JP5379356B2 - 木材用防蟻防腐剤組成物及び木材用防蟻防腐剤 - Google Patents
木材用防蟻防腐剤組成物及び木材用防蟻防腐剤 Download PDFInfo
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- JP5379356B2 JP5379356B2 JP2007150262A JP2007150262A JP5379356B2 JP 5379356 B2 JP5379356 B2 JP 5379356B2 JP 2007150262 A JP2007150262 A JP 2007150262A JP 2007150262 A JP2007150262 A JP 2007150262A JP 5379356 B2 JP5379356 B2 JP 5379356B2
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- 230000002335 preservative effect Effects 0.000 title claims description 34
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- 239000005757 Cyproconazole Substances 0.000 claims description 6
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- CUDYYMUUJHLCGZ-UHFFFAOYSA-N 2-(2-methoxypropoxy)propan-1-ol Chemical compound COC(C)COC(C)CO CUDYYMUUJHLCGZ-UHFFFAOYSA-N 0.000 description 1
- WYVVKGNFXHOCQV-UHFFFAOYSA-N 3-iodoprop-2-yn-1-yl butylcarbamate Chemical compound CCCCNC(=O)OCC#CI WYVVKGNFXHOCQV-UHFFFAOYSA-N 0.000 description 1
- PORQOHRXAJJKGK-UHFFFAOYSA-N 4,5-dichloro-2-n-octyl-3(2H)-isothiazolone Chemical compound CCCCCCCCN1SC(Cl)=C(Cl)C1=O PORQOHRXAJJKGK-UHFFFAOYSA-N 0.000 description 1
- HWWKEEKUMAZJLL-UHFFFAOYSA-N 4-bromo-2,5-dichlorophenol Chemical compound OC1=CC(Cl)=C(Br)C=C1Cl HWWKEEKUMAZJLL-UHFFFAOYSA-N 0.000 description 1
- 229940100484 5-chloro-2-methyl-4-isothiazolin-3-one Drugs 0.000 description 1
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- WGOWCPGHOCIHBW-UHFFFAOYSA-N Dichlofenthion Chemical compound CCOP(=S)(OCC)OC1=CC=C(Cl)C=C1Cl WGOWCPGHOCIHBW-UHFFFAOYSA-N 0.000 description 1
- RUPBZQFQVRMKDG-UHFFFAOYSA-M Didecyldimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCC[N+](C)(C)CCCCCCCCCC RUPBZQFQVRMKDG-UHFFFAOYSA-M 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- VQXSOUPNOZTNAI-UHFFFAOYSA-N Pyrethrin I Natural products CC(=CC1CC1C(=O)OC2CC(=O)C(=C2C)CC=C/C=C)C VQXSOUPNOZTNAI-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
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- VEMKTZHHVJILDY-UXHICEINSA-N bioresmethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-UXHICEINSA-N 0.000 description 1
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- DHNRXBZYEKSXIM-UHFFFAOYSA-N chloromethylisothiazolinone Chemical compound CN1SC(Cl)=CC1=O DHNRXBZYEKSXIM-UHFFFAOYSA-N 0.000 description 1
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Description
次の成分(a)、(b)および(c);
(a)防蟻活性成分
(b)防腐活性成分
(c)イソチアゾリン系殺菌活性成分
を含有することを特徴とする木材用防蟻防腐組成物である。
防蟻防腐剤の調製1:
防蟻活性成分として、ネオニコチノイド系のイミダクロプリド(97%:日本バイエルクロップサイエンス社製)、防腐活性成分としてEBI剤のシプロコナゾール(96%:SDSバイオテック社)、イソチアゾリン系殺菌剤として、2−n−オクチル−4−イソチアゾリン−3−オン(ナガセケムテック社)を用い、さらにそれら活性成分の溶剤であるn−メチル−2−ピロリドン及び白灯油、溶解共力剤であるジグリセリンボラートモノオレート及びポリオキシエチレン硬化ヒマシ油を、下記表1に示したそれぞれの配合量で混合、撹拌し、均一な組成物を調製した(製剤例1〜6)。なお、表中の数値は質量部を示す(下記表2〜5において同じ)。
防蟻防腐剤の調製2:
防蟻活性成分として、アセタミプリド(98%:関東化学社製)、防腐活性成分として、テブコナゾール(98%:和光純薬社製)、イソチアゾリン系殺菌剤として、2−n−オクチル−4−イソチアゾリン−3−オン(ナガセケムテック社)を用い、さらにそれら活性成分の溶剤であるメタノール、ジグリセリンボラートモノオレート、ポリオキシエチレン硬化ヒマシ油及び白灯油を、下記表2に示したそれぞれの配合量で混合、撹拌し、均一な組成物を調製した(製剤例7〜12)。
防蟻防腐剤の調製3:
防蟻活性成分として、合成ピレスロイド系のエトフェンプロックス(99%:関東化学社製)、防腐活性成分として、サンプラス(75%:三共株式会社製)、イソチアゾリン系殺菌剤として、5−クロロ−2−メチル−4−イソチアゾリン−3−オン(ナガセケムテック社)を用い、さらにそれら活性成分の溶剤であるアセトン、ジグリセリンボラートモノオレート、ポリオキシエチレン硬化ヒマシ油及び白灯油を、下記表3に示したそれぞれの配合量で混合、撹拌し、均一な組成物を調製した(製剤例13〜16)。
防蟻防腐剤の調製4:
防蟻活性成分として、ビフェントリン(97%:関東化学社製)、防腐活性成分として、有機ヨウ素系のIF−1000S(ナガセケムテック社)、イソチアゾリン系殺菌剤として、1,2−ベンズイソチアゾリン−3−オン(ナガセケムテック社)を用い、さらにそれら活性成分の溶剤であるアセトン、ジグリセリンボラートモノオレート、ポリオキシエチレン硬化ヒマシ油及び白灯油を、下記表4に示したそれぞれの配合量で混合、撹拌し、均一な組成物を調製した(製剤例17〜20)。
防蟻防腐剤の調製5:
防蟻活性成分として、ピロール環系のクロロフェナピル(99%:関東化学社製)、防腐活性成分として、プロピコナゾール(98%:和光純薬社製)、イソチアゾリン系殺菌剤として、2−メチル−4−イソチアゾリン−3−オン(ナガセケムテック社)を用い、さらにそれら活性成分の溶剤であるアセトン、ジグリセリンボラートモノオレート、ポリオキシエチレン硬化ヒマシ油及び白灯油を、下記表5に示したそれぞれの配合量で混合、撹拌し、均一な組成物を調製した(製剤例21〜24)。
防蟻効果試験:
製造例1ないし5で調製した防蟻防腐剤を用いて、(社)日本木材保存協会規格、第11号、1992年、「塗布・吹付け・浸せき処理用木材防蟻剤の防蟻効力試験方法」、(2)野外試験方法に準じて防蟻効果試験を行った。以下に試験法を具体的に記載する。
供試木材片:アカマツの辺材を350(L)×30(R)×30(T)mm二方マサの
直方体とし、一端約50mmを削ってくい状にし、表面を平滑かつ正確に
カンナ仕上げした木材片を作製した。その木材片の含水率が12〜15%
になるまで風乾した。
薬剤塗布 :製剤例1ないし24の防蟻防腐剤を200g/m2の割合で木材片に塗布
し10日間以上室内で乾燥させた。
試験地 :鹿児島県日置郡吹上町国有林内
Claims (7)
- 次の成分(a)、(b)および(c);
(a)防蟻活性成分
(b)防腐活性成分
(c)2−n−オクチル−4−イソチアゾリン−3−オン
を含有し、成分(a)および(b)の組み合せが、(a)イミダクロプリドおよび(b)
シプロコナゾール、または、(a)アセタミプリドおよび(b)テブコナゾールであることを特徴とする木材用防蟻防腐剤組成物(但し、マイクロカプセルを含有するものを除く)。 - 成分(a)の防蟻活性成分の含有量が0.01〜50質量%である請求項第1項記載の木材用防蟻防腐剤組成物。
- 成分(b)の防腐活性成分の含有量が0.01〜50質量%である請求項第1項または第2項に記載の木材用防蟻防腐剤組成物。
- 成分(c)の2−n−オクチル−4−イソチアゾリン−3−オンの含有量が0.01〜50質量%である請求項第1項ないし第3項の何れかの項に記載の木材用防蟻防腐剤組成物。
- 請求項1ないし4のいずれかの木材用防蟻防腐剤組成物を含有してなる木材用防蟻防腐剤。
- 油剤、乳剤、水溶剤、液剤、エマルション製剤、マイクロエマルション製剤又はサスポエマルション製剤である請求項第5項に記載の木材用防蟻防腐剤。
- 木部表面処理用である請求項第5項または第6項に記載の木材用防蟻防腐剤。
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CN108935529A (zh) * | 2018-08-24 | 2018-12-07 | 湖州市南浔三亚家私有限公司 | 木板防虫剂 |
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