JP4415776B2 - Aluminum laminate film thermal welding equipment for multilayer electric double layer capacitors - Google Patents

Aluminum laminate film thermal welding equipment for multilayer electric double layer capacitors Download PDF

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JP4415776B2
JP4415776B2 JP2004199993A JP2004199993A JP4415776B2 JP 4415776 B2 JP4415776 B2 JP 4415776B2 JP 2004199993 A JP2004199993 A JP 2004199993A JP 2004199993 A JP2004199993 A JP 2004199993A JP 4415776 B2 JP4415776 B2 JP 4415776B2
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laminate film
aluminum laminate
double layer
electric double
current collecting
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JP2006024660A (en
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征博 三島
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Meidensha Corp
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/13Energy storage using capacitors

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  • Electric Double-Layer Capacitors Or The Like (AREA)
  • Fixed Capacitors And Capacitor Manufacturing Machines (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To surely weld an aluminum laminate film and collector terminals by one-time welding operation without causing defective sealing. <P>SOLUTION: The bottom crimping board 14 of a heat welding apparatus 11 is divided into two in the lengthwise direction, and then the divided parts are integrated together via an elastic material 15 to form a new bottom crimping board 16. On both sides of the elastic material 15 of the bottom crimping board 16, a pair of collector terminal storing recesses 16a and 16b having nearly the same width as that of the collector terminals 9 are formed at an interval wider than that of the collector terminals 9. At the time of welding, the bottom crimping board 16 is constricted in the lengthwise direction to conform the interval of the collector terminal storing recesses 16a and 16b to that of the collector terminals 9, and then the collector terminals 9 are stored in the collector terminal storing recesses 16a and 16b. Then, ends of the aluminum laminate film 10 and the collector terminals 9 are held between a top crimping board 12 and the bottom crimping board 16 and are welded by heat crimping. <P>COPYRIGHT: (C)2006,JPO&amp;NCIPI

Description

この発明は、積層型電気二重層キャパシタのアルミラミネートフィルム熱溶着装置に関するものである。   The present invention relates to an aluminum laminate film heat welding apparatus for a multilayer electric double layer capacitor.

図2は特許文献1に示された従来の積層型電気二重層キャパシタ本体8の断面図を示し、活性炭電極を接着した2枚の集電極板1の間に、アルミ箔基材2aの両面に活性炭電極2bを接着した中間電極2とイオンが移動可能なセパレータ3とを交互に重ねて挟み込み、中間電極2及びセパレータ3の外周には内部の電解液等が漏れないように、また中間電極2間を絶縁するためにシール機能を有するゴムパッキン4を設けている。又、集電極板1の外面側には加圧板5を設け、絶縁スペーサ6を介してボルト7で締め付けることにより、密閉構造で加圧力を加えた構造としている。   FIG. 2 is a cross-sectional view of a conventional multilayer electric double layer capacitor body 8 disclosed in Patent Document 1, and is disposed on both surfaces of an aluminum foil base 2a between two collector plates 1 to which activated carbon electrodes are bonded. The intermediate electrode 2 to which the activated carbon electrode 2b is bonded and the separator 3 to which ions can move are alternately stacked and sandwiched so that the inner electrolyte 2 and the separator 3 do not leak to the outer periphery, and the intermediate electrode 2 A rubber packing 4 having a sealing function is provided to insulate the gap. Further, a pressure plate 5 is provided on the outer surface side of the collector electrode plate 1 and is tightened with a bolt 7 via an insulating spacer 6 so that pressure is applied in a sealed structure.

図3(a),(b)は従来の積層型電気二重層キャパシタ本体8の平面図及び正面図を示し、実際には集電極板1には一対の集電端子9が突出して設けられている。又、図4(a),(b)に示すように、キャパシタ本体8は外気遮断のためにアルミラミネートフィルム10により包装され、アルミラミネートフィルム10の内部は真空引きされ、集電端子9はアルミラミネートフィルム10の端部と熱溶着される。なお、積層型電気二重層キャパシタ本体8は実際には見えない。
特開2003−217987号公報
FIGS. 3A and 3B are a plan view and a front view of a conventional multilayer electric double layer capacitor body 8. In practice, a pair of current collecting terminals 9 are provided to protrude from the current collecting plate 1. Yes. 4 (a) and 4 (b), the capacitor body 8 is wrapped with an aluminum laminate film 10 to block outside air, the inside of the aluminum laminate film 10 is evacuated, and the current collecting terminal 9 is made of aluminum. It is heat welded to the end of the laminate film 10. The multilayer electric double layer capacitor body 8 is not actually visible.
JP 2003-217987 A

図5はキャパシタ本体8の一部拡大図を示し、メンテナンス性の向上から集電端子9は集電極板1とは別の部品で構成され、集電端子9の一部は集電極板1と加圧板5との間に挿入される。しかし、このように、別々の部品としたことによって、キャパシタ本体8の組立段階において、集電端子9の間隔が多少ずれたまま組み立てられてしまうことがある。   FIG. 5 shows a partially enlarged view of the capacitor main body 8, and the collector terminal 9 is constituted by a part different from the collector electrode plate 1 for improvement of maintainability, and a part of the collector terminal 9 is part of the collector electrode plate 1. It is inserted between the pressure plate 5. However, by using separate components as described above, the assembly of the capacitor body 8 may be assembled with the gap between the current collecting terminals 9 slightly deviated.

一方、図6及び図7は積層型電気二重層キャパシタのアルミラミネートフィルム熱溶着装置における真空包装用熱溶着器による熱溶着の様子を示す斜視図及び集電端子と下側圧着板との関係を示す説明図を示し、熱溶着器11は鉄製の上側圧着板12と下側圧着板13とを有し、約190℃に加熱された一対の圧着板12,13によりアルミラミネートフィルム10の端部は5気圧の圧力で圧着される。この際、アルミラミネートフィルム10が集電端子9によって損傷しないように、下側圧着板13には集電端子9を収納するための集電端子収納溝13a,13bが集電端子9の厚さに合わせた深さで一対設けられており、集電端子9の位置ずれに対応するために集電端子収納溝13a,13bの幅に裕度を持たせて集電端子9の幅より若干広めにしているが、集電端子9の間隔のずれが大きいと、集電端子9は集電端子収納溝13a,13bに収まったとしても、アルミラミネートフィルム10と集電端子9との間に隙間が生じてシール不良を起こすことがある。   On the other hand, FIGS. 6 and 7 are perspective views showing the state of heat welding by a vacuum packaging heat welder in an aluminum laminate film heat welding apparatus of a multilayer electric double layer capacitor, and the relationship between the current collector terminal and the lower crimping plate. The thermal welder 11 has an iron upper crimping plate 12 and a lower crimping plate 13, and an end portion of the aluminum laminate film 10 by a pair of crimping plates 12 and 13 heated to about 190 ° C. Is pressure-bonded at a pressure of 5 atm. At this time, in order to prevent the aluminum laminated film 10 from being damaged by the current collecting terminal 9, current collecting terminal housing grooves 13 a and 13 b for housing the current collecting terminal 9 are formed in the lower crimping plate 13. A pair with a depth corresponding to the current collector terminal 9 is provided, and the width of the current collector terminal receiving grooves 13a and 13b is given a margin to be slightly wider than the width of the current collector terminal 9 in order to cope with the displacement of the current collector terminal 9. However, if the gap between the current collecting terminals 9 is large, the gap between the aluminum laminated film 10 and the current collecting terminals 9 is not reduced even if the current collecting terminals 9 are accommodated in the current collecting terminal receiving grooves 13a and 13b. May cause seal failure.

そのため、従来では、図8に示すように、下側圧着板13の長さを半分にし、集電端子収納溝13aも一つだけとして、1回目の溶着作業では一方の集電端子9を含む半分のアルミラミネートフィルム10の端部の溶着を行い、2回目の溶着作業では他方の集電端子9を含む残り半分のアルミラミネートフィルム10の端部の溶着を行い、溶着を確実に行うようにしていたが、溶着作業が二度手間となるという欠点があった。   Therefore, conventionally, as shown in FIG. 8, the length of the lower pressure-bonding plate 13 is halved, the current collecting terminal receiving groove 13a is only one, and one current collecting terminal 9 is included in the first welding operation. The end of the half aluminum laminate film 10 is welded, and in the second welding operation, the end of the other half of the aluminum laminate film 10 including the other current collecting terminal 9 is welded to ensure the welding. However, there was a drawback that the welding work was troublesome twice.

この発明は上記のような課題を解決するために成されたものであり、1回の溶着作業でアルミラミネートフィルムと集電端子との溶着をシール不良を生じることなく確実に行うことができる積層型電気二重層キャパシタのアルミラミネートフィルム溶着装置を得ることを目的とする。   The present invention has been made to solve the above-described problems, and is a laminate that can reliably perform welding between an aluminum laminate film and a current collecting terminal without causing a sealing failure in one welding operation. An object of the present invention is to obtain an aluminum laminate film welding apparatus for a type electric double layer capacitor.

この発明の請求項1に係る積層型電気二重層キャパシタのアルミラミネートフィルム熱溶着装置は、一対の突出した集電端子を有する積層型電気二重層キャパシタ本体をアルミラミネートフィルムに包装して内部を真空引きし、アルミラミネートフィルムの端部と集電端子とを熱溶着器の一対の圧着板により挟んで熱溶着する積層型電気二重層キャパシタのアルミラミネートフィルム熱溶着装置において、一方の圧着板を長さ方向に2分割し、間に弾性材を介して一体化し、弾性材の両側において集電端子の幅とほぼ同じ幅の集電端子収納溝を集電端子の間隔より広い間隔で一対設け、この圧着板を長さ方向に圧縮して集電端子収納溝の間隔を集電端子の間隔に合わせるようにしたものである。   According to a first aspect of the present invention, there is provided an aluminum laminate film heat welding apparatus for a multilayer electric double layer capacitor, wherein a multilayer electric double layer capacitor body having a pair of protruding current collecting terminals is packaged in an aluminum laminate film and the inside is vacuumed. In an aluminum laminate film heat welding device for a laminated electric double layer capacitor, the end of the aluminum laminate film and the current collecting terminal are sandwiched between a pair of crimping plates of a heat welder and heat-welded. It is divided into two in the vertical direction, integrated with an elastic material in between, and a pair of current collecting terminal receiving grooves having a width substantially the same as the width of the current collecting terminal is provided on both sides of the elastic material at a wider interval than the current collecting terminal interval This crimping plate is compressed in the length direction so that the distance between the collecting terminal receiving grooves matches the distance between the collecting terminals.

請求項2に係る積層型電気二重層キャパシタのアルミラミネートフィルム熱溶着装置は、弾性材としてシリコンゴムを用いたものである。   An aluminum laminate film heat welding apparatus for a multilayer electric double layer capacitor according to claim 2 uses silicon rubber as an elastic material.

請求項3に係る積層型電気二重層キャパシタのアルミラミネートフィルム熱溶着装置は、弾性材としてフッ素ゴムを用いたものである。   The aluminum laminated film heat welding apparatus for a multilayer electric double layer capacitor according to claim 3 uses fluorine rubber as an elastic material.

請求項4に係る積層型電気二重層キャパシタのアルミラミネートフィルム熱溶着装置は、弾性材としてバイトンゴムを用いたものである。   The aluminum laminate film heat welding apparatus for a multilayer electric double layer capacitor according to claim 4 uses Viton rubber as an elastic material.

以上のようにこの発明の請求項1によれば、一方の圧着板を2分割して間に弾性材を介して一体化し、弾性材の両側において集電端子の幅と同じ幅の集電端子収納溝を集電端子の間隔より広い間隔で一対設けており、溶着時にはこの圧着板を長さ方向に圧縮して集電端子収納溝の間隔を集電端子の間隔に合わせるようにしており、1回の溶着作業でアルミラミネートフィルムの端部と集電端子との溶着をシール不良を生ずることなく、確実に行うことができる。   As described above, according to the first aspect of the present invention, one crimping plate is divided into two parts and integrated with an elastic material therebetween, and the current collecting terminals have the same width as the current collecting terminals on both sides of the elastic material. A pair of storage grooves are provided at intervals wider than the interval between the current collecting terminals, and at the time of welding, this crimping plate is compressed in the length direction so that the interval between the current collecting terminal storage grooves matches the interval between the current collecting terminals. The welding of the end portion of the aluminum laminate film and the current collecting terminal can be reliably performed without causing a sealing failure by a single welding operation.

又、請求項2によれば、弾性材としてシリコンゴムを用いており、請求項1と同様の効果を得ることができる。   According to the second aspect, silicon rubber is used as the elastic material, and the same effect as in the first aspect can be obtained.

請求項3によれば、弾性材としてフッ素ゴムを用いており、圧着板を長さ方向に圧縮したときの溝の間隔の変化を大きくすることができ、集電端子の間隔が大きくずれたときにも容易に対応することができる。   According to claim 3, when the fluororubber is used as the elastic material, the change in the groove interval when the crimping plate is compressed in the length direction can be increased, and the interval between the current collecting terminals is greatly deviated. Can be easily accommodated.

請求項4によれば、弾性材としてバイトンゴムを用いており、アルミラミネートフィルムとの剥離性がよくなる。その他、請求項1と同様の効果を奏する。   According to the fourth aspect, viton rubber is used as the elastic material, and the peelability from the aluminum laminate film is improved. In addition, the same effects as those of the first aspect are obtained.

実施最良形態1
以下、この発明を実施するための最良の形態を図面とともに説明する。図1はこの発明の実施最良形態1による積層型電気二重層キャパシタのアルミラミネートフィルム熱溶着装置における真空包装用熱溶着器の熱溶着の説明図であり、溶着器11の鉄製の下側圧着板14を長さ方向に2分割して分割部分14a,14bとし、その間にシリコンゴムからなる弾性材15を挟んで一体化して下側圧着板16を形成する。下側圧着板16においては、弾性材15の両側で集電端子9の幅とほぼ同じ幅で集電端子9の厚さとほぼ同じ深さの集電端子収納溝16a,16bを集電端子9の間隔より広い間隔で一対設ける。
Best Embodiment 1
The best mode for carrying out the present invention will be described below with reference to the drawings. FIG. 1 is an explanatory view of heat welding of a heat-sealing device for vacuum packaging in an aluminum laminate film heat-welding device for a multilayer electric double layer capacitor according to Embodiment 1 of the present invention. 14 is divided into two parts 14a and 14b in the length direction, and an elastic material 15 made of silicon rubber is sandwiched between them to form a lower pressure-bonding plate 16. In the lower crimping plate 16, the current collecting terminal receiving grooves 16 a and 16 b having the same width as the current collecting terminal 9 and the same depth as the current collecting terminal 9 are formed on both sides of the elastic material 15. A pair is provided with an interval wider than the interval.

溶着に際しては、下側圧着板16を長さ方向に圧縮して集電端子収納溝16a,16bの間隔を集電端子9の間隔と一致させ、集電端子9を集電端子収納溝16a,16bに収納し、アルミラミネートフィルム10の端部及び集電端子9を上側圧着板12と下側圧着板16とにより挟んで加熱圧着して溶着する。   At the time of welding, the lower crimping plate 16 is compressed in the length direction so that the distance between the current collecting terminal receiving grooves 16a and 16b is equal to the distance between the current collecting terminals 9, and the current collecting terminal 9 is connected to the current collecting terminal receiving grooves 16a, 16b, the end of the aluminum laminate film 10 and the current collecting terminal 9 are sandwiched between the upper pressure-bonding plate 12 and the lower pressure-bonding plate 16, and are heat-pressed and welded.

実施最良形態1においては、下側圧着板14を長さ方向に2分割し、間にシリコンゴムからなる弾性材15を介して一体化して下側圧着板16を形成しており、アルミラミネートフィルム10の端部及び集電端子9を圧着する際に、集電端子9の間隔が集電端子収納溝16a,16bの間隔とずれていても、下側圧着板16を長さ方向に圧縮することにより集電端子収納溝16a,16bの間隔を集電端子9の間隔に合わせることができる。このため、1回の溶着作業で集電端子9等の溶着をシール不良を生じることなく、確実に行うことができる。   In the first embodiment, the lower pressure-bonding plate 14 is divided into two in the length direction, and the lower pressure-bonding plate 16 is formed integrally with an elastic material 15 made of silicon rubber therebetween. When the end portion of 10 and the current collecting terminal 9 are crimped, the lower pressure-bonding plate 16 is compressed in the length direction even if the distance between the current collecting terminals 9 is shifted from the distance between the current collecting terminal housing grooves 16a and 16b. Thus, the interval between the current collecting terminal housing grooves 16 a and 16 b can be adjusted to the distance between the current collecting terminals 9. For this reason, welding of the current collector terminals 9 and the like can be reliably performed without causing a sealing failure in one welding operation.

実施最良形態2
実施最良形態1においては、弾性材15としてシリコンゴムを用いたが、実施最良形態2においては弾性材15としてフッ素ゴムを用いる。フッ素ゴムはシリコンゴムより弾性率が高く、長さ方向に圧縮した際の集電端子収納溝16a,16bの間隔の変化が大きい。このため、集電端子9の間隔ずれが大きい場合でも柔軟に対応できる。その他、実施最良形態1と同様な効果を奏する。
Embodiment 2
In the first embodiment, silicon rubber is used as the elastic material 15, but in the second embodiment, fluorine rubber is used as the elastic material 15. Fluororubber has a higher elastic modulus than silicon rubber, and the change in the interval between the current collecting terminal receiving grooves 16a and 16b when compressed in the length direction is large. For this reason, even when the gap | interval gap | deviation of the current collection terminal 9 is large, it can respond flexibly. In addition, the same effects as in the first embodiment are obtained.

実施最良形態3
実施最良形態3においては、弾性材15としてバイトンゴムを用いる。バイトンゴムはアルミラミネートフィルム10との剥離性が良く、溶着作業の後の作業性が良い。その他、実施最良形態1と同様の効果を奏する。
Embodiment 3
In the third embodiment, viton rubber is used as the elastic material 15. Viton rubber has good peelability from the aluminum laminate film 10 and good workability after welding work. In addition, the same effects as in the first embodiment are obtained.

この発明の実施最良形態1による積層型電気二重層キャパシタのアルミラミネートフィルム熱溶着装置における真空包装用熱溶着器の熱溶着の説明図である。It is explanatory drawing of the heat welding of the heat welding machine for vacuum packaging in the aluminum laminated film heat welding apparatus of the multilayer type electric double layer capacitor by Embodiment 1 of this invention. 特許文献1に示された従来の積層型電気二重層キャパシタ本体の断面図である。1 is a cross-sectional view of a conventional multilayer electric double layer capacitor main body disclosed in Patent Document 1. FIG. 従来の積層型電気二重層キャパシタ本体の平面図及び正面図である。It is the top view and front view of the conventional multilayer type electric double layer capacitor main body. 従来の積層型電気二重層キャパシタ本体を真空包装した状態の平面図及び正面図である。It is the top view and front view of the state which vacuum-packed the conventional multilayer type electric double layer capacitor main body. 積層型電気二重層キャパシタ本体の一部拡大図である。It is a partially expanded view of a multilayer electric double layer capacitor body. 従来の積層型電気二重層キャパシタのアルミラミネートフィルム熱溶着装置における真空包装用熱溶着器による熱溶着の様子を示す斜視図である。It is a perspective view which shows the mode of the heat welding by the heat welding machine for vacuum packaging in the aluminum lamination film heat welding apparatus of the conventional multilayer electric double layer capacitor. 従来の積層型電気二重層キャパシタのアルミラミネートフィルム熱溶着装置における真空包装用熱溶着器の集電端子と下側圧着板との関係を示す説明図である。It is explanatory drawing which shows the relationship between the current collection terminal of the heat welder for vacuum packaging in the conventional aluminum laminated film heat welding apparatus of a multilayer electric double layer capacitor, and a lower side crimping board. 従来の積層型電気二重層キャパシタのアルミラミネートフィルム熱溶着装置における真空包装用熱溶着器による改良された熱圧着の様子を示す説明図である。It is explanatory drawing which shows the mode of the thermocompression bonding improved with the heat welding machine for vacuum packaging in the aluminum lamination film heat welding apparatus of the conventional multilayer electric double layer capacitor.

符号の説明Explanation of symbols

8…積層型電気二重層キャパシタ本体
9…集電端子
10…アルミラミネートフィルム
11…熱溶着器
12…上側圧着板
14,16…下側圧着板
15…弾性材
16a,16b…集電端子収納溝
DESCRIPTION OF SYMBOLS 8 ... Multilayer type electric double layer capacitor main body 9 ... Current collecting terminal 10 ... Aluminum laminate film 11 ... Thermal welder 12 ... Upper side crimping plate 14, 16 ... Lower side crimping plate 15 ... Elastic material 16a, 16b ... Current collecting terminal accommodation groove

Claims (4)

一対の突出した集電端子を有する積層型電気二重層キャパシタ本体をアルミラミネートフィルムに包装して内部を真空引きし、アルミラミネートフィルムの端部と集電端子とを熱溶着器の一対の圧着板により挟んで熱溶着する積層型電気二重層キャパシタのアルミラミネートフィルム熱溶着装置において、一方の圧着板を長さ方向に2分割し、間に弾性材を介して一体化し、弾性材の両側において集電端子の幅とほぼ同じ幅の集電端子収納溝を集電端子の間隔より広い間隔で一対設け、この圧着板を長さ方向に圧縮して集電端子収納溝の間隔を集電端子の間隔に合わせるようにしたことを特徴とする積層型電気二重層キャパシタのアルミラミネートフィルム熱溶着装置。   A multilayer electric double layer capacitor body having a pair of protruding current collecting terminals is wrapped in an aluminum laminate film, the inside is evacuated, and the end of the aluminum laminate film and the current collecting terminal are paired with a pair of pressure bonding plates of a heat welder In an aluminum laminate film heat welding apparatus for a multilayer electric double layer capacitor that is sandwiched between and thermally bonded, one crimping plate is divided into two in the length direction and integrated with an elastic material between them, and collected on both sides of the elastic material. A pair of current collecting terminal receiving grooves having a width substantially the same as the width of the current terminal is provided at a distance wider than the distance between the current collecting terminals, and this crimping plate is compressed in the length direction so that the distance between the current collecting terminal receiving grooves is An aluminum laminate film heat welding apparatus for a multilayer electric double layer capacitor, characterized in that it is adapted to the interval. 弾性材としてシリコンゴムを用いたことを特徴とする請求項1記載の積層型電気二重層キャパシタのアルミラミネートフィルム熱溶着装置。   2. An aluminum laminate film heat welding apparatus for a multilayer electric double layer capacitor according to claim 1, wherein silicon rubber is used as the elastic material. 弾性材としてフッ素ゴムを用いたことを特徴とする請求項1記載の積層型電気二重層キャパシタのアルミラミネートフィルム熱溶着装置。   2. The aluminum laminate film heat welding apparatus for a multilayer electric double layer capacitor according to claim 1, wherein fluorine rubber is used as the elastic material. 弾性材としてバイトンゴムを用いたことを特徴とする請求項1記載の請求項1記載の積層型電気二重層キャパシタのアルミラミネートフィルム熱溶着装置。
2. An aluminum laminate film heat welding apparatus for a multilayer electric double layer capacitor according to claim 1, wherein viton rubber is used as the elastic material.
JP2004199993A 2004-07-07 2004-07-07 Aluminum laminate film thermal welding equipment for multilayer electric double layer capacitors Expired - Fee Related JP4415776B2 (en)

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JP2008028296A (en) * 2006-07-25 2008-02-07 Meidensha Corp Laminated electric double layer capacitor
JP5034794B2 (en) * 2007-09-06 2012-09-26 株式会社明電舎 Electric double layer capacitor
JP2009064992A (en) * 2007-09-07 2009-03-26 Meidensha Corp Laminated electric double-layer capacitor
WO2009031427A1 (en) * 2007-09-07 2009-03-12 Meidensha Corporation Electric double layer capacitor
JP2009065080A (en) * 2007-09-10 2009-03-26 Meidensha Corp Laminated electric double-layer capacitor
JP5217323B2 (en) 2007-09-14 2013-06-19 株式会社明電舎 Bipolar multilayer electric double layer capacitor

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