JP5218685B2 - 樹脂組成物およびそれからなる成形品 - Google Patents
樹脂組成物およびそれからなる成形品 Download PDFInfo
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- JP5218685B2 JP5218685B2 JP2012059607A JP2012059607A JP5218685B2 JP 5218685 B2 JP5218685 B2 JP 5218685B2 JP 2012059607 A JP2012059607 A JP 2012059607A JP 2012059607 A JP2012059607 A JP 2012059607A JP 5218685 B2 JP5218685 B2 JP 5218685B2
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- resin
- resin composition
- methacrylic
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- polylactic acid
- Prior art date
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- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- GHAZCVNUKKZTLG-UHFFFAOYSA-N N-ethyl-succinimide Natural products CCN1C(=O)CCC1=O GHAZCVNUKKZTLG-UHFFFAOYSA-N 0.000 description 1
- HDFGOPSGAURCEO-UHFFFAOYSA-N N-ethylmaleimide Chemical compound CCN1C(=O)C=CC1=O HDFGOPSGAURCEO-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 239000004696 Poly ether ether ketone Substances 0.000 description 1
- 229930182556 Polyacetal Natural products 0.000 description 1
- 239000004697 Polyetherimide Substances 0.000 description 1
- 229920000331 Polyhydroxybutyrate Polymers 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004734 Polyphenylene sulfide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 241001362551 Samba Species 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 239000005083 Zinc sulfide Substances 0.000 description 1
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000007259 addition reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000012773 agricultural material Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- VCNTUJWBXWAWEJ-UHFFFAOYSA-J aluminum;sodium;dicarbonate Chemical compound [Na+].[Al+3].[O-]C([O-])=O.[O-]C([O-])=O VCNTUJWBXWAWEJ-UHFFFAOYSA-J 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
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- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 238000009360 aquaculture Methods 0.000 description 1
- 244000144974 aquaculture Species 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- AOJOEFVRHOZDFN-UHFFFAOYSA-N benzyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC1=CC=CC=C1 AOJOEFVRHOZDFN-UHFFFAOYSA-N 0.000 description 1
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- 229920001222 biopolymer Polymers 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
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- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
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- 239000004917 carbon fiber Substances 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 239000012461 cellulose resin Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000002361 compost Substances 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- QYQADNCHXSEGJT-UHFFFAOYSA-N cyclohexane-1,1-dicarboxylate;hydron Chemical compound OC(=O)C1(C(O)=O)CCCCC1 QYQADNCHXSEGJT-UHFFFAOYSA-N 0.000 description 1
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- 125000004386 diacrylate group Chemical group 0.000 description 1
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- 229910000514 dolomite Inorganic materials 0.000 description 1
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- 239000003822 epoxy resin Substances 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
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- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
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- 239000000314 lubricant Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
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- 239000000696 magnetic material Substances 0.000 description 1
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- 125000005641 methacryl group Chemical group 0.000 description 1
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- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- RFUCOAQWQVDBEU-UHFFFAOYSA-N methyl 2-(hydroxymethyl)prop-2-enoate Chemical compound COC(=O)C(=C)CO RFUCOAQWQVDBEU-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
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- IQFXJRXOTKFGPN-UHFFFAOYSA-N n-ethenyl-n-ethylethanamine Chemical compound CCN(CC)C=C IQFXJRXOTKFGPN-UHFFFAOYSA-N 0.000 description 1
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- IOXXVNYDGIXMIP-UHFFFAOYSA-N n-methylprop-2-en-1-amine Chemical compound CNCC=C IOXXVNYDGIXMIP-UHFFFAOYSA-N 0.000 description 1
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- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- FVXBCDWMKCEPCL-UHFFFAOYSA-N nonane-1,1-diol Chemical compound CCCCCCCCC(O)O FVXBCDWMKCEPCL-UHFFFAOYSA-N 0.000 description 1
- 239000010449 novaculite Substances 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- NWAHZAIDMVNENC-UHFFFAOYSA-N octahydro-1h-4,7-methanoinden-5-yl methacrylate Chemical compound C12CCCC2C2CC(OC(=O)C(=C)C)C1C2 NWAHZAIDMVNENC-UHFFFAOYSA-N 0.000 description 1
- OEIJHBUUFURJLI-UHFFFAOYSA-N octane-1,8-diol Chemical compound OCCCCCCCCO OEIJHBUUFURJLI-UHFFFAOYSA-N 0.000 description 1
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- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
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- 239000004014 plasticizer Substances 0.000 description 1
- 239000005015 poly(hydroxybutyrate) Substances 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920001230 polyarylate Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
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- 239000004632 polycaprolactone Substances 0.000 description 1
- 229920005668 polycarbonate resin Polymers 0.000 description 1
- 239000004431 polycarbonate resin Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
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- 229920013716 polyethylene resin Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920001522 polyglycol ester Polymers 0.000 description 1
- 239000009719 polyimide resin Substances 0.000 description 1
- 239000011116 polymethylpentene Substances 0.000 description 1
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- 229920000098 polyolefin Polymers 0.000 description 1
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- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920006380 polyphenylene oxide Polymers 0.000 description 1
- 229920000069 polyphenylene sulfide Polymers 0.000 description 1
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- 229920001296 polysiloxane Polymers 0.000 description 1
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- 230000008439 repair process Effects 0.000 description 1
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- 239000002453 shampoo Substances 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
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- 239000001384 succinic acid Substances 0.000 description 1
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- 238000009864 tensile test Methods 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
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Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Biological Depolymerization Polymers (AREA)
Description
(1)(A)ポリ乳酸系樹脂および(B)メタクリル系樹脂を重量比((A)ポリ乳酸系樹脂/(B)メタクリル系樹脂)が90/10〜10/90で配合してなる樹脂組成物であって、(A)ポリ乳酸系樹脂が、L体が95%以上含まれるかまたはD体が95%以上含まれ、かつ、重量平均分子量が1万以上、50万以下であり、(B)メタクリル系樹脂の少なくとも1種が、重量平均分子量5万〜45万かつシンジオタクチシチー45〜56%、かつガラス転移温度が110℃以上、および230℃の温度かつ37.2Nの荷重でのメルトフローレートが、1〜30g/10分のメタクリル系樹脂である樹脂組成物であって、樹脂組成物中におけるメタクリル系樹脂のシンジオタクチシチーとアイソタクチシチーの比(シンジオタクチシチー/アイソタクチシチー)が、3.0〜8.5である樹脂組成物、
(2)樹脂組成物の、ガラス転移温度が、70℃以上である(1)に記載の樹脂組成物、
(3)(A)ポリ乳酸系樹脂および(B)メタクリル系樹脂の配合比が、59/41〜10/90である(1)〜(2)のいずれかに記載の樹脂組成物、
(4)樹脂組成物の、190℃、21.2N荷重にて測定したメルトフローレートが、30g/10分以下、0.1g/10分以上である(1)〜(3)のいずれかに記載の樹脂組成物、
(5)(1)〜(4)のいずれかに記載の樹脂組成物からなる成形品、
(6)成形品が、射出成形品、押出成形品、ブロー成形品、フィルムのいずれかである(5)記載の成形品、
である。
(A−1)ポリL乳酸樹脂(D体1.2%、重量平均分子量12万)
(A−2)ポリL乳酸樹脂(D体1.2%、重量平均分子量15万)
(A−3)ポリL乳酸樹脂(D体1.2%、重量平均分子量21万)
(B−1)メタクリル樹脂(住友化学製“スミペックスLG21” 重量平均分子量8万、ガラス転移温度105℃、シンジオタクチシチー41%、MFR21g/10分(230℃、37.2N))
(B−2)メタクリル樹脂(クラレ製“パラペット”HR−L、重量平均分子量9万、ガラス転移温度117℃、シンジオタクチシチー56%、MFR2g/10分(230℃、37.2N))
(B−3)メタクリル樹脂(住友化学製“スミペックス”LG35、重量平均分子量10万、ガラス転移温度90℃、シンジオタクチシチー39%、MFR35g/10分(230℃、37.2N))
ゲルパーミエーションクロマトグラフィー(GPC)により測定した標準PMMA換算の重量平均分子量の値である。溶媒にヘキサフルオロイソプロパノールを用い、流速0.5mL/minとし、試料濃度1mg/mLの溶液を0.1mL注入して測定した。
1H−NMR測定により測定した値である。1H−NMR測定は、日本電子製JNM−AL400を用いて、溶媒として重水素化クロロホルムを用い、試料濃度20mg/mLとして測定した。シンジオタクチシチー、ヘテロタクチシチー、アイソタクチシチーとしてそれぞれ観察される0.9ppm、1.0ppm、1.2ppmの直鎖分岐のメチル基のピークの積分強度の合計を100%として、それぞれのピークの積分強度の割合を百分率で表した値をそれぞれシンジオタクチシチー、ヘテロタクチシチー、アイソタクチシチーとした。
JIS K7121に準じて、示差走査型熱量計(セイコー電子製RDC220)により測定した。測定条件は、試料10mg、窒素雰囲気下中、昇温速度20℃/分である。
日本電色工業製ヘイズメーターNDH−300Aを用いて、JIS−K7105に準じ、5cm×5cm×1mmの板状成形品のヘイズを測定した。
樹脂組成物の流動性について、JIS K7210に準じて、190℃、21.2N荷重において測定した。
ASTM法D638に準じて、ASTM1号ダンベル成形品を用いて、引張試験を行った。
JIS K5600−5−4に準じて、5cm×5cm×1mmの板状成形品の鉛筆硬度を測定した。
表1に示すようにポリ乳酸系樹脂、メタクリル系樹脂を配合し、30mm径の二軸押出機を用い、シリンダー温度200℃、回転数200rpmの条件で溶融混練を行いペレット状の樹脂組成物を得た。
表2に示すようにポリ乳酸系樹脂、メタクリル系樹脂を配合し、30mm径の二軸押出機を用い、シリンダー温度200℃、回転数200rpmの条件で溶融混練を行いペレット状の樹脂組成物を得た。
実施例9〜10については、表3に示すようにポリ乳酸系樹脂およびメタクリル系樹脂を配合する以外は、全て実施例1と同様にして樹脂組成物および成形品を作成し、ガラス転移温度、ヘイズ、MFRを求めた。
◎:30度以上
○:20〜30度
△:15〜20度
×:15度以下。
◎:問題なく再生することができる。
○:やや変形しているものの、再生することができる。
△:読みとりエラーが一部あり、再生が不充分である。
×:全く再生できない。
Claims (6)
- (A)ポリ乳酸系樹脂および(B)メタクリル系樹脂を重量比((A)ポリ乳酸系樹脂/(B)メタクリル系樹脂)が90/10〜10/90で配合してなる樹脂組成物であって、(A)ポリ乳酸系樹脂が、L体が95%以上含まれるかまたはD体が95%以上含まれ、かつ、重量平均分子量が1万以上、50万以下であり、(B)メタクリル系樹脂の少なくとも1種が、重量平均分子量5万〜45万かつシンジオタクチシチー45〜56%、かつガラス転移温度が110℃以上、および230℃の温度かつ37.2Nの荷重でのメルトフローレートが、1〜30g/10分のメタクリル系樹脂である樹脂組成物であって、樹脂組成物中におけるメタクリル系樹脂のシンジオタクチシチーとアイソタクチシチーの比(シンジオタクチシチー/アイソタクチシチー)が、3.0〜8.5である樹脂組成物。
- 樹脂組成物のガラス転移温度が、70℃以上である請求項1に記載の樹脂組成物。
- (A)ポリ乳酸系樹脂および(B)メタクリル系樹脂の配合比が、59/41〜10/90である請求項1〜2のいずれかに記載の樹脂組成物。
- 樹脂組成物の、190℃、21.2N荷重にて測定したメルトフローレートが、30g/10分以下、0.1g/10分以上である請求項1〜3のいずれかに記載の樹脂組成物。
- 請求項1〜4のいずれか1項に記載の樹脂組成物からなる成形品。
- 成形品が、射出成形品、押出成形品、ブロー成形品、フィルムのいずれかである請求項5記載の成形品。
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