JP5084281B2 - Method for producing antiglare glitter film - Google Patents

Method for producing antiglare glitter film Download PDF

Info

Publication number
JP5084281B2
JP5084281B2 JP2007023612A JP2007023612A JP5084281B2 JP 5084281 B2 JP5084281 B2 JP 5084281B2 JP 2007023612 A JP2007023612 A JP 2007023612A JP 2007023612 A JP2007023612 A JP 2007023612A JP 5084281 B2 JP5084281 B2 JP 5084281B2
Authority
JP
Japan
Prior art keywords
film
resin layer
layer
heat
microspheres
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2007023612A
Other languages
Japanese (ja)
Other versions
JP2008191275A (en
Inventor
真一 森本
清 久我
求 藤木
豊 片山
恵美 村山
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unitika Sparklite Ltd
Original Assignee
Unitika Sparklite Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unitika Sparklite Ltd filed Critical Unitika Sparklite Ltd
Priority to JP2007023612A priority Critical patent/JP5084281B2/en
Publication of JP2008191275A publication Critical patent/JP2008191275A/en
Application granted granted Critical
Publication of JP5084281B2 publication Critical patent/JP5084281B2/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Landscapes

  • Optical Elements Other Than Lenses (AREA)
  • Laminated Bodies (AREA)

Description

本発明は、防眩性光輝フィルムの製造方法に関するものである。 The present invention relates to a method for producing an antiglare bright film .

従来の光輝フィルムとしては例えばＰＥＴフィルムに金属蒸着を施したものや、透明なフィルムに光輝性顔料（酸化チタンをコーティングした雲母など）を含有したものなどが一般的に知られており、何れも美麗な金属光沢を有するものである。また、特許文献１では薄膜層を多数積層して干渉色を発するものが開示されている。これらは衣料、建材、包装材など多様な用途で装飾材料として用いられてきた。また、反射防止、あるいは防眩のためのフィルムとしては、透明フィルムに反射防止層を積層したフィルムが知られており、特許文献２には反射防止層として透明フィルムに透光性の微粒子を分散させたものが開示され、さらに特許文献３には反射防止層として屈折率の異なる層を多数積層したものが開示されている。
特許第２９５１８９０号公報 特許第３５１５４０１号公報 特許第３４９０２４１号公報 Conventional bright films are generally known, for example, those obtained by depositing metal on a PET film, and transparent films containing a bright pigment (such as mica coated with titanium oxide). It has a beautiful metallic luster. Patent Document 1 discloses a technique in which a large number of thin film layers are stacked to generate an interference color. These have been used as decorative materials in various applications such as clothing, building materials and packaging materials. Further, as a film for antireflection or antiglare, a film in which an antireflection layer is laminated on a transparent film is known, and Patent Document 2 disperses translucent fine particles in the transparent film as an antireflection layer. Further, Patent Document 3 discloses a multilayer structure in which a number of layers having different refractive indexes are laminated as an antireflection layer.
Japanese Patent No. 2951890 Japanese Patent No. 3515401 Japanese Patent No. 3490241

従来の光輝フィルムは何れもメタリック感を持たせたものや、干渉色を反射するように作られ、光沢性に優れている。しかし、表面での反射率が高すぎるために、反射輝度は高いが、穏やかなメタリック感や穏やかな干渉色の反射光を発するということがないため、防眩性が要求されるような用途での使用や、あるいは意匠性の観点から防眩性が要求される用途には不向きであった。また、従来の防眩性フィルムはＣＲＴディスプレーや液晶表示板などの表面に貼って、光の反射を和らげる目的で使用されてきているが、これらの防眩性フィルムは光を拡散反射させるのみで、特に意匠性はなく、また装飾用途などに使用できるものではない。   All of the conventional glitter films have a metallic feeling and are made to reflect interference colors, and are excellent in gloss. However, since the reflectance at the surface is too high, the reflection brightness is high, but it does not emit a reflected light with a gentle metallic feeling or a gentle interference color, so it is used in applications where anti-glare properties are required. It is unsuitable for the use which requires anti-glare property from the viewpoint of use of, or design nature. In addition, conventional anti-glare films have been used for the purpose of softening light reflection by sticking to the surface of CRT displays and liquid crystal display panels, but these anti-glare films only diffuse and reflect light. In particular, it has no design properties and cannot be used for decorative purposes.

本発明の目的は、このような課題を解決するものであり、構成が簡単にして防眩性に優れ、しかも意匠的にも効果を発揮する防眩性光輝フィルムを提供することにある。   An object of the present invention is to solve such problems, and to provide an anti-glare glitter film that has a simple structure, is excellent in anti-glare properties, and is also effective in design.

本発明の請求項１に記載の防眩性光輝フィルムの製造方法は、耐熱性シートの上に熱軟化性樹脂層を積層してなる基材フィルムを熱軟化性樹脂層の融点付近で加熱して熱軟化性樹脂層を軟化させた状態で熱軟化性樹脂層の上から微小球を撒布して微小球を熱軟化性樹脂層に付着させ、基材フィルムを熱軟化性樹脂層の融点を超える温度に加熱して熱軟化性樹脂層を溶融させて微小球を自重で直径の約３０〜７０％を熱軟化性樹脂層に埋没させた後に、基材フィルムを冷却して熱軟化性樹脂層に微小球を固着させ、微小球が露出する熱軟化性樹脂層の上から微小球を覆うように接着剤層を積層して乾燥硬化させた後、接着剤層を微小球とともに熱軟化性樹脂層から剥離して基材フィルムの熱軟化性樹脂層の表面にほぼ半球状の無数の凹部を形成し、熱軟化性樹脂層の上から凹部を埋め且つ凹部上端から適当厚みを備えるように透明フィルムを形成し、透明フィルムの上に発色層を積層し、発色層を積層した透明フィルムを基材フィルムから剥離することを特徴とする。
請求項２に記載の防眩性光輝フィルムの製造方法は、発色層が光輝性顔料を含む透明樹脂もしくは光輝性の発色フィルムであることを特徴とする。 According to a first aspect of the present invention, there is provided a method for producing an antiglare glitter film, comprising heating a base film obtained by laminating a heat softening resin layer on a heat resistant sheet in the vicinity of a melting point of the heat softening resin layer. With the heat-softening resin layer softened, the microspheres are distributed from above the heat-softening resin layer to adhere the microspheres to the heat-softening resin layer, and the base film has the melting point of the heat-softening resin layer. After heating to a temperature exceeding 60 ° C., the thermosoftening resin layer is melted, and the microspheres are buried in about 30 to 70% of the diameter by the dead weight in the thermosoftening resin layer, and then the base film is cooled to obtain the thermosoftening resin. After the microspheres are fixed to the layer, the adhesive layer is laminated and dried and cured so as to cover the microspheres from the heat-softening resin layer where the microspheres are exposed, and then the adhesive layer is heat-softened together with the microspheres. Peel from the resin layer and form numerous almost hemispherical recesses on the surface of the heat-softening resin layer of the base film A transparent film is formed so as to fill the concave portion from above the thermosoftening resin layer and to have an appropriate thickness from the upper end of the concave portion, to laminate a coloring layer on the transparent film, and to form a transparent film on which the coloring layer is laminated as a base film It is characterized by peeling from.
The method for producing an anti-glare glitter film according to claim 2 is characterized in that the coloring layer is a transparent resin containing a glitter pigment or a glitter coloring film .

請求項３に記載の防眩性光輝フィルムの製造方法は、透明フィルムが透明弾性樹脂であり、発色層が光輝性顔料を含む透明弾性樹脂もしくは弾性のある光輝性の発色フィルムであることを特徴とする。 The method for producing an antiglare glitter film according to claim 3 is characterized in that the transparent film is a transparent elastic resin, and the coloring layer is a transparent elastic resin containing a glittering pigment or an elastic glittering coloring film. And

以上のように、本発明の防眩性光輝フィルムは、構成が簡単にして光沢度が低く、防眩性に優れ、しかも意匠的にも効果を発揮する防眩性光輝フィルムを安価に提供することができる。また、透明フィルムが透明弾性樹脂であり、発色層が光輝性顔料を含む透明弾性樹脂もしくは弾性のある光輝性の発色フィルムであることにより布の伸縮に伴ない追随性を得ることができる。   As described above, the anti-glare glitter film of the present invention provides an anti-glare glitter film having a simple structure, low gloss, excellent anti-glare property, and effective in design at low cost. be able to. In addition, when the transparent film is a transparent elastic resin and the color developing layer is a transparent elastic resin containing a glitter pigment or an elastic glitter color developing film, it is possible to obtain a follow-up property as the fabric stretches.

以下、本発明の一実施の形態を、図１および図２を用いて具体的に説明する。
図１において、１は本実施の形態の防眩性光輝フィルムで、この防眩性光輝フィルム１は発色層２の上に表面に微小な径の無数の半球状凸部３を有する透明フィルム４が積層されて作られている。この防眩性光輝フィルム１は前記発色層２の裏面に接着剤層５を塗布し、この接着剤層５を介して生地などの被着体６に装着される。 Hereinafter, an embodiment of the present invention will be specifically described with reference to FIGS. 1 and 2.
In FIG. 1, reference numeral 1 denotes an antiglare glitter film of the present embodiment. This antiglare glitter film 1 has a transparent film 4 having innumerable hemispherical convex portions 3 with minute diameters on the surface of the color developing layer 2. Are made by laminating. This anti-glare glitter film 1 has an adhesive layer 5 applied to the back surface of the color developing layer 2 and is attached to an adherend 6 such as a fabric through the adhesive layer 5.

図２は上記防眩性光輝フィルム１の製造手順を示し、図２（Ａ）に示すポリエチレンテレフタレートフィルムや紙などの耐熱性シート７の上にポリエチレンなどの熱軟化性樹脂層８を積層してなる基材フィルム９が用いられ、この基材フィルム９を熱軟化性樹脂層８の融点付近で加熱して熱軟化性樹脂層８を軟化させた状態で図２（Ｂ）に示すように熱軟化性樹脂層８の上から微小球１０を撒布し、この微小球１０を熱軟化性樹脂層８に付着させる。そして、かかる状態で熱軟化性樹脂層８の融点を超える温度に基材フィルム９を加熱することによって熱軟化性樹脂層８を溶融させ、前記微小球１０を自重でその直径の約３０〜７０％を熱軟化性樹脂層８に埋没させる。この微小球１０の直径は前記熱軟化性樹脂層８の厚みと関係し、特に限定されるものではないが、１〜５００μｍの範囲のものが利用しやすく、また比重およびコストの面からガラス微小球が好ましく利用できる。そして、前述のように微小球１０を熱軟化性樹脂層８に埋没させた後、基材フィルム９を冷却させて熱軟化性樹脂層８に微小球１０を固着させ、その後図２（Ｃ）に示すように微小球１０が露出する熱軟化性樹脂層８の上から微小球１０を覆うように接着剤層１１を塗布により積層する。そして、この接着剤層１１を乾燥硬化させた後、図２（Ｄ）に示すように接着剤層１１を微小球１０とともに熱軟化性樹脂層８から剥離することにより基材フィルム９の熱軟化性樹脂層８の表面に図２（Ｅ）に示すようにほぼ半球状の無数の凹部１２が形成される。このようにして得られた基材フィルム９に対し熱軟化性樹脂層８の上から前記凹部１２を完全に埋め且つ凹部１２上端から適当厚みを備えるように図２（Ｆ）に示すように透明樹脂を用いて溶剤コーティングや溶融押出しコーティングにより透明フィルム４を形成する。その後、図２（Ｇ）に示すように透明フィルム４の上に発色層２を積層する。この発色層２の積層手段としては着色剤を含有する樹脂を用いて透明フィルム４の上に溶剤コーティングや溶融押出しコーティングにより積層する方法、あるいは光輝性の発色フィルムを接着剤を用いて透明フィルム４の上にラミネートする方法が採用される。発色層２に用いられる着色剤としては一般に光輝性顔料と呼ばれるものを使用する。光輝性顔料として酸化チタンをコーティングした雲母など、一般にパール顔料と呼ばれている顔料を使用する場合は、透明フィルム４の形成の際に、前記凹部１２をほぼ完全に埋めるようにコーティングするのが好ましい。その理由としては、透明フィルム４の前記凹部１４側とは反対側の面をフラットな状態に仕上げ、この透明フィルム４に積層される発色層２の光輝性顔料が平面状に配列されているのが好ましいからである。発色層２に使用される光輝性顔料としてはパール顔料と呼ばれている顔料の他に、金属薄膜の微細薄片や、多層に積層された干渉性薄膜の微細薄片などを使用できる。発色層２に対し白もしくは黒に着色した不透明層を積層すると光輝性顔料の発色が一層引き立つようになるが、不透明層は必ずしも必要ではない。また、発色層２は多層であっても良い。前述のように透明フィルム４に発色層２が積層されてなる防眩性光輝フィルムは図２（Ｈ）に示すように基材フィルム９から剥離されて完成となるが、防眩性光輝フィルムの実際の使用に当たっては図２（Ｈ）に示すように基材フィルム９から剥離された後、発色層２に接着剤層５を積層して防眩性光輝フィルムを様々な媒体に貼付したり、あるいは接着剤層５を介して衣類などに貼り付け、縫製するものである。   FIG. 2 shows a manufacturing procedure of the antiglare glitter film 1 and a heat softening resin layer 8 such as polyethylene is laminated on a heat resistant sheet 7 such as polyethylene terephthalate film or paper shown in FIG. A base film 9 is used, and the base film 9 is heated in the vicinity of the melting point of the heat softening resin layer 8 to soften the heat softening resin layer 8 as shown in FIG. The microspheres 10 are spread over the softening resin layer 8, and the microspheres 10 are attached to the heat softening resin layer 8. In such a state, the base film 9 is heated to a temperature exceeding the melting point of the thermosoftening resin layer 8 to melt the thermosoftening resin layer 8, and the microspheres 10 are about 30 to 70 in diameter with their own weight. % Is buried in the thermosoftening resin layer 8. The diameter of the microspheres 10 is related to the thickness of the thermosoftening resin layer 8 and is not particularly limited. However, those having a diameter in the range of 1 to 500 μm are easy to use, and the glass microspheres are used in terms of specific gravity and cost. A sphere can be preferably used. Then, after the microspheres 10 are embedded in the thermosoftening resin layer 8 as described above, the base film 9 is cooled to fix the microspheres 10 to the thermosoftening resin layer 8, and then FIG. 2 (C). The adhesive layer 11 is laminated by coating so as to cover the microspheres 10 from above the heat-softening resin layer 8 from which the microspheres 10 are exposed. Then, after the adhesive layer 11 is dried and cured, the adhesive film 11 is peeled from the heat-softening resin layer 8 together with the microspheres 10 as shown in FIG. As shown in FIG. 2E, innumerable concave portions 12 that are substantially hemispherical are formed on the surface of the conductive resin layer 8. As shown in FIG. 2 (F), the base film 9 thus obtained is transparent as shown in FIG. 2 (F) so as to completely fill the concave portion 12 from above the heat-softening resin layer 8 and to have an appropriate thickness from the upper end of the concave portion 12. The transparent film 4 is formed by solvent coating or melt extrusion coating using a resin. Thereafter, the coloring layer 2 is laminated on the transparent film 4 as shown in FIG. As a means for laminating the color developing layer 2, a method of laminating a transparent film 4 with a resin containing a colorant on the transparent film 4 by solvent coating or melt extrusion coating, or a glittering color developing film using an adhesive. A method of laminating on is adopted. As the colorant used for the color forming layer 2, a so-called bright pigment is generally used. When using a pigment generally referred to as a pearl pigment such as mica coated with titanium oxide as a bright pigment, it is necessary to coat the concave portion 12 so as to be almost completely filled when the transparent film 4 is formed. preferable. The reason is that the surface of the transparent film 4 opposite to the concave portion 14 is finished in a flat state, and the glitter pigments of the coloring layer 2 laminated on the transparent film 4 are arranged in a planar shape. Is preferable. As the bright pigment used in the color forming layer 2, in addition to a pigment called a pearl pigment, fine thin pieces of metal thin films, fine thin pieces of coherent thin films laminated in multiple layers, and the like can be used. When an opaque layer colored white or black is laminated on the color developing layer 2, the color of the glitter pigment is further enhanced, but the opaque layer is not always necessary. The color developing layer 2 may be a multilayer. As described above, the antiglare glitter film in which the coloring layer 2 is laminated on the transparent film 4 is peeled off from the base film 9 as shown in FIG. In actual use, after being peeled off from the base film 9 as shown in FIG. 2 (H), the adhesive layer 5 is laminated on the coloring layer 2 and the anti-glare glitter film is attached to various media. Alternatively, it is attached to clothing or the like via the adhesive layer 5 and sewn.

ところで、前記透明フィルム４とは透明ないし半透明なフィルムを含み、前記発色層２の色が確認できるものであれば、光透過度などで示される透明性について特に規定するものではない。   By the way, if the transparent film 4 includes a transparent or translucent film and the color of the coloring layer 2 can be confirmed, the transparency indicated by the light transmittance is not particularly specified.

次に、本発明の具体的な実施例について説明する。なお、ここで示す実施例はあくまでも一例であって、必ずしもこの実施例に限定されるものではない。
（実施例１）
厚さ７５μｍのポリエチレンテレフタレートフィルムに、厚さ４０μｍのポリエチレンフィルムをラミネートして得た基材フィルムを１２０℃で３分間加熱し、表層のポリエチレンフィルムを軟化させた状態で、平均粒子径が６０μｍのガラス微小球をほぼ一面に撒布してポリエチレンフィルム上にガラス微小球を付着させた後、このガラス微小球が付着する基材フィルムを１４０℃で２分間加熱してポリエチレンフィルムを溶融させ、ガラス微小球の直径の約５０％をポリエチレンフィルム部分に埋没させた。その後、基材フィルムを冷却後、ガラス微小球の撒布面を水洗いしてポリエチレンフィルム部分に埋没していないガラス微小球を除去した。次いで、ガラス微小球が露出するポリエチレンフィルムの上からガラス微小球を覆うように接着剤層としてアクリル樹脂を厚さ６０μｍで一様に積層した後、この接着剤層をガラス微小球とともにポリエチレンフィルム部分から剥離した。これにより、表面のポリエチレンフィルム部分に半径が約３０μｍの半球状の無数の凹部がほぼ全面に存在する基材フィルムを得た。次いで、この基材フィルムの凹部を有する側の表面にポリカーボネート系ウレタン樹脂をイソシアネート硬化剤とともにジメチルホルムアミドを溶剤として、乾燥後に凹部が完全に埋まり凹部から突出する部分の乾燥膜厚が約１０μｍになるようにコーティングし、乾燥硬化させて透明フィルムを形成した。さらにこの透明フィルムの上から透明フィルムと同じ樹脂を用いてパール顔料を樹脂１００質量部に対し２０質量部混入したものを乾燥膜厚が約１０μｍになるようにコーティングし、乾燥硬化させて発色層を形成した。そして、前記透明フィルムと発色層とからなる防眩性光輝フィルムを被着体に装着させるために発色層の上から接着剤層としてウレタン系接着剤をジメチルホルムアミドを溶剤として乾燥膜厚が約４０μｍになるようにコーティングした。最後に基材フィルムから透明フィルム、発色層、接着剤層からなる積層体を剥離し、表面に微小な径の無数の半球状凸部を有する防眩性光輝フィルムを得た。
（実施例２）
実施例１の透明フィルムおよび発色層を形成するためのポリカーボネート系ウレタン樹脂をポリエーテル・ウレタン系の透明弾性樹脂に混合したものに代え、また被着体に接着するための接着剤層の樹脂を弾性ウレタン系の樹脂に代えた他は、実施例１と同様の工程にして伸縮性の防眩性光輝フィルムを得た。なお、実施例２において発色層として弾性のある光輝性の発色フィルムを用いることも可能である。
（比較例１）
実施例１のガラス微小球を用いた凹部形成を省略し、ポリエチレンテレフタレートフィルムにポリエチレンフィルムをラミネートして得た基材フィルムをそのまま基材として以下実施例１と同様に光輝フィルムを得た。これを実施例１および２との比較用フィルムとした。 Next, specific examples of the present invention will be described. In addition, the Example shown here is an example to the last, Comprising: It is not necessarily limited to this Example.
Example 1
A base film obtained by laminating a polyethylene film having a thickness of 40 μm on a polyethylene terephthalate film having a thickness of 75 μm was heated at 120 ° C. for 3 minutes to soften the polyethylene film on the surface layer, and the average particle diameter was 60 μm. After the glass microspheres are spread on almost one surface and the glass microspheres are attached on the polyethylene film, the base film to which the glass microspheres are attached is heated at 140 ° C. for 2 minutes to melt the polyethylene film. About 50% of the diameter of the sphere was embedded in the polyethylene film part. Thereafter, the substrate film was cooled, and then the surface of the glass microspheres was washed with water to remove the glass microspheres not buried in the polyethylene film portion. Next, an acrylic resin is uniformly laminated with a thickness of 60 μm as an adhesive layer so as to cover the glass microspheres from above the polyethylene film from which the glass microspheres are exposed. Peeled off. As a result, a base film having an infinite number of hemispherical recesses with a radius of about 30 μm on the entire surface of the polyethylene film portion was obtained. Next, on the surface of the base film having the recesses, polycarbonate urethane resin is used as an isocyanate curing agent and dimethylformamide as a solvent, and the dry film thickness of the portion where the recesses are completely filled and protruded from the recesses is about 10 μm after drying. Were coated and dried and cured to form a transparent film. Further, a coating layer of pearl pigment mixed with 20 parts by mass with respect to 100 parts by mass of the resin using the same resin as the transparent film is coated on the transparent film so as to have a dry film thickness of about 10 μm, and dried and cured to form a coloring layer. Formed. Then, in order to attach the antiglare bright film comprising the transparent film and the color developing layer to the adherend, a dry film thickness of about 40 μm is obtained by using urethane adhesive as the adhesive layer from the color developing layer and dimethylformamide as the solvent. It was coated to become. Finally, the laminate composed of the transparent film, the coloring layer, and the adhesive layer was peeled off from the base film to obtain an antiglare bright film having innumerable hemispherical convex portions with minute diameters on the surface.
(Example 2)
The resin of the adhesive layer for adhering to the adherend is used instead of the polycarbonate urethane resin for forming the transparent film and color forming layer of Example 1 mixed with the polyether-urethane transparent elastic resin. A stretchable antiglare bright film was obtained in the same manner as in Example 1 except that the elastic urethane resin was used. In Example 2, it is also possible to use an elastic glossy coloring film as the coloring layer.
(Comparative Example 1)
The formation of recesses using the glass microspheres of Example 1 was omitted, and a bright film was obtained in the same manner as in Example 1 below using the base film obtained by laminating a polyethylene film on a polyethylene terephthalate film as it was. This was used as a film for comparison with Examples 1 and 2.

上記した実施例１、２と比較例１の評価結果を表１に示す。防眩性については日本電色工業（株）製の光沢度計ＶＧ２０００を用い、ＪＩＳＺ８７４１に従って６０度の光沢度で評価した。   Table 1 shows the evaluation results of Examples 1 and 2 and Comparative Example 1 described above. The antiglare property was evaluated using a gloss meter VG2000 manufactured by Nippon Denshoku Industries Co., Ltd., with a glossiness of 60 degrees according to JISZ8741.

Figure 0005084281
表１に示す結果から明らかなように実施例１および２は比較例１と比較して光沢度が低く、防眩性に富むことが分かる。また、実施例２では布の伸縮に伴ない追随性を示した。
Figure 0005084281
 As is clear from the results shown in Table 1, it can be seen that Examples 1 and 2 have a lower gloss than Comparative Example 1 and are rich in antiglare properties. Moreover, in Example 2, the followability accompanying the expansion and contraction of the cloth was shown.

本発明の一実施の形態における防眩性光輝フィルムの拡大断面図である。It is an expanded sectional view of the glare-proof glittering film in one embodiment of the present invention. 同防眩性光輝フィルムの製造工程図である。It is a manufacturing-process figure of the same glare-proof glittering film.

符号の説明Explanation of symbols

１ 防眩性光輝フィルム
２ 発色層
３ 半球状凸部
４ 透明フィルム
５ 接着剤層
６ 被着体
７ 耐熱性シート
８ 熱軟化性樹脂層
９ 基材フィルム
１０ 微小球
１１ 接着剤層
１２ 凹部 DESCRIPTION OF SYMBOLS 1 Anti-glare bright film 2 Color development layer 3 Hemispherical convex part 4 Transparent film 5 Adhesive layer 6 Adhering body 7 Heat resistant sheet 8 Thermosoftening resin layer 9 Base film 10 Microsphere 11 Adhesive layer 12 Recessed part

Claims (3)

耐熱性シートの上に熱軟化性樹脂層を積層してなる基材フィルムを熱軟化性樹脂層の融点付近で加熱して熱軟化性樹脂層を軟化させた状態で熱軟化性樹脂層の上から微小球を撒布して微小球を熱軟化性樹脂層に付着させ、基材フィルムを熱軟化性樹脂層の融点を超える温度に加熱して熱軟化性樹脂層を溶融させて微小球を自重で直径の約３０〜７０％を熱軟化性樹脂層に埋没させた後に、基材フィルムを冷却して熱軟化性樹脂層に微小球を固着させ、微小球が露出する熱軟化性樹脂層の上から微小球を覆うように接着剤層を積層して乾燥硬化させた後、接着剤層を微小球とともに熱軟化性樹脂層から剥離して基材フィルムの熱軟化性樹脂層の表面にほぼ半球状の無数の凹部を形成し、熱軟化性樹脂層の上から凹部を埋め且つ凹部上端から適当厚みを備えるように透明フィルムを形成し、透明フィルムの上に発色層を積層し、発色層を積層した透明フィルムを基材フィルムから剥離することを特徴とする防眩性光輝フィルムの製造方法。The base film formed by laminating the heat-softening resin layer on the heat-resistant sheet is heated in the vicinity of the melting point of the heat-softening resin layer to soften the heat-softening resin layer. Disperse the microspheres from the surface to adhere the microspheres to the thermosoftening resin layer, heat the base film to a temperature exceeding the melting point of the thermosoftening resin layer, melt the thermosoftening resin layer, After immersing about 30 to 70% of the diameter in the thermosoftening resin layer, the base film is cooled to fix the microspheres to the thermosoftening resin layer, and the thermosoftening resin layer in which the microspheres are exposed. After the adhesive layer is laminated and dried and cured so as to cover the microspheres from above, the adhesive layer is peeled off from the heat-softening resin layer together with the microspheres and is almost on the surface of the heat-softening resin layer of the base film. Innumerable hemispherical recesses are formed, the recesses are filled from above the heat-softening resin layer, and appropriate from the top of the recesses. Forming a transparent film to include a body, a coloring layer laminated on the transparent film, method of manufacturing the antiglare bright film and then exfoliating the transparent film obtained by laminating a color layer from a substrate film. 発色層は光輝性顔料を含む透明樹脂もしくは光輝性の発色フィルムであることを特徴とする請求項１記載の防眩性光輝フィルムの製造方法。 Coloring layer manufacturing method of the antiglare bright film according to claim 1, wherein the a color film of the transparent resin or glitter containing bright pigment. 透明フィルムが透明弾性樹脂であり、発色層が光輝性顔料を含む透明弾性樹脂もしくは弾性のある光輝性の発色フィルムであることを特徴とする請求項１記載の防眩性光輝フィルムの製造方法。 2. The method for producing an antiglare glitter film according to claim 1, wherein the transparent film is a transparent elastic resin, and the color developing layer is a transparent elastic resin containing a glitter pigment or an elastic glitter color developing film .
JP2007023612A 2007-02-02 2007-02-02 Method for producing antiglare glitter film Active JP5084281B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2007023612A JP5084281B2 (en) 2007-02-02 2007-02-02 Method for producing antiglare glitter film

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2007023612A JP5084281B2 (en) 2007-02-02 2007-02-02 Method for producing antiglare glitter film

Publications (2)

Publication Number Publication Date
JP2008191275A JP2008191275A (en) 2008-08-21
JP5084281B2 true JP5084281B2 (en) 2012-11-28

Family

ID=39751464

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2007023612A Active JP5084281B2 (en) 2007-02-02 2007-02-02 Method for producing antiglare glitter film

Country Status (1)

Country Link
JP (1) JP5084281B2 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102946909A (en) * 2010-06-16 2013-02-27 帝斯曼知识产权资产管理有限公司 A package comprising a sterilized content
CN103332031B (en) * 2013-05-30 2016-02-10 合肥京东方光电科技有限公司 The preparation method, scattering rete and preparation method thereof of galley, display unit

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0515836A (en) * 1991-07-16 1993-01-26 Dainippon Printing Co Ltd Production of direction selective ray adjusting sheet
JPH07295487A (en) * 1994-04-27 1995-11-10 Aisin Chem Co Ltd Photo-recursive reflecting paint film, and its formation method
JP3541128B2 (en) * 1997-09-30 2004-07-07 株式会社資生堂 Colored light retroreflective material
JP2002202405A (en) * 2000-10-23 2002-07-19 Kureha Elastomer Co Ltd Optical filter for display screen
JP3432507B1 (en) * 2002-06-13 2003-08-04 株式会社丸仁 Color retroreflective material

Also Published As

Publication number Publication date
JP2008191275A (en) 2008-08-21

Similar Documents

Publication Publication Date Title
CN100426012C (en) Hue variable retroreflection sheet
CN102179962B (en) Decorating material with cubic effect
RU2660073C2 (en) High reflectivity open bead method and material
KR20190019201A (en) Decorative film and articles thereof
JPH06509394A (en) A transfer whose surface is decorated with a highly durable print, in particular a print containing a combination of special light-reflecting and colored areas, and a method for producing the same.
WO2002032644A1 (en) Antireflective formed article and method for preparation thereof, and mold for antireflective formed article
KR20140049943A (en) Process for reflective products
JP2015085589A (en) In-mold transfer foil and molded article using the same
KR101752847B1 (en) color changeable film for outside with the self recovering functions
CN106707386B (en) Colorful high-brightness heat pasting film
WO2018166385A1 (en) Decorative thin film
CN104908380B (en) A kind of transfevent decorating film
JP2008096820A (en) Optical film and manufacturing method thereof
JP5084281B2 (en) Method for producing antiglare glitter film
JP2022100336A (en) Discoloration body having glossiness
JP3432507B1 (en) Color retroreflective material
JP3881686B2 (en) Variable hue retroreflective sheet
JP2019084821A (en) Light-transmissive decorative film, molded article including light-transmissive decorative film, production method thereof, and lighting display device
CN115461219A (en) Decorative material, method for producing decorative material, and laminate using decorative material
WO2021085084A1 (en) Uneven structural body and layered body
CN201423865Y (en) Printing film with alternating colorful light
JP2015214031A (en) Transfer film and decorative molding
WO2016063633A1 (en) Retroreflective material
CN102501421A (en) Frosted hardened film for in-mold decoration
TWM585906U (en) Anti-glare optical film, safety helmet having the optical film, and container having the optical film

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20100201

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20110810

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20110830

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20111031

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20120807

A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20120904

R150 Certificate of patent or registration of utility model

Ref document number: 5084281

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

Free format text: JAPANESE INTERMEDIATE CODE: R150

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20150914

Year of fee payment: 3

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250