JP4449630B2 - 真空断熱材、及び真空断熱材を具備する冷蔵庫 - Google Patents
真空断熱材、及び真空断熱材を具備する冷蔵庫 Download PDFInfo
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- JP4449630B2 JP4449630B2 JP2004219702A JP2004219702A JP4449630B2 JP 4449630 B2 JP4449630 B2 JP 4449630B2 JP 2004219702 A JP2004219702 A JP 2004219702A JP 2004219702 A JP2004219702 A JP 2004219702A JP 4449630 B2 JP4449630 B2 JP 4449630B2
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- Prior art keywords
- heat insulating
- insulating material
- vacuum heat
- moisture adsorbent
- surface area
- Prior art date
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- 239000012212 insulator Substances 0.000 title description 3
- 239000011810 insulating material Substances 0.000 claims description 78
- 239000003463 adsorbent Substances 0.000 claims description 73
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 60
- 239000000292 calcium oxide Substances 0.000 claims description 59
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 58
- 239000011162 core material Substances 0.000 claims description 25
- 239000002245 particle Substances 0.000 claims description 22
- 239000005022 packaging material Substances 0.000 claims description 12
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 11
- 239000000920 calcium hydroxide Substances 0.000 claims description 11
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 11
- 239000006260 foam Substances 0.000 claims description 11
- 239000003365 glass fiber Substances 0.000 claims description 11
- 239000004745 nonwoven fabric Substances 0.000 claims description 11
- 230000035699 permeability Effects 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 6
- 238000005057 refrigeration Methods 0.000 claims description 5
- 230000004888 barrier function Effects 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 235000012255 calcium oxide Nutrition 0.000 description 58
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 46
- 238000009413 insulation Methods 0.000 description 20
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 18
- 239000011148 porous material Substances 0.000 description 17
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 15
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 14
- 238000001179 sorption measurement Methods 0.000 description 11
- 239000000843 powder Substances 0.000 description 10
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 9
- 150000001342 alkaline earth metals Chemical class 0.000 description 9
- 239000000395 magnesium oxide Substances 0.000 description 9
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 9
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 9
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 8
- 229910000019 calcium carbonate Inorganic materials 0.000 description 7
- 238000010521 absorption reaction Methods 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000000835 fiber Substances 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 239000011521 glass Substances 0.000 description 5
- 239000010410 layer Substances 0.000 description 5
- 238000010298 pulverizing process Methods 0.000 description 5
- 238000007789 sealing Methods 0.000 description 5
- 239000002344 surface layer Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 230000006866 deterioration Effects 0.000 description 4
- 238000007873 sieving Methods 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 229910021536 Zeolite Inorganic materials 0.000 description 3
- 230000004913 activation Effects 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 239000011491 glass wool Substances 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000010457 zeolite Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000006114 decarboxylation reaction Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000012774 insulation material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229920006284 nylon film Polymers 0.000 description 2
- 238000005192 partition Methods 0.000 description 2
- 239000000741 silica gel Substances 0.000 description 2
- 229910002027 silica gel Inorganic materials 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 230000002123 temporal effect Effects 0.000 description 2
- 238000004438 BET method Methods 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 description 1
- 229910001863 barium hydroxide Inorganic materials 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- YWEUIGNSBFLMFL-UHFFFAOYSA-N diphosphonate Chemical compound O=P(=O)OP(=O)=O YWEUIGNSBFLMFL-UHFFFAOYSA-N 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- 238000001027 hydrothermal synthesis Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000002650 laminated plastic Substances 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 229920000092 linear low density polyethylene Polymers 0.000 description 1
- 239000004707 linear low-density polyethylene Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- DLYUQMMRRRQYAE-UHFFFAOYSA-N phosphorus pentoxide Inorganic materials O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000009461 vacuum packaging Methods 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Images
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- Thermal Insulation (AREA)
- Refrigerator Housings (AREA)
Description
図1は、本発明の実施の形態1における真空断熱材の断面図である。
図3は、本発明の実施の形態2における真空断熱材を適用した冷蔵庫の断面図であり、本発明の冷蔵庫の一例として示している。
水分吸着剤4は、アルカリ土類金属の酸化物として酸化カルシウムを適用している。
水分吸着剤4は、アルカリ土類金属の酸化物として酸化カルシウムを適用している。
水分吸着剤4は、アルカリ土類金属の酸化物として酸化カルシウムを適用している。
この時、酸化カルシウムの比表面積は10m2/g、細孔容積は0.09ml/gであった。
水分吸着剤4は、アルカリ土類金属の酸化物として酸化マグネシウムを適用している。
水分吸着剤4は、アルカリ土類金属の酸化物として酸化バリウムを適用している。
水分吸着剤4、及びその他吸着剤を適用せずに真空断熱材を作製した。
水分吸着剤4は、アルカリ土類金属の酸化物として酸化カルシウムを適用している。
水分吸着剤4は、アルカリ土類金属の酸化物として酸化カルシウムを適用している。
水分吸着剤4は、アルカリ土類金属の酸化物として酸化カルシウムを適用している。
2 芯材
3 外包材
4 水分吸着剤
31 冷蔵庫
32 断熱箱体
33 外箱
34 内箱
35 硬質ウレタンフォーム(硬質樹脂フォーム)
46 ドア体
Claims (2)
- 芯材と、水分吸着剤と、前記芯材と前記水分吸着剤を被覆するガスバリア性を有する外包材とからなり、内部を減圧密閉した真空断熱材であって、前記芯材はガラス短繊維のウェブの積層体からなり、前記水分吸着剤は平均粒径が1mm以上5mm未満で比表面積が10m2/g以上である酸化カルシウムを通気性を有する不織布に充填したものであって、前記酸化カルシウムは比表面積を10m 2 /g以上とするために少なくとも水酸化カルシウムを焙焼して形成したものを含む真空断熱材。
- 少なくとも冷蔵機能を有する冷蔵庫であって、冷蔵庫の外箱と内箱とで形成される空間に硬質樹脂フォームを充填した断熱箱体または断熱ドア体の少なくともいずれかにおいて、前記内箱と前記外箱との間に請求項1に記載の真空断熱材を具備する冷蔵庫。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004219702A JP4449630B2 (ja) | 2004-07-28 | 2004-07-28 | 真空断熱材、及び真空断熱材を具備する冷蔵庫 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004219702A JP4449630B2 (ja) | 2004-07-28 | 2004-07-28 | 真空断熱材、及び真空断熱材を具備する冷蔵庫 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2006038122A JP2006038122A (ja) | 2006-02-09 |
JP4449630B2 true JP4449630B2 (ja) | 2010-04-14 |
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JP2004219702A Expired - Fee Related JP4449630B2 (ja) | 2004-07-28 | 2004-07-28 | 真空断熱材、及び真空断熱材を具備する冷蔵庫 |
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JP (1) | JP4449630B2 (ja) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008106532A (ja) * | 2006-10-26 | 2008-05-08 | Matsushita Electric Ind Co Ltd | 真空断熱材 |
JP2009287862A (ja) * | 2008-05-30 | 2009-12-10 | Panasonic Corp | 蓄熱容器 |
KR101752669B1 (ko) * | 2013-12-10 | 2017-06-30 | 삼성전자주식회사 | 진공단열재 및 이를 포함하는 냉장고 |
JP2016107226A (ja) * | 2014-12-09 | 2016-06-20 | 三星電子株式会社Samsung Electronics Co.,Ltd. | 吸着材、および、これを用いた真空断熱材 |
-
2004
- 2004-07-28 JP JP2004219702A patent/JP4449630B2/ja not_active Expired - Fee Related
Also Published As
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JP2006038122A (ja) | 2006-02-09 |
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