JP5191093B2 - Sol-like fragrance composition - Google Patents
Sol-like fragrance composition Download PDFInfo
- Publication number
- JP5191093B2 JP5191093B2 JP2005289461A JP2005289461A JP5191093B2 JP 5191093 B2 JP5191093 B2 JP 5191093B2 JP 2005289461 A JP2005289461 A JP 2005289461A JP 2005289461 A JP2005289461 A JP 2005289461A JP 5191093 B2 JP5191093 B2 JP 5191093B2
- Authority
- JP
- Japan
- Prior art keywords
- sol
- fragrance composition
- fragrance
- oil
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000003205 fragrance Substances 0.000 title claims description 150
- 239000000203 mixture Substances 0.000 title claims description 105
- 239000003349 gelling agent Substances 0.000 claims description 25
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 239000000679 carrageenan Substances 0.000 claims description 9
- 235000010418 carrageenan Nutrition 0.000 claims description 9
- 229920001525 carrageenan Polymers 0.000 claims description 9
- 229940113118 carrageenan Drugs 0.000 claims description 9
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical group [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 claims description 9
- 238000005259 measurement Methods 0.000 claims description 8
- 230000035515 penetration Effects 0.000 claims description 8
- 230000014759 maintenance of location Effects 0.000 claims description 4
- 239000004615 ingredient Substances 0.000 claims description 2
- 239000000499 gel Substances 0.000 description 33
- 235000019441 ethanol Nutrition 0.000 description 14
- 239000003921 oil Substances 0.000 description 14
- 235000019198 oils Nutrition 0.000 description 14
- -1 uranium thiol Chemical class 0.000 description 14
- 239000007788 liquid Substances 0.000 description 13
- 230000000694 effects Effects 0.000 description 10
- 238000002156 mixing Methods 0.000 description 10
- 238000011156 evaluation Methods 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 239000003431 cross linking reagent Substances 0.000 description 5
- 239000000796 flavoring agent Substances 0.000 description 5
- 235000019634 flavors Nutrition 0.000 description 5
- 229940098465 tincture Drugs 0.000 description 5
- SPEUIVXLLWOEMJ-UHFFFAOYSA-N 1,1-dimethoxyethane Chemical compound COC(C)OC SPEUIVXLLWOEMJ-UHFFFAOYSA-N 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 4
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 description 4
- 229940022663 acetate Drugs 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 241000402754 Erythranthe moschata Species 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 230000001747 exhibiting effect Effects 0.000 description 3
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 3
- 230000001953 sensory effect Effects 0.000 description 3
- DCXXKSXLKWAZNO-UHFFFAOYSA-N (2-methyl-6-methylideneoct-7-en-2-yl) acetate Chemical compound CC(=O)OC(C)(C)CCCC(=C)C=C DCXXKSXLKWAZNO-UHFFFAOYSA-N 0.000 description 2
- RCHLXMOXBJRGNX-UHFFFAOYSA-N 1-butylcyclohexan-1-ol Chemical group CCCCC1(O)CCCCC1 RCHLXMOXBJRGNX-UHFFFAOYSA-N 0.000 description 2
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 2
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 2
- PRNCMAKCNVRZFX-UHFFFAOYSA-N 3,7-dimethyloctan-1-ol Chemical compound CC(C)CCCC(C)CCO PRNCMAKCNVRZFX-UHFFFAOYSA-N 0.000 description 2
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
- ZCTQGTTXIYCGGC-UHFFFAOYSA-N Benzyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OCC1=CC=CC=C1 ZCTQGTTXIYCGGC-UHFFFAOYSA-N 0.000 description 2
- UYWQUFXKFGHYNT-UHFFFAOYSA-N Benzylformate Chemical compound O=COCC1=CC=CC=C1 UYWQUFXKFGHYNT-UHFFFAOYSA-N 0.000 description 2
- DZNVIZQPWLDQHI-UHFFFAOYSA-N Citronellyl formate Chemical compound O=COCCC(C)CCC=C(C)C DZNVIZQPWLDQHI-UHFFFAOYSA-N 0.000 description 2
- VCYVDHAWDPDCKW-UHFFFAOYSA-N Citrusal Chemical compound C1=CC(=O)OC2=C(CC(C)(C)C=O)C(OC)=CC=C21 VCYVDHAWDPDCKW-UHFFFAOYSA-N 0.000 description 2
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 description 2
- CRZQGDNQQAALAY-UHFFFAOYSA-N Methyl benzeneacetate Chemical compound COC(=O)CC1=CC=CC=C1 CRZQGDNQQAALAY-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- KGEKLUUHTZCSIP-HOSYDEDBSA-N [(1s,4s,6r)-1,7,7-trimethyl-6-bicyclo[2.2.1]heptanyl] acetate Chemical compound C1C[C@]2(C)[C@H](OC(=O)C)C[C@H]1C2(C)C KGEKLUUHTZCSIP-HOSYDEDBSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- HMKKIXGYKWDQSV-KAMYIIQDSA-N alpha-Amylcinnamaldehyde Chemical compound CCCCC\C(C=O)=C\C1=CC=CC=C1 HMKKIXGYKWDQSV-KAMYIIQDSA-N 0.000 description 2
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 2
- QUKGYYKBILRGFE-UHFFFAOYSA-N benzyl acetate Chemical compound CC(=O)OCC1=CC=CC=C1 QUKGYYKBILRGFE-UHFFFAOYSA-N 0.000 description 2
- XUPYJHCZDLZNFP-UHFFFAOYSA-N butyl butanoate Chemical compound CCCCOC(=O)CCC XUPYJHCZDLZNFP-UHFFFAOYSA-N 0.000 description 2
- ULDHMXUKGWMISQ-UHFFFAOYSA-N carvone Chemical compound CC(=C)C1CC=C(C)C(=O)C1 ULDHMXUKGWMISQ-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- NEHNMFOYXAPHSD-UHFFFAOYSA-N citronellal Chemical compound O=CCC(C)CCC=C(C)C NEHNMFOYXAPHSD-UHFFFAOYSA-N 0.000 description 2
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 description 2
- JOZKFWLRHCDGJA-UHFFFAOYSA-N citronellol acetate Chemical compound CC(=O)OCCC(C)CCC=C(C)C JOZKFWLRHCDGJA-UHFFFAOYSA-N 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- NNRLDGQZIVUQTE-UHFFFAOYSA-N gamma-Terpineol Chemical compound CC(C)=C1CCC(C)(O)CC1 NNRLDGQZIVUQTE-UHFFFAOYSA-N 0.000 description 2
- HIGQPQRQIQDZMP-UHFFFAOYSA-N geranil acetate Natural products CC(C)=CCCC(C)=CCOC(C)=O HIGQPQRQIQDZMP-UHFFFAOYSA-N 0.000 description 2
- HIGQPQRQIQDZMP-DHZHZOJOSA-N geranyl acetate Chemical compound CC(C)=CCC\C(C)=C\COC(C)=O HIGQPQRQIQDZMP-DHZHZOJOSA-N 0.000 description 2
- MLFHJEHSLIIPHL-UHFFFAOYSA-N isoamyl acetate Chemical compound CC(C)CCOC(C)=O MLFHJEHSLIIPHL-UHFFFAOYSA-N 0.000 description 2
- 150000002596 lactones Chemical class 0.000 description 2
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 2
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 2
- UWKAYLJWKGQEPM-LBPRGKRZSA-N linalyl acetate Chemical compound CC(C)=CCC[C@](C)(C=C)OC(C)=O UWKAYLJWKGQEPM-LBPRGKRZSA-N 0.000 description 2
- VAMXMNNIEUEQDV-UHFFFAOYSA-N methyl anthranilate Chemical compound COC(=O)C1=CC=CC=C1N VAMXMNNIEUEQDV-UHFFFAOYSA-N 0.000 description 2
- OSWPMRLSEDHDFF-UHFFFAOYSA-N methyl salicylate Chemical compound COC(=O)C1=CC=CC=C1O OSWPMRLSEDHDFF-UHFFFAOYSA-N 0.000 description 2
- 230000000877 morphologic effect Effects 0.000 description 2
- ZRSNZINYAWTAHE-UHFFFAOYSA-N p-methoxybenzaldehyde Chemical compound COC1=CC=C(C=O)C=C1 ZRSNZINYAWTAHE-UHFFFAOYSA-N 0.000 description 2
- MDHYEMXUFSJLGV-UHFFFAOYSA-N phenethyl acetate Chemical compound CC(=O)OCCC1=CC=CC=C1 MDHYEMXUFSJLGV-UHFFFAOYSA-N 0.000 description 2
- 239000010666 rose oil Substances 0.000 description 2
- 235000019719 rose oil Nutrition 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- MGSRCZKZVOBKFT-UHFFFAOYSA-N thymol Chemical compound CC(C)C1=CC=C(C)C=C1O MGSRCZKZVOBKFT-UHFFFAOYSA-N 0.000 description 2
- 239000013585 weight reducing agent Substances 0.000 description 2
- GRWFGVWFFZKLTI-UHFFFAOYSA-N α-pinene Chemical compound CC1=CCC2C(C)(C)C1C2 GRWFGVWFFZKLTI-UHFFFAOYSA-N 0.000 description 2
- NPNUFJAVOOONJE-ZIAGYGMSSA-N β-(E)-Caryophyllene Chemical compound C1CC(C)=CCCC(=C)[C@H]2CC(C)(C)[C@@H]21 NPNUFJAVOOONJE-ZIAGYGMSSA-N 0.000 description 2
- PSQYTAPXSHCGMF-BQYQJAHWSA-N β-ionone Chemical compound CC(=O)\C=C\C1=C(C)CCCC1(C)C PSQYTAPXSHCGMF-BQYQJAHWSA-N 0.000 description 2
- SFEOKXHPFMOVRM-UHFFFAOYSA-N (+)-(S)-gamma-ionone Natural products CC(=O)C=CC1C(=C)CCCC1(C)C SFEOKXHPFMOVRM-UHFFFAOYSA-N 0.000 description 1
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 description 1
- DTGKSKDOIYIVQL-WEDXCCLWSA-N (+)-borneol Chemical compound C1C[C@@]2(C)[C@@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-WEDXCCLWSA-N 0.000 description 1
- BGCIAWBDYRWKEK-UHFFFAOYSA-N (1-butylcyclohexyl) acetate Chemical group CCCCC1(OC(C)=O)CCCCC1 BGCIAWBDYRWKEK-UHFFFAOYSA-N 0.000 description 1
- 239000001695 (2E)-1,1-dimethoxy-3,7-dimethylocta-2,6-diene Substances 0.000 description 1
- ZSKAJFSSXURRGL-PKNBQFBNSA-N (2e)-1,1-dimethoxy-3,7-dimethylocta-2,6-diene Chemical compound COC(OC)\C=C(/C)CCC=C(C)C ZSKAJFSSXURRGL-PKNBQFBNSA-N 0.000 description 1
- HLCSDJLATUNSSI-JXMROGBWSA-N (2e)-3,7-dimethylocta-2,6-dienenitrile Chemical compound CC(C)=CCC\C(C)=C\C#N HLCSDJLATUNSSI-JXMROGBWSA-N 0.000 description 1
- SDOFMBGMRVAJNF-KVTDHHQDSA-N (2r,3r,4r,5r)-6-aminohexane-1,2,3,4,5-pentol Chemical compound NC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO SDOFMBGMRVAJNF-KVTDHHQDSA-N 0.000 description 1
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 description 1
- 239000001147 (3aR,5aS,9aS,9bR)-3a,6,6,9a-tetramethyl-2,4,5,5a,7,8,9,9b-octahydro-1H-benzo[e][1]benzofuran Substances 0.000 description 1
- 229940098795 (3z)- 3-hexenyl acetate Drugs 0.000 description 1
- KHWTYGFHPHRQMP-UHFFFAOYSA-N (4-propan-2-ylcyclohexyl)methanol Chemical compound CC(C)C1CCC(CO)CC1 KHWTYGFHPHRQMP-UHFFFAOYSA-N 0.000 description 1
- 239000001244 (E)-1-(2,6,6-trimethyl-1-cyclohex-2-enyl)pent-1-en-3-one Substances 0.000 description 1
- 239000001674 (E)-1-(2,6,6-trimethyl-1-cyclohexenyl)but-2-en-1-one Substances 0.000 description 1
- KJPRLNWUNMBNBZ-QPJJXVBHSA-N (E)-cinnamaldehyde Chemical compound O=C\C=C\C1=CC=CC=C1 KJPRLNWUNMBNBZ-QPJJXVBHSA-N 0.000 description 1
- OOCCDEMITAIZTP-QPJJXVBHSA-N (E)-cinnamyl alcohol Chemical compound OC\C=C\C1=CC=CC=C1 OOCCDEMITAIZTP-QPJJXVBHSA-N 0.000 description 1
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- XFPXWDJICXBWRU-UHFFFAOYSA-N (R)-Dihydrocitronellol acetate Chemical compound CC(C)CCCC(C)CCOC(C)=O XFPXWDJICXBWRU-UHFFFAOYSA-N 0.000 description 1
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- IMRYETFJNLKUHK-SJCJKPOMSA-N (S,S)-traseolide Chemical compound CC1=C(C(C)=O)C=C2[C@@H](C(C)C)[C@H](C)C(C)(C)C2=C1 IMRYETFJNLKUHK-SJCJKPOMSA-N 0.000 description 1
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- KHQDWCKZXLWDNM-KPKJPENVSA-N (e)-2-ethyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)but-2-en-1-ol Chemical compound CC\C(CO)=C/CC1CC=C(C)C1(C)C KHQDWCKZXLWDNM-KPKJPENVSA-N 0.000 description 1
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- GJJSUPSPZIZYPM-UHFFFAOYSA-N 1,4-dioxacyclohexadecane-5,16-dione Chemical compound O=C1CCCCCCCCCCC(=O)OCCO1 GJJSUPSPZIZYPM-UHFFFAOYSA-N 0.000 description 1
- MRMOPGVGWFNHIN-UHFFFAOYSA-N 1,6-dioxacycloheptadecan-7-one Chemical compound O=C1CCCCCCCCCCOCCCCO1 MRMOPGVGWFNHIN-UHFFFAOYSA-N 0.000 description 1
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- MFKRHJVUCZRDTF-UHFFFAOYSA-N 3-methoxy-3-methylbutan-1-ol Chemical compound COC(C)(C)CCO MFKRHJVUCZRDTF-UHFFFAOYSA-N 0.000 description 1
- CNJLMVZFWLNOEP-UHFFFAOYSA-N 4,7,7-trimethylbicyclo[4.1.0]heptan-5-one Chemical compound O=C1C(C)CCC2C(C)(C)C12 CNJLMVZFWLNOEP-UHFFFAOYSA-N 0.000 description 1
- WWJLCYHYLZZXBE-UHFFFAOYSA-N 5-chloro-1,3-dihydroindol-2-one Chemical compound ClC1=CC=C2NC(=O)CC2=C1 WWJLCYHYLZZXBE-UHFFFAOYSA-N 0.000 description 1
- AUBLFWWZTFFBNU-UHFFFAOYSA-N 6-butan-2-ylquinoline Chemical compound N1=CC=CC2=CC(C(C)CC)=CC=C21 AUBLFWWZTFFBNU-UHFFFAOYSA-N 0.000 description 1
- AZUVBPVDRHGGEP-UHFFFAOYSA-N 6a,9a-dimethyl-4,5,7,8,9,9a-hexahydro-6aH-dipyrrolo(2,3-b;3',2',1'-hi)indole Natural products CC(=C)C1CCC(C)=CCCC(C)=CCCC(C)=CC1O AZUVBPVDRHGGEP-UHFFFAOYSA-N 0.000 description 1
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- NVEQFIOZRFFVFW-UHFFFAOYSA-N 9-epi-beta-caryophyllene oxide Natural products C=C1CCC2OC2(C)CCC2C(C)(C)CC21 NVEQFIOZRFFVFW-UHFFFAOYSA-N 0.000 description 1
- FMYCPRQGKSONCP-UHFFFAOYSA-N Acetal R Chemical compound CCCOC(C)OCCC1=CC=CC=C1 FMYCPRQGKSONCP-UHFFFAOYSA-N 0.000 description 1
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- SATCULPHIDQDRE-UHFFFAOYSA-N piperonal Chemical compound O=CC1=CC=C2OCOC2=C1 SATCULPHIDQDRE-UHFFFAOYSA-N 0.000 description 1
- 239000001738 pogostemon cablin oil Substances 0.000 description 1
- 239000001367 polianthes tuberosa l. flower oil Substances 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 239000010668 rosemary oil Substances 0.000 description 1
- 229940058206 rosemary oil Drugs 0.000 description 1
- 239000010671 sandalwood oil Substances 0.000 description 1
- KWVISVAMQJWJSZ-VKROHFNGSA-N solasodine Chemical compound O([C@@H]1[C@@H]([C@]2(CC[C@@H]3[C@@]4(C)CC[C@H](O)CC4=CC[C@H]3[C@@H]2C1)C)[C@@H]1C)[C@]11CC[C@@H](C)CN1 KWVISVAMQJWJSZ-VKROHFNGSA-N 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 235000019721 spearmint oil Nutrition 0.000 description 1
- 229940087124 spike lavender oil Drugs 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000010676 star anise oil Substances 0.000 description 1
- 125000005504 styryl group Chemical group 0.000 description 1
- 239000010678 thyme oil Substances 0.000 description 1
- 229960000790 thymol Drugs 0.000 description 1
- NPFVOOAXDOBMCE-UHFFFAOYSA-N trans-3-hexenyl acetate Natural products CCC=CCCOC(C)=O NPFVOOAXDOBMCE-UHFFFAOYSA-N 0.000 description 1
- 239000010679 vetiver oil Substances 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
- ZFNVDHOSLNRHNN-UHFFFAOYSA-N xi-3-(4-Isopropylphenyl)-2-methylpropanal Chemical compound O=CC(C)CC1=CC=C(C(C)C)C=C1 ZFNVDHOSLNRHNN-UHFFFAOYSA-N 0.000 description 1
- CRIGTVCBMUKRSL-ALCCZGGFSA-N α-damascone Chemical compound C\C=C/C(=O)C1C(C)=CCCC1(C)C CRIGTVCBMUKRSL-ALCCZGGFSA-N 0.000 description 1
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q13/00—Formulations or additives for perfume preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
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- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Cosmetics (AREA)
- Fats And Perfumes (AREA)
Description
本発明は、ゾル状芳香剤組成物に関する。より詳細には、使用により経時的に、ゾル状からゲル状に形態が変化し、持続的に安定な芳香効果を奏することができるゾル状芳香剤組成物に関する。 The present invention relates to a sol-like fragrance composition. More specifically, the present invention relates to a sol-like fragrance composition that changes its form from a sol state to a gel shape over time and can provide a stable and stable fragrance effect.
従来、芳香剤として、液状形態とゲル状形態のものが知られている。従来のゲル状形態の芳香剤では、固体状であり、芳香剤が容器からこぼれ落ちることがないという利点があるが、使用に伴って、芳香剤の表面が固化した膜で覆われてしまい、使用時間の経過と共に発香性が低減するという欠点があった。一方、液状形態の芳香剤は、開口部が大きい容器に収容して使用すると、良好な発香性を安定で持続的に示すことができることが分かっている。しかしながら、液状形態の芳香剤は、流動性が高く、容器からこぼれ落ち易いため、開口部が小さく内容物がこぼれにくい構造の容器や、不織布等の揮散部材に芳香剤を含浸させて揮発できるように設計された容器に収容して使用されているのが現状である。このような容器に収容して、液状形態の芳香剤を使用すると、容器の開口部が小さいことにより芳香剤の発香速度が低くなったり、揮散部材に目詰まりが起こることにより芳香剤の発香性が不十分になるといった欠点があった。 Conventionally, as a fragrance, a liquid form and a gel form are known. In the conventional gel-like fragrance, it is solid and has the advantage that the fragrance does not spill out of the container, but with use, the surface of the fragrance is covered with a solidified film, There was a drawback that the fragrance decreased with the passage of time of use. On the other hand, it has been found that the liquid form fragrance can stably and continuously exhibit good fragrance when used in a container having a large opening. However, liquid form fragrance is highly fluid and easily spills out of the container, so that it can be volatilized by impregnating the fragrance with a volatile material such as a container with a small opening and a content that does not easily spill, or a non-woven fabric. The current situation is that they are housed in designed containers. When the liquid form fragrance is used in such a container, the fragrance speed of the fragrance decreases due to the small opening of the container or the volatile agent is released due to clogging of the volatilizing member. There was a disadvantage that the fragrance became insufficient.
また、従来、液状形態の芳香剤は、使用によって含有成分が揮発しても、残存する芳香剤は液状形態が保たれているように処方されている（例えば、特許文献１参照）。一方、これまでに、含有成分の揮発により芳香剤自体が減量すると、液状形態からゲル状形態に変化するように設計された液状形態の芳香剤については一切知られていない。
本発明は、液状形態の芳香剤の利点（即ち、安定な発香性を示す点）と、ゲル状形態の芳香剤の利点（即ち、容器からこぼれにくい点）とを併せ持つ芳香剤組成物を提供することを目的とする。また、本発明の目的は、持続的で安定な発香性を示す芳香剤組成物を提供することである。 The present invention provides a fragrance composition that combines the advantages of a fragrance in a liquid form (that is, a point exhibiting stable fragrance) and the advantages of a fragrance in a gel form (that is, a point that is difficult to spill from a container). The purpose is to provide. Moreover, the objective of this invention is providing the fragrance composition which shows the persistent and stable fragrance property.
本発明者らは、上記課題を解決すべく鋭意検討したところ、使用によって経時的に芳香剤組成物が減量するのに伴ってゾル状からゲル状に形態が変化する、従来にない新たなタイプのゾル状芳香剤組成物を作製した。そして、上記ゾル状芳香剤組成物は、持続的に安定な発香性を示し得ることを見出した。更に、上記ゾル状芳香剤組成物は、ゾル状態で粘稠性を備えることが可能であり、容器からこぼれ落ち難いように処方することができるので、開口部が大きい容器に収容して使用できることを見出した。本発明は、これらの知見に基づいて、更に検討を重ねることにより完成したものである。 The present inventors have intensively studied to solve the above-mentioned problems. As a result, the form of the fragrance composition is reduced over time by use, and the form changes from a sol to a gel. A sol-like fragrance composition was prepared. And it discovered that the said sol-like fragrance | flavor composition could show the stable fragrance property continuously. Furthermore, since the sol-like fragrance composition can be provided with a viscosity in a sol state and can be formulated so as not to easily spill from the container, it can be used by being accommodated in a container having a large opening. I found it. The present invention has been completed by further studies based on these findings.
即ち、本発明は、下記に掲げるゾル状芳香剤組成物を提供する。
項１． 芳香成分、ゲル化剤及び揮発性基剤を含有するゾル状芳香剤組成物であって、含有成分の揮発に伴ってゾル状態からゲル状態に変化することを特徴とする、ゾル状芳香剤組成物。
項２． 含有成分の揮発によってゾル状芳香剤組成物の総量の内５０重量％が減量するまでに、保形性を有するゲル状態を呈することを特徴とする、項１に記載のゾル状芳香剤組成物。
項３． 前記保形性を有するゲル状態において、レオメータ測定値によるゲル強度が1〜100g（測定条件：検体保存温度25℃、感圧軸の針径10ｍｍφ、針入速度30mm/min、針入長10ｍｍ）であることを特徴とする、項２に記載のゾル状芳香剤組成物。
項４． 粘度が100〜8000 mPa・sである、項１乃至３の何れかに記載のゾル状芳香剤組成物。
項５． ゲル化剤がιカラギーナンである、項１乃至４の何れかに記載のゾル状芳香剤組成物。
項６． ゲル化剤がゾル状芳香剤組成物の総量に対して0.1〜10重量％の割合で含有されている、項１乃至５の何れかに記載のゾル状芳香剤組成物。
That is, the present invention provides sol-like fragrance compositions listed below.
Item 1. A sol-like fragrance composition comprising a fragrance component, a gelling agent and a volatile base, wherein the sol-like fragrance composition changes from a sol state to a gel state as the component components volatilize. object.
Item 2. Item 2. The sol-like fragrance composition according to item 1, wherein the sol-like fragrance composition exhibits a shape-retaining gel state until 50% by weight of the total amount of the sol-like fragrance composition is reduced by volatilization of the components. .
Item 3. In the gel state having the shape-retaining property, the gel strength according to the rheometer measurement value is 1 to 100 g (measurement conditions: specimen storage temperature 25 ° C., pressure sensitive axis needle diameter 10 mmφ, penetration speed 30 mm / min, penetration length 10 mm) Item 3. The sol-like fragrance composition according to Item 2, which is
Item 4. Item 4. The sol-like fragrance composition according to any one of Items 1 to 3, having a viscosity of 100 to 8000 mPa · s.
Item 5. Item 5. The sol-like fragrance composition according to any one of Items 1 to 4, wherein the gelling agent is ι carrageenan.
Item 6. Item 6. The sol-like fragrance composition according to any one of Items 1 to 5, wherein the gelling agent is contained in a proportion of 0.1 to 10% by weight with respect to the total amount of the sol-like fragrance composition.
以下に、本発明を詳細に説明する。なお、本発明において、特に言及しない限り、ゾル状態、ゾル状、ゲル状態、又はゲル状とは、常温（２５±１℃）における組成物の状態を示す。 The present invention is described in detail below. In the present invention, unless otherwise specified, the sol state, the sol state, the gel state, or the gel state indicates the state of the composition at normal temperature (25 ± 1 ° C.).
本発明の芳香剤組成物に含まれる芳香成分については、天然香料、天然香料から分離された単離香料、合成香料のいずれであってもよく、従来の芳香剤に使用されている公知の芳香成分を使用することができる。芳香成分として、具体的には、炭素数６〜１２のアルデヒド、アニスアルデヒド、アセタールＲ、アセトフェノン、アセチルセドレン、アドキサール、アリルアミルグリコレート、アリルシクロヘキサンプロピオネート、アルファダマスコン、アンブレットリッド、アンブロキサン、アミルシンナミックアルデヒド、アミルシンナミックアルデヒドジメチルアセタール、アミルバレリアネート、アミルサリシレート、イソアミルアセテート、アセチルユゲノール、イソアミルサリシレート、インドール、αイオノン、βイオノン、αメチルイオノン、βメチルイオノン、γメチルイオノン、インデン、エチルワニリン、オウランチオール、オークモスＮｏ.１、オリボン、オキシフェニロン、カリオフィレン、カシュメラン、カルボン、ガラキソリッド、キャロン、クマリン、パラクレジールメチルエーテル、ゲラニオール、ゲラニルアセテート、ゲラニルフォーメート、ゲラニルニトリル、テトラヒドロゲラニオール、テトラヒドロゲラニールアセテート、コアボン、サンダロア、サンデラ、サンタレックス、サンタリノール、メチルサリシレート、シンナミックアルコール、シンナミックアルデヒド、シスジャスモン、シトラール、シトラールジメチルアセタール、シトラサール、シトロネラール、シトロネロール、シトロネリルアセテート、シトロネリルフォーメート、シトロネリルニトリル、シクラセット、シクラメンアルデヒド、シクラプロップ、シンナミルアセテート、ジヒドロジャスモン、ジメトール、イソシクロシトラール、ジャスマール、ジャスモラクトン、ジャスモフィラン、スチラリールアセテート、スチラリールプロピオネート、セドロアンバー、セドリルアセテート、セドロール、セレストリッド、βダマスコン、αターピネオール、γターピネオール、ターピニルアセテート、チモール、デルタダマスコン、デルタＣ６〜Ｃ１３ラクトン、トナリッド、トラセオライド、トリプラール、イソノニルアセテート、ネロール、ネリールアセテート、ネオベルガメート、ノピールアセテート、ノピールアルコール、バクダノール、ヒヤシンスジメチルアセタール、ヒドロトロピックアルコール、ヒドロキシシトロネラール、αピネン、ブチルブチレート、パラターシャリーブチルシクロヘキサノール、パラターシャリーブチルシクロヘキシルアセテート、オルトターシャリーブチルシクロヘキサノール、ジフェニルオキサイド、フルイテート、フェンチールアルコール、フェニルエチルフェニルアセテート、イソブチルキノリン、フェニルエチルアルコール、フェニルエチルアセテート、フェニルアセトアルデハイドジメチルアセタール、ベンジルアセテート、ベンジルアルコール、ベンジルサリシレート、ベルガミールアセテート、ベンズアルデヒド、ベンジルフォーメート、ジメチルベンジルカービノール、ヘディオン、ヘリオナール、ヘリオトロピン、シス−３−ヘキセノール、シス−３−ヘキセニールアセテート、シス−３−ヘキセニールサリシレート、ヘキシルシンナミックアルデヒド、ヘキシルサリシレート、ペンタリッド、ベルドックス、オルトボルニルアセテート、イソボルニルアセテート、イソボルネオール、エンド−ボルネオール、マンザネート、マイヨール、ミューゲアルデヒド、ミラックアルデヒド、ジヒドロミルセノール、ジミルセトール、ムゴール、ムスクＴＭ−II、ムスク７８１、ムスクＣ１４、ムスクＴ、ムスクケトン、ムスクチベチン、ムスクモスケン、メンサニールアセテート、メンソネート、メチルアンスラニレート、メチルユゲノール、メントール、メチルフェニルアセテート、ユゲノール、イソユゲノール、メチルイソユゲノール、γＣ６〜１３ラクトン、ライムオキサイド、メチルラベンダーケトン、ジヒドロリナロール、リグストラール、リリアール、リモネン、リナロール、リナロールオキサイド、テトラヒドロリナロール、テトラヒドロリナリールアセテート、リナリルアセテート、リラール、ルバフラン、ローズフェノン、ローズオキサイド、ワニリン、ベンゾイン、ペルーバルサム、トルーバルサム、チュベローズ油、ムスクチンキ、カストリウムチンキ、シベットチンキ、アンバーグリスチンキ、ペパーミント油、ペリラ油、プチグレン油、パイン油、ローズ油、ローズマリー油、しょう脳油、芳油、クラリーセージ油、サンダルウッド油、スペアミント油、スパイクラベンダー油、スターアニス油、ラバンジン油、ラベンダー油、レモン油、レモングラス油、ライム油、ネロリ油、オークモス油、オコチア油、パチュリ油、タイム油、トンカ豆チンキ、テレピン油、ワニラ豆チンキ、バジル油、ナツメグ油、シトロネラ油、クローブ油、ボアドローズ油、カナンガ油、カルダモン油、カシア油、シダーウッド油、オレンジ油、マンダリン油、タンジェリン油、アニス油、ベイ油、コリアンダー油、エレミ油、ユーカリ油、フェンネル油、ガルバナム油、ゼラニウム油、ヒバ油、桧油、ジャスミン油、ベチバー油、ベルガモット油、イランイラン油、グレープフルーツ油、ゆず油等を挙げることができる。これらの芳香成分は、１種単独で使用してもよく、また２種以上を任意に組み合わせて調香して使用することもできる。 The fragrance component contained in the fragrance composition of the present invention may be a natural fragrance, an isolated fragrance separated from a natural fragrance, or a synthetic fragrance, and is a known fragrance used in conventional fragrances. Ingredients can be used. Specific examples of aromatic components include aldehydes having 6 to 12 carbon atoms, anisaldehyde, acetal R, acetophenone, acetyl cedrene, adoxal, allyl amyl glycolate, allyl cyclohexane propionate, alpha damascone, amblet lid, Ambroxan, amylcinnamic aldehyde, amylcinnamic aldehyde dimethyl acetal, amyl valericate, amyl salicylate, isoamyl acetate, acetyl yugenol, isoamyl salicylate, indole, α ionone, β ionone, α methyl ionone, β methyl ionone, γ methyl ionone, indene , Ethyl alliline, uranium thiol, oak moss No. 1, olibon, oxyphenylone, caryophyllene, cashmerelan, carvone, galaxo , Caron, coumarin, paracresyl methyl ether, geraniol, geranyl acetate, geranyl formate, geranyl nitrile, tetrahydrogeraniol, tetrahydrogeranyl acetate, coabon, sandaroa, sandera, santa rex, santalinol, methyl salicylate, cinnamic Alcohol, cinnamic aldehyde, cis jasmon, citral, citral dimethyl acetal, citrusal, citronellal, citronellol, citronellyl acetate, citronellyl formate, citronellil nitrile, cyclaset, cyclamenaldehyde, cyclaprop, cinnamyl acetate, dihydrojasmon, Dimethol, isocyclocitral, jasmar, jasmolactone, jasmo Filan, styryl reel acetate, styryl propionate, cedro amber, cedol acetate, cedrol, celestrido, β damascone, α terpineol, γ terpineol, tarpinyl acetate, thymol, delta damascon, delta C6-C13 Lactone, tonalid, traseolide, tripral, isononyl acetate, nerol, neryl acetate, neobergamate, nopelacetate, nopele alcohol, bacdanol, hyacinth dimethyl acetal, hydrotropic alcohol, hydroxycitronellal, alpha pinene, butyl butyrate Rate, para tertiary butyl cyclohexanol, para tertiary butyl cyclohexyl acetate, ortho tertiary butyl cyclohexanol, di Phenyl oxide, fluitate, phenthyl alcohol, phenyl ethyl phenyl acetate, isobutyl quinoline, phenyl ethyl alcohol, phenyl ethyl acetate, phenyl acetoaldehyde dimethyl acetal, benzyl acetate, benzyl alcohol, benzyl salicylate, bergamyl acetate, benzaldehyde, benzyl formate, Dimethylbenzylcarbinol, hedion, helional, heliotropin, cis-3-hexenol, cis-3-hexenyl acetate, cis-3-hexenyl salicylate, hexylcinnamic aldehyde, hexyl salicylate, pentalide, bellox, ortho Bornyl acetate, isobornyl acetate, isoborneol, endo-borneo , Manzanate, mayol, mugealdehyde, miracaldehyde, dihydromyrsenol, dimyrcetol, mugor, musk TM-II, musk 781, musk C14, musk T, musk ketone, musk civetine, musk mosken, mensanil acetate, mensonate, methyl Anthranilate, Methyl Yugenol, Menthol, Methyl Phenyl Acetate, Yugenol, Iso Yugenol, Methyl Iso Yugenol, γC 6-13 Lactone, Lime Oxide, Methyl Lavender Ketone, Dihydrolinalol, Ligstral, Lilyal, Limonene, Linalool, Linalool Oxide, Tetrahydro Linalool, tetrahydrolinalyl acetate, linalyl acetate, rilal, rubafuran, rosephenone, rose o Kide, crocodile, benzoin, perubalsum, trubalsum, tuberose oil, mustin tincture, castrium tincture, civet tincture, ambergris tincture, peppermint oil, perilla oil, petitgren oil, pine oil, rose oil, rosemary oil, bran oil , Good oil, clary sage oil, sandalwood oil, spearmint oil, spike lavender oil, star anise oil, lavandin oil, lavender oil, lemon oil, lemongrass oil, lime oil, neroli oil, oak moss oil, okothia oil, patchouli oil, Thyme oil, tonka bean tincture, turpentine oil, vanilla bean tincture, basil oil, nutmeg oil, citronella oil, clove oil, bored rose oil, cananga oil, cardamom oil, cassia oil, cedarwood oil, orange oil, mandarin oil, tangerine oil, anise Bay oil, coriander oil, elemi oil, eucalyptus oil, fennel oil, galvanum oil, geranium oil, hiba oil, cocoon oil, jasmine oil, vetiver oil, bergamot oil, ylang ylang oil, grapefruit oil, yuzu oil, etc. Can do. These fragrance components may be used alone or in combination with any combination of two or more.
本発明の芳香剤組成物において、芳香成分の配合割合については、使用する芳香成分の種類、該芳香剤組成物の発香性の強度等に応じて適宜設定されるが、一例として、該芳香剤組成物の総量に対して、芳香成分が総量で0.1〜15重量％、好ましくは0.2〜10重量％、更に好ましくは0.3〜5重量％が挙げられる。 In the fragrance composition of the present invention, the blending ratio of the fragrance component is appropriately set according to the type of the fragrance component to be used, the intensity of the fragrance of the fragrance composition, etc. The total amount of the fragrance component is 0.1 to 15% by weight, preferably 0.2 to 10% by weight, more preferably 0.3 to 5% by weight, based on the total amount of the agent composition.
本発明の芳香剤組成物は、更にゲル化剤を含有する。本発明において、ゲル化剤は、組成物中の濃度に応じて、組成物をゾル状態（液体形態）にしたり、ゲル状態にしたりすることが可能なものが採用される。 The fragrance composition of the present invention further contains a gelling agent. In the present invention, as the gelling agent, a gelling agent that can make the composition into a sol state (liquid form) or a gel state is employed depending on the concentration in the composition.
本発明の芳香剤組成物において、ゲル化剤は、該芳香剤組成物中の含有成分の揮発に伴って、該芳香剤組成物の形態をゾル状態からゲル状態に変化させるために配合される。即ち、本発明の芳香剤組成物において、ゲル化剤の配合割合は、ゾル状態が保持される程度であり、且つ芳香剤組成物中の含有成分が揮発して該芳香剤組成物が減量すると、該芳香剤組成物がゲル状態に変化する程度に設定される。 In the fragrance composition of the present invention, the gelling agent is blended to change the form of the fragrance composition from the sol state to the gel state as the components contained in the fragrance composition volatilize. . That is, in the fragrance composition of the present invention, the blending ratio of the gelling agent is such that the sol state is maintained, and when the contained components in the fragrance composition are volatilized and the fragrance composition is reduced. The fragrance composition is set to such an extent that it changes to a gel state.
より具体的には、以下のような形態挙動を示すように、ゲル化剤を配合しておくことが望ましい。即ち、本発明の芳香剤組成物の含有成分が揮発して、芳香剤組成物の総量の内50重量％が減量するまでに（即ち、芳香剤組成物１００重量部の内、合計50重量部の含有成分が揮発するまでに）、保形性を有するゲル状態を呈する。ここで、保形性を有するゲル状態とは、一定の形状が保持される程度にゲル化されている状態をいい、具体的には、ゲル強度が1〜100g、好ましくは2〜80g、更に好ましくは3〜50gである状態が例示される。本発明において、ゲル強度は、レオメーター（SUN RHEO METER CR-500DX；株式会社サン科学製）により、検体温度25℃、感圧軸（アダプター）の針径10ｍｍφ、針入速度30mm/minにおける針入度試験において、感圧軸を深さ10ｍｍまで押し込む際に感圧軸にかかる荷重(g)である。 More specifically, it is desirable to blend a gelling agent so as to exhibit the following form behavior. That is, until the content of the fragrance composition of the present invention volatilizes and 50% by weight of the total amount of the fragrance composition is reduced (that is, 50 parts by weight in total of 100 parts by weight of the fragrance composition). Until the contained component volatilizes), a gel state having shape retention is exhibited. Here, the gel state having shape retention refers to a state in which the gel is gelled to such an extent that a certain shape is maintained. Specifically, the gel strength is 1 to 100 g, preferably 2 to 80 g, The state which is preferably 3 to 50 g is exemplified. In the present invention, the gel strength is measured with a rheometer (SUN RHEO METER CR-500DX; manufactured by Sun Kagaku Co., Ltd.) at a specimen temperature of 25 ° C., a pressure sensitive shaft (adapter) needle diameter of 10 mmφ, and a needle penetration speed of 30 mm / min. This is the load (g) applied to the pressure sensitive shaft when the pressure sensitive shaft is pushed down to a depth of 10 mm in the penetration test.
上記のように、芳香剤組成物の減量に伴ってゾル状態からゲル状態に変化する挙動を示すことにより、該芳香剤組成物の発香性（芳香効果）が安定で持続的に奏されると共に、芳香剤組成物の残量を量ではなく、形態を指標として判断することが可能になる。 As described above, by exhibiting a behavior that changes from a sol state to a gel state as the fragrance composition is reduced in weight, the fragrance property (fragrance effect) of the fragrance composition is stably and continuously exhibited. At the same time, it is possible to determine the remaining amount of the fragrance composition as an index instead of the amount.
本発明に使用されるゲル化剤としては、芳香剤組成物に、上記の形態挙動を付与できるものであれば特に制限されない。ゲル化剤の具体例としては、ιカラギーナン、κカラギーナン、λカラギーナン、ジェランガム、タマリンドガム、寒天、ペクチン等が例示される。これらのゲル化剤は、１種単独で使用してもよく、２種以上を組み合わせて使用してもよい。これらの中でも、ιカラギーナンは、濃度の変化によりゲル化する作用が大きく変動するため好適である。また、ιカラギーナンを配合すると、芳香剤組成物の減量に伴って、ひび割れ等の外観上の不具合がなく、１つの塊となった透明なゲルが形成されるという有利な効果も得られる。 The gelling agent used in the present invention is not particularly limited as long as it can impart the above morphological behavior to the fragrance composition. Specific examples of the gelling agent include ι carrageenan, κ carrageenan, λ carrageenan, gellan gum, tamarind gum, agar, pectin and the like. These gelling agents may be used alone or in combination of two or more. Among these, ι carrageenan is preferable because the action of gelation greatly varies depending on the concentration change. In addition, when ι carrageenan is blended, there is an advantageous effect that a transparent gel is formed as one lump without any defects in appearance such as cracks as the fragrance composition is reduced.
本発明の芳香剤組成物におけるゲル化剤の配合割合については、使用するゲル化剤の特性、他の配合成分の種類や量等を考慮して、上記の形態挙動を具備するように適宜設定される。一例として、芳香剤組成物の総量に対して、ゲル化剤が、通常0.1〜10重量％、好ましくは0.2〜8重量％、更に好ましくは0.3〜7重量％となる割合が例示される。より具体的には、ゲル化剤としてιカラギーナンを使用する場合であれば、芳香剤組成物の総量に対して、ιカラギーナンが、例えば0.1〜6重量％、好ましくは0.2〜5重量％、更に好ましくは0.3〜4重量％となる割合が例示される。 The blending ratio of the gelling agent in the fragrance composition of the present invention is appropriately set so as to have the above morphological behavior in consideration of the characteristics of the gelling agent used, the type and amount of other blending components, etc. Is done. As an example, the proportion of the gelling agent is usually 0.1 to 10% by weight, preferably 0.2 to 8% by weight, more preferably 0.3 to 7% by weight with respect to the total amount of the fragrance composition. More specifically, when ι carrageenan is used as a gelling agent, ι carrageenan is, for example, 0.1 to 6% by weight, preferably 0.2 to 5% by weight, based on the total amount of the fragrance composition. A proportion of 0.3 to 4% by weight is exemplified.
更に、本発明の芳香剤組成物は、揮発性基剤を含有する。揮発性基剤としては、室内等の環境で揮発する基剤成分である限り、特に制限されず、一般に、芳香剤組成物の基剤として配合されているものを広く使用することができる。揮発性基剤として、具体的には、水；メタノール、エタノール、プロパノール、ブタノール等の炭素数１〜3の低級アルコール；n-プロピルアルコール；イソプロピルアルコール等が例示される。これらの揮発性基剤は、１種を単独で使用しても、２種以上を組み合わせて使用してもよい。これらの中で、好ましくは、水、炭素数１〜3の低級アルコール及びこれらの組み合わせである。揮発性基剤として、更に好ましくは、水と、20℃での蒸気圧が2.4〜6.0kPaの範囲にあるアルコールとの組み合わせが例示される。特に好ましくは水とエタノールの組み合わせである。例えば、水と炭素数１〜３の低級アルコールを組み合わせて使用する場合、両者の比率については特に制限されないが、例えば、水100重量部に対して、該低級アルコールが0.1〜50重量部、好ましくは1〜40重量部となる比率が例示される。 Furthermore, the fragrance composition of the present invention contains a volatile base. The volatile base is not particularly limited as long as it is a base component that volatilizes in an environment such as a room, and in general, what is blended as a base of the fragrance composition can be widely used. Specific examples of the volatile base include water; lower alcohols having 1 to 3 carbon atoms such as methanol, ethanol, propanol and butanol; n-propyl alcohol; isopropyl alcohol and the like. These volatile bases may be used alone or in combination of two or more. Of these, water, lower alcohols having 1 to 3 carbon atoms, and combinations thereof are preferable. More preferable examples of the volatile base include a combination of water and an alcohol having a vapor pressure in the range of 2.4 to 6.0 kPa at 20 ° C. Particularly preferred is a combination of water and ethanol. For example, when water and a lower alcohol having 1 to 3 carbon atoms are used in combination, the ratio between the two is not particularly limited, but for example, the lower alcohol is 0.1 to 50 parts by weight, preferably 100 parts by weight of water. The ratio is 1 to 40 parts by weight.
また、本発明の芳香剤組成物において、揮発性基剤として、揮発速度が異なる２種以上の成分を使用し、それらの成分の混合比を適宜調整することにより、芳香剤組成物の揮発速度（減量速度）を制御することが可能になる。例えば、揮発性基剤として水と該低級アルコールを組み合わせて使用する場合、炭素数１〜3の低級アルコールは水に比べて揮発速度が高いため、水に対する該低級アルコールの配合比を高める程、ゾル状芳香剤組成物の揮発速度（減量速度）が速くなり、使用後速やかにゲル形態に変化させることができる。 Moreover, in the fragrance composition of the present invention, two or more components having different volatilization rates are used as the volatile base, and the volatilization rate of the fragrance composition is adjusted by appropriately adjusting the mixing ratio of these components. It is possible to control (weight loss rate). For example, when water and the lower alcohol are used in combination as a volatile base, the lower alcohol having 1 to 3 carbon atoms has a higher volatilization rate than water, so that the mixing ratio of the lower alcohol to water is increased. The volatilization rate (weight reduction rate) of the sol-like fragrance composition is increased, and can be rapidly changed to a gel form after use.
本発明の芳香剤組成物において、揮発性基剤の配合割合については、他の成分の配合割合等によって変動するが、一例として、該芳香剤組成物の総量に対して、揮発性基剤が総量で0.1〜99.5重量％、好ましくは１〜99重量％、更に好ましくは3〜95重量％となる割合が挙げられる。 In the fragrance composition of the present invention, the blending ratio of the volatile base varies depending on the blending ratio of other components, etc., but as an example, the volatile base is added to the total amount of the fragrance composition. The total amount is 0.1 to 99.5% by weight, preferably 1 to 99% by weight, and more preferably 3 to 95% by weight.
本発明の芳香剤組成物は、本発明の効果を妨げない範囲で、上記成分の他に、3-メチル-3-メトキシ-1-ブタノール、プロピレングリコール、ジプロピレングリコール等の芳香成分の溶解剤；非イオン性界面活性剤（ポリオキシエチレンアルキルエーテル、ポリオキシエチレン硬化ひまし油、アニオン性界面活性剤、両性界面活性剤等の界面活性剤；脱塩型ベタイン化合物、変性有機酸化合物、トリエタノールアミン等の消臭剤；1,2-ベンズイソチアゾリン-3-オン、2n-オクチル-イソチアゾリン-3-オン等の防腐剤；酸化防止剤；紫外線吸収剤；顔料、染料等の色素；シリコーン等の他の成分を適当量含有してもよい。 The fragrance composition of the present invention is a solubilizer of fragrance components such as 3-methyl-3-methoxy-1-butanol, propylene glycol, and dipropylene glycol, in addition to the above components, as long as the effects of the present invention are not hindered. ; Nonionic surfactant (polyoxyethylene alkyl ether, polyoxyethylene hydrogenated castor oil, anionic surfactant, amphoteric surfactant, etc .; desalted betaine compound, modified organic acid compound, triethanolamine Deodorants such as 1,2-benzisothiazolin-3-one, 2n-octyl-isothiazolin-3-one, etc .; antioxidants; UV absorbers; pigments, dyes, etc .; An appropriate amount of these components may be contained.
なお、乳酸カルシウム、塩化カリウム、塩化カルシウム等の架橋剤は、ゲル化剤のゲル化作用を強固にし、ゲル化剤を含む組成物でゾル状態を保持することが困難になることが多い。また、架橋剤が添加されて形成されたゲル状の芳香剤は、使用に伴って、芳香剤の表面が架橋剤の作用により固化する場合があり、発香性が低減することがある。それ故、良好なゾル状態を形成させ、持続的に良好な発香性を発現させるという観点から、本発明の芳香剤組成物には、ゲル化剤の不純物として不可避的に配合される場合等を除いて、架橋剤を配合しないことが望ましい。 In addition, crosslinking agents such as calcium lactate, potassium chloride, and calcium chloride often strengthen the gelling action of the gelling agent, and it is often difficult to maintain a sol state with the composition containing the gelling agent. Moreover, the gel-like fragrance | flavor formed by adding a crosslinking agent may solidify the surface of an fragrance | flavor by the effect | action of a crosslinking agent with use, and fragrance property may reduce. Therefore, from the viewpoint of forming a good sol state and continuously expressing good fragrance, the fragrance composition of the present invention is inevitably blended as an impurity of the gelling agent, etc. It is desirable not to add a crosslinking agent except for.
本発明のゾル状芳香剤組成物の粘度については、特に制限されない。但し、流動性を維持しつつ、容器からこぼれ難くして、開口部が大きい容器に収容しても好適に使用できるように粘稠性を備えさせるという観点から、該ゾル状芳香剤組成物の粘度は、例えば100〜8000 mPa・s、好ましくは200〜7000 mPa・s、更に好ましくは300〜6000 mPa・sであることが望ましい。当該粘度の測定条件は、次の通りである：B型回転粘度計（東機産業株式会社製、TOKI VISCOMETER RB-80L、No.2ローター）、回転数30rpm、25℃、500ｍLのビーカーに芳香剤組成物400mlを収容したものをサンプルとして測定。上記範囲の粘度を具備させるには、前述するゲル化剤の種類や配合割合、揮発性基剤の種類や配合割合等を適宜調整すればよい。 The viscosity of the sol-like fragrance composition of the present invention is not particularly limited. However, from the viewpoint of maintaining the fluidity, making it difficult to spill from the container, and providing the viscosity so that it can be suitably used even when accommodated in a container having a large opening, the sol-like fragrance composition is The viscosity is, for example, 100 to 8000 mPa · s, preferably 200 to 7000 mPa · s, and more preferably 300 to 6000 mPa · s. The measurement conditions of the viscosity are as follows: B-type rotational viscometer (manufactured by Toki Sangyo Co., Ltd., TOKI VISCOMETER RB-80L, No.2 rotor), fragrance in a beaker of 30 rpm, 25 ° C, 500 mL Measured as a sample containing 400 ml of the agent composition. In order to provide the viscosity in the above range, the type and blending ratio of the gelling agent described above, the kind and blending ratio of the volatile base, etc. may be appropriately adjusted.
本発明の芳香剤組成物は、使用によって経時的に芳香剤組成物が減量するのに伴ってゾル状からゲル状に形態が変化する、従来にない新たなタイプのゾル状芳香剤組成物である。このような形態の変動性に基づいて、本発明の芳香剤組成物は、その残存量を形状を指標として判断できるという利点もある。 The fragrance composition of the present invention is an unprecedented new type of sol-like fragrance composition that changes in form from a sol to a gel as the fragrance composition is reduced over time by use. is there. Based on such form variability, the fragrance composition of the present invention also has an advantage that its remaining amount can be determined using the shape as an index.
また、本発明の芳香剤組成物は、含有成分の揮発によってゲル状に形態が変化し、従来のゲル状芳香剤のように架橋剤が必須ではない。それ故、本発明の芳香剤組成物は、従来のゲル状芳香剤のように含有成分の揮発に伴ってその表面が固化した膜に覆われることがなく、持続的に安定な発香性を示すように処方することもできる。 In addition, the fragrance composition of the present invention changes into a gel form due to volatilization of the contained components, and a crosslinking agent is not essential as in the case of a conventional gel fragrance. Therefore, the fragrance composition of the present invention is not covered with a film whose surface is solidified with the volatilization of the components as in the conventional gel fragrance, and has a stable and stable fragrance. It can also be prescribed as shown.
更に、本発明の芳香剤組成物は、ゾル状態で粘稠性を備えることが可能であり、容器からこぼれ落ち難い性質を備え得るので、従来の液状洗浄剤では実用困難であった容器（即ち、開口部が大きい容器）に収容して、発香性を高めた状態で使用することも可能である。 Furthermore, since the fragrance composition of the present invention can be provided with a viscosity in a sol state and can be provided with a property that does not easily spill from the container, it is a container that has been difficult to use with conventional liquid detergents (that is, It is also possible to use it in a state in which it is stored in a container having a large opening) and has enhanced fragrance properties.
以下、試験例及び実施例を挙げて本発明を説明するが、本発明はこれらに限定されるものではない。
試験例１
表１に示す組成のゾル状芳香剤組成物（実施例１）、液状芳香剤組成物（比較例１）及びゲル状芳香剤組成物（比較例２）を調製した。これらの芳香剤組成物各100ｇを、上部が開口しているカップ状容器に収容して、室温で30日間静置した。各芳香剤組成物について、調製直後、室温静置15日後、及び室温静置30日後に、芳香効果について官能評価を行った。芳香効果の官能評価は、具体的には次のようにして実施した。即ち、容積１０００Ｌのステンレス製のボックス内を無臭と感じるまで換気を行った後に、評価対象の芳香剤組成物をボックス内に置いて、ボックス内を室温（約２５℃）に保った状態で、２０分間放置した。次いで、ボックス正面の小窓に鼻を近づけて、香りを嗅知することにより、香りの評価を行った。香りの評価は、８人のパネラーにより、「香りの強さ」、「香りの嗜好性」及び「香りの総合評価」について、下記の基準に従って数値化することにより判定した。
＜判定基準＞
（Ａ）香りの強さ
５：強い
４：やや強い
３：普通
２：やや弱い
１：弱い
（Ｂ）香りの嗜好性
２：良い
１：やや良い
０：普通
−１：やや悪い
−２：悪い
（Ｃ）香りの総合評価
２：良い
１：やや良い
０：普通
−１：やや悪い
−２：悪い
EXAMPLES Hereinafter, although a test example and an Example are given and this invention is demonstrated, this invention is not limited to these.
Test example 1
A sol-like fragrance composition (Example 1), a liquid fragrance composition (Comparative Example 1) and a gel-like fragrance composition (Comparative Example 2) having the composition shown in Table 1 were prepared. 100 g of each of these fragrance compositions was placed in a cup-shaped container having an open top and allowed to stand at room temperature for 30 days. Each fragrance composition was subjected to sensory evaluation for the fragrance effect immediately after preparation, 15 days after standing at room temperature, and 30 days after standing at room temperature. Specifically, the sensory evaluation of the aroma effect was performed as follows. That is, after ventilating the inside of the 1000L stainless steel box until it feels odorless, the fragrance composition to be evaluated was placed in the box, and the box was kept at room temperature (about 25 ° C). Left for 20 minutes. Next, the scent was evaluated by bringing the nose close to the small window in front of the box and smelling the scent. The evaluation of the scent was determined by digitizing “scent intensity”, “scent preference” and “scent evaluation” according to the following criteria by eight panelists.
<Criteria>
(A) Aroma intensity 5: Strong 4: Slightly strong 3: Normal 2: Slightly weak 1: Weak
(B) Scent preference 2: Good 1: Somewhat good 0: Normal -1: Somewhat bad -2: Bad
(C) Overall evaluation of fragrance 2: Good 1: Somewhat good 0: Normal -1: Somewhat bad -2: Bad
また、実施例１の芳香剤組成物は、次のような形態挙動を示した。即ち、実施例１の芳香剤組成物は、試験開始時（調製直後）に100ｇであったのが、室温静置15日後に50ｇに減量（即ち、50％減量）しており、この時点で透明で１つのゲル状の塊を形成していた。また、室温静置30日後には、更に10ｇにまで減量（即ち、90％減量）しており、この時点では１つの固形状の塊を形成していた。参考のために、図２に、調製直後の実施例１の芳香剤組成物を撮影した写真（図２のＡ）、室温静置15日後に実施例１の芳香剤組成物を撮影した写真（図２のＢ）及び室温静置30日後に実施例１の芳香剤組成物を撮影した写真（図２のＣ）を示す。 Moreover, the fragrance | flavor composition of Example 1 showed the following form behavior. That is, the fragrance composition of Example 1 was 100 g at the start of the test (immediately after preparation), but was reduced to 50 g (ie, 50% reduction) after 15 days of standing at room temperature. It was transparent and formed one gel-like lump. Further, after standing at room temperature for 30 days, the weight was further reduced to 10 g (that is, 90% weight reduction), and one solid lump was formed at this point. For reference, FIG. 2 shows a photograph of the fragrance composition of Example 1 immediately after preparation (A in FIG. 2), and a photograph of the fragrance composition of Example 1 taken 15 days after standing at room temperature ( Fig. 2B) and a photograph (C of Fig. 2) taken of the fragrance composition of Example 1 after standing at room temperature for 30 days are shown.
試験例２
上記表１に示す実施例１のゾル状の芳香剤組成物１００ｇを、上部が開口しているカップ容器（幅5cm、奥行き5cm、高さ5cm）に入れて、室温で放置した。カップ容器内の芳香剤組成物が５０％減量した時点で、該芳香剤組成物は保形成を備えているゲル状態を呈していることが確認できた。調製直後のゾル状態を呈している芳香剤組成物と、５０％減量した時点のゲル状態を呈している芳香剤組成物について、レオメータ測定値によるゲル強度（測定条件：検体温度25℃、感圧軸の針径10ｍｍφ、針入速度30mm/min、針入長10ｍｍ、最大荷重２ｋｇ）を測定した。この結果、調製直後の実施例１の芳香剤組成物は、ゾル状態を呈していることからも分かるようにゲル強度は０ｇであった。一方、５０％減量した時点において、ゲル状態を呈している芳香剤組成物は、レオメータ測定値によるゲル強度は４ｇであった。
Test example 2
100 g of the sol-like fragrance composition of Example 1 shown in Table 1 above was placed in a cup container (width 5 cm, depth 5 cm, height 5 cm) having an open top and left at room temperature. When the amount of the fragrance composition in the cup container was reduced by 50%, it was confirmed that the fragrance composition exhibited a gel state having retention. For the fragrance composition presenting the sol state immediately after preparation and the fragrance composition presenting the gel state when reduced by 50%, the gel strength (measurement condition: specimen temperature 25 ° C., pressure sensitive) measured by rheometer The needle diameter of the shaft was 10 mmφ, the penetration speed was 30 mm / min, the penetration length was 10 mm, and the maximum load was 2 kg). As a result, the fragrance composition of Example 1 immediately after preparation had a gel strength of 0 g as can be seen from the fact that it was in a sol state. On the other hand, at the time when the amount was reduced by 50%, the fragrance composition exhibiting a gel state had a gel strength of 4 g as measured by a rheometer.
試験例３
表２に示す組成のゾル状芳香剤組成物を調製し、その粘度について測定を行った。粘度の測定条件は、次の通りである：B型回転粘度計（東機産業株式会社製、TOKI VISCOMETER RB-80L、No.2ローター）、回転数30rpm、25℃、500ｍLのビーカーに芳香剤組成物400mlを収容したものをサンプルとして測定。
Test example 3
A sol-like fragrance composition having the composition shown in Table 2 was prepared, and the viscosity was measured. Viscosity measurement conditions are as follows: B-type rotational viscometer (TOKI VISCOMETER RB-80L, No.2 rotor, manufactured by Toki Sangyo Co., Ltd.), 30 rpm, 25 ° C, 500 mL beaker with air freshener A sample containing 400 ml of the composition was measured.
測定結果を表２に示す。この結果から、ゲル化剤とエタノールの濃度を適宜調整することにより、種々の粘稠性を示すゾル状態の芳香剤組成物が得られることが確認できた。 The measurement results are shown in Table 2. From this result, it was confirmed that by adjusting the concentration of the gelling agent and ethanol appropriately, sol-state fragrance compositions having various viscosities can be obtained.
Claims (6)
ゾル状芳香剤組成物であり、
ゲル化剤がカラギーナンであり、
揮発性基剤が水と低級アルコールの組み合わせであって、
含有成分の揮発によってゾル状芳香剤組成物の総量の内５０重量％が減量するまでに、保形性を有するゲル状態を呈し、
前記保形性を有するゲル状態において、レオメータ測定値によるゲル強度が1〜100ｇ（測定条件:検体保存温度25℃、感圧軸の針径10mmφ、針入速度30mm/min、針入長10mm）であり、
Ｂ型回転粘度計、回転数30rpm、25℃、500mLのビーカーに前記ゾル状芳香剤組成物400mlを収容したものをサンプルとして測定したときの粘度が100〜8000mPa・sである
ゾル状芳香剤組成物。 A sol-like fragrance composition containing a fragrance component, a gelling agent and a volatile base, characterized in that it changes from a sol state to a gel state at 25 ± 1 ° C. as the component components volatilize. ,
A sol-like fragrance composition,
The gelling agent is carrageenan,
The volatile base is a combination of water and a lower alcohol ,
By the volatilization of the ingredients, 50% by weight of the total amount of the sol-like fragrance composition is reduced to exhibit a gel state having shape retention,
In the gel state having the shape retaining property, the gel strength according to the rheometer measurement value is 1 to 100 g (measurement conditions: specimen storage temperature 25 ° C., pressure sensitive axis needle diameter 10 mmφ, penetration speed 30 mm / min, penetration length 10 mm) And
B-type rotational viscometer, sol-like fragrance composition having a viscosity of 100 to 8000 mPa · s when measured as a sample in which 400 ml of the sol-like fragrance composition is contained in a beaker of 30 rpm, 25 ° C. and 500 mL object.
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| JPS5813507A (en) * | 1981-07-14 | 1983-01-26 | Taiyo Koryo Kk | Gelatinous aromatic composition |
| JPS6064914A (en) * | 1983-08-23 | 1985-04-13 | Erimochiyou | Base for perfume |
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