにより、被洗浄物品表面の余分な洗浄剤成分と残留汚染物質が吹き飛ばされ、良好な仕上がり状態の洗浄物品を得ることができる。 Further, by air blowing the article to be cleaned after cleaning, excess cleaning components and residual contaminants on the surface of the article to be cleaned are blown away, and a cleaned article having a good finish can be obtained.
次に発明を実施するための最良の形態を挙げて本発明をさらに詳しく説明する。
本発明の洗浄剤に使用される成分（I）のカチオン系界面活性剤および両性イオン系界面活性剤は、特に制限はなく、乳化性と吸着性を考慮し、自由に選択することができる。例えば、カチオン系界面活性剤では、アルキルアミンおよびその塩、アルキルジアミンおよびその塩、ジアルキルジメチルアンモニウム塩、モノアルキルトリメチルアンモニウム塩、また、これらにアルキレンオキサイドを付加したものなどが挙げられ、両性イオン系界面活性剤では、脂肪酸アミドプロピルベタイン、イミダゾニウムベタイン、アルキルアミンオキサイドなどが挙げられる。
Next, the present invention will be described in more detail with reference to the best mode for carrying out the invention.
The cationic surfactant and the zwitterionic surfactant of component (I) used in the cleaning agent of the present invention are not particularly limited, and can be freely selected in consideration of emulsifying properties and adsorptive properties. Examples of cationic surfactants include alkylamines and salts thereof, alkyldiamines and salts thereof, dialkyldimethylammonium salts, monoalkyltrimethylammonium salts, and those obtained by adding an alkylene oxide to these. Examples of the surfactant include fatty acid amidopropyl betaine, imidazolium betaine, and alkylamine oxide.
上記成分（I）の配合量は、洗浄剤において、０．０５〜３．００質量％を占める量であり、成分（I）の配合量が０．０５質量％未満であると、乳化力が低下して良好な洗浄力が得られなくなり、一方、成分（I）の配合量が３．００質量％を超えると、被洗浄物品表面に残留する成分が多くなり、エアブロー後の仕上がり状態を損ねることとなる。 The compounding amount of the component (I) is an amount that occupies 0.05 to 3.00% by mass in the cleaning agent, and the emulsifying power is less than 0.05% by mass of the component (I). On the other hand, when the blending amount of component (I) exceeds 3.00% by mass, the amount of components remaining on the surface of the article to be cleaned increases and the finished state after air blowing is impaired. It will be.
本発明の洗浄剤に使用される成分（II）の水に難溶性のグリコールエーテルは、その種類に制限はなく、成分（II）を水中に投入した場合の溶解度が２０質量％以下のものが好ましい。具体的には、エチレングリコールモノヘキシルエーテル（溶解度１．０質量％）、エチレングリコールモノフェニルエーテル（溶解度２．６質量％）、エチレングリコールジブチルエーテル（溶解度０．２質量％）、ジエチレングリコールジブチルエーテル（溶解度０．３質量％）、ジエチレングリコールモノブチルエーテルアセテート（溶解度６．５質量％）などのエチレングリコール系、プロピレングリコールモノブチルエーテル（溶解度６．０質量％）、プロピレングリコールモノフェニルエーテル（溶解度１．０質量％）、ジプロピレングリコールモノプロピルエーテル（溶解度１９．０質量％）、ジプロピレングリコールモノブチルエーテル（溶解度４．３質量％）、トリプロピレングリコールモノブチルエーテル（溶解度３．０質量％）、プロピレングリコールジアセテート（溶解度８．０質量％）、３−メチル−３−メトキシブチルアセテート（溶解度６．８質量％）などのプロピレングリコール系などが挙げられる。 The water-insoluble glycol ether of the component (II) used in the cleaning agent of the present invention is not limited in its type, and the solubility when the component (II) is introduced into water is 20% by mass or less. preferable. Specifically, ethylene glycol monohexyl ether (solubility 1.0 mass%), ethylene glycol monophenyl ether (solubility 2.6 mass%), ethylene glycol dibutyl ether (solubility 0.2 mass%), diethylene glycol dibutyl ether ( Solubility 0.3% by mass), ethylene glycol-based diethylene glycol monobutyl ether acetate (solubility 6.5% by mass), propylene glycol monobutyl ether (solubility 6.0% by mass), propylene glycol monophenyl ether (solubility 1.0 mass) %), Dipropylene glycol monopropyl ether (solubility 19.0 mass%), dipropylene glycol monobutyl ether (solubility 4.3 mass%), tripropylene glycol monobutyl ether (solubility 3.0) The amount%), propylene glycol diacetate (solubility 8.0% by weight), 3-methyl-3-methoxybutyl acetate (solubility 6.8% by mass), and the like propylene glycol and the like.
上記成分（II）の水に対する溶解度が２０質量％を超えると、成分（II）の水への溶解性が良くなる反面、汚染物質である油性物質の洗浄剤中への溶解性が下がり、成分（II）を多量に配合しなければ汚染物の十分な溶解性が得られなくなり、成分（II）の配合量が多くなると、被洗浄物品表面における成分（II）の残留性が高くなり、洗浄後の乾燥性や仕上がり状態を低下させることとなる。 When the solubility of the above component (II) in water exceeds 20% by mass, the solubility of the component (II) in water is improved, but the solubility of the oily substance, which is a contaminant, in the detergent is decreased, and the component If a large amount of (II) is not blended, sufficient solubility of the contaminants cannot be obtained, and if the amount of component (II) increases, the persistence of component (II) on the surface of the article to be cleaned increases and cleaning is performed. Later drying and finishing will be reduced.
上記成分（II）の配合量は、洗浄剤において、０．５０〜５．００質量％を占める量であり、成分（II）の配合量が０．５０質量％未満であると、汚染物の洗浄剤中への溶解性が低下し、良好な洗浄力が得られなくなり、一方、成分（II）の配合量が５．００質量％を超えると、被洗浄物品表面に残留する成分が多くなり、洗浄後の乾燥性を低下させることとなる。 The blending amount of the component (II) is an amount occupying 0.50 to 5.00% by mass in the cleaning agent, and if the blending amount of the component (II) is less than 0.50% by mass, Solubility in the cleaning agent decreases and good detergency cannot be obtained. On the other hand, if the amount of component (II) exceeds 5.00% by mass, more components remain on the surface of the article to be cleaned. The drying property after washing will be reduced.
本発明の洗浄剤に使用される成分（III）の水は、洗浄後の被洗浄物品表面における残留物を削減し良好な仕上がり状態を得るために、塩類を除去したイオン交換水を使用することが望ましい。使用量は成分（Ｉ）と成分（II）と成分（III）との合計が１００質量％になる量、すなわち、成分（III）が９２．００〜９９．４５質量％になる量である。 The component (III) water used in the cleaning agent of the present invention uses ion-exchanged water from which salts have been removed in order to reduce the residue on the surface of the article to be cleaned and obtain a good finish. Is desirable. The amount used is such that the total of component (I), component (II) and component (III) is 100% by mass, that is, the amount of component (III) is 92.00 to 99.45% by mass.
本発明の洗浄剤は、上記３成分を単に混合攪拌することで調製でき、調製に際しては、本発明の効果を損なわない範囲において、石油系炭化水素溶剤、非イオン系界面活性剤、高分子物質などの乳化安定剤、防腐剤、防錆剤、着色剤、香料などの助剤を加えてもよい。特にイソパラフィン系、ノルマルパラフィン系、ナフテン系、芳香族系などの石油系炭化水素溶剤を洗浄剤全量中で０．５〜５質量％の範囲で含むことにより、被洗浄物品の油性汚れに対して、脱脂性・溶解性に優れ、かつ金属への腐食が少ない洗浄剤とすることができる。 The cleaning agent of the present invention can be prepared by simply mixing and stirring the above three components. In the preparation, a petroleum hydrocarbon solvent, a nonionic surfactant, a polymer substance, as long as the effects of the present invention are not impaired. Auxiliary agents such as emulsion stabilizers, antiseptics, rust inhibitors, colorants, fragrances and the like may be added. In particular, by containing petroleum hydrocarbon solvents such as isoparaffinic, normal paraffinic, naphthenic, aromatic, etc. in the range of 0.5 to 5% by mass in the total amount of cleaning agent, against oily stains on articles to be cleaned Therefore, it is possible to obtain a cleaning agent which is excellent in degreasing and solubility and has little corrosion on metal.
本発明の洗浄剤は、前記各成分が前記の配合量で配合されたものでもよいし、成分（I）と成分（II）とを、前記の配合比率を保って高濃度に含む水溶液（原液）であってもよく、好ましくは調製時に濃厚物である原液を調製し、使用時にその原液を各成分が前記の濃度になるように希釈して使用することが好ましい。以上の本発明の洗浄剤は、１気圧の状態においてその引火点が７０℃以上である。 The cleaning agent of the present invention may be one in which each of the above components is blended in the above blending amount, or an aqueous solution (stock solution) containing component (I) and component (II) at a high concentration while maintaining the above blending ratio. It is preferable that a stock solution that is a concentrated product is prepared at the time of preparation, and the stock solution is diluted and used so that each component has the above-mentioned concentration at the time of use. The above-described cleaning agent of the present invention has a flash point of 70 ° C. or higher at 1 atm.
本発明の物品の洗浄方法は、上記本発明の洗浄剤を、被洗浄物品表面にスプレー塗布することで、該塗布液中に汚染物を溶解または乳化させ、続いてエアブローすることにより、被洗浄物品の表面に残っている洗浄剤を吹き飛ばすとともに、被洗浄物品表面を乾燥させることを特徴としている。 In the method for cleaning an article of the present invention, the cleaning agent of the present invention is spray-coated on the surface of the article to be cleaned, so that contaminants are dissolved or emulsified in the coating solution, followed by air blowing, thereby cleaning the article to be cleaned. The cleaning agent remaining on the surface of the article is blown away, and the surface of the article to be cleaned is dried.
上記本発明の洗浄方法の対象となる被洗浄物品は特に限定されないが、本発明の洗浄方法が特に好適に適用される被洗浄物品としては、例えば、自動車や鉄道車両などのブレーキ装置、エンジン、エンジン周りの部品などが挙げられる。 The article to be cleaned that is the target of the cleaning method of the present invention is not particularly limited. Examples of the article to be cleaned to which the cleaning method of the present invention is particularly preferably applied include, for example, brake devices such as automobiles and railway vehicles, engines, These include parts around the engine.
被洗浄物品に対する洗浄剤の付与方法としては、被洗浄物品が立体構造物である場合には、スプレー法が最も好ましい。被洗浄物品の表面には洗浄剤がある程度の時間留まっていることが好ましく、例えば、洗浄剤をスプレー付与後、約１〜１０秒間程度の間隔をおいて、物品表面にエアブローを行うことで、物品表面の洗浄剤は吹き飛ばされ、同時に物品表面には、汚染物を含む洗浄剤が残ることなく表面が乾燥される。 As a method for applying the cleaning agent to the article to be cleaned, the spray method is most preferable when the article to be cleaned is a three-dimensional structure. It is preferable that the cleaning agent stays on the surface of the article to be cleaned for a certain period of time, for example, after spraying the cleaning agent, by performing air blow on the surface of the article at an interval of about 1 to 10 seconds, The cleaning agent on the surface of the article is blown away, and at the same time, the surface of the article is dried without leaving a cleaning agent containing contaminants.
上記において、被洗浄物品に付与する洗浄剤の量は特に限定されず、汚染状況によって適宜決定すればよく、例えば、表面１ｍ2あたり約１００〜１５００ｇの洗浄剤が付着する量であることが好ましい。物品表面に形成された洗浄剤水膜に短時間で汚染物が溶解若しくは乳化するように、洗浄剤を温めて使用してもよいし、また、被洗浄物品を温めておいてもよい。また、エアブローに際しては使用するエアの温度を、例えば、３０〜８０℃程度に高めておくことで、乾燥をさらに促進させることができる。使用するスプレー装置およびエアブロー装置としては、従来公知のスプレー装置やエアブロー装置がいずれも使用可能であるが、例えば、特開平１１−５９３４０号公報や特開２００１−３００４４２号公報に記載の如き洗浄兼エアブロー装置が好ましく使用できる。 In the above, the amount of the cleaning agent to be applied to the article to be cleaned is not particularly limited, and may be appropriately determined depending on the contamination state. For example, it is preferable that about 100 to 1500 g of the cleaning agent adheres per 1 m 2 of the surface. . The cleaning agent may be warmed and used so that contaminants dissolve or emulsify in the cleaning agent water film formed on the surface of the article, or the article to be cleaned may be warmed. In addition, when air is blown, drying can be further promoted by increasing the temperature of air used to, for example, about 30 to 80 ° C. As the spray device and air blow device to be used, any conventionally known spray device or air blow device can be used. For example, as described in JP-A-11-59340 and JP-A-2001-300442 An air blow device can be preferably used.
本発明の洗浄方法における洗浄条件の１例を以下に示す。
［スプレー条件］
液温 ２０〜５０℃
噴射圧 ０．５〜１０ＭＰａ
噴射距離 １０〜５０ｃｍ
噴射時間 １０〜３０秒間
［スプレーとエアブローとの時間間隔］３〜１０秒間
［エアブロー条件］
エア温度 ２０〜７０℃
噴射圧 ０．５〜１０ＭＰａ
噴射距離 １０〜５０ｃｍ
噴射時間 ５〜３０秒間
An example of the cleaning conditions in the cleaning method of the present invention is shown below.
[Spray conditions]
Liquid temperature 20-50 ° C
Injection pressure 0.5-10MPa
Injection distance 10-50cm
Injection time 10 to 30 seconds [Time interval between spray and air blow] 3 to 10 seconds [Air blow conditions]
Air temperature 20 ~ 70 ℃
Injection pressure 0.5-10MPa
Injection distance 10-50cm
Injection time 5-30 seconds
以上の本発明の洗浄方法によって、物品表面に付着した汚染物は容易にかつ完璧に除去され、汚染物や洗浄剤成分の残留物が殆ど存在しない良好な洗浄仕上がり状態の表面を有する物品を得ることができる。 By the cleaning method of the present invention, the contaminants attached to the surface of the article are easily and completely removed, and an article having a surface with a good cleaning finish in which almost no contaminants or residues of detergent components are present is obtained. be able to.
以下に実施例および比較例を挙げて本発明をさらに詳しく説明する。但し、本発明はこれらの実施例によってなんら制限されるものではない。 Hereinafter, the present invention will be described in more detail with reference to Examples and Comparative Examples. However, the present invention is not limited to these examples.
［実施例１］
成分（I）のカチオン系界面活性剤（ポリオキシエチレンアルキルアミン）３質量部と、成分（II）のグリコールエーテル（ジプロピレングリコールモノプロピルエーテル）５質量部と、成分（III）の水（イオン交換水）９２質量部とを混合し、撹拌溶解させて、実施例１の洗浄剤とした。
[Example 1]
3 parts by weight of component (I) cationic surfactant (polyoxyethylene alkylamine), 5 parts by weight of component (II) glycol ether (dipropylene glycol monopropyl ether), and water (ion) of component (III) Exchanged water) 92 parts by mass was mixed and dissolved by stirring to obtain the cleaning agent of Example 1.
［実施例２〜６、比較例１〜７］
以下、実施例１と同様の操作により、実施例２〜６、比較例１〜７の洗浄剤を得た。組成は表１に、成分の詳細は表２に、評価結果は表３、４に記載した。
なお、以上の実施例および比較例の洗浄剤の引火点はいずれも７０℃以上である。
[Examples 2-6, Comparative Examples 1-7]
Hereinafter, the cleaning agents of Examples 2 to 6 and Comparative Examples 1 to 7 were obtained by the same operation as Example 1. The composition is shown in Table 1, the details of the components are shown in Table 2, and the evaluation results are shown in Tables 3 and 4.
The flash points of the cleaning agents in the above examples and comparative examples are both 70 ° C. or higher.
（試験）
［試験方法１ 洗浄試験］
十分に脱脂洗浄した冷間圧延鋼板（ＳＰＣＣ−ＳＢ）を試験板とし、これにガソリンエンジン用オイルを１ｇ塗布し、これを汚染板とする。上記汚染板へ実施例および比較例の洗浄剤をスプレー（塗布量：１０００ｇ／ｍ2）し、５秒間放置後にエアブロー（エア温度：２５℃）にて汚染板表面に残っている洗浄剤を吹き飛ばし、洗浄された試験板の外観を目視評価する。
スプレーおよびエアブローの条件を以下に記す。
(test)
[Test Method 1 Cleaning Test]
A cold-rolled steel plate (SPCC-SB) that has been thoroughly degreased and washed is used as a test plate, and 1 g of gasoline engine oil is applied to this plate as a contaminated plate. The cleaning agent of Examples and Comparative Examples is sprayed onto the above-mentioned contaminated plate (application amount: 1000 g / m 2 ), and after left for 5 seconds, the cleaning agent remaining on the surface of the contaminated plate is blown off by air blow (air temperature: 25 ° C.). The appearance of the cleaned test plate is visually evaluated.
The spray and air blow conditions are described below.
スプレー条件 ：噴射圧 ０．７ＭＰａ
噴射距離 ３０ｃｍ
噴射時間 １０秒間
エアブロー条件：噴射圧 ０．７ＭＰａ
噴射距離 ３０ｃｍ
噴射時間 １０秒間
Spray conditions: Injection pressure 0.7 MPa
Injection distance 30cm
Injection time 10 seconds Air blow condition: Injection pressure 0.7MPa
Injection distance 30cm
Injection time 10 seconds
［試験方法２ 乳化試験］
実施例および比較例の洗浄剤を試験管に５ｍｌ採り、これにガソリンエンジン用オイルをスポイトで０．２ｇ滴下する。この試験管に蓋をして１回上下を反転させて内容液を混合した後、内容液の状態を目視評価する。
[Test Method 2 Emulsification Test]
5 ml of the cleaning agent of Examples and Comparative Examples is taken in a test tube, and 0.2 g of gasoline engine oil is dropped into the test tube with a dropper. After covering the test tube and inverting the top and bottom once to mix the content liquid, the state of the content liquid is visually evaluated.
［試験方法３ 材質影響試験］
各種材質の試験片を実施例１〜６の洗浄剤に１時間浸漬した後、取り出してエアブローにより残留液を吹き飛ばす。
上記試験片の外観を目視評価する。
試験片材質：鉄、アルミニウム、ＡＢＳ樹脂、天然ゴム
[Test Method 3 Material Effect Test]
After the test pieces of various materials are immersed in the cleaning agents of Examples 1 to 1 for 1 hour, they are taken out and the residual liquid is blown away by air blowing.
The appearance of the test piece is visually evaluated.
Specimen material: Iron, aluminum, ABS resin, natural rubber
［評価基準］
各試験法の評価基準は次の通りである。
［試験方法１ 洗浄試験］（目視判定）
［洗浄性］
◎：オイルおよびシミの無い清浄な状態となる。
○：オイルは無いが、若干のシミが残る。
△：一部分オイルが残留する。
×：全体にオイルが残留する。
[Evaluation criteria]
The evaluation criteria for each test method are as follows.
[Test Method 1 Cleaning Test] (Visual Judgment)
[Cleanability]
(Double-circle): It will be in a clean state without oil and a spot.
○: There is no oil, but some spots remain.
Δ: Part of oil remains.
X: Oil remains throughout.
［乾燥性］
◎：残留液が無く乾燥している。
○：若干、水滴が残る。
△：薄い液の膜が残る。
×：全体に液が残留している。
[Drying]
A: There is no residual liquid and it is dry.
○: Some water droplets remain.
Δ: A thin liquid film remains.
X: The liquid remains in the whole.
［試験方法２ 乳化試験］（目視判定）
◎：乳白色に乳化する。
○：乳白色に乳化するが、油滴が少量残る。
△：オイルが粗く分散する。
×：殆ど乳化しない。
[Test Method 2 Emulsification Test] (Visual Judgment)
(Double-circle): It emulsifies milky white.
○: Although emulsified milky white, a small amount of oil droplets remain.
Δ: The oil is coarsely dispersed.
X: Almost not emulsified.
［試験方法３ 材質影響試験］（目視判定）
◎：全く変化が観られない。
○：若干のシミが残る。
△：薄い変色が観られる。
×：変色または、膨潤する。
[Test Method 3 Material Effect Test] (Visual Judgment)
A: No change is observed at all.
○: Some stains remain.
Δ: Light discoloration is observed.
X: Discoloration or swelling.
表３の評価結果より、実施例１から６では、いずれも洗浄性、乾燥性、乳化性において良好な性能を有していた。良好な洗浄性は、高い乳化力により得られ、良好な乾燥性は、撥水性または水切れ性を有する表面をつくることと、エアブローによる乾燥行程を行うことにより達成されている。この洗浄性と撥水性または水切れ性は、従来にない特出した効果であると言える。 From the evaluation results of Table 3, Examples 1 to 6 all had good performance in terms of detergency, drying property and emulsifying property. Good detergency is obtained by a high emulsifying power, and good dryness is achieved by creating a surface having water repellency or drainage and performing a drying process by air blow. This detergency and water repellency or water drainage can be said to be unprecedented effects.
比較例１〜７は、洗浄性、乾燥性のどちらかにおいて不具合があり、本発明の目的とする効果は得られないものである。 In Comparative Examples 1 to 7, there is a defect in either cleaning property or drying property, and the intended effect of the present invention cannot be obtained.
さらに、実施例１〜６においては、各種材質に対する洗浄剤の影響は少なく、いずれの洗浄剤も十分に使用に耐える性能であった。特に鉄に対しては、腐食などの影響のみならず、防錆作用を併せもつことが確認された。 Furthermore, in Examples 1-6, there was little influence of the cleaning agent with respect to various materials, and any cleaning agent was the performance which fully endured use. Especially for iron, it was confirmed that it not only has the effect of corrosion, but also has a rust preventive action.
実施例７
実施例１における洗浄剤において、イオン交換水の量を９１質量部とし、さらにイソパラフィン系溶剤（沸点２１０〜２６０℃）１質量部を加えて乳化させた以外は、実施例１と同様に本発明の洗浄剤を得た。この洗浄剤は、実施例１の洗浄剤と同様の洗浄性を示し、さらに油性汚れに対しても優れた脱脂性・洗浄性を有し、かつ金属を腐食しないものであった。
Example 7
The present invention is the same as in Example 1 except that the amount of ion-exchanged water in the cleaning agent in Example 1 is 91 parts by mass, and 1 part by mass of an isoparaffin solvent (boiling point 210 to 260 ° C.) is added and emulsified. A cleaning agent was obtained. This cleaning agent showed the same cleaning properties as the cleaning agent of Example 1, and also had excellent degreasing properties and cleaning properties against oily soil, and did not corrode metals.
本発明の洗浄剤により、車両などの各種部品洗浄において、洗浄剤の引火性による危険が無く、被洗浄物品を腐食させずに、迅速かつ良好な洗浄性、仕上がり状態を有する洗浄物品を得ることができる。 With the cleaning agent of the present invention, in cleaning various parts such as vehicles, there is no danger due to the flammability of the cleaning agent, and a cleaning article having a quick and good cleaning property and finished state is obtained without corroding the article to be cleaned. Can do.
Claims (6)
カチオン系界面活性剤および／または両性イオン系界面活性剤を０．０５〜３．０３質量％（Ｉ）と、水に対する溶解度が２０質量％以下であるグリコールエーテル０．５０〜５．０５質量％（II）と、水９１．９２〜９９．４５質量％（III）とを含み（但し、アニオン系界面活性剤を含むものを除く）、
前記成分（Ｉ）、前記成分（II）、及び前記成分（III）の合計が、１００質量％であることを特徴とする水系洗浄剤組成物。 Spraying the surface of the article to be cleaned with a water-based cleaning composition to dissolve and / or emulsify contaminants in the water film of the water-based cleaning composition, and air blowing to dissolve and / or emulsify the contaminants An aqueous cleaning composition for use in a method for cleaning an article comprising a step of obtaining an article having a dried surface by blowing off the aqueous cleaning composition,
Cationic surface active agents and / or 0.05 to 3.03 wt% zwitterionic surfactant and (I), solubility in water is less than 20 wt% glycol ether from 0.50 to 5.05 wt% (excluding, however, those containing an anionic surfactant) and (II), water from 91.92 to 99.45 wt% (III) and a containing body,
The total amount of said component (I), said component (II), and said component (III) is 100 mass%, The aqueous cleaning composition characterized by the above-mentioned.
エアブローして汚染物が溶解および／または乳化している前記水系洗浄剤組成物を吹き飛ばして乾燥した表面を有する物品を得る工程とからなることを特徴とする物品の洗浄方法。 Step an aqueous detergent composition according to any one of claims 1 to 5 sprays applied to be cleaned article surface, Ru contaminants dissolved and / or emulsified in water film of the aqueous cleaning composition When,
Article cleaning method characterized by Rukoto a and a step of obtaining an article having a surface contamination by blowing air through was dried Fukitoba dissolution and / or emulsion to have pre Symbol aqueous detergent composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2009021912A JP5530638B2 (en) | 2008-01-31 | 2009-02-02 | Aqueous detergent composition and article cleaning method |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2008020391 | 2008-01-31 | ||
| JP2008020391 | 2008-01-31 | ||
| JP2009021912A JP5530638B2 (en) | 2008-01-31 | 2009-02-02 | Aqueous detergent composition and article cleaning method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2009203473A JP2009203473A (en) | 2009-09-10 |
| JP5530638B2 true JP5530638B2 (en) | 2014-06-25 |
Family
ID=41146042
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009021912A Active JP5530638B2 (en) | 2008-01-31 | 2009-02-02 | Aqueous detergent composition and article cleaning method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP5530638B2 (en) |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61101280A (en) * | 1984-10-23 | 1986-05-20 | 本田技研工業株式会社 | Washing method and washer |
| JP3326052B2 (en) * | 1995-08-15 | 2002-09-17 | 花王株式会社 | Liquid detergent composition |
| JPH11279589A (en) * | 1998-03-30 | 1999-10-12 | Nicca Chem Co Ltd | Antibacterial detergent for housing |
| JP2003176497A (en) * | 2001-12-10 | 2003-06-24 | Lion Corp | Cleanser composition for glass |
| JP2003183697A (en) * | 2001-12-20 | 2003-07-03 | Lion Corp | Detergent composition for rest room |
| JP2004059806A (en) * | 2002-07-30 | 2004-02-26 | Johnson Professional Co Ltd | Detergent composition for hard surface |
| JP2004149678A (en) * | 2002-10-30 | 2004-05-27 | Sanyo Chem Ind Ltd | Liquid bleaching detergent composition |
| JP4429001B2 (en) * | 2003-12-15 | 2010-03-10 | ライオン株式会社 | Multipurpose liquid detergent composition |
| JP2005187741A (en) * | 2003-12-26 | 2005-07-14 | Kao Corp | Method for improving foam property |
| JP2006007024A (en) * | 2004-06-23 | 2006-01-12 | Mitsuba Corp | Washing method of conductive member |
| JP4979908B2 (en) * | 2005-08-12 | 2012-07-18 | 花王株式会社 | Hard surface drainage imparting agent |
| JP2007260502A (en) * | 2006-03-27 | 2007-10-11 | Aisin Aw Co Ltd | Workpiece cleaning apparatus |
| JP2007277303A (en) * | 2006-04-03 | 2007-10-25 | Soft99 Corporation | Detergent for coated surface |
-
2009
- 2009-02-02 JP JP2009021912A patent/JP5530638B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| JP2009203473A (en) | 2009-09-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP6226144B2 (en) | Detergent composition stock solution, detergent composition and cleaning method | |
| JP2523111B2 (en) | Demulsifying detergent formulation | |
| US7951766B1 (en) | Bio-based solvents and methods for using same | |
| AU726452B2 (en) | Low-foam cleaning agent | |
| JPH10237491A (en) | Composition for washing and drying vehicle | |
| JP2013518138A (en) | Low volatile organic compounds | |
| WO2012065093A1 (en) | Hard surface cleaning composition | |
| WO1994022965A2 (en) | Improved floor stripping composition and method | |
| JPH06506496A (en) | Low-volatile organic compound cleaning compositions and methods | |
| JP5530638B2 (en) | Aqueous detergent composition and article cleaning method | |
| JP2002121598A (en) | Industrial detergent | |
| JPH09502759A (en) | Cleaning composition | |
| JPH0680995A (en) | Low-residue detergent | |
| JPH01221498A (en) | Detergent composition for bathroom | |
| EP3144373B1 (en) | Neutral aqueous cleaning composition | |
| JP2011089030A (en) | Detergent for degreasing and cleaning, and cleaning method | |
| JPH07305100A (en) | Acidic microemulsion composition | |
| JP6064144B2 (en) | Hard surface cleaning composition | |
| JP2000008080A (en) | Industrial detergent composition and cleaning using the same | |
| JP3305260B2 (en) | Aqueous cleaning composition for pressurized spray and cleaning method | |
| JPH06336600A (en) | Cleaning composition and cleaning method | |
| JPH01149981A (en) | Water soluble degreasing composition | |
| JP2008120917A (en) | Detergent composition | |
| JP6780172B1 (en) | Water-based cleaning agent and cleaning method using the water-based cleaning agent | |
| JP2001011435A (en) | Agent for water-repelling treatment |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20120120 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20130530 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20130604 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20130725 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20140415 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20140421 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 5530638 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |