JP5283111B2 - 光反射材料 - Google Patents
光反射材料 Download PDFInfo
- Publication number
- JP5283111B2 JP5283111B2 JP2008217614A JP2008217614A JP5283111B2 JP 5283111 B2 JP5283111 B2 JP 5283111B2 JP 2008217614 A JP2008217614 A JP 2008217614A JP 2008217614 A JP2008217614 A JP 2008217614A JP 5283111 B2 JP5283111 B2 JP 5283111B2
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- JP
- Japan
- Prior art keywords
- light
- shielding effect
- reflecting material
- light reflecting
- ultraviolet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000463 material Substances 0.000 title claims description 47
- 230000000694 effects Effects 0.000 claims description 42
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 28
- 239000002245 particle Substances 0.000 claims description 27
- 239000000203 mixture Substances 0.000 claims description 22
- 239000002537 cosmetic Substances 0.000 claims description 12
- 239000012720 thermal barrier coating Substances 0.000 claims description 12
- 239000004745 nonwoven fabric Substances 0.000 claims description 6
- 239000004744 fabric Substances 0.000 claims description 5
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 description 18
- 238000000576 coating method Methods 0.000 description 18
- 239000003973 paint Substances 0.000 description 18
- 239000000049 pigment Substances 0.000 description 15
- -1 candles Substances 0.000 description 12
- 239000003960 organic solvent Substances 0.000 description 12
- 239000000839 emulsion Substances 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 238000000034 method Methods 0.000 description 10
- 229920005989 resin Polymers 0.000 description 10
- 239000011347 resin Substances 0.000 description 10
- 239000000377 silicon dioxide Substances 0.000 description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
- 239000007864 aqueous solution Substances 0.000 description 8
- 235000019441 ethanol Nutrition 0.000 description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 8
- 239000004014 plasticizer Substances 0.000 description 8
- 229920003002 synthetic resin Polymers 0.000 description 8
- 239000000057 synthetic resin Substances 0.000 description 8
- 239000002253 acid Substances 0.000 description 6
- 239000010419 fine particle Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 230000004888 barrier function Effects 0.000 description 5
- 238000007796 conventional method Methods 0.000 description 5
- 239000004205 dimethyl polysiloxane Substances 0.000 description 5
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 5
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 5
- 229910052710 silicon Inorganic materials 0.000 description 5
- 239000010703 silicon Substances 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 229940008099 dimethicone Drugs 0.000 description 4
- 239000002270 dispersing agent Substances 0.000 description 4
- 229930182490 saponin Natural products 0.000 description 4
- 150000007949 saponins Chemical class 0.000 description 4
- 235000017709 saponins Nutrition 0.000 description 4
- 230000000475 sunscreen effect Effects 0.000 description 4
- 239000000516 sunscreening agent Substances 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- COBPKKZHLDDMTB-UHFFFAOYSA-N 2-[2-(2-butoxyethoxy)ethoxy]ethanol Chemical compound CCCCOCCOCCOCCO COBPKKZHLDDMTB-UHFFFAOYSA-N 0.000 description 3
- OADIZUFHUPTFAG-UHFFFAOYSA-N 2-[2-(2-ethylhexoxy)ethoxy]ethanol Chemical compound CCCCC(CC)COCCOCCO OADIZUFHUPTFAG-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 3
- 229920000180 alkyd Polymers 0.000 description 3
- 150000003863 ammonium salts Chemical class 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000008199 coating composition Substances 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000005562 fading Methods 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 3
- 229920000053 polysorbate 80 Polymers 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 235000019353 potassium silicate Nutrition 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- 229940088594 vitamin Drugs 0.000 description 3
- 229930003231 vitamin Natural products 0.000 description 3
- 235000013343 vitamin Nutrition 0.000 description 3
- 239000011782 vitamin Substances 0.000 description 3
- 239000001052 yellow pigment Substances 0.000 description 3
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- GHOKWGTUZJEAQD-ZETCQYMHSA-N (D)-(+)-Pantothenic acid Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCC(O)=O GHOKWGTUZJEAQD-ZETCQYMHSA-N 0.000 description 2
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- MPDGHEJMBKOTSU-YKLVYJNSSA-N 18beta-glycyrrhetic acid Chemical compound C([C@H]1C2=CC(=O)[C@H]34)[C@@](C)(C(O)=O)CC[C@]1(C)CC[C@@]2(C)[C@]4(C)CC[C@@H]1[C@]3(C)CC[C@H](O)C1(C)C MPDGHEJMBKOTSU-YKLVYJNSSA-N 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 2
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Natural products OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- QFOHBWFCKVYLES-UHFFFAOYSA-N Butylparaben Chemical compound CCCCOC(=O)C1=CC=C(O)C=C1 QFOHBWFCKVYLES-UHFFFAOYSA-N 0.000 description 2
- 208000002177 Cataract Diseases 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 2
- YZCKVEUIGOORGS-OUBTZVSYSA-N Deuterium Chemical compound [2H] YZCKVEUIGOORGS-OUBTZVSYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 229910001335 Galvanized steel Inorganic materials 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000004166 Lanolin Substances 0.000 description 2
- 244000280244 Luffa acutangula Species 0.000 description 2
- 235000009814 Luffa aegyptiaca Nutrition 0.000 description 2
- 239000004640 Melamine resin Substances 0.000 description 2
- 229920000877 Melamine resin Polymers 0.000 description 2
- XUMBMVFBXHLACL-UHFFFAOYSA-N Melanin Chemical compound O=C1C(=O)C(C2=CNC3=C(C(C(=O)C4=C32)=O)C)=C2C4=CNC2=C1C XUMBMVFBXHLACL-UHFFFAOYSA-N 0.000 description 2
- 241000218657 Picea Species 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 208000000453 Skin Neoplasms Diseases 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 206010042496 Sunburn Diseases 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- POJWUDADGALRAB-UHFFFAOYSA-N allantoin Chemical compound NC(=O)NC1NC(=O)NC1=O POJWUDADGALRAB-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 235000001014 amino acid Nutrition 0.000 description 2
- 229940024606 amino acid Drugs 0.000 description 2
- 150000001413 amino acids Chemical class 0.000 description 2
- 235000012538 ammonium bicarbonate Nutrition 0.000 description 2
- 239000001099 ammonium carbonate Substances 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 235000006708 antioxidants Nutrition 0.000 description 2
- 235000010323 ascorbic acid Nutrition 0.000 description 2
- 229960005070 ascorbic acid Drugs 0.000 description 2
- 239000011668 ascorbic acid Substances 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- QUKGYYKBILRGFE-UHFFFAOYSA-N benzyl acetate Chemical compound CC(=O)OCC1=CC=CC=C1 QUKGYYKBILRGFE-UHFFFAOYSA-N 0.000 description 2
- KVYGGMBOZFWZBQ-UHFFFAOYSA-N benzyl nicotinate Chemical compound C=1C=CN=CC=1C(=O)OCC1=CC=CC=C1 KVYGGMBOZFWZBQ-UHFFFAOYSA-N 0.000 description 2
- FUWUEFKEXZQKKA-UHFFFAOYSA-N beta-thujaplicin Chemical compound CC(C)C=1C=CC=C(O)C(=O)C=1 FUWUEFKEXZQKKA-UHFFFAOYSA-N 0.000 description 2
- 229940085262 cetyl dimethicone Drugs 0.000 description 2
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 239000008406 cosmetic ingredient Substances 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- 229910052805 deuterium Inorganic materials 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 238000000635 electron micrograph Methods 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- LZCLXQDLBQLTDK-UHFFFAOYSA-N ethyl 2-hydroxypropanoate Chemical compound CCOC(=O)C(C)O LZCLXQDLBQLTDK-UHFFFAOYSA-N 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- 239000008397 galvanized steel Substances 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- RWSXRVCMGQZWBV-WDSKDSINSA-N glutathione Chemical compound OC(=O)[C@@H](N)CCC(=O)N[C@@H](CS)C(=O)NCC(O)=O RWSXRVCMGQZWBV-WDSKDSINSA-N 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 229940093915 gynecological organic acid Drugs 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 239000003906 humectant Substances 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- TYQCGQRIZGCHNB-JLAZNSOCSA-N l-ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(O)=C(O)C1=O TYQCGQRIZGCHNB-JLAZNSOCSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 235000019388 lanolin Nutrition 0.000 description 2
- 229940039717 lanolin Drugs 0.000 description 2
- 239000006210 lotion Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000003094 microcapsule Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
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- 238000010422 painting Methods 0.000 description 2
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- 235000018102 proteins Nutrition 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- ZUFQODAHGAHPFQ-UHFFFAOYSA-N pyridoxine hydrochloride Chemical compound Cl.CC1=NC=C(CO)C(CO)=C1O ZUFQODAHGAHPFQ-UHFFFAOYSA-N 0.000 description 2
- 235000002020 sage Nutrition 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- 201000000849 skin cancer Diseases 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 2
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 2
- RWQNBRDOKXIBIV-UHFFFAOYSA-N thymine Chemical compound CC1=CNC(=O)NC1=O RWQNBRDOKXIBIV-UHFFFAOYSA-N 0.000 description 2
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- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
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- WGVKWNUPNGFDFJ-DQCZWYHMSA-N β-tocopherol Chemical compound OC1=CC(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C WGVKWNUPNGFDFJ-DQCZWYHMSA-N 0.000 description 2
- WTVHAMTYZJGJLJ-UHFFFAOYSA-N (+)-(4S,8R)-8-epi-beta-bisabolol Natural products CC(C)=CCCC(C)C1(O)CCC(C)=CC1 WTVHAMTYZJGJLJ-UHFFFAOYSA-N 0.000 description 1
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- RGZSQWQPBWRIAQ-CABCVRRESA-N (-)-alpha-Bisabolol Chemical compound CC(C)=CCC[C@](C)(O)[C@H]1CCC(C)=CC1 RGZSQWQPBWRIAQ-CABCVRRESA-N 0.000 description 1
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- KIUKXJAPPMFGSW-DNGZLQJQSA-N (2S,3S,4S,5R,6R)-6-[(2S,3R,4R,5S,6R)-3-Acetamido-2-[(2S,3S,4R,5R,6R)-6-[(2R,3R,4R,5S,6R)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylic acid Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 KIUKXJAPPMFGSW-DNGZLQJQSA-N 0.000 description 1
- MRAMPOPITCOOIN-VIFPVBQESA-N (2r)-n-(3-ethoxypropyl)-2,4-dihydroxy-3,3-dimethylbutanamide Chemical compound CCOCCCNC(=O)[C@H](O)C(C)(C)CO MRAMPOPITCOOIN-VIFPVBQESA-N 0.000 description 1
- DAFHKNAQFPVRKR-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylpropanoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)C DAFHKNAQFPVRKR-UHFFFAOYSA-N 0.000 description 1
- YYGNTYWPHWGJRM-UHFFFAOYSA-N (6E,10E,14E,18E)-2,6,10,15,19,23-hexamethyltetracosa-2,6,10,14,18,22-hexaene Chemical compound CC(C)=CCCC(C)=CCCC(C)=CCCC=C(C)CCC=C(C)CCC=C(C)C YYGNTYWPHWGJRM-UHFFFAOYSA-N 0.000 description 1
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
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- 239000011590 β-tocopherol Substances 0.000 description 1
- 239000002478 γ-tocopherol Substances 0.000 description 1
- QUEDXNHFTDJVIY-DQCZWYHMSA-N γ-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-DQCZWYHMSA-N 0.000 description 1
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- Cosmetics (AREA)
- Silicon Compounds (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
- Optical Filters (AREA)
Description
(i)紫外から近赤外光までの波長範囲の光を平均90%以上で反射し、または
(ii)UV−A領域及びUV−B領域の紫外光を90%以上反射し、または
(iii)可視光線を95%以上反射し、または
(vi)800nm〜2100nmまでの近赤外光を80%以上反射する
特徴を有する光反射材料と、当該光反射材料を含む
(v)紫外線遮蔽効果を有する遮熱塗料組成物
(vi)紫外線遮蔽効果を及び遮熱効果を有する化粧料
紫外線遮蔽効果、内部隠蔽効果、または遮熱効果を有するフィルム、織編物、または不織布に関するものである。
ティング行っている例は多い。例えば、特開2005−023277、特開2004−010903、特開2002−166505、特開平11−323197、特開2007−238640、特開2006−298967、特開2006−045447等をあげることができる。しかしながら、これら材料の光の反射率は十分に高いとは言えず、塗料化した場合の赤外線透過率は多くのもので60〜70%程度である。
項2 UV−A領域及びUV−B領域の紫外光を90%以上反射する特徴を有する、項1に記載の光反射材料。
項3 可視光線を95%以上反射する特徴を有する、請求項1に記載の光反射材料。
項4 800nm〜2100nmまでの近赤外光を80%以上反射する特徴を有する、項1に記載の光反射材料。
項5 項1〜4のいずれかに記載の光反射材料を含む、紫外線遮蔽効果を有する遮熱塗料組成物。
項6 項1〜4のいずれかに記載の光反射材料を含む、紫外線遮蔽効果、または遮熱効果を有する化粧料。
項7 項1〜4のいずれかに記載の光反射材料を含む、紫外線遮蔽効果、内部隠蔽効果、または遮熱効果を有するフィルム。
項8 項1〜4のいずれかに記載の光反射材料を含む、紫外線遮蔽効果、内部隠蔽効果、または遮熱効果を有する織編物。
項9 項1〜4のいずれかに記載の光反射材料を含む、紫外線遮蔽効果、内部隠蔽効果、または遮熱効果を有する不織布。
である。
造方法」に基づき作成されたものであるがこれに限らない。
、水質処理設備での紫外線を用いた殺菌効果の向上、または光重合反応の制御においても、紫外線遮蔽製品が求められている。上記のメガネ、サングラス、ゴーグル、またはコンタクトレンズなどの製品は、白内障等の眼科疾患の予防等を期待され、紫外線遮蔽製品としての需要が考えられる。
を充填又は混練し、常法により製造することができる。このような成分としては、造膜助剤、樹脂やエマルジョン樹脂等のビヒクル、可塑剤、顔料、分散剤、消泡剤等がある。本発明の遮熱塗料組成物の具体例としては、例えば、上記の低熱伝導体、構造助剤及びシランカップリング剤と、更にビヒクル及び顔料を必須成分とするものが挙げられる。
レングリコールモノn−ブチルエーテル(商品名:ブチルトリグリコール(BTG))、ジエチレングリコールモノ2−エチルヘキシルエーテル(商品名:2−エチルヘキシルジグリコール(EHDG))等が挙げられる。
等を単独、併用しても良い。
添加して分散させてもよい。
チル、酢酸エチル等が挙げられる。これらは単独で用いても、2種類以上を併用してもよい。
可塑剤
レシチン、ポリソルベート、ジメチコーンコポリオール、グリコール、クエン酸エステル、グリセリン、ジメチコーン、及び「国際化粧料成分の辞書及びハンドブック」、第4巻、(第9版、2002年)、他の類似する成分、より詳細には、2927ページに開示されている可塑剤を含む。
界面活性剤
Polysorbate−20,Laureth−7,Laureth−4,SEPPICから入手可能なSepigel(商標)305、及び「国際化粧料成分の辞書及びハンドブック」、第4巻、(第9版、2002年)に開示されている他の類似する成分、より詳細には、2962〜2971に開示されている乳化剤を含む。有機シリコーン乳化剤は、Goldschmidt Chemical社から入手可能なセチルジメチコーンコ
ポリオールポリグリセリル−4−イソステアレート−ヘキシルラウレート(ABIL(商標)WE09)セチルジメチコーンコポリオール(ABIL(商標)EM90),(ABIL(商標)EM97),ラウリルメチコーンコポリオール(5200),シクロメチコン(及び)GEシリコーン社から入手可能なジメチコーンコポリオール(DC5225C及びDC3225C)、シクロペンタシロキサン&ジメチコーンコポリオール(GESF1528)又は当業者に公知である任意の他の配合物を含む。
脂分
スクワレン、流動パラフィン、牛脂、モクロウ、ミツロウ、キャンデリラロウ、カルナバロウ、鯨ロウ、ラノリン、シクロメチコン、ジメチルポリシロキサン、ジフェニルポリシロキサンなどの油分。
高級アルコール
カプリルアルコール、ラウリルアルコール、ミリスチルアルコール、セチルアルコール、コレステロール、フィトステロールなどの高級アルコール。
高級脂肪酸
カプリン酸、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ベヘニン酸、ラノリン脂肪酸、リノール酸、リノレン酸などの高級脂肪酸。
保湿剤
ポリエチレングリコール、グリセリン、ソルビトール、キシリトール、マルチトール、ムコ多糖、ヒアルロン酸、コンドロイチン硫酸、キトサンなどの保湿剤。
増粘剤
メチルセルロース、エチルセルロース、アラビアガム、ポリビニルアルコールなどの増粘剤。
有機溶剤
エタノール、1,3−ブチレングリコールなどの有機溶剤。
酸化防止剤
ブチルヒドロキシトルエン、トコフェロール、フィチン酸などの酸化防止剤。
抗菌防腐剤
安息香酸、サリチル酸、ソルビン酸、パラオキシ安息香酸エステル(エチルパラベン、ブチルパラベンなど)、ヘキサクロロフェンなどの抗菌防腐剤。
アミノ酸
グリシン、アラニン、バリン、ロイシン、セリン、トレオニン、フェニルアラニン、チロシン、アスパラギン酸、アスパラギン、グルタミン、タウリン、アルギニン、ヒスチジンなどのアミノ酸と塩酸塩。
有機酸
アシルサルコシン酸(例えばラウロイルサルコシンナトリウム)、グルタチオン、クエン酸、リンゴ酸、酒石酸、乳酸などの有機酸。
ビタミン類
ビタミンA及びその誘導体、ビタミンB6塩酸塩、ビタミンB6トリパルミテート、ビタミンB6ジオクタノエート、ビタミンB2及びその誘導体、ビタミンB12、ビタミンB15及びその誘導体などのビタミンB類、アスコルビン酸、アスコルビン酸リン酸エステル(塩)、アスコルビン酸ジパルミテートなどのビ タミンC類、α−トコフェロール
、β−トコフェロール、γ−トコフェロール、ビタミンEアセテート、ビタミンEニコチネートなどのビタミンE類、ビタミンD類、ビタミンH、パントテン酸、パンテチンなどのビタミン類。
各種薬剤
ニコチン酸アミド、ニコチン酸ベンジル、γ−オリザノール、アラントイン、グリチルリチン酸(塩)、グリチルレチン酸及びその誘導体、ヒノキチオール、ム シジン、ビサ
ボロール、ユーカリプトール、チモール、イノシトール、サポニン類(サイコサポニン、ニンジンサポニン、ヘチマサポニン、ムクロジサポニンな ど)、パントテニルエチルエ
ーテル、エチニルエストラジオール、トラネキサム酸、セファランチン、プラセンタエキスなどの各種薬剤。
金属封鎖剤
ギシギシ、クララ、コウホネ、オレンジ、セージ、タイム、ノコギリソウ、ゼニアオイ、センキュウ、センブリ、トウキ、トウヒ、バーチ、スギナ、ヘチマ、マ ロニエ、ユキ
ノシタ、アルニカ、ユリ、ヨモギ、シャクヤク、アロエ、クチナシ、サワラなどの有機溶剤、アルコール、多価アルコール、水、水性アルコールなどで抽出した天然エキス。
実施例1
[サンプル1の合成]
特開2007-230794「特異な殻を持つ中空シリカおよびその製造方法」に基づ
き、シリカ粒子を合成した。
実施例2
[サンプル2の合成]
特開2007−230794「特異な殻を持つ中空シリカおよびその製造方法」に基づき、ポリメタクリル酸ナトリウム水溶液等の添加物無しで、特開昭63-270306や
特開昭61−227913で記載されているシリカ粒子を、比較対照サンプルとして合成した。
lとした内部水溶液、tween80(1.01g:モル数は混合物につき不明)とSpan80(0.50g:モル数は混合物につき不明)をn−ヘキサンに溶かし全体積を72mlとした油相溶液、炭酸水素アンモニウム(39.8g、504mmol)を水に溶解させ全体積を250mlとした外部水溶液を用いて、サンプル2を合成した。
実施例3:サンプル3の合成
特開2007−230794「特異な殻を持つ中空シリカおよびその製造方法」に基づき、シリカ粒子を合成した。
実施例4
[粒子の紫外可視光反射特性]
日本分光社製、紫外可視分光光度計V−550、積分球ユニットISV−469を用いて、粒子を粉末試料用ホルダーに充填して、粒子サンプルの紫外可視光(波長200〜800nm)反射特性を反射率(%R)として測定した。図1には、サンプル1とサンプル2の結果を、図2には、サンプル2とサンプル3の結果を示す。
実施例5
[粒子の近赤外光反射特性]
日本分光社製、紫外可視分光光度計V−670、積分球ユニットISN−723を用いて、粒子を粉末試料用ホルダーに充填して、粒子サンプルの近赤外光(波長800〜2100nm)反射特性を反射率(%R)として測定した。図3に、サンプル1−3の結果を示す。なお、1400、1900nm近傍に観測される低い反射率は、シリカやシリカへの吸着水による近赤外光の吸収によるものであり、近赤外光を透過しているものではない。
家屋、ビル、工場や倉庫等の一般建築の塗料中の光反射剤として用いられ、太陽光の注ぎ込みに伴う室内温度上昇を抑制する遮熱塗料、および道路や自動車等の車体への遮熱コーティングをあげることができる。また、可視光の高い反射性能を用いて、外部から室内の様子を見えづらくする内部隠蔽性フィルムや関連する商品。可視光の高反射材料、衣服や他の生活関連物の「透け」を防止するために用いることもできる。さらに紫外光を反射できるため、化粧品や他の分野でのUVカット関連商品への応用も可能と思われる。その他、ディスプレイや照明等の光関連分野での利用も想定される。
Claims (7)
- 複数のマクロ細孔多孔構造を有し、酸化ケイ素系の殻から構成される中空粒子からなり、UV−A領域及びUV−B領域の紫外光を90%以上反射し、可視光線を95%以上反射し、且つ800nm〜2100nmまでの近赤外光を80%以上反射する特徴を有する光反射材料。
- 請求項1に記載の遮熱効果を有する光反射材料。
- 請求項1に記載の光反射材料を含む、紫外線遮蔽効果を有する遮熱塗料組成物。
- 請求項1に記載の光反射材料を含む、紫外線遮蔽効果、または遮熱効果を有する化粧料。
- 請求項1に記載の光反射材料を含む、紫外線遮蔽効果、内部隠蔽効果、または遮熱効果を有するフィルム。
- 請求項1に記載の光反射材料を含む、紫外線遮蔽効果、内部隠蔽効果、または遮熱効果を有する織編物。
- 請求項1に記載の光反射材料を含む、紫外線遮蔽効果、内部隠蔽効果、または遮熱効果を有する不織布。
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