JP4520522B2 - Hair care solution - Google Patents
Hair care solution Download PDFInfo
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- JP4520522B2 JP4520522B2 JP2008231607A JP2008231607A JP4520522B2 JP 4520522 B2 JP4520522 B2 JP 4520522B2 JP 2008231607 A JP2008231607 A JP 2008231607A JP 2008231607 A JP2008231607 A JP 2008231607A JP 4520522 B2 JP4520522 B2 JP 4520522B2
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- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 58
- 239000007788 liquid Substances 0.000 claims description 30
- 229910052697 platinum Inorganic materials 0.000 claims description 29
- 102000008186 Collagen Human genes 0.000 claims description 20
- 108010035532 Collagen Proteins 0.000 claims description 20
- 229920001436 collagen Polymers 0.000 claims description 20
- 108090000765 processed proteins & peptides Proteins 0.000 claims description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 230000003647 oxidation Effects 0.000 claims description 11
- 238000007254 oxidation reaction Methods 0.000 claims description 11
- 230000036512 infertility Effects 0.000 claims description 2
- 230000000694 effects Effects 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000011888 foil Substances 0.000 description 3
- 230000006870 function Effects 0.000 description 3
- CSHFHJNMIMPJST-HOTGVXAUSA-N methyl (2s)-2-[[(2s)-2-[[2-[(2-aminoacetyl)amino]acetyl]amino]-3-phenylpropanoyl]amino]-4-methylpentanoate Chemical compound NCC(=O)NCC(=O)N[C@H](C(=O)N[C@@H](CC(C)C)C(=O)OC)CC1=CC=CC=C1 CSHFHJNMIMPJST-HOTGVXAUSA-N 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000004806 packaging method and process Methods 0.000 description 3
- -1 polyethylene Polymers 0.000 description 3
- 239000003755 preservative agent Substances 0.000 description 3
- 229920000298 Cellophane Polymers 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 230000003064 anti-oxidating effect Effects 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 102000004196 processed proteins & peptides Human genes 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 239000002453 shampoo Substances 0.000 description 2
- 238000012795 verification Methods 0.000 description 2
- 238000012371 Aseptic Filling Methods 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- UPIXZLGONUBZLK-UHFFFAOYSA-N platinum Chemical compound [Pt].[Pt] UPIXZLGONUBZLK-UHFFFAOYSA-N 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 230000009993 protective function Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000011882 ultra-fine particle Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
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- Cosmetics (AREA)
- Containers And Plastic Fillers For Packaging (AREA)
- Containers Having Bodies Formed In One Piece (AREA)
- Packages (AREA)
Description
この発明は、ヘアケア液に関し、特に、例えばコールドパーマ及びアイロンパーマに使用するパーマ液に添加する添加剤に関する発明である。 The present invention relates to a hair care liquid, and particularly relates to an additive added to a permanent liquid used for, for example, a cold permanent and an iron permanent.
従来は、髪に「艶」「潤い」「しっとり感」を与えるため粉末のコラーゲンペプチドをパーマ液またはカラー液に溶かして用いている。 Conventionally, a powdered collagen peptide is dissolved in a perm solution or a color solution in order to give the hair “lustration”, “moisture”, and “moist feeling”.
コラーゲンペプチドは、通常粉末のため、パーマ液に溶けづらいという問題があった。
また、髪の毛が、酸化により痛むことに対しての対応は充分なされていなかった。
パーマ液またはカラー液に添加する、ヘアケア製品は、短時間で溶解させる必要がある。そのため、添加するものはパーマ液またはカラー液同様の液体が好ましい。
ところが、コラーゲンペプチド水溶液は、微生物により腐敗し、長時間保存することは困難である。
保存料を用いることは可能であるが、髪にダメージを与える可能性がある。
このように、パーマ液またはカラー液による髪の酸化に対しては、コラーゲンペプチドでは解決できない状況である。
そのために、この発明の主たる目的は、髪に「艶」「潤い」「しっとり感」を与え、髪の酸化を抑えることができるヘアケア液を提供することである。
Since collagen peptides are usually powders, there is a problem that they are difficult to dissolve in perm solution.
Moreover, the response | compatibility with respect to the hair hurting by oxidation was not enough.
The hair care product added to the permanent liquid or the color liquid needs to be dissolved in a short time. Therefore, the liquid to be added is preferably a liquid similar to a permanent liquid or a color liquid.
However, an aqueous collagen peptide solution is spoiled by microorganisms and is difficult to store for a long time.
Preservatives can be used but can damage the hair.
As described above, the collagen peptide cannot solve the hair oxidation by the permanent liquid or the color liquid.
Therefore, the main object of the present invention is to provide a hair care solution that can impart “luster”, “moisture”, and “moist feeling” to the hair, and suppress hair oxidation.
この発明の請求項１にかかるヘアケア液は、下記の（１）コラーゲンペプチド、（２）白金ナノコロイド及び（３）水を混合し、パーマ液又はカラー液による髪の酸化を防ぐために溶解して使用するまで無菌状態を維持するように１３０−１５０℃に加熱されてなる、ヘアケア液である。
（１）コラーゲンペプチド１０重量％ないし５０重量％
（２）ナノレベルにまで超微粒子化した白金ナノコロイド０．０３５重量％ないし０．２８５重量％
（３）水 残量
この発明の請求項２にかかるヘアケア液は、下記の（１）コラーゲンペプチド、（２）白金ナノコロイド及び（３）水が、パーマ液又はカラー液による髪の酸化を防ぐために溶解して使用するまで無菌状態を維持するように１３０−１５０℃に加熱されて、容器に無菌充填され、ヒートシールした、ヘアケア液である。
（１）コラーゲンペプチド１０重量％ないし５０重量％
（２）ナノレベルにまで超微粒子化した白金ナノコロイド０．０３５重量％ないし０．２８５重量％
（３）水 残量
The hair care liquid according to claim 1 of the present invention is prepared by mixing the following (1) collagen peptide, (2) platinum nanocolloid and (3) water, and dissolving the hair to prevent oxidation of the hair by the permanent liquid or the color liquid. It is a hair care solution that is heated to 130-150 ° C. so that it remains sterile until use.
(1) co color Gen peptide 10 wt% to 50 wt%
(2) 0.035 wt% to 0.285 wt% of platinum nanocolloid micronized to the nano level
(3) Remaining amount of water The hair care solution according to claim 2 of the present invention has the following (1) collagen peptide, (2) platinum nanocolloid and (3) water to prevent hair oxidation by a permanent solution or a color solution. It is a hair care solution that is heated to 130-150 ° C. so as to maintain sterility until dissolved and used, and aseptically filled into a container and heat sealed.
(1) co color Gen peptide 10 wt% to 50 wt%
(2) 0.035 wt% to 0.285 wt% of platinum nanocolloid micronized to the nano level
(3) Water remaining
この発明によれば、パーマ液やカラー液による髪の酸化に対しては、ナノレベル（１０億分の３ｍ）にまで超微粒子化した抗酸化作用を有した白金ナノコロイドを配合することにより、パーマ液やカラー液による髪の酸化を抑える働きが付加される。
そして、実際にパーマ液に添加して利用したところ、従来の粉末コラーゲンと比べてツヤ感、しっとり感が上昇し、指どおりもスムーズになった。また、仔細に髪の毛を観察すると、キューティクルの損傷が少ないことが確認された。
According to the present invention, for the oxidation of hair with a perm liquid or a color liquid, by blending platinum nanocolloid with an anti-oxidation effect that has been microparticulated to the nano level (3 parts per billion), A function to suppress hair oxidation by perm and color liquids is added.
When actually added to the perm solution and used, the gloss and moist feeling increased compared to conventional powdered collagen, and the finger was smooth. Further, when the hair was closely observed, it was confirmed that the cuticle was less damaged.
この発明の上述の目的、その他の目的、特徴及び利点は、図面を参照して行う以下の発明を実施するための最良の形態の説明から一層明らかとなろう。 The above-described object, other objects, features, and advantages of the present invention will become more apparent from the following description of the best mode for carrying out the invention with reference to the drawings.
この発明にかかるヘアケア製品は、截頭円錐状カップ型小型容器（ポーションパック容器）１０に、ヘアケア液５０を充填されている。
この小型容器１０は、その上端に開口部１２ａを有するカップ状の容器本体１２を含む。
容器本体１２の胴部１６は、底１４の縁部１４ｃから上方に延びて形成される。この胴部１６は、その機械的強度を上げるために、その中央部から下部にわたる部分をひだ状に形成してもよい。
また、胴部１６の上端から外側に延びて、つば部１８が形成されている。このつば部１８は、そこに後述する蓋２２を取り付けるためのものである。
さらに、つば部１８の一端から外側に延びて、つまみ部２０が形成されている。また、つば部１８と蓋部２２との間が溶着され、容器本体１２の開口部１２ａの上面を閉塞するように、蓋２２が形成される。つまみ部２０の中央から先端にかけては、段差部２４が形成され、蓋２２をつば部１８から切り離しやすくするように構成されている。
小型容器１０にヘアケア液５０を無菌充填する方法としては、例えば、ヘアケア液５０を１３０℃〜１５０℃に加熱し、４〜５秒間加熱状態を継続して、小型容器１０にヘアケア液５０を充填し、フィルム状の蓋材をヒートシールにて定着させる。
In the hair care product according to the present invention, a hair cone 50 is filled in a frustoconical cup-shaped small container (portion pack container) 10.
The small container 10 includes a cup-shaped container body 12 having an opening 12a at its upper end.
The body portion 16 of the container body 12 is formed to extend upward from the edge portion 14 c of the bottom 14. In order to increase the mechanical strength of the body portion 16, a portion extending from the central portion to the lower portion may be formed in a pleated shape.
A flange portion 18 is formed extending outward from the upper end of the body portion 16. This collar part 18 is for attaching the lid | cover 22 mentioned later there.
Further, a knob portion 20 is formed extending outward from one end of the collar portion 18. In addition, the lid 22 is formed so that the flange portion 18 and the lid portion 22 are welded and the upper surface of the opening 12a of the container body 12 is closed. A stepped portion 24 is formed from the center to the tip of the knob portion 20 so that the lid 22 can be easily separated from the collar portion 18.
As a method of aseptically filling the hair care solution 50 into the small container 10, for example, the hair care solution 50 is heated to 130 ° C. to 150 ° C., and the heating state is continued for 4 to 5 seconds to fill the hair care solution 50 into the small container 10. Then, the film-like lid material is fixed by heat sealing.
ヘアケア液５０は、下記の構成を備える。
水に、下記の（１）コラーゲンペプチド及び（２）白金ナノコロイドを混合してなる。
（１）コラーゲンペプチド１０重量％ないし５０重量％
（２）白金ナノコロイド０．０３５重量％ないし０．２８５重量％
（３）水 残量
The hair care liquid 50 has the following configuration.
The following (1) collagen peptide and (2) platinum nanocolloid are mixed in water.
(1) 10% to 50% by weight of collagen peptide
(2) Platinum nanocolloid 0.035 wt% to 0.285 wt%
(3) Water remaining
白金ナノコロイドが０．０３５重量％を下回ると白金の作用である酸化を抑える働きが極端に減少し、また、０．２８５重量％を超えると、効果としてはそれ以上増加することはない。 If the platinum nanocolloid is less than 0.035% by weight, the action of suppressing oxidation, which is the action of platinum, is extremely reduced, and if it exceeds 0.285% by weight, the effect is not further increased.
コラーゲンペプチド及びプラチナは、化粧品に用いるグレードである。
コラーゲンペプチドは、髪に潤いと栄養を与え、髪の保護役であるキューティクルを頑丈に作る働きがある。
プラチナ（白金）は、ナノレベル（１０億分の３ｍ）にまで超微粒子化した白金ナノコロイドであり、これは、抗酸化作用があり、パーマやカラーによる髪の酸化を抑える働きがあり、髪の毛に充分に浸透させることができる。
液体なのでパーマ液（髪の毛にカールやしなやかさ、コシを与える）またはカラー液（髪の毛に色をつける）には容易に溶解する。
無菌充填ポーションパック包装とすれば、保存料を使用せず、液体でも腐敗の心配がなく、開封前であれば長期間衛生的である。
Collagen peptides and platinum are the grades used in cosmetics .
Collagen peptide moisturizes and nourishes hair, and has a function of making a cuticle that is a protective function of hair firmly.
Platinum (Platinum) is a nano-sized platinum nano colloid that is made into ultrafine particles (3 parts per billion). It has an anti-oxidation effect and functions to suppress hair oxidation by permanents and colors. Can be sufficiently penetrated.
Since it is a liquid, it dissolves easily in permanent liquids (which give curls, suppleness, and firmness to the hair) or color liquids (which color the hair).
Aseptic filling portion pack packaging does not use preservatives, there is no risk of spoilage even with liquids, and it is hygienic for a long time before opening.
下記の（１）コラーゲンペプチド（分子量５０００）及び（２）白金ナノコロイドが、截頭円錐状のカップ状小型容器１０に無菌充填され、蓋をヒートシールした、ヘアケア液。
（１）コラーゲンペプチド３０重量％
（２）白金ナノコロイド０．１９重量％
（３）水 残量
この実施例１のヘアケア液は、無菌充填がされているので、保管状況に関係なく、長期間の保存が可能になり、腐敗の心配がなく、保存料が無添加で製造が可能となっている。
A hair care solution in which the following (1) collagen peptide (molecular weight 5000) and (2) platinum nanocolloid are aseptically filled into a truncated cone-shaped cup-shaped container 10 and the lid is heat-sealed.
(1) Collagen peptide 30% by weight
(2) 0.19% by weight of platinum nanocolloid
(3) Remaining water Since the hair care solution of Example 1 is aseptically filled, it can be stored for a long period of time regardless of storage conditions, there is no risk of decay, and no preservative is added. Manufacture is possible.
実施例１のヘアケア液１０ｍｌを、パーマ液５０ｍｌに混ぜて使用いただき、髪へもたらす効果を検証したところ、毛先のパサツキがなくなり、毛先が落ち着き、まとまりやすくなっている。又、実施例１のヘアケア液１０ｍｌを、カラーリング時にカラー液５０ｍｌに混ぜて使用いただき、髪へもたらす効果を検証したところ、毛先のパサツキがなくなり、毛先が落ち着き、まとまりやすくなっている。
１回の使用量、１０ｍｌに容器充填しているので、使いやすく、無駄がない。
When 10 ml of the hair care solution of Example 1 was mixed with 50 ml of the perm solution and used to verify the effect on the hair, the hair tip was smooth, the hair tip settled down, and it was easy to unite. Further, 10 ml of the hair care liquid of Example 1 was mixed with 50 ml of the color liquid at the time of coloring, and the effect on the hair was verified.
Since the container is filled to 10ml, it is easy to use and there is no waste.
添付の図２（写真１）及び図３（写真２）において、プラチナ使用としているのが、実施例１のヘアケア液を用いた例を示す。
図２（写真１）において示すように、プラチナを用いた本実施例の方が、プラチナを用いない比較例に比して、艶感、しっとり感が上昇し、指どおりもスムーズになっている。
図３（写真２）において示すように、プラチナを用いた本実施例の方が、プラチナを用いない比較例に比して、毛先のパサツキがなくなり、毛先が落ち着き、まとまりやすくなっている。
In the attached FIG. 2 (Photo 1) and FIG. 3 (Photo 2), the use of platinum is an example using the hair care solution of Example 1.
As shown in FIG. 2 (Photo 1), the present example using platinum has higher gloss and moist feeling than the comparative example not using platinum, and the finger is smooth. .
As shown in FIG. 3 (Photo 2), the present example using platinum is free from fluffiness at the tip of the hair, and the tip of the hair settles down more easily than the comparative example not using platinum. .
プラチナ＋コラーゲンとあるのが、実施例１のヘアケア液を用いた例を示す。
電子顕微鏡による毛髪検証結果は、添付の図４（写真３）の通りである。
図４（写真３）において示すように、プラチナを用いた本実施例の方が、プラチナを用いない比較例に比して、シャンプーとリンスをしたときに用いた場合も、またパーマ液に一定の割合（パーマ液５重量部、本実施例品１重量部）で溶解して用いた場合も、キューティクルの損傷が少ない。
An example of using the hair care solution of Example 1 is platinum + collagen.
The results of hair verification using an electron microscope are as shown in FIG. 4 (Photo 3).
As shown in FIG. 4 (Photo 3), this example using platinum is more consistent with the permanent solution when used when shampooing and rinsing than the comparative example not using platinum. The cuticle is less damaged even when dissolved at a ratio of 5 parts by weight (perm liquid 5 parts by weight, 1 part by weight of the product of this example).
下記の（１）コラーゲンペプチド（分子量５０００）及び（２）白金ナノコロイドが、截頭円錐状のカップ状小型容器１０に無菌充填され、蓋をヒートシールした、ヘアケア液。
（１）コラーゲンペプチド３０重量％
（２）白金ナノコロイド０．０３５重量％
（３）水 残量
A hair care solution in which the following (1) collagen peptide (molecular weight 5000) and (2) platinum nanocolloid are aseptically filled into a truncated cone-shaped cup-shaped container 10 and the lid is heat-sealed.
(1) Collagen peptide 30% by weight
(2) 0.035% by weight of platinum nanocolloid
(3) Water remaining
下記の（１）コラーゲンペプチド（分子量３０００）及び（２）白金ナノコロイドが、截頭円錐状のカップ状小型容器１０に無菌充填され、蓋をヒートシールした、ヘアケア液。
（１）コラーゲンペプチド３０重量％
（２）白金ナノコロイド０．１９重量％
（３）水 残量
A hair care solution in which the following (1) collagen peptide (molecular weight 3000) and (2) platinum nanocolloid is aseptically filled into a truncated cone-shaped cup-shaped container 10 and the lid is heat-sealed.
(1) Collagen peptide 30% by weight
(2) 0.19% by weight of platinum nanocolloid
(3) Water remaining
実施例１のヘアケア液１０ｍｌをパーマ液５０ｍｌに溶かして、パーマをしたところ表１に示すような結果が得られた。 When 10 ml of the hair care solution of Example 1 was dissolved in 50 ml of the permanent solution and permed, the results shown in Table 1 were obtained.
この発明は、前記実施の形態のヘアケア液に限らず、この発明の思想に基き種々変更することが可能である。 The present invention is not limited to the hair care liquid of the above embodiment, and various modifications can be made based on the idea of the present invention.
カップ状小型容器１０に代えて、ストリップ包装、すなわち、主として、ポリエチレンフィルム、防湿セロハン、ポリエチレン加工セロハン（いわゆるポリセロ）、アルミはくなどを用い、１回の使用量のヘアケア液を三方シールにより区分包装して、各区分を簡単に切り取れるようにしてもよい。また、ポリエチレンテレフタレート（ＰＥＴ）、アルミはく、ポリアミド、アルミはく、ポリエチレンをラミネートしたフィルムなどを用い、１回の使用量のヘアケア液を三方シールにより区分包装して、各区分を簡単に切り取れるようにしてもよい。その他、包装容器は、例えば、１３０℃〜１５０℃に加熱し、４〜５秒間加熱状態を継続した、ヘアケア液５０を充填するに適したものであれば、他の形状でもよい。また、遮光性及び密封性に優れたものがよい。 Instead of the cup-shaped small container 10, strip packaging, that is, mainly using polyethylene film, moisture-proof cellophane, polyethylene-processed cellophane (so-called polycello), aluminum foil, etc., is used to separate a single use amount of hair care liquid by a three-way seal. It may be packaged so that each section can be easily cut. In addition, using polyethylene terephthalate (PET), aluminum foil, polyamide, aluminum foil, polyethylene laminated film, etc., each usage amount of hair care solution is divided and packaged with a three-side seal, and each division is easily cut. You may make it take. In addition, the packaging container may have other shapes as long as it is suitable for filling the hair care solution 50 that is heated to 130 ° C. to 150 ° C. and kept in the heated state for 4 to 5 seconds. Moreover, the thing excellent in light-shielding property and sealing performance is good.
この発明にかかるヘアケア液は、パーマ前のプレシャンプー、パーマ液またはカラー剤及びパーマ処理後のシャンプートリートメントに混ぜて使用することができる。 The hair care liquid according to the present invention can be used by mixing with a pre-perm shampoo, a perm liquid or a color agent, and a shampoo treatment after perm treatment.
１０ 小型容器
１２ 容器本体
１２ａ 開口部
１４ 底
１４ｃ 縁部
１６ 胴部
１８ つば部
２０ つまみ部
２４ 段差部
２２ 蓋
５０ ヘアケア液
DESCRIPTION OF SYMBOLS 10 Small container 12 Container main body 12a Opening part 14 Bottom 14c Edge part 16 Trunk part 18 Collar part 20 Knob part 24 Step part 22 Lid 50 Hair care liquid
Claims (2)
（１）コラーゲンペプチド１０重量％ないし５０重量％
（２）ナノレベルにまで超微粒子化した白金ナノコロイド０．０３５重量％ないし０．２８５重量％
（３）水 残量 The following (1) collagen peptide, (2) Colloidal platinum and (3) of water were mixed, so as to maintain sterility until use by dissolving in order to prevent oxidation of the hair by perm solution or color liquid 130- A hair care solution heated to 150 ° C.
(1) co color Gen peptide 10 wt% to 50 wt%
(2) 0.035 wt% to 0.285 wt% of platinum nanocolloid micronized to the nano level
(3) Water remaining
（１）コラーゲンペプチド１０重量％ないし５０重量％
（２）ナノレベルにまで超微粒子化した白金ナノコロイド０．０３５重量％ないし０．２８５重量％
（３）水 残量 The following (1) collagen peptide, (2) platinum nanocolloid, and (3) water are dissolved at 130-150 ° C. until they are dissolved and used in order to prevent hair oxidation by a perm solution or a color solution. is heated to, it is aseptically filled into containers and heat sealed, hair care solution.
(1) co color Gen peptide 10 wt% to 50 wt%
(2) 0.035 wt% to 0.285 wt% of platinum nanocolloid micronized to the nano level
(3) Water remaining
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| TWI449500B (en) * | 2010-02-26 | 2014-08-21 | Melodian Co Ltd | Nutritional supplement food and manufacturing method |
| JP5636231B2 (en) * | 2010-09-13 | 2014-12-03 | ホーユー株式会社 | Hair treatment composition |
| JP5973158B2 (en) * | 2011-12-09 | 2016-08-23 | 花王株式会社 | Hair cosmetics |
| JP5801778B2 (en) * | 2012-09-12 | 2015-10-28 | 向井 孝 | Permanent wave treatment method |
| JP6063253B2 (en) * | 2012-12-27 | 2017-01-18 | 株式会社エンプラス | Manufacturing method and manufacturing apparatus for packaged injection molded product |
| JP2015105248A (en) * | 2013-11-29 | 2015-06-08 | 富士フイルム株式会社 | Hair dyeing agent |
| JP6168377B1 (en) * | 2015-08-21 | 2017-07-26 | 株式会社Ｉｃｔｂグローバル | Hair shaping method which is straightening treatment or permanent wave treatment, and hair treatment liquid for hair shaping treatment |
| JP2019189546A (en) * | 2018-04-21 | 2019-10-31 | 日出男 山脇 | Silicon elution liquid for scalp and hair |
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| JP2010083586A (en) | 2010-04-15 |
| JP4627562B2 (en) | 2011-02-09 |
| JP4520523B2 (en) | 2010-08-04 |
| JP4520520B2 (en) | 2010-08-04 |
| JP2009029782A (en) | 2009-02-12 |
| JP2009029818A (en) | 2009-02-12 |
| JP2009029819A (en) | 2009-02-12 |
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