JP5215758B2 - ナノ粉末含有複合材料およびそれを製造するための組成物 - Google Patents
ナノ粉末含有複合材料およびそれを製造するための組成物 Download PDFInfo
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- JP5215758B2 JP5215758B2 JP2008182915A JP2008182915A JP5215758B2 JP 5215758 B2 JP5215758 B2 JP 5215758B2 JP 2008182915 A JP2008182915 A JP 2008182915A JP 2008182915 A JP2008182915 A JP 2008182915A JP 5215758 B2 JP5215758 B2 JP 5215758B2
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- 239000000203 mixture Substances 0.000 title claims description 45
- 239000002131 composite material Substances 0.000 title claims description 41
- 239000011858 nanopowder Substances 0.000 title claims description 29
- 229920000642 polymer Polymers 0.000 claims description 35
- 238000004140 cleaning Methods 0.000 claims description 25
- 239000004094 surface-active agent Substances 0.000 claims description 24
- 239000002657 fibrous material Substances 0.000 claims description 21
- -1 polyethylene Polymers 0.000 claims description 20
- 230000000051 modifying effect Effects 0.000 claims description 14
- 238000002156 mixing Methods 0.000 claims description 9
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 7
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 4
- 239000003945 anionic surfactant Substances 0.000 claims description 4
- 239000003093 cationic surfactant Substances 0.000 claims description 4
- 239000002736 nonionic surfactant Substances 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical group CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 claims description 4
- 239000013538 functional additive Substances 0.000 claims description 3
- 239000004814 polyurethane Substances 0.000 claims description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 2
- ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- 229920006197 POE laurate Polymers 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 239000004743 Polypropylene Substances 0.000 claims description 2
- 150000005215 alkyl ethers Chemical class 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 229940009868 aluminum magnesium silicate Drugs 0.000 claims description 2
- 229960000686 benzalkonium chloride Drugs 0.000 claims description 2
- XIWFQDBQMCDYJT-UHFFFAOYSA-M benzyl-dimethyl-tridecylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 XIWFQDBQMCDYJT-UHFFFAOYSA-M 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 claims description 2
- 229920001971 elastomer Polymers 0.000 claims description 2
- 235000013773 glyceryl triacetate Nutrition 0.000 claims description 2
- 239000001087 glyceryl triacetate Substances 0.000 claims description 2
- 229940094506 lauryl betaine Drugs 0.000 claims description 2
- 239000010985 leather Substances 0.000 claims description 2
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 claims description 2
- 239000000391 magnesium silicate Substances 0.000 claims description 2
- 229910052919 magnesium silicate Inorganic materials 0.000 claims description 2
- 235000019792 magnesium silicate Nutrition 0.000 claims description 2
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 claims description 2
- 229940049964 oleate Drugs 0.000 claims description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 2
- 239000011118 polyvinyl acetate Substances 0.000 claims description 2
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 2
- 239000005060 rubber Substances 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 235000012239 silicon dioxide Nutrition 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- 229960002622 triacetin Drugs 0.000 claims description 2
- 239000011787 zinc oxide Substances 0.000 claims description 2
- 229920000098 polyolefin Polymers 0.000 claims 4
- TUSDEZXZIZRFGC-UHFFFAOYSA-N 1-O-galloyl-3,6-(R)-HHDP-beta-D-glucose Natural products OC1C(O2)COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC1C(O)C2OC(=O)C1=CC(O)=C(O)C(O)=C1 TUSDEZXZIZRFGC-UHFFFAOYSA-N 0.000 claims 1
- 239000001263 FEMA 3042 Substances 0.000 claims 1
- LRBQNJMCXXYXIU-PPKXGCFTSA-N Penta-digallate-beta-D-glucose Natural products OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-PPKXGCFTSA-N 0.000 claims 1
- 239000002781 deodorant agent Substances 0.000 claims 1
- 229940071161 dodecylbenzenesulfonate Drugs 0.000 claims 1
- 239000010452 phosphate Substances 0.000 claims 1
- LRBQNJMCXXYXIU-NRMVVENXSA-N tannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-NRMVVENXSA-N 0.000 claims 1
- 229940033123 tannic acid Drugs 0.000 claims 1
- 235000015523 tannic acid Nutrition 0.000 claims 1
- 229920002258 tannic acid Polymers 0.000 claims 1
- 239000012802 nanoclay Substances 0.000 description 19
- 239000003607 modifier Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 6
- 238000005498 polishing Methods 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- 230000001464 adherent effect Effects 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000012459 cleaning agent Substances 0.000 description 2
- 239000011538 cleaning material Substances 0.000 description 2
- 230000001877 deodorizing effect Effects 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000013618 particulate matter Substances 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- XPKQZVMNPLADPZ-UHFFFAOYSA-N CC(C)C.CC(C)C.CC(CCCC(O)O)(C)C Chemical compound CC(C)C.CC(C)C.CC(CCCC(O)O)(C)C XPKQZVMNPLADPZ-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 150000001924 cycloalkanes Chemical class 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 239000002761 deinking Substances 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 229920001610 polycaprolactone Polymers 0.000 description 1
- 239000004632 polycaprolactone Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000909 polytetrahydrofuran Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000015227 regulation of liquid surface tension Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000001648 tannin Substances 0.000 description 1
- 229920001864 tannin Polymers 0.000 description 1
- 235000018553 tannin Nutrition 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 235000012431 wafers Nutrition 0.000 description 1
- 238000004018 waxing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3749—Polyolefins; Halogenated polyolefins; Natural or synthetic rubber; Polyarylolefins or halogenated polyarylolefins
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3753—Polyvinylalcohol; Ethers or esters thereof
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Nanotechnology (AREA)
- Composite Materials (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Physics & Mathematics (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
本発明の好ましい実施形態において、組成物は、100重量部のポリマーと、0.1〜40重量部の界面活性剤と、0.1〜40重量部のポリマー改質成分と、0.1〜100重量部のミクロ/ナノ粉末と、0.1〜8重量部の繊維材料とを含有する。
本発明のさらに好ましい実施形態において、ナノクレイ複合材料の製造のために用いられる組成物は、100重量部のポリマーと、0.5〜30重量部の界面活性剤と、0.5〜30重量部の改質剤と、0.1〜50重量部のミクロ/ナノ粉末と、0.1〜8重量部の繊維材料とを含有する。
本発明のさらに好ましい実施形態において、ナノクレイ複合材料の製造のために用いられる組成物は、100重量部のポリマーと、0.5〜30重量部の界面活性剤と、0.5〜30重量部のポリマー改質剤と、0.1〜50重量部のミクロ/ナノ粉末と、0.1〜8重量部の繊維材料とを含有する。
いくつかの実施形態において、可撓性ナノクレイ複合材料の製造に用いられる組成物は、芳香性および脱脂性などの複合機能の強化のために、たとえば、次亜塩素酸カルシウム、クエン酸、またはタンニン酸など、要求に応じた機能性添加剤をさらに含有する。
実施例1 ナノクレイ複合材料の調製
本明細書中に開示したすべての特徴は、他の方法と組み合わされてもよいし、同一、同等または同様の目的のための特徴によって入れ替えられてもよい。したがって、特に顕著な特徴を除いたすべての特徴は同等または同様の特徴の単なる例にすぎない。
Claims (13)
- 100重量部のポリオレフィンと、
0.1〜40重量部の界面活性剤と、
0.1〜40重量部のポリマー改質成分と、
0.1〜100重量部のミクロ/ナノ粉末と、
0.1〜10重量部の繊維材料とを含有する可撓性ナノ粉末含有複合材料の製造のための組成物であって、
前記ポリマー改質成分はトリアセチンであり、前記繊維材料はパルプであり、
前記複合材料は、自動車の清掃用途、ポリウレタンレザー上のインクプリントの清掃用途、又は脱臭用途で使用される、可撓性ナノ粉末含有複合材料の製造のための組成物。 - 100重量部のポリオレフィンと、
0.5〜30重量部の界面活性剤と、
0.5〜30重量部のポリマー改質成分と、
0.1〜50重量部のミクロ/ナノ粉末と、
0.1〜8重量部の繊維材料と
を含有する請求項1に記載の組成物。 - 100重量部のポリオレフィンと、
1〜20重量部の界面活性剤と、
1〜20重量部のポリマー改質成分と、
0.1〜25重量部のミクロ/ナノ粉末と、
0.5〜5重量部の繊維材料と
を含有する請求項2に記載の組成物。 - 前記ポリオレフィンは、ポリエチレン、ポリプロピレン、ポリ酢酸ビニル、ゴム、またはそれらの混合物からなる請求項1に記載の組成物。
- 前記界面活性剤は、アニオン性界面活性剤、カチオン性界面活性剤、非イオン性界面活性剤、またはそれらの混合物からなる請求項1に記載の組成物。
- 前記アニオン性界面活性剤は、ポリオキシエチレンアルキルエーテルホスフェート、カルボキシル化アルキルエトキシレート、カルボキシル化ドデシルベンゼンスルホネート、またはアンモニウムポリオキシエチレンアルキルエーテルサルフェートからなる請求項5に記載の組成物。
- 前記カチオン性界面活性剤は、四級アンモニウム塩、塩化ベンズアルコニウム、またはラウリルベタインからなる請求項5に記載の組成物。
- 前記非イオン性界面活性剤は、ポリオキシエチレンアルキルエーテル、オレイン酸ポリオキシエチレン、ステアリン酸ポリオキシエチレン、またはラウリン酸ポリオキシエチレンからなることを特徴とする請求項5に記載の組成物。
- 前記ミクロ/ナノ粉末の材料は、二酸化ケイ素、二酸化チタン、酸化亜鉛、炭酸カルシウム、酸化アルミニウム、ケイ酸マグネシウム、またはそれらの混合物からなる請求項1に記載の組成物。
- 前記ミクロ/ナノ粉末の粒子半径は50nm〜900nmである請求項1に記載の組成物。
- 機能性添加剤をさらに含有する請求項1に記載の組成物。
- 前記機能性添加剤は、次亜塩素酸カルシウム、クエン酸、またはタンニン酸からなる請求項11に記載の組成物。
- 請求項1に記載の組成物を調合して製造されるナノ粉末含有複合材料。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
TW096139642 | 2007-10-23 | ||
TW096139642A TWI408163B (zh) | 2007-10-23 | 2007-10-23 | 奈米黏土複合材料及製備該複合材料之組合物 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2009102611A JP2009102611A (ja) | 2009-05-14 |
JP5215758B2 true JP5215758B2 (ja) | 2013-06-19 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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JP2008182915A Expired - Fee Related JP5215758B2 (ja) | 2007-10-23 | 2008-07-14 | ナノ粉末含有複合材料およびそれを製造するための組成物 |
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CN103319907A (zh) * | 2013-05-10 | 2013-09-25 | 张悦雯 | 一种新型环保纳米材料 |
CN114404643A (zh) * | 2021-12-24 | 2022-04-29 | 北京积水潭医院 | 一种单宁酸原位改性的两性离子聚合物医用粘合剂及其制备方法 |
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DE1950669C3 (de) * | 1969-10-08 | 1982-05-13 | Metallgesellschaft Ag, 6000 Frankfurt | Verfahren zur Vliesherstellung |
US5382400A (en) * | 1992-08-21 | 1995-01-17 | Kimberly-Clark Corporation | Nonwoven multicomponent polymeric fabric and method for making same |
JP2966235B2 (ja) * | 1993-06-04 | 1999-10-25 | 古舘 忠夫 | 可塑性柔軟砥石 |
JP3699541B2 (ja) | 1996-07-09 | 2005-09-28 | 日本合成化学工業株式会社 | 成形機用洗浄剤 |
CN1358791A (zh) | 2000-12-12 | 2002-07-17 | 海尔科化工程塑料国家工程研究中心有限公司 | 一种制造农用棚膜用聚合物无机纳米复合组合物及其制备方法 |
US20050159063A1 (en) * | 2004-01-16 | 2005-07-21 | Bernard Hill | Disposable cleaning substrate |
JP4376648B2 (ja) | 2004-02-05 | 2009-12-02 | ダイセルポリマー株式会社 | 洗浄用樹脂組成物 |
JP2007077183A (ja) | 2005-09-12 | 2007-03-29 | Daicel Polymer Ltd | 成形機用の洗浄剤樹脂組成物 |
US20070179236A1 (en) * | 2006-02-01 | 2007-08-02 | Landon Shayne J | Sealant composition having reduced permeability to gas |
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TWI408163B (zh) | 2013-09-11 |
TW200918587A (en) | 2009-05-01 |
JP2009102611A (ja) | 2009-05-14 |
US20090105112A1 (en) | 2009-04-23 |
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