JP5124473B2 - 重縮合反応性樹脂のナノ多孔質ポリマーフォーム - Google Patents
重縮合反応性樹脂のナノ多孔質ポリマーフォーム Download PDFInfo
- Publication number
- JP5124473B2 JP5124473B2 JP2008543792A JP2008543792A JP5124473B2 JP 5124473 B2 JP5124473 B2 JP 5124473B2 JP 2008543792 A JP2008543792 A JP 2008543792A JP 2008543792 A JP2008543792 A JP 2008543792A JP 5124473 B2 JP5124473 B2 JP 5124473B2
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- JP
- Japan
- Prior art keywords
- polycondensation
- polymer foam
- resin
- reactive resin
- nanoporous polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/28—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
- B82B3/00—Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/22—After-treatment of expandable particles; Forming foamed products
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2201/00—Foams characterised by the foaming process
- C08J2201/04—Foams characterised by the foaming process characterised by the elimination of a liquid or solid component, e.g. precipitation, leaching out, evaporation
- C08J2201/05—Elimination by evaporation or heat degradation of a liquid phase
- C08J2201/0502—Elimination by evaporation or heat degradation of a liquid phase the liquid phase being organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2361/00—Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2361/00—Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
- C08J2361/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08J2361/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
- C08J2361/28—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with melamine
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08L61/22—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds
- C08L61/24—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds with urea or thiourea
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08L61/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
- C08L61/28—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with melamine
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Nanotechnology (AREA)
- Manufacturing & Machinery (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Phenolic Resins Or Amino Resins (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
- Polyesters Or Polycarbonates (AREA)
- Polyurethanes Or Polyureas (AREA)
Description
a)有機溶剤中の重縮合反応性樹脂の溶液を準備する段階、
b)この溶液を重縮合反応性樹脂のための硬化触媒と混合し、かつ反応性成分をゲルの形成下に硬化させる段階及び
c)有機溶剤を除去する段階
を含んでなるナノ多孔質ポリマーフォームの製造方法が見出された。
比表面積を、BET(DIN 66131)によって決定した。
テトラヒドロフラン中の10質量%Luwipal 44溶液を、37質量%塩酸と、固体を基準として質量比5:1で混合し、乾燥器中で60℃で3時間、ゲル化させた。得られたオルガノゲルを室温で空気中で乾燥させた。得られたキセロゲルの水銀多孔度測定は、1000nm未満の孔径を有する主細孔容積割合を有する80%の全多孔度を示した。比表面積は170m2/gであった。
アセトン中10質量%Luvipal 44溶液を、37質量%塩酸と、固体を基準として質量比5:1で混合した。ゲル化を、乾燥器中で60℃及び3時間で行った。得られたオルガノゲルを空気中で乾燥させた。水銀多孔度測定は、1000nm未満の孔径を有する主細孔容積割合を有する86%の全多孔度を示した。比表面積は25m2/gであった。
テトラヒドロフラン中の10質量%Luvipal 44溶液を、p−トルエンスルホン酸と、固体を基準として質量比5:1で混合し、混合物30mlにつき完全脱塩水1gと混合した。ゲル化を、乾燥器中で60℃で3時間行った。得られたオルガノゲルを空気中で乾燥させた。ナノ多孔質ポリマーフォームの水銀多孔度測定は、1000nm未満の孔径を有する主細孔容積割合を有する75%の全多孔度を示した。比表面積は82m2/gであった。
Claims (8)
- ナノ多孔質ポリマーフォームの製造方法であって、次の段階:
a)有機溶剤中の重縮合反応性樹脂の溶液を準備する段階、
b)この溶液を重縮合反応性樹脂のための硬化触媒と混合し、かつ反応性成分をゲルの形成下に硬化させる段階及び
c)有機溶剤を除去する段階
を含み、前記段階b)における溶液が10質量%未満の含水量を有する、ナノ多孔質ポリマーフォームの製造方法。 - 重縮合樹脂−反応性樹脂として、尿素−ホルムアルデヒド樹脂又はメラミン−ホルムアルデヒド樹脂を使用する、請求項1記載の方法。
- 段階b)における重縮合反応性樹脂の硬化を、アルコールの脱離下に行う、請求項1又は2記載の方法。
- 重縮合反応性樹脂として、水10質量%未満と混和可能である疎水性樹脂を使用する、請求項1から3までのいずれか1項記載の方法。
- 溶剤として、常圧で120℃未満の沸点を有する、炭化水素、アルコール、ケトン、エーテル、アルキルエステル又はそれらの混合物を使用する、請求項1から4までのいずれか1項記載の方法。
- 硬化触媒として有機酸又は無機酸を使用する、請求項1から5までのいずれか1項記載の方法。
- 請求項1から6までのいずれか1項記載の方法によって得ることができる、10〜1000nmの範囲内の平均孔径を有するナノ多孔質ポリマーフォーム。
- 断熱のための、請求項7記載のナノ多孔質ポリマーフォームの使用。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102005059303A DE102005059303A1 (de) | 2005-12-09 | 2005-12-09 | Nanoporösen Polymerschaumstoffe aus Polykondensations-Reaktivharzen |
DE102005059303.8 | 2005-12-09 | ||
PCT/EP2006/069132 WO2007065847A1 (de) | 2005-12-09 | 2006-11-30 | Nanoporöse polymerschaumstoffe aus polykondensations-reaktivharzen |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2009518486A JP2009518486A (ja) | 2009-05-07 |
JP5124473B2 true JP5124473B2 (ja) | 2013-01-23 |
Family
ID=37696418
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2008543792A Expired - Fee Related JP5124473B2 (ja) | 2005-12-09 | 2006-11-30 | 重縮合反応性樹脂のナノ多孔質ポリマーフォーム |
Country Status (11)
Country | Link |
---|---|
US (1) | US8008362B2 (ja) |
EP (1) | EP1960459B1 (ja) |
JP (1) | JP5124473B2 (ja) |
KR (1) | KR101369681B1 (ja) |
CN (1) | CN101316886B (ja) |
AT (1) | ATE497516T1 (ja) |
BR (1) | BRPI0619589A2 (ja) |
DE (2) | DE102005059303A1 (ja) |
ES (1) | ES2360730T3 (ja) |
PL (1) | PL1960459T3 (ja) |
WO (1) | WO2007065847A1 (ja) |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102008022018A1 (de) * | 2008-05-02 | 2009-11-05 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Außenschicht für ein wärmedämmendes Hüllsystem eines Gebäudes |
US8785509B2 (en) * | 2008-05-02 | 2014-07-22 | Industrial Science & Technology Network, Inc. | Superinsulation with nanopores |
US9291752B2 (en) | 2013-08-19 | 2016-03-22 | 3M Innovative Properties Company | Retroreflecting optical construction |
US8808811B2 (en) * | 2009-04-15 | 2014-08-19 | 3M Innovative Properties Company | Process and apparatus for a nanovoided article |
US9464179B2 (en) | 2009-04-15 | 2016-10-11 | 3M Innovative Properties Company | Process and apparatus for a nanovoided article |
US10539722B2 (en) | 2009-04-15 | 2020-01-21 | 3M Innovative Properties Company | Optical film |
WO2011050254A1 (en) | 2009-10-24 | 2011-04-28 | 3M Innovative Properties Company | Light source and display system incorporating same |
WO2011050232A2 (en) * | 2009-10-24 | 2011-04-28 | 3M Innovative Properties Company | Process for gradient nanovoided article |
KR101716922B1 (ko) | 2009-12-08 | 2017-03-15 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 도광체 및 저굴절률 필름을 포함하는 광학 구조체 |
WO2011129831A1 (en) | 2010-04-15 | 2011-10-20 | 3M Innovative Properties Company | Retroreflective articles including optically active areas and optically inactive areas |
JP5997132B2 (ja) | 2010-04-15 | 2016-09-28 | スリーエム イノベイティブ プロパティズ カンパニー | 再帰反射性物品及びその形成方法 |
KR20130092396A (ko) | 2010-04-15 | 2013-08-20 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | 광학적 활성 영역 및 광학적 불활성 영역을 포함하는 재귀반사성 물품 |
KR20140009451A (ko) | 2011-03-04 | 2014-01-22 | 바스프 에스이 | 복합 부재 |
US9126386B2 (en) | 2011-03-04 | 2015-09-08 | Basf Se | Composite elements |
WO2013139885A1 (en) | 2012-03-23 | 2013-09-26 | Basf Se | A process for template-assisted production of nanoporous amino resin foams |
US10100513B2 (en) * | 2012-11-05 | 2018-10-16 | Basf Se | Process for producing profiled elements |
DE102015000393A1 (de) | 2014-01-21 | 2015-07-23 | Frank Becher | Verfahren zur Herstellung von geschlossen-porigen Erzeugnissen mit hohlen Zellen, mittels dessen der Druck in den Zellen kontrolliert während des Aufschäumens erhöht oder reduziert werden kann, sowie Erzeugnisse, die nach diesem Verfahren hergestellt werden |
WO2015193336A1 (en) | 2014-06-20 | 2015-12-23 | Basf Se | Nanoporous carbon foams |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS50119892A (ja) * | 1974-03-08 | 1975-09-19 | ||
CA1137458A (en) * | 1978-08-31 | 1982-12-14 | Robert P. Zajac | Highly absorptive macroporous polymers |
US4307201A (en) * | 1978-08-31 | 1981-12-22 | Diamond Shamrock Corporation | Highly adsorptive macroporous polymers |
DE3534738A1 (de) * | 1985-09-28 | 1987-04-09 | Basf Ag | Verfahren zur herstellung von elastischen melamin-schaumstoffen |
US4822697A (en) * | 1986-12-03 | 1989-04-18 | Dow Corning Corporation | Platinum and rhodium catalysis of low temperature formation multilayer ceramics |
US5086085A (en) * | 1991-04-11 | 1992-02-04 | The United States Of America As Represented By The Department Of Energy | Melamine-formaldehyde aerogels |
US5128382A (en) * | 1991-11-15 | 1992-07-07 | The University Of Akron | Microcellular foams |
US5945084A (en) | 1997-07-05 | 1999-08-31 | Ocellus, Inc. | Low density open cell organic foams, low density open cell carbon foams, and methods for preparing same |
AU5862099A (en) | 1998-10-22 | 2000-05-15 | Huntsman Ici Chemicals Llc | Insulated bodies |
US6143360A (en) * | 1999-12-13 | 2000-11-07 | Dow Corning Corporation | Method for making nanoporous silicone resins from alkylydridosiloxane resins |
DE10335957A1 (de) * | 2003-08-04 | 2005-02-24 | Basf Ag | Formteile aus Melamin/Formaldehyd-Schaumstoffen mit geringer Formaldehyd-Emission |
DE10353745A1 (de) | 2003-11-17 | 2005-06-23 | Basf Ag | Nanoporöse Polymerschaumstoffe durch Aushärten von Reaktivharzen in Mikroemulsion |
-
2005
- 2005-12-09 DE DE102005059303A patent/DE102005059303A1/de not_active Withdrawn
-
2006
- 2006-11-30 EP EP06830236A patent/EP1960459B1/de not_active Not-in-force
- 2006-11-30 BR BRPI0619589-0A patent/BRPI0619589A2/pt not_active IP Right Cessation
- 2006-11-30 DE DE502006008858T patent/DE502006008858D1/de active Active
- 2006-11-30 US US12/096,727 patent/US8008362B2/en not_active Expired - Fee Related
- 2006-11-30 KR KR1020087016541A patent/KR101369681B1/ko not_active IP Right Cessation
- 2006-11-30 ES ES06830236T patent/ES2360730T3/es active Active
- 2006-11-30 AT AT06830236T patent/ATE497516T1/de active
- 2006-11-30 JP JP2008543792A patent/JP5124473B2/ja not_active Expired - Fee Related
- 2006-11-30 CN CN2006800444472A patent/CN101316886B/zh not_active Expired - Fee Related
- 2006-11-30 PL PL06830236T patent/PL1960459T3/pl unknown
- 2006-11-30 WO PCT/EP2006/069132 patent/WO2007065847A1/de active Application Filing
Also Published As
Publication number | Publication date |
---|---|
DE502006008858D1 (de) | 2011-03-17 |
EP1960459B1 (de) | 2011-02-02 |
KR20080081026A (ko) | 2008-09-05 |
BRPI0619589A2 (pt) | 2012-12-11 |
EP1960459A1 (de) | 2008-08-27 |
KR101369681B1 (ko) | 2014-03-04 |
ES2360730T3 (es) | 2011-06-08 |
ATE497516T1 (de) | 2011-02-15 |
PL1960459T3 (pl) | 2011-07-29 |
DE102005059303A1 (de) | 2007-06-21 |
CN101316886B (zh) | 2011-11-30 |
WO2007065847A1 (de) | 2007-06-14 |
CN101316886A (zh) | 2008-12-03 |
US20090005468A1 (en) | 2009-01-01 |
JP2009518486A (ja) | 2009-05-07 |
US8008362B2 (en) | 2011-08-30 |
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