JP4563750B2 - 水性フロアーポリッシュ組成物 - Google Patents
水性フロアーポリッシュ組成物 Download PDFInfo
- Publication number
- JP4563750B2 JP4563750B2 JP2004250281A JP2004250281A JP4563750B2 JP 4563750 B2 JP4563750 B2 JP 4563750B2 JP 2004250281 A JP2004250281 A JP 2004250281A JP 2004250281 A JP2004250281 A JP 2004250281A JP 4563750 B2 JP4563750 B2 JP 4563750B2
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- JP
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- Prior art keywords
- floor polish
- polyalkylene glycol
- general formula
- aqueous floor
- polish composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims description 38
- 229920001515 polyalkylene glycol Polymers 0.000 claims description 26
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- 125000003827 glycol group Chemical group 0.000 claims description 6
- 150000005846 sugar alcohols Polymers 0.000 claims description 6
- 125000002947 alkylene group Chemical group 0.000 claims description 4
- 125000005702 oxyalkylene group Chemical group 0.000 claims description 4
- 238000006116 polymerization reaction Methods 0.000 claims description 4
- 238000012661 block copolymerization Methods 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 238000007334 copolymerization reaction Methods 0.000 claims description 3
- 235000011187 glycerol Nutrition 0.000 claims description 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 2
- 239000000600 sorbitol Substances 0.000 claims description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 15
- 239000004014 plasticizer Substances 0.000 description 15
- 239000001993 wax Substances 0.000 description 15
- 150000001875 compounds Chemical class 0.000 description 11
- WTLBZVNBAKMVDP-UHFFFAOYSA-N tris(2-butoxyethyl) phosphate Chemical compound CCCCOCCOP(=O)(OCCOCCCC)OCCOCCCC WTLBZVNBAKMVDP-UHFFFAOYSA-N 0.000 description 10
- -1 adipic acid ester Chemical class 0.000 description 9
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 8
- 238000009408 flooring Methods 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 7
- 239000004094 surface-active agent Substances 0.000 description 7
- 239000000839 emulsion Substances 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- 229910052698 phosphorus Inorganic materials 0.000 description 4
- 239000011574 phosphorus Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical group CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Natural products OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 235000019271 petrolatum Nutrition 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 229920005749 polyurethane resin Polymers 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- BTVWZWFKMIUSGS-UHFFFAOYSA-N 2-methylpropane-1,2-diol Chemical compound CC(C)(O)CO BTVWZWFKMIUSGS-UHFFFAOYSA-N 0.000 description 1
- QUKFNRQNPQSTPD-UHFFFAOYSA-N 2-methylpropanoic acid;pentane-1,3-diol Chemical compound CC(C)C(O)=O.CCC(O)CCO QUKFNRQNPQSTPD-UHFFFAOYSA-N 0.000 description 1
- MFKRHJVUCZRDTF-UHFFFAOYSA-N 3-methoxy-3-methylbutan-1-ol Chemical compound COC(C)(C)CCO MFKRHJVUCZRDTF-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000004264 Petrolatum Substances 0.000 description 1
- RVGRUAULSDPKGF-UHFFFAOYSA-N Poloxamer Chemical compound C1CO1.CC1CO1 RVGRUAULSDPKGF-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920002582 Polyethylene Glycol 600 Polymers 0.000 description 1
- AZUZXOSWBOBCJY-UHFFFAOYSA-N Polyethylene, oxidized Polymers OC(=O)CCC(=O)C(C)C(O)CCCCC=O AZUZXOSWBOBCJY-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000005011 alkyl ether group Chemical group 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 229920006026 co-polymeric resin Polymers 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-N hexanedioic acid Natural products OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000012170 montan wax Substances 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 229920003986 novolac Polymers 0.000 description 1
- 235000019645 odor Nutrition 0.000 description 1
- 235000019809 paraffin wax Nutrition 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- 229940066842 petrolatum Drugs 0.000 description 1
- 239000012169 petroleum derived wax Substances 0.000 description 1
- 235000019381 petroleum wax Nutrition 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920001983 poloxamer Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Description
本発明の水性フロアーポリッシュ組成物(実施例1〜11)および本発明以外の水性フロアーポリッシュ組成物(比較例1〜3)を、表1および表2の組成となるように作成した。表中の数字は、フロアーポリッシュ組成物中の質量%を示す。
アクリル樹脂エマルジョンA:プライマルDuraplus2(ローム&ハース社製)(アクリル−スチレン系共重合樹脂エマルジョン)
アクリル樹脂エマルジョンB:プライマルE2409(ローム&ハース社製)
ポリウレタン樹脂エマルジョン:NeorezR960(アーチケミカル社製)
ポリエチレングリコール:PEG600(三洋化成工業社製)
ポリプロピレングリコール:アデカポールDL30(旭電化工業社製)
ポリオキシエチレンポリオキシプロピレングリコール:プロノン201(日本油脂社製)
ポリオキシアルキレングリコール:25R−4(BASF Japan社製)
ポリオキシアルキレングリコールグリセリン付加物:サンニックスGP250(三洋化成工業社製)
ワックスエマルジョン:ハイテックE4B(東邦化学工業社製)
上記作成した水性フロアーポリッシュ組成物を、JIS K 3920−2001に準拠した評価方法により、レべリング性、光沢度、耐ヒールマーク性について評価した。評価の基準は以下のとおりである。結果を表3、表4に示す。
<レベリング性>
ホモジニアスビニル床タイル、ジニアスプレーンGE110(タジマ社製)を用いて3回塗布後測定し、結果を下記の5段階にて評価した。
5:きわめて優秀
4:優秀
3:良好
2:普通
1:不良
コンポジションビニル床タイル、PタイルP60(タジマ社製)を用いて3回塗布後測定した。値はJIS K 3920−2001に従って、基準面の光沢度を100としたときの百分率で表した。
ジニアスプレーンGE110(タジマ社製)を用いて測定し、結果を下記の5段階にて評価した。
5:きわめて優秀
4:優秀
3:良好
2:普通
1:不良
Claims (2)
- 一般式(2)で表されるポリアルキレングリコールの多価アルコール付加物を含有することを特徴とする水性フロアーポリッシュ組成物。
- 前記水性フロアーポリッシュ組成物中における、前記一般式(2)で表されるポリアルキレングリコールの多価アルコール付加物の合計量が、前記水性フロアーポリッシュ組成物における全不揮発分中の0.1〜20質量%であることを特徴とする請求項1に記載の水性フロアーポリッシュ組成物。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004250281A JP4563750B2 (ja) | 2004-08-30 | 2004-08-30 | 水性フロアーポリッシュ組成物 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004250281A JP4563750B2 (ja) | 2004-08-30 | 2004-08-30 | 水性フロアーポリッシュ組成物 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2006063272A JP2006063272A (ja) | 2006-03-09 |
JP4563750B2 true JP4563750B2 (ja) | 2010-10-13 |
Family
ID=36110031
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2004250281A Active JP4563750B2 (ja) | 2004-08-30 | 2004-08-30 | 水性フロアーポリッシュ組成物 |
Country Status (1)
Country | Link |
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JP (1) | JP4563750B2 (ja) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5710229B2 (ja) * | 2009-12-19 | 2015-04-30 | ローム アンド ハース カンパニーRohm And Haas Company | フロアポリッシュ組成物 |
JP5653196B2 (ja) * | 2010-12-03 | 2015-01-14 | 株式会社Adeka | 床用水性艶出し剤組成物 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4861518A (en) * | 1988-08-01 | 1989-08-29 | Ecolab Inc. | Non-filming high performance solid floor cleaner |
JPH0578619A (ja) * | 1990-03-29 | 1993-03-30 | Eastman Kodak Co | 光沢が改良された床つや出し組成物 |
JPH0892529A (ja) * | 1994-09-20 | 1996-04-09 | Yuho Chem Kk | フロアーポリッシュ用組成物 |
JP2001131495A (ja) * | 1999-08-26 | 2001-05-15 | Kao Corp | 床用処理剤 |
JP2002053817A (ja) * | 2000-08-09 | 2002-02-19 | Rinrei:Kk | 床用艶出し剤組成物 |
JP2003013010A (ja) * | 2001-06-29 | 2003-01-15 | Johnson Professional Co Ltd | フロアーポリッシュ用組成物 |
JP2004238595A (ja) * | 2003-02-04 | 2004-08-26 | Toho Chem Ind Co Ltd | 水性フロアーポリッシュ用レベリング剤 |
-
2004
- 2004-08-30 JP JP2004250281A patent/JP4563750B2/ja active Active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4861518A (en) * | 1988-08-01 | 1989-08-29 | Ecolab Inc. | Non-filming high performance solid floor cleaner |
JPH0578619A (ja) * | 1990-03-29 | 1993-03-30 | Eastman Kodak Co | 光沢が改良された床つや出し組成物 |
JPH0892529A (ja) * | 1994-09-20 | 1996-04-09 | Yuho Chem Kk | フロアーポリッシュ用組成物 |
JP2001131495A (ja) * | 1999-08-26 | 2001-05-15 | Kao Corp | 床用処理剤 |
JP2002053817A (ja) * | 2000-08-09 | 2002-02-19 | Rinrei:Kk | 床用艶出し剤組成物 |
JP2003013010A (ja) * | 2001-06-29 | 2003-01-15 | Johnson Professional Co Ltd | フロアーポリッシュ用組成物 |
JP2004238595A (ja) * | 2003-02-04 | 2004-08-26 | Toho Chem Ind Co Ltd | 水性フロアーポリッシュ用レベリング剤 |
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JP2006063272A (ja) | 2006-03-09 |
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