JP5283172B2 - 潤滑剤中の添加剤としてのチタン化合物およびチタン錯体 - Google Patents
潤滑剤中の添加剤としてのチタン化合物およびチタン錯体 Download PDFInfo
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- JP5283172B2 JP5283172B2 JP2008504225A JP2008504225A JP5283172B2 JP 5283172 B2 JP5283172 B2 JP 5283172B2 JP 2008504225 A JP2008504225 A JP 2008504225A JP 2008504225 A JP2008504225 A JP 2008504225A JP 5283172 B2 JP5283172 B2 JP 5283172B2
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- Prior art keywords
- titanium
- oil
- ppm
- metal
- lubricating
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- 239000000654 additive Substances 0.000 title claims description 20
- 150000003608 titanium Chemical class 0.000 title claims description 6
- 239000000314 lubricant Substances 0.000 title description 25
- 150000003609 titanium compounds Chemical class 0.000 title description 12
- 239000010936 titanium Substances 0.000 claims description 97
- 239000000203 mixture Substances 0.000 claims description 76
- 229910052719 titanium Inorganic materials 0.000 claims description 76
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 69
- 239000003921 oil Substances 0.000 claims description 66
- 229910052751 metal Inorganic materials 0.000 claims description 54
- 239000002184 metal Substances 0.000 claims description 54
- 239000000463 material Substances 0.000 claims description 44
- 239000002270 dispersing agent Substances 0.000 claims description 38
- -1 titanium (IV) alkoxide Chemical class 0.000 claims description 35
- 239000003963 antioxidant agent Substances 0.000 claims description 33
- 230000001050 lubricating effect Effects 0.000 claims description 33
- 229910052698 phosphorus Inorganic materials 0.000 claims description 33
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 32
- 239000011574 phosphorus Substances 0.000 claims description 32
- 239000003795 chemical substances by application Substances 0.000 claims description 28
- 238000000034 method Methods 0.000 claims description 27
- 239000003599 detergent Substances 0.000 claims description 25
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 claims description 25
- 230000003078 antioxidant effect Effects 0.000 claims description 20
- 239000012459 cleaning agent Substances 0.000 claims description 18
- 239000002253 acid Substances 0.000 claims description 14
- 230000000996 additive effect Effects 0.000 claims description 12
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical class [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 11
- 229910052717 sulfur Inorganic materials 0.000 claims description 11
- 239000011593 sulfur Substances 0.000 claims description 11
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims description 10
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 8
- 229910052750 molybdenum Inorganic materials 0.000 claims description 8
- 239000011733 molybdenum Substances 0.000 claims description 8
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 6
- 238000002485 combustion reaction Methods 0.000 claims description 6
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims description 5
- 229960004889 salicylic acid Drugs 0.000 claims description 5
- 150000007513 acids Chemical class 0.000 claims description 4
- 235000019198 oils Nutrition 0.000 description 64
- 125000001183 hydrocarbyl group Chemical group 0.000 description 32
- 238000012360 testing method Methods 0.000 description 26
- 238000009472 formulation Methods 0.000 description 20
- 239000003085 diluting agent Substances 0.000 description 19
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical compound O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 19
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 18
- 125000004432 carbon atom Chemical group C* 0.000 description 15
- 150000001875 compounds Chemical class 0.000 description 15
- 150000003839 salts Chemical class 0.000 description 15
- 239000000126 substance Substances 0.000 description 13
- LCKIEQZJEYYRIY-UHFFFAOYSA-N Titanium ion Chemical class [Ti+4] LCKIEQZJEYYRIY-UHFFFAOYSA-N 0.000 description 11
- 150000002148 esters Chemical class 0.000 description 11
- 230000002378 acidificating effect Effects 0.000 description 10
- 150000001408 amides Chemical class 0.000 description 10
- 239000002585 base Substances 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 10
- 239000010705 motor oil Substances 0.000 description 10
- 229920000642 polymer Polymers 0.000 description 10
- 239000004215 Carbon black (E152) Substances 0.000 description 9
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 9
- 239000012141 concentrate Substances 0.000 description 9
- 229930195733 hydrocarbon Natural products 0.000 description 9
- 229960002317 succinimide Drugs 0.000 description 9
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 8
- 150000002430 hydrocarbons Chemical class 0.000 description 8
- 229940014800 succinic anhydride Drugs 0.000 description 8
- 239000004034 viscosity adjusting agent Substances 0.000 description 8
- 239000011701 zinc Substances 0.000 description 8
- 229910052725 zinc Inorganic materials 0.000 description 8
- 230000008901 benefit Effects 0.000 description 7
- 229910052739 hydrogen Inorganic materials 0.000 description 7
- 239000004615 ingredient Substances 0.000 description 7
- 229920000768 polyamine Polymers 0.000 description 7
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 6
- 125000000129 anionic group Chemical group 0.000 description 6
- 239000011575 calcium Substances 0.000 description 6
- 239000006185 dispersion Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- CMGDVUCDZOBDNL-UHFFFAOYSA-N 4-methyl-2h-benzotriazole Chemical compound CC1=CC=CC2=NNN=C12 CMGDVUCDZOBDNL-UHFFFAOYSA-N 0.000 description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 5
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 5
- 150000001298 alcohols Chemical class 0.000 description 5
- 150000001336 alkenes Chemical class 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 5
- 239000002199 base oil Substances 0.000 description 5
- 229910052791 calcium Inorganic materials 0.000 description 5
- 239000003153 chemical reaction reagent Substances 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
- 239000010687 lubricating oil Substances 0.000 description 5
- 229910021645 metal ion Inorganic materials 0.000 description 5
- 150000002739 metals Chemical class 0.000 description 5
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 5
- 229920005862 polyol Polymers 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 125000001424 substituent group Chemical group 0.000 description 5
- 239000010689 synthetic lubricating oil Substances 0.000 description 5
- 239000003981 vehicle Substances 0.000 description 5
- FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical class ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 239000002518 antifoaming agent Substances 0.000 description 4
- 239000007795 chemical reaction product Substances 0.000 description 4
- NAGJZTKCGNOGPW-UHFFFAOYSA-N dithiophosphoric acid Chemical compound OP(O)(S)=S NAGJZTKCGNOGPW-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 150000002431 hydrogen Chemical class 0.000 description 4
- 239000000543 intermediate Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000011777 magnesium Substances 0.000 description 4
- 239000002480 mineral oil Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 150000002894 organic compounds Chemical class 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 150000002989 phenols Chemical class 0.000 description 4
- 150000003014 phosphoric acid esters Chemical class 0.000 description 4
- 150000003077 polyols Chemical class 0.000 description 4
- OGHBATFHNDZKSO-UHFFFAOYSA-N propan-2-olate Chemical compound CC(C)[O-] OGHBATFHNDZKSO-UHFFFAOYSA-N 0.000 description 4
- CQRYARSYNCAZFO-UHFFFAOYSA-N salicyl alcohol Chemical compound OCC1=CC=CC=C1O CQRYARSYNCAZFO-UHFFFAOYSA-N 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- 241000588733 Pseudescherichia vulneris Species 0.000 description 3
- RYYWUUFWQRZTIU-UHFFFAOYSA-N Thiophosphoric acid Chemical class OP(O)(S)=O RYYWUUFWQRZTIU-UHFFFAOYSA-N 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 125000003342 alkenyl group Chemical group 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 150000001735 carboxylic acids Chemical class 0.000 description 3
- 239000000571 coke Substances 0.000 description 3
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical class C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 235000010446 mineral oil Nutrition 0.000 description 3
- 239000005078 molybdenum compound Substances 0.000 description 3
- 150000002752 molybdenum compounds Chemical class 0.000 description 3
- 239000002105 nanoparticle Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 description 3
- 229960001860 salicylate Drugs 0.000 description 3
- 229910052723 transition metal Inorganic materials 0.000 description 3
- 150000003624 transition metals Chemical class 0.000 description 3
- KTXWGMUMDPYXNN-UHFFFAOYSA-N 2-ethylhexan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCCC(CC)C[O-].CCCCC(CC)C[O-].CCCCC(CC)C[O-].CCCCC(CC)C[O-] KTXWGMUMDPYXNN-UHFFFAOYSA-N 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- 239000005711 Benzoic acid Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 238000005698 Diels-Alder reaction Methods 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 229910010413 TiO 2 Inorganic materials 0.000 description 2
- 239000007983 Tris buffer Substances 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 150000004996 alkyl benzenes Chemical class 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 150000001414 amino alcohols Chemical class 0.000 description 2
- 150000008064 anhydrides Chemical class 0.000 description 2
- 150000004982 aromatic amines Chemical class 0.000 description 2
- 235000010233 benzoic acid Nutrition 0.000 description 2
- 150000001639 boron compounds Chemical class 0.000 description 2
- GPUNINFXOLRXEJ-UHFFFAOYSA-N butanedioic acid;titanium Chemical compound [Ti].OC(=O)CCC(O)=O GPUNINFXOLRXEJ-UHFFFAOYSA-N 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
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- UZEFVQBWJSFOFE-UHFFFAOYSA-N dibutyl hydrogen phosphite Chemical compound CCCCOP(O)OCCCC UZEFVQBWJSFOFE-UHFFFAOYSA-N 0.000 description 2
- JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
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- 239000011572 manganese Substances 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 150000002736 metal compounds Chemical class 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
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- 239000002530 phenolic antioxidant Substances 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 235000011007 phosphoric acid Nutrition 0.000 description 2
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- 230000009467 reduction Effects 0.000 description 2
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- 241000894007 species Species 0.000 description 2
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- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- RYYWUUFWQRZTIU-UHFFFAOYSA-K thiophosphate Chemical compound [O-]P([O-])([O-])=S RYYWUUFWQRZTIU-UHFFFAOYSA-K 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- 235000010215 titanium dioxide Nutrition 0.000 description 2
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- OBETXYAYXDNJHR-SSDOTTSWSA-M (2r)-2-ethylhexanoate Chemical group CCCC[C@@H](CC)C([O-])=O OBETXYAYXDNJHR-SSDOTTSWSA-M 0.000 description 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- WGOMEMWEJIKLSU-UJUIXPSJSA-J (z)-octadec-9-enoate;titanium(4+) Chemical compound [Ti+4].CCCCCCCC\C=C/CCCCCCCC([O-])=O.CCCCCCCC\C=C/CCCCCCCC([O-])=O.CCCCCCCC\C=C/CCCCCCCC([O-])=O.CCCCCCCC\C=C/CCCCCCCC([O-])=O WGOMEMWEJIKLSU-UJUIXPSJSA-J 0.000 description 1
- BIGYLAKFCGVRAN-UHFFFAOYSA-N 1,3,4-thiadiazolidine-2,5-dithione Chemical compound S=C1NNC(=S)S1 BIGYLAKFCGVRAN-UHFFFAOYSA-N 0.000 description 1
- YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 description 1
- RZRNAYUHWVFMIP-KTKRTIGZSA-N 1-oleoylglycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-KTKRTIGZSA-N 0.000 description 1
- MSYNCHLYGJCFFY-UHFFFAOYSA-B 2-hydroxypropane-1,2,3-tricarboxylate;titanium(4+) Chemical compound [Ti+4].[Ti+4].[Ti+4].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O MSYNCHLYGJCFFY-UHFFFAOYSA-B 0.000 description 1
- ROGIWVXWXZRRMZ-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1 ROGIWVXWXZRRMZ-UHFFFAOYSA-N 0.000 description 1
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 description 1
- GBBHWGRJHHNAGT-UHFFFAOYSA-N 3-hexadecyloxolane-2,5-dione Chemical compound CCCCCCCCCCCCCCCCC1CC(=O)OC1=O GBBHWGRJHHNAGT-UHFFFAOYSA-N 0.000 description 1
- ORWXSLFJBJGMCL-UHFFFAOYSA-N 5-(2-methylpropoxy)-1,4,2,3,5lambda5-dioxadithiaphospholane 5-oxide Chemical compound P1(=O)(OCC(C)C)OSSO1 ORWXSLFJBJGMCL-UHFFFAOYSA-N 0.000 description 1
- DQKVMDNCLZIACU-UHFFFAOYSA-J 7,7-dimethyloctanoate;titanium(4+) Chemical compound [Ti+4].CC(C)(C)CCCCCC([O-])=O.CC(C)(C)CCCCCC([O-])=O.CC(C)(C)CCCCCC([O-])=O.CC(C)(C)CCCCCC([O-])=O DQKVMDNCLZIACU-UHFFFAOYSA-J 0.000 description 1
- RREANTFLPGEWEN-MBLPBCRHSA-N 7-[4-[[(3z)-3-[4-amino-5-[(3,4,5-trimethoxyphenyl)methyl]pyrimidin-2-yl]imino-5-fluoro-2-oxoindol-1-yl]methyl]piperazin-1-yl]-1-cyclopropyl-6-fluoro-4-oxoquinoline-3-carboxylic acid Chemical group COC1=C(OC)C(OC)=CC(CC=2C(=NC(\N=C/3C4=CC(F)=CC=C4N(CN4CCN(CC4)C=4C(=CC=5C(=O)C(C(O)=O)=CN(C=5C=4)C4CC4)F)C\3=O)=NC=2)N)=C1 RREANTFLPGEWEN-MBLPBCRHSA-N 0.000 description 1
- LJKQIQSBHFNMDV-UHFFFAOYSA-N 7-thiabicyclo[4.1.0]hepta-2,4-dien-6-ol Chemical class C1=CC=CC2(O)C1S2 LJKQIQSBHFNMDV-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- FHRLECAMEQJXGP-UHFFFAOYSA-N C1(CCCCC1)[Zn]C1CCCCC1.P(O)(O)(=S)S Chemical compound C1(CCCCC1)[Zn]C1CCCCC1.P(O)(O)(=S)S FHRLECAMEQJXGP-UHFFFAOYSA-N 0.000 description 1
- WMLANVNNZOHYDP-UHFFFAOYSA-N CC(C)CC[Zn] Chemical compound CC(C)CC[Zn] WMLANVNNZOHYDP-UHFFFAOYSA-N 0.000 description 1
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- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
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- JUWGUJSXVOBPHP-UHFFFAOYSA-B titanium(4+);tetraphosphate Chemical class [Ti+4].[Ti+4].[Ti+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O JUWGUJSXVOBPHP-UHFFFAOYSA-B 0.000 description 1
- IKXFIBBKEARMLL-UHFFFAOYSA-N triphenoxy(sulfanylidene)-$l^{5}-phosphane Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=S)OC1=CC=CC=C1 IKXFIBBKEARMLL-UHFFFAOYSA-N 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
- C10M159/12—Reaction products
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
- C10M159/12—Reaction products
- C10M159/18—Complexes with metals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M163/00—Lubricating compositions characterised by the additive being a mixture of a compound of unknown or incompletely defined constitution and a non-macromolecular compound, each of these compounds being essential
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/04—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing aromatic monomers, e.g. styrene
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/028—Overbased salts thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/26—Overbased carboxylic acid salts
- C10M2207/262—Overbased carboxylic acid salts derived from hydroxy substituted aromatic acids, e.g. salicylates
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Description
本願は、2005年3月28日に出願された、米国仮出願番号60/665,715からの優先権の利益を主張する。
本発明は、例えばエンジン油における、デポジット制御、酸化、および濾過性などの特性に対して有利な効果を有する、可溶性チタン含有物質を含有する潤滑剤組成物に関する。
本発明は、
(a)潤滑粘度の油;
(b)油溶性チタン含有物質の形態の、重量で1ppm〜1000ppmのチタン;ならびに
(c)少なくとも1種の添加剤であって、
(i)耐磨耗剤、
(ii)分散剤、
(iii)酸化防止剤、および
(iv)洗浄剤、
からなる群より選択される、添加剤、
を含有する潤滑組成物を提供する。
(a)潤滑粘度の油;
(b)油溶性チタン含有物質の形態の、重量で1ppm〜50ppm未満のチタンであって、この油溶性チタン含有物質は、チタンアルコキシド、チタンで修飾された分散剤、芳香族カルボン酸のチタン塩、および硫黄含有酸のチタン塩からなる群より選択される、チタン;ならびに
(c)少なくとも1種の添加剤であって、
(i)耐磨耗剤、
(ii)分散剤、
(iii)酸化防止剤、および
(iv)洗浄剤、
からなる群より選択される、添加剤
を含有する潤滑組成物を提供する。
(a)潤滑粘度の油;
(b)20,000未満の数平均分子量を有する油溶性チタン含有物質の形態の、重量で1ppm〜1000ppmのチタン;
(c)Ti含有酸化防止剤以外の酸化防止剤、および
(d)Ti含有洗浄剤以外の金属含有洗浄剤、
を含有する潤滑組成物を供給する工程を包含する。
(a)潤滑粘度の油;
(b)20,000未満の数平均分子量を有する油溶性チタン含有物質の形態の、重量で1ppm〜50ppm未満のチタン;
(c)Ti含有酸化防止剤以外の酸化防止剤、および
(d)Ti含有洗浄剤以外の金属含有洗浄剤、
を含有する潤滑組成物を供給する工程を包含する。
種々の好ましい特徴および実施形態が、非限定的な例示によって、以下に記載される。
炭化水素置換基(すなわち、脂肪族置換基(例えば、アルキルまたはアルケニル)、脂環式置換基(例えば、シクロアルキル、シクロアルケニル)、ならびに芳香族置換された芳香族置換基、脂肪族置換された芳香族置換基、および脂環式置換された芳香族置換基、ならびに環が分子の別の部分を介して結合している(例えば、2つの置換基が一緒になって1つの環を形成する)環式置換基);
置換炭化水素置換基(すなわち、本明細書の文脈において、置換基の主として炭化水素の性質を変化させない非炭化水素基(例えば、ハロ(特に、クロロおよびフルオロ)、ヒドロキシ、アルコキシ、メルカプト、アルキルメルカプト、ニトロ、ニトロソ、ならびにスルホキシ)を含む置換基);
ヘテロ置換基(すなわち、本発明の文脈において、主として炭化水素の特徴を有するが、環または鎖中に炭素以外のものを含む(その他は炭素原子からなる)置換基)。ヘテロ原子としては、硫黄、酸素、窒素が挙げられ、そしてピリジル、フリル、チエニルおよびイミダゾリルなどの置換基を包含する。一般に、2つ以下、好ましくは1つ以下の、非炭化水素置換基が、ヒドロカルビル基中の10個ごとの炭素原子について存在する。代表的に、ヒドロカルビル基中には、非炭化水素置換基は存在しない。
100重量部のAPI Group 2ベースストック(130Nおよび260N);
15部の市販のスチレン−イソプレン粘度改変剤(市販の物質中に存在する希釈油成分を含有する);
0.2部の無水マレイン酸/スチレンコポリマー流動点降下剤(約54%の希釈油を含有する)
7.2部のスクシンイミド分散剤(50%の希釈油を含有する)
3.04部の多重オーバーベース化硫酸カルシウム、フェネート、およびサリキサレート洗浄剤(各々、27%〜51%の希釈油を含有する)
1.51部の酸化防止剤(硫黄化オレフィン−硫黄化Diels−Alder付加体)、ヒンダードフェノールエステル、およびジアルキルアリールアミン
0.98部のジ(第二級)アルキルジチオリン酸亜鉛(9%の希釈油を含有する)
0.01部の市販の消泡剤
1.05部のさらなる希釈油。
93重量部のAPI Group 2ベースストック(SAE−30);
2.8部のスクシンイミド分散剤(49%の希釈油を含有する)
0.7部のジ(第二級)アルキルジチオリン酸亜鉛(9%の希釈油を含有する)
3.1部の多重オーバーベース化スルホン酸カルシウムおよびフェネート分散剤(各々、27%〜52%の希釈油を含有する)
0.2部の市販のフェノール系酸化防止剤
0.008部の市販の消泡剤
0.1部のさらなる希釈油。
100重量部のAPI Group 2ベースストック(600N);
4.24部のスクシンイミド分散剤(40%の希釈油を含有する)
0.30部のジ(第二級)アルキルジチオリン酸亜鉛(9%の希釈油を含有する)
2.48部のオーバーベース化スルホン酸カルシウムおよびフェネート分散剤(各々、27%〜47%の希釈油を含有する)
2.06部の市販の酸化防止剤
0.007部の市販の消泡剤
0.29部のさらなる希釈油。
Claims (10)
- 内燃機関を潤滑させるための方法であって、該方法は、該機関に潤滑組成物を供給する工程を包含し、該潤滑組成物は、
(a)潤滑粘度の油;
(b)20,000未満の数平均分子量を有する油溶性チタン含有物質の形態の、重量で10ppm〜1000ppmのチタン;
(c)Ti含有酸化防止剤以外の酸化防止剤、および
(d)サリチル酸洗浄剤を含むTi含有洗浄剤以外の0.1重量%〜5.0重量%の金属含有洗浄剤、
を含有する、方法。 - 前記油溶性チタン含有物質が、チタン(IV)アルコキシドまたはチタン(IV)カルボン酸塩を含有する、請求項1に記載の方法。
- 前記油溶性チタン含有物質が、チタン(IV)イソプロポキシドを含有する、請求項1に記載の方法。
- 前記油溶性チタン含有物質が、チタンで修飾された分散剤を含有する、請求項1に記載の方法。
- 前記組成物中のモリブデンの量が、重量で150ppm未満である、請求項1に記載の方法。
- 前記潤滑組成物が、
(e)耐磨耗剤、および
(f)分散剤、
からなる群より選択される少なくとも1種の添加剤をさらに含有する、請求項1に記載の方法。 - 前記耐磨耗剤が、リン含有耐磨耗剤を含有する、請求項6に記載の方法。
- 前記組成物が、重量で1200ppm未満のリンを含有する、請求項6に記載の方法。
- 前記内燃機関が、ヘビーデューティーディーゼル機関である、請求項1に記載の方法。
- 潤滑組成物であって、
(a)潤滑粘度の油;
(b)油溶性チタン含有物質の形態の、10ppm〜50ppm未満のチタンであって、該油溶性チタン含有物質は、チタンアルコキシド、チタンで修飾された分散剤、芳香族カルボン酸のチタン塩、および硫黄含有酸のチタン塩からなる群より選択される、チタン;ならびに
(c)少なくとも1種の添加剤であって、サリチル酸洗浄剤を含む洗浄剤である、添加剤、
を含有する、潤滑組成物。
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PCT/US2006/011116 WO2006105022A1 (en) | 2005-03-28 | 2006-03-27 | Titanium compounds and complexes as additives in lubricants |
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US7879774B2 (en) * | 2004-07-19 | 2011-02-01 | Afton Chemical Corporation | Titanium-containing lubricating oil composition |
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US7709423B2 (en) * | 2005-11-16 | 2010-05-04 | Afton Chemical Corporation | Additives and lubricant formulations for providing friction modification |
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US7772167B2 (en) * | 2006-12-06 | 2010-08-10 | Afton Chemical Corporation | Titanium-containing lubricating oil composition |
US7776800B2 (en) * | 2005-12-09 | 2010-08-17 | Afton Chemical Corporation | Titanium-containing lubricating oil composition |
US7767632B2 (en) * | 2005-12-22 | 2010-08-03 | Afton Chemical Corporation | Additives and lubricant formulations having improved antiwear properties |
US8301328B2 (en) * | 2006-03-22 | 2012-10-30 | General Electric Company | Method for servicing a vehicle |
US7553673B2 (en) * | 2006-11-13 | 2009-06-30 | Rohmax Additives Gmbh | Quality control of a functional fluid |
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-
2006
- 2006-03-27 CN CN2011101552871A patent/CN102229842A/zh active Pending
- 2006-03-27 EP EP10010705.1A patent/EP2290044B1/en not_active Revoked
- 2006-03-27 EP EP06739734.9A patent/EP1877526B1/en active Active
- 2006-03-27 JP JP2008504225A patent/JP5283172B2/ja active Active
- 2006-03-27 EP EP22169858.2A patent/EP4098724A1/en active Pending
- 2006-03-27 CN CNA2006800103868A patent/CN101151353A/zh active Pending
- 2006-03-27 WO PCT/US2006/011116 patent/WO2006105022A1/en active Application Filing
- 2006-03-27 AU AU2006230100A patent/AU2006230100B2/en active Active
- 2006-03-27 US US11/389,697 patent/US7727943B2/en active Active
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- 2006-03-27 EP EP16182863.7A patent/EP3118286B1/en active Active
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US7727943B2 (en) | 2010-06-01 |
EP1877526B1 (en) | 2015-05-13 |
US8268759B2 (en) | 2012-09-18 |
CN102229842A (zh) | 2011-11-02 |
JP2013057082A (ja) | 2013-03-28 |
US20060217271A1 (en) | 2006-09-28 |
CN101151353A (zh) | 2008-03-26 |
EP4098724A1 (en) | 2022-12-07 |
EP2290044B1 (en) | 2016-11-09 |
EP3118286A1 (en) | 2017-01-18 |
AU2006230100A1 (en) | 2006-10-05 |
AU2006230100B2 (en) | 2011-07-07 |
EP3118286B1 (en) | 2022-08-24 |
US20100173813A1 (en) | 2010-07-08 |
EP1877526A1 (en) | 2008-01-16 |
AU2006230100A2 (en) | 2006-10-05 |
CA2602378C (en) | 2014-01-28 |
US20100173814A1 (en) | 2010-07-08 |
EP2290044A1 (en) | 2011-03-02 |
CA2602378A1 (en) | 2006-10-05 |
WO2006105022A1 (en) | 2006-10-05 |
JP2008534744A (ja) | 2008-08-28 |
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