JP4794442B2 - 無箔バリヤラミネート - Google Patents
無箔バリヤラミネート Download PDFInfo
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- JP4794442B2 JP4794442B2 JP2006524457A JP2006524457A JP4794442B2 JP 4794442 B2 JP4794442 B2 JP 4794442B2 JP 2006524457 A JP2006524457 A JP 2006524457A JP 2006524457 A JP2006524457 A JP 2006524457A JP 4794442 B2 JP4794442 B2 JP 4794442B2
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- 230000004888 barrier function Effects 0.000 title claims description 58
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- 239000004715 ethylene vinyl alcohol Substances 0.000 claims description 61
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- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 41
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- 239000011111 cardboard Substances 0.000 claims description 37
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- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 claims description 8
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- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 6
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- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 20
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- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 6
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- 150000003722 vitamin derivatives Chemical class 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- MXAOILAHPVJWBS-UHFFFAOYSA-N 10-(azepan-1-yl)-10-oxodecanamide Chemical compound NC(=O)CCCCCCCCC(=O)N1CCCCCC1 MXAOILAHPVJWBS-UHFFFAOYSA-N 0.000 description 1
- GUOSQNAUYHMCRU-UHFFFAOYSA-N 11-Aminoundecanoic acid Chemical compound NCCCCCCCCCCC(O)=O GUOSQNAUYHMCRU-UHFFFAOYSA-N 0.000 description 1
- 229920003298 Nucrel® Polymers 0.000 description 1
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- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
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- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
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- 235000015203 fruit juice Nutrition 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- RZXDTJIXPSCHCI-UHFFFAOYSA-N hexa-1,5-diene-2,5-diol Chemical compound OC(=C)CCC(O)=C RZXDTJIXPSCHCI-UHFFFAOYSA-N 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000002648 laminated material Substances 0.000 description 1
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- PZRHRDRVRGEVNW-UHFFFAOYSA-N milrinone Chemical compound N1C(=O)C(C#N)=CC(C=2C=CN=CC=2)=C1C PZRHRDRVRGEVNW-UHFFFAOYSA-N 0.000 description 1
- 229960003574 milrinone Drugs 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
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Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/10—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/306—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl acetate or vinyl alcohol (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2317/00—Animal or vegetable based
- B32B2317/12—Paper, e.g. cardboard
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2323/00—Polyalkenes
- B32B2323/04—Polyethylene
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2329/00—Polyvinylalcohols, polyvinylethers, polyvinylaldehydes, polyvinylketones or polyvinylketals
- B32B2329/04—Polyvinylalcohol
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2377/00—Polyamides
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2439/00—Containers; Receptacles
- B32B2439/70—Food packaging
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/1379—Contains vapor or gas barrier, polymer derived from vinyl chloride or vinylidene chloride, or polymer containing a vinyl alcohol unit
- Y10T428/1383—Vapor or gas barrier, polymer derived from vinyl chloride or vinylidene chloride, or polymer containing a vinyl alcohol unit is sandwiched between layers [continuous layer]
Landscapes
- Laminated Bodies (AREA)
- Wrappers (AREA)
- Packages (AREA)
Description
図1に示されている構造と整合性のとれた無箔バリヤラミネートは、層13に5lb/リームのナイロン6、層14に6lb/リームのEVOH、層15に5lb/リームのナイロン6、及び層19に3lb/リームのEVOHを使用して製造した。このラミネートは、本出願の一部継続出願の出願シリアル番号第10/288,841号に定義されたラミネート(比較サンプル1)と比較した。これは、ボール紙支持体、その上に低密度ポリエチレンの層を適用してラミネートの外面を提供し、前記基板の下側上に適用されたポリアミドポリマー、前記ポリアミドポリマー層の下側に適用されたエチレンビニルアルコールコポリマーの層、前記エチレンビニルアルコールコポリマーの下側に適用された第一の結合層、前記第一の結合層の下側に適用されたポリオレフィン層、前記ポリオレフィン層上に適用された第二の結合層、前記第二の結合層の下側に適用されたエチレンビニルアルコールコポリマーの第二の層、前記第二のエチレンビニルアルコールコポリマー層の下側に適用された第三の結合層、続いて製品接触表面を形成するポリオレフィンポリマー層を含む。Kinseyの米国特許第6,110,548号に記載のラミネート(比較サンプル2)は、低密度ポリエチレンの外部層を有するボール紙支持体、前記支持体の内側のポリアミド層、前記ポリアミド層の下側上に適用された結合層、前記結合層の下側に適用された第一のポリオレフィンポリマー層、前記第一のポリオレフィンポリマー層の下側の第二のポリオレフィンポリマー層、前記第二のポリオレフィンポリマー層の下側に配置された第二の結合層、前記第二の結合層の下側に配置されたエチレンビニルアルコールコポリマー、前記エチレンビニルアルコールコポリマー層の下側に適用された第三の結合層及び、前記第三の結合層の下側に配置されたポリオレフィンポリマーの最終層を含む。
Claims (22)
- a)第一の表面と第二の表面とを有するボール紙支持体、前記第二の表面は第一の表面の反対の位置にあり;
b)前記ボール紙支持体の第二の表面上に直接適用されたポリオレフィン層;
c)前記ボール紙支持体の第一の表面上に直接適用された第一のポリアミド層;
d)前記第一のポリアミド層上に直接適用されたEVOHの第一の無箔の酸素バリヤ層;
e)EVOHの前記第一の無箔の酸素バリヤ層上に直接適用された第二のポリアミド層;
f)前記第二のポリアミド層上に直接適用された第一の結合層;
g)前記第一の結合層上に直接適用されたEVOH、ポリビニルアルコール、ポリアミド、ポリエステル、ポリエチレンテレフタレート、ポリオレフィン、環式オレフィンコポリマー、ポリカーボネート、液晶ポリマー及びそのブレンド、並びに乾燥剤、モレキュラーシーブ及びシクロデキストリンからなる群から選択される少なくとも一種の部材と上記群の構成員のいずれかとのブレンドからなる群から選択される第二の無箔の酸素バリヤ層;
h)前記第二の無箔の酸素バリヤ層上に直接適用された第二の結合層;及び
i)最も内側の層及び製品接触層として前記第二の結合層上に適用されたポリオレフィン層からなる無箔のバリヤラミネート。 - 前記ボール紙支持体の第二の表面に適用された前記ポリオレフィン層がポリエチレンである、請求項1に記載の無箔のバリヤラミネート。
- 前記第二の結合層上に適用され、且つ前記製品接触層を形成する前記ポリオレフィン層がポリエチレンである、請求項1に記載の無箔のバリヤラミネート。
- 前記第一及び第二のポリアミド層がそれぞれ、ナイロン6、ナイロン66、ナイロン10、ナイロン6−10、ナイロン11、ナイロン12、アモルファスナイロン、MXD-6及びナイロンナノ複合体からなる群から選択される部材を含む、請求項1に記載の無箔のバリヤラミネート。
- 前記第二の無箔の酸素バリヤ層がEVOHである、請求項1に記載の無箔のバリヤラミネート。
- 前記結合層がそれぞれ、無水マレイン酸官能基で変性されたエチレンベースのコポリマーである、請求項1に記載の無箔のバリヤラミネート。
- 前記第二の無箔の酸素バリヤ層が26〜44モル%のエチレンを含むEVOHである、請求項5に記載の無箔のバリヤラミネート。
- 前記第二の無箔の酸素バリヤ層が、前記第一の結合層上に直接コーティングされたポリオレフィンの層と前記ポリオレフィン層上に直接コーティングされた第三の結合層とによって前記第一の結合層から隔てられている、請求項1に記載の無箔のバリヤラミネート。
- a)第一の表面と第二の表面とをもつボール紙支持体、前記第二の表面は第一の表面の反対の位置にあり;
b)前記ボール紙支持体の第二の表面上に直接適用されたポリオレフィン層;
c)前記ボール紙支持体の第一の表面上に直接適用された第一のポリアミド層;
d)前記第一のポリアミド層上に直接適用されたEVOHの第一の無箔の酸素バリヤ層;
e)EVOHの前記第一の無箔の酸素バリヤ層上に直接適用された第二のポリアミド層;
f)前記第二のポリアミド層上に直接適用された第一の結合層;
g)前記第一の結合層上に直接適用されたポリオレフィン層;
h)前記ポリオレフィン層上に直接適用された第二の結合層;
i)前記第二の結合層上に直接適用されたEVOH、ポリビニルアルコール、ポリアミド、ポリエステル、ポリエチレンテレフタレート、ポリオレフィン、環式オレフィンコポリマー、ポリカーボネート、液晶ポリマー及びそのブレンド、並びに乾燥剤、モレキュラーシーブ及びシクロデキストリンからなる群から選択される少なくとも一種の部材と上記群の構成員のいずれかとのブレンドからなる群から選択される第二の無箔の酸素バリヤ層;
j)前記第二の無箔の酸素バリヤ層上に直接適用された第三の結合層;及び
k)最も内側の層及び製品接触層として前記第三の結合層上に適用されたポリオレフィン層
を含む無箔の高度酸素バリヤラミネート。 - 前記第二の無箔の酸素バリヤ層がEVOHを含む、請求項9に記載の無箔の高度酸素バリヤラミネート。
- ボール紙容器内に貯蔵されたフルーツと柑橘系ジュースとを含む飲料を貯蔵する方法であって、前記容器が請求項1に記載のラミネートから形成されている、前記方法。
- ボール紙容器内に貯蔵されたフルーツと柑橘系ジュースとを含む飲料を貯蔵する方法であって、前記容器が請求項9に記載のラミネートから形成されている、前記方法。
- 食品を含むシールされた容器であって、前記容器は請求項1に記載のラミネートから構成されており、前記食品は前記容器内に熱間充填され、該食品は食品中の微生物を全て本質的に殺すのに充分な温度に加熱されており、該容器はシールされ、該容器内の該食品は冷却される、前記容器。
- 食品を含むシールされた容器であって、前記容器は請求項9に記載のラミネートから構成されており、前記食品は容器内に熱間充填され、該食品は食品中の微生物を全て本質的に殺すのに充分な温度に加熱されており、該容器はシールされ、該容器内の該食品は冷却される、前記容器。
- 食品を含むシールされた容器であって、該容器は、請求項9に記載のラミネートから構成され、前記製品が容器内に冷間充填される、前記容器。
- 請求項1に記載のラミネートから構成された空の容器。
- 請求項9に記載のラミネートから構成された空の容器。
- 請求項10に記載のラミネートから構成された空の容器。
- 請求項1に記載のバリヤラミネートを含む液体食品の貯蔵用ラミネート化包装材料。
- 請求項9に記載のバリヤラミネートを含む液体食品の貯蔵用ラミネート化包装材料。
- 請求項1に記載のバリヤラミネートを含むボール紙容器に貯蔵されたフルーツと柑橘系ジュースとを含む飲料を貯蔵する方法。
- 請求項9に記載のバリヤラミネートを含むボール紙容器に貯蔵されたフルーツと柑橘系ジュースとを含む飲料を貯蔵する方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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US10/647,955 US20040037983A1 (en) | 2002-03-25 | 2003-08-26 | Non-foil barrier laminates |
US10/647,955 | 2003-08-26 | ||
PCT/IB2004/002755 WO2005018932A1 (en) | 2003-08-26 | 2004-08-26 | Non-foil barrier laminates |
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JP2007503337A JP2007503337A (ja) | 2007-02-22 |
JP4794442B2 true JP4794442B2 (ja) | 2011-10-19 |
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US (1) | US20040037983A1 (ja) |
EP (1) | EP1658175B1 (ja) |
JP (1) | JP4794442B2 (ja) |
KR (1) | KR101139114B1 (ja) |
CN (1) | CN100431835C (ja) |
AR (1) | AR045511A1 (ja) |
AT (1) | ATE444851T1 (ja) |
CA (1) | CA2534500C (ja) |
DE (1) | DE602004023521D1 (ja) |
ES (1) | ES2331886T3 (ja) |
IL (1) | IL173899A0 (ja) |
MX (1) | MXPA06002136A (ja) |
PA (1) | PA8610301A1 (ja) |
SV (1) | SV2005001863A (ja) |
TW (1) | TWI333453B (ja) |
WO (1) | WO2005018932A1 (ja) |
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DE202011050151U1 (de) * | 2011-05-17 | 2012-08-22 | Günter Keienburg | Getränkedose, die weitgehend aus zellstoffhaltigem Material besteht und eine lebensmittelverträgliche Barriereschicht aufweist, für unter Überdruck stehende Getränke |
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-
2003
- 2003-08-26 US US10/647,955 patent/US20040037983A1/en not_active Abandoned
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2004
- 2004-08-26 JP JP2006524457A patent/JP4794442B2/ja active Active
- 2004-08-26 PA PA20048610301A patent/PA8610301A1/es unknown
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- 2004-08-26 TW TW093125495A patent/TWI333453B/zh not_active IP Right Cessation
- 2004-08-26 EP EP04769179A patent/EP1658175B1/en not_active Not-in-force
- 2004-08-26 ES ES04769179T patent/ES2331886T3/es active Active
- 2004-08-26 MX MXPA06002136A patent/MXPA06002136A/es active IP Right Grant
- 2004-08-26 KR KR1020067003800A patent/KR101139114B1/ko active IP Right Grant
- 2004-08-26 CA CA2534500A patent/CA2534500C/en active Active
- 2004-08-26 AT AT04769179T patent/ATE444851T1/de not_active IP Right Cessation
- 2004-08-26 SV SV2004001863A patent/SV2005001863A/es not_active Application Discontinuation
- 2004-08-26 DE DE602004023521T patent/DE602004023521D1/de active Active
- 2004-08-26 CN CNB2004800242984A patent/CN100431835C/zh active Active
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Also Published As
Publication number | Publication date |
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CN1842416A (zh) | 2006-10-04 |
ES2331886T3 (es) | 2010-01-19 |
EP1658175B1 (en) | 2009-10-07 |
MXPA06002136A (es) | 2006-05-17 |
SV2005001863A (es) | 2005-06-16 |
ATE444851T1 (de) | 2009-10-15 |
US20040037983A1 (en) | 2004-02-26 |
DE602004023521D1 (de) | 2009-11-19 |
WO2005018932A1 (en) | 2005-03-03 |
JP2007503337A (ja) | 2007-02-22 |
IL173899A0 (en) | 2006-07-05 |
CA2534500C (en) | 2012-07-17 |
KR20060134907A (ko) | 2006-12-28 |
CA2534500A1 (en) | 2005-03-03 |
TWI333453B (en) | 2010-11-21 |
AR045511A1 (es) | 2005-11-02 |
EP1658175A1 (en) | 2006-05-24 |
CN100431835C (zh) | 2008-11-12 |
KR101139114B1 (ko) | 2012-04-30 |
PA8610301A1 (es) | 2005-08-04 |
TW200517253A (en) | 2005-06-01 |
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