JP4376927B2 - Phase change optical recording medium and optical recording method thereof - Google Patents

Phase change optical recording medium and optical recording method thereof Download PDF

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JP4376927B2
JP4376927B2 JP2007180087A JP2007180087A JP4376927B2 JP 4376927 B2 JP4376927 B2 JP 4376927B2 JP 2007180087 A JP2007180087 A JP 2007180087A JP 2007180087 A JP2007180087 A JP 2007180087A JP 4376927 B2 JP4376927 B2 JP 4376927B2
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肇 譲原
美樹子 安部
浩司 出口
栄子 鈴木
裕司 三浦
和典 伊藤
通治 安倍
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Ricoh Co Ltd
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Description

本発明は、相変化型光記録媒体、特に書き換え型DVD媒体とその記録方法に関するものである。   The present invention relates to a phase change optical recording medium, and more particularly to a rewritable DVD medium and a recording method thereof.

大容量の画像データを扱うようになり、益々大容量の記録媒体が要求されている。また、これら大容量のデータを高速に記録再生することも要求されている。相変化型光記録媒体は、CD、DVDの書き換え型記録媒体に用いられており、大容量で高速記録が可能であること、及びROMとの互換が高いことから普及してきた。特にCD−ROM、CD−Rの高速化が著しく、相変化型光記録媒体も一層の高速化が要求されている。そして、高線速に対応したディスクは、低線速ディスクに対応している低速ドライブでも記録できることが望ましく、CD−Rは、これが可能であり、広い線速をカバーできている。
一方、高線速で記録するためには、より高いピークパワーが出せる高出力レーザーが必要になる。しかし、低速ドライブに搭載されているレーザー光の出力は高速対応ドライブの出力より低いのが普通であり、高線速対応ディスクを低線速且つより低いパワーで記録することは相変化型光記録媒体では難しい。
Since large-capacity image data has been handled, an increasingly large-capacity recording medium is required. In addition, it is required to record and reproduce these large volumes of data at high speed. Phase change optical recording media are used for rewritable recording media such as CDs and DVDs, and have become widespread because they are capable of high-capacity and high-speed recording and have high compatibility with ROMs. In particular, CD-ROMs and CD-Rs are remarkably increased in speed, and phase-change optical recording media are required to be further increased in speed. It is desirable that the disk corresponding to the high linear velocity can be recorded even by a low-speed drive compatible with the low linear velocity disk. The CD-R can do this and can cover a wide linear velocity.
On the other hand, in order to record at a high linear velocity, a high output laser capable of producing a higher peak power is required. However, the output of laser light mounted on low-speed drives is usually lower than the output of high-speed compatible drives, and recording high-speed compatible disks at low linear speed and lower power is a phase change optical recording It is difficult in the medium.

相変化型光記録媒体の場合、高線速記録が可能になるように媒体構成を最適化するが、そうすると低い線速で記録する場合も、高い線速で記録する場合と同様に最適なピークパワーがより高くなる。高い記録線速に対応した記録媒体をより低パワーで記録するためには感度を向上させる必要があるが、そのための一つの方法として、媒体の反射率を下げる方法がある。しかし、DVDの場合には、DVD−ROMとの互換を確保する必要があるために、反射率を必要以上に下げることはできない。書き換え可能型DVDにおいては、ここ数年間で商品化されている線速は2.4倍速が最高であり、これより速い線速で記録でき、しかも従来の低線速ドライブで記録できる下位互換可能な相変化型光記録媒体はない。
これらの要求を満たすためには、低いパワーで記録でき、しかも、ピークパワーのマージンが広い相変化型光記録媒体用の記録材料、媒体構成、最適記録方法を見出すことが必要である。そのような記録方法として、従来の記録マークを形成する方法において、パルスの最後部のバイアスパワー印加終了時間を記録線速に関係なく無くしてしまう特許文献1記載の方法がある。しかし、この方法では、広い線速に対応し且つ良好な記録特性を得ることは難しい。
In the case of a phase change optical recording medium, the medium configuration is optimized so that high linear velocity recording is possible. However, when recording at a low linear velocity, the optimum peak is the same as when recording at a high linear velocity. Power is higher. In order to record a recording medium corresponding to a high recording linear velocity at a lower power, it is necessary to improve sensitivity. As one method for that purpose, there is a method of reducing the reflectance of the medium. However, in the case of a DVD, since it is necessary to ensure compatibility with a DVD-ROM, the reflectance cannot be lowered more than necessary. For rewritable DVDs, the linear speed that has been commercialized in the past few years is the highest at 2.4 times speed, and can be recorded at higher linear speeds and can be backward compatible with conventional low linear speed drives. There is no such phase change optical recording medium.
In order to satisfy these requirements, it is necessary to find a recording material, medium configuration, and optimum recording method for a phase change optical recording medium that can be recorded with low power and that has a wide peak power margin. As such a recording method, there is a method described in Patent Document 1 in which the bias power application end time at the end of the pulse is eliminated regardless of the recording linear velocity in the conventional method of forming a recording mark. However, with this method, it is difficult to deal with a wide linear velocity and obtain good recording characteristics.

また、記録線速に応じてピークパワー印加時間を変え、パルスの最後部のバイアスパワー印加終了時間を設けるという特許文献2記載の方法がある。
更に、この方法を基にした、記録半径位置の内周から外周に向かって記録線速が連続的に変化するCAV方式に対応した記録方法として特許文献3記載の方法がある。しかし、この方法では、先頭部のピークパワー印加開始時間を、線速の変化に応じてウインドウ幅に一定の比例定数を乗じた時間で制御しているものの、パルス列最後部のバイアスパワー印加終了時間に制限があって、高線速記録の特性が十分得られない場合がある。
上記の他に、最高線速2.4倍速対応ドライブと記録再生互換性があり、かつ最高線速4倍速で記録可能な媒体に対するCAV記録に対応可能な記録方法に関するものとして、特願2002−261281号(本出願人の先願)がある。
しかし、この発明では、先頭部のピークパワー印加開始時間の制御が十分でなく、記録特性の項目によっては良好な特性が得られない場合がある。
Further, there is a method described in Patent Document 2 in which the peak power application time is changed according to the recording linear velocity, and the bias power application end time is provided at the end of the pulse.
Furthermore, as a recording method corresponding to the CAV method in which the recording linear velocity continuously changes from the inner circumference to the outer circumference of the recording radius position based on this method, there is a method described in Patent Document 3. However, in this method, although the peak power application start time at the beginning is controlled by a time obtained by multiplying the window width by a constant proportional constant according to the change in linear velocity, the bias power application end time at the end of the pulse train is controlled. In some cases, the characteristics of high linear velocity recording cannot be obtained sufficiently.
In addition to the above, Japanese Patent Application No. 2002-2002 relates to a recording method compatible with CAV recording on a medium that is compatible with recording and reproduction with a maximum linear speed of 2.4 × speed and can be recorded at the maximum linear speed of 4 ×. No. 261281 (the prior application of the present applicant).
However, in the present invention, the peak power application start time at the head is not sufficiently controlled, and good characteristics may not be obtained depending on the item of recording characteristics.

特許第2941703号公報Japanese Patent No. 2941703 特開2001−060319号公報JP 2001-060319 A 特開平2000−149262号公報JP 2000-149262 A

相変化型光記録媒体は、高線速記録に適した媒体にするために媒体構成、記録材料を最適化すると、低線速から高線速まで記録可能にするためには照射するパルス状の光のパルス時間制御だけでは、広い線速範囲で良好な特性を得ることが難しい。しかし、媒体を使用する側にとっては、同一媒体で広い線速をカバーしていれば、線速毎に媒体を使い分ける必要がないので都合がよい。そのための方法としては、より高いピークパワーを照射し、記録方法を最適化すれば一応記録は可能になる。
しかし、従来の方法では、所定の長さのマークを記録する際に、照射パルス列の先頭部のピークパワー印加開始時間を、記録線速毎に精度よく制御しないと、記録特性であるアシンメトリーが適性な範囲に入り難くなり、記録データを正しく再生できず、データエラーになってしまう。これに伴い、ピークパワーに対する特性のマージンが狭くなるため、記録信号品質がより劣化し易くなる。
そこで、本発明では、ピークパワーの低い低線速対応ドライヴで記録が可能で、且つ高線速対応ドライヴでも記録が可能な相変化型光記録媒体に対して、高速でランダムにアクセスし記録できるCAV対応のドライブにより記録するための光記録方法の提供を目的とする。
また、本発明では、低いピークパワー範囲で低線速記録が可能で且つ高いピークパワー範囲で高線速記録が可能な相変化型光記録媒体に対して、媒体の内周部から外周部に亘って線速が低線速から高線速まで連続的に変化するCAV記録を行うのに適した光記録方法の提供を目的とする。中でも、書き換え型DVD媒体であって、最高線速がDVDの4倍速であり、且つ1倍速〜2.4倍速で記録するドライブとの下位互換が可能な光記録媒体に対して有効な光記録方法の提供を目的とする。
更に、上記光記録方法に対応可能な相変化型光記録媒体の提供を目的とする。
The phase change type optical recording medium has a pulse-like shape to be irradiated to enable recording from a low linear velocity to a high linear velocity by optimizing the medium configuration and recording material in order to make the medium suitable for high linear velocity recording. It is difficult to obtain good characteristics in a wide linear velocity range only by controlling the pulse time of light. However, it is convenient for the user who uses the medium, as long as the same medium covers a wide linear velocity, it is not necessary to use a different medium for each linear velocity. As a method for that purpose, if a higher peak power is irradiated and the recording method is optimized, recording becomes possible.
However, in the conventional method, when recording a mark of a predetermined length, if the peak power application start time at the head of the irradiation pulse train is not accurately controlled for each recording linear velocity, asymmetry as a recording characteristic is appropriate. The recorded data cannot be properly reproduced, resulting in a data error. Along with this, the characteristic margin with respect to the peak power is narrowed, so that the recording signal quality is more likely to deteriorate.
Therefore, in the present invention, it is possible to randomly access and record at high speed on a phase change optical recording medium that can be recorded by a low linear velocity drive with low peak power and can be recorded by a high linear velocity drive. An object of the present invention is to provide an optical recording method for recording with a CAV-compatible drive.
In the present invention, the phase change type optical recording medium capable of low linear velocity recording in a low peak power range and high linear velocity recording in a high peak power range is changed from the inner peripheral portion to the outer peripheral portion of the medium. An object of the present invention is to provide an optical recording method suitable for performing CAV recording in which the linear velocity continuously changes from a low linear velocity to a high linear velocity. In particular, optical recording is effective for an optical recording medium that is a rewritable DVD medium and has a maximum linear velocity of 4 times that of DVD and can be backward compatible with a drive that records at 1 to 2.4 times speed. The purpose is to provide a method.
It is another object of the present invention to provide a phase change type optical recording medium that is compatible with the above optical recording method.

上記課題は次の1)〜)の発明(以下、本発明1〜という)によって解決される。
1) 相変化型光記録媒体に対し、記録可能な最低線速と最高線速の範囲内の線速を用い、ピークパワー(Pp)、消去パワー(Pe)及びバイアスパワー(Pb)の3値で照射パワーを制御し、マーク形成時はピークパワー(Pp)とバイアスパワー(Pb)をパルス状に交互に印加し、前記マーク形成のためのパルス印加時間を、内周部から外周部に向けて変化する線速に対応したウインドウ幅Twで変化させる記録方法(CAV記録)において、先頭部のピークパワー印加開始時間の基準〔記録マーク信号の先頭(立ち上がり)から1Twシフトした時間〕をa、最後部のバイアスパワー印加終了時間の基準〔記録マーク信号の後端(立ち下がり)に相当する時間〕をbとして、変化する各線速毎に基準aに対する先頭部のピークパワーの印加を開始するまでの時間(dTtop)を、ウインドウ幅Twの(k/16)倍(kは整数)とすることを特徴とする光記録方法。
2) ピークパワー印加時間(Ttop)、中間部の印加時間(Tmp)、及び、基準bに対する最後部のバイアスパワーの印加を終了するまでの時間(dTera)のうちの少なくとも一つを、ウインドウ幅Twの(k/16)倍(kは整数)で変化させることを特徴とする1)記載の光記録方法。
3) ピークパワー印加時間(Ttop)及び中間部の印加時間(Tmp)が、固定された時間(定数項)を有することを特徴とする2)記載の光記録方法。
4) 線速が速くなるに従い、前記(dTtop)を減少させ、前記(dTera)を増加させる(即ち、最後部のバイアスパワー印加時間を減少させる)ことを特徴とする1)〜3)の何れかに記載の光記録方法。
) 記録可能な線速の範囲が、基準線速の1.0倍以上、4.00倍以下であることを特徴とする1)〜)の何れかに記載の光記録方法。
) 最低線速が基準線速に対して1.65倍速、最高線速と最低線速の間の速度が基準線速に対して2.83倍速、最高線速が基準線速に対して4.00倍速である各線速毎の(dTtop)、(Ttop)、(Tmp)及び(dTera)の情報が予め記録されていることを特徴とする1)〜)の何れかに記載の記録方法に対応可能な相変化型光記録媒体。
The above problems are solved by the following inventions 1) to 6 ) (hereinafter referred to as the present inventions 1 to 6 ).
1) Three values of peak power (Pp), erasing power (Pe), and bias power (Pb) using a linear velocity within the range of the lowest linear velocity that can be recorded and the highest linear velocity for the phase change type optical recording medium. The irradiation power is controlled by applying a peak power (Pp) and a bias power (Pb) alternately at the time of mark formation, and the pulse application time for the mark formation is directed from the inner periphery to the outer periphery. In the recording method (CAV recording) for changing the window width Tw corresponding to the linear velocity that changes, the reference of the peak power application start time at the beginning [time shifted by 1 Tw from the beginning (rise) of the recording mark signal] is a, The peak power of the head portion relative to the reference a is set for each changing linear velocity, where b is the reference of the end time of bias power application at the last portion (the time corresponding to the trailing edge (falling edge) of the recording mark signal). The optical recording method characterized in that the time (dTtop) until the start of application of-is set to (k / 16) times (k is an integer) times the window width Tw.
2) At least one of the peak power application time (Ttop), the intermediate application time (Tmp), and the time (dTera) until the application of the bias power at the last part with respect to the reference b is determined as the window width. The optical recording method according to 1), wherein the optical recording method is changed by (k / 16) times Tw (k is an integer).
3) The optical recording method according to 2), wherein the peak power application time (Ttop) and the intermediate application time (Tmp) have a fixed time (constant term).
4) Any of 1) to 3), wherein (dTtop) is decreased and (dTera) is increased (that is, the last bias power application time is decreased) as the linear velocity increases. An optical recording method according to claim 1.
5 ) The optical recording method according to any one of 1) to 4 ), wherein the recordable linear velocity range is 1.0 to 4.00 times the reference linear velocity.
6 ) The minimum linear speed is 1.65 times the reference linear speed, the speed between the highest and the lowest linear speed is 2.83 times the reference linear speed, and the highest linear speed is the reference linear speed. Recording according to any one of 1) to 5 ), wherein (dTtop), (Ttop), (Tmp), and (dTera) information is recorded in advance for each linear velocity of 4.00 times speed A phase change optical recording medium compatible with the method.

以下、上記本発明について詳しく説明する。
本発明は、例えば直径120mmの相変化型光記録媒体に対して、ユーザーデータ領域の最内周半径位置24mmから最外周半径位置58mm付近までCAV記録を行なう場合に、記録可能な最低線速と最高線速の範囲内の線速を用い、ピークパワー(Pp)、消去パワー(Pe)及びバイアスパワー(Pb)の3値で照射パワーを制御し、マーク形成時はピークパワー(Pp)とバイアスパワー(Pb)をパルス状に交互に印加し、前記マーク形成のためのパルス印加時間を、内周部から外周部に向けて変化する線速に対応したウインドウ幅Twで変化させると共に、先頭部のピークパワー印加開始時間の基準〔記録マーク信号の先頭(立ち上がり)から1Tシフトした時間〕をa、最後部のバイアスパワー印加終了時間の基準〔記録マーク信号の後端(立ち下がり)に相当する時間〕をbとして、各線速毎に基準aに対する先頭部のピークパワーの印加を開始するまでの時間(dTtop)を、ウインドウ幅Twの(k/16)倍(kは整数)とするものである。
これにより、広い線速範囲で良好な記録特性を得ることが可能となる。中でもアシンメトリーの改善に有効な記録方法である。また、最低記録線速と中間線速までの線速範囲においては、更に低いピークパワーでCAV記録が可能になる。
後述する表1に示したように、(dTtop)は線速毎に変化する。
Hereinafter, the present invention will be described in detail.
In the present invention, for example, when performing CAV recording on a phase change optical recording medium having a diameter of 120 mm from the innermost radial position of 24 mm to the vicinity of the outermost radial position of 58 mm in the user data area, Using a linear velocity within the range of the maximum linear velocity, the irradiation power is controlled by three values of peak power (Pp), erasing power (Pe), and bias power (Pb). At the time of mark formation, peak power (Pp) and bias are controlled. The power (Pb) is alternately applied in the form of pulses, and the pulse application time for forming the mark is changed with the window width Tw corresponding to the linear velocity changing from the inner periphery toward the outer periphery, and the leading portion reference peak power application start time of the [recording mark signal of the first time that 1T shifted from (rise)] a, the end portion of the bias power criteria applied end time [recorded mer The time corresponding to the trailing edge of the signal (falling)] as b, and each each linear velocity, time to start the application of the peak power of the head portion relative to the reference a a (dTtop), a window width Tw (k / 16) Multiply (k is an integer).
Thereby, it is possible to obtain good recording characteristics in a wide linear velocity range. In particular, this is an effective recording method for improving asymmetry. In the linear velocity range from the lowest recording linear velocity to the intermediate linear velocity, CAV recording can be performed with a lower peak power.
As shown in Table 1 described later, (dTtop) changes for each linear velocity.

本発明4は、内周側の低線速記録から外周側の高線速記録まで、更に良好な記録特性を得るのに有効な記録方法である。基準線速の4.00倍のような高線速で記録した場合、記録層はアモルファスに近い状態になっている。従って、記録線速を高速にしていく場合に、本発明4のように最後部のバイアスパワー印加時間を減少させてもよく、更に0にすることもできる。
本発明は、特に好ましい記録線速範囲に関するものである。なお、DVDの基準線速は、3.49m/sである。
本発明の光記録媒体では、基準線速の1.65倍速、2.83倍速、4.00倍速に相当する各線速毎の(dTtop)、(Ttop)、(Tmp)及び(dTera)の情報が予め記録されているので、本発明1〜の何れかの記録方法に対応可能である。なお、通常の場合、ストラテジに関する情報は予め媒体に記録されている。
The present invention 4 is an effective recording method for obtaining better recording characteristics from low linear velocity recording on the inner circumference side to high linear velocity recording on the outer circumference side. When recording is performed at a high linear velocity such as 4.00 times the reference linear velocity, the recording layer is in an almost amorphous state. Therefore, when the recording linear velocity is increased, the last bias power application time may be decreased as in the fourth aspect of the present invention, and can be further reduced to zero.
The present invention 5 relates to a particularly preferable recording linear velocity range. Note that the reference linear velocity of DVD is 3.49 m / s.
In the optical recording medium of the sixth aspect , (dTtop), (Ttop), (Tmp), and (dTera) for each linear velocity corresponding to 1.65 times, 2.83 times, and 4.00 times the reference linear velocity. Since the information is recorded in advance, the recording method according to any one of the first to fifth aspects of the present invention can be supported. In a normal case, information on the strategy is recorded in advance on the medium.

本発明の対象となる相変化型光記録媒体は、レーザーの波長が400〜780nmの範囲で記録再生可能なものである。例えばDVDの場合、レーザーの波長650〜665nm、対物レンズの開口率0.60〜0.65として、入射光のビーム径が1μm以下であり、最短マーク長は0.4μmである。
DVDの1倍速は、線速約3.5m/s(3.49m/s)であり、クロック周波数は26.16MHz(Tw:38.2ナノ秒)になる。DVDの4倍速は、線速約14m/s(13.96m/s)になり、クロック周波数は104.6MHz(Tw:9.56ナノ秒)である。
本発明において、特に最大記録線速14m/sに最適な光記録媒体を、直径120mmでデータ記録開始の最内周半径位置24mmから最外周半径位置58mm付近までをCAV記録する場合、1.65倍速から4倍速(中間線速2.83倍速)と、1倍速から2.4倍速の2種類のCAV記録を行う。
The phase-change optical recording medium that is the subject of the present invention is one that can be recorded and reproduced in a laser wavelength range of 400 to 780 nm. For example, in the case of DVD, the laser beam wavelength is 650 to 665 nm, the objective lens has an aperture ratio of 0.60 to 0.65, the beam diameter of incident light is 1 μm or less, and the shortest mark length is 0.4 μm.
The 1 × speed of DVD is about 3.5 m / s (3.49 m / s), and the clock frequency is 26.16 MHz (Tw: 38.2 nanoseconds). The quadruple speed of DVD is about 14 m / s (13.96 m / s), and the clock frequency is 104.6 MHz (Tw: 9.56 nanoseconds).
In the present invention, an optical recording medium particularly suitable for a maximum recording linear velocity of 14 m / s is 1.65 when CAV recording is performed at a diameter of 120 mm from the innermost peripheral radial position of 24 mm to the outermost peripheral radial position of around 58 mm. Two types of CAV recording are performed, from double speed to quadruple speed (intermediate linear speed 2.83 times speed) and from single speed to 2.4 times speed.

本発明の対象となる光記録媒体はこのような記録が可能な媒体であり、更に記録方法により良好な特性を得るため、発光波形を以下のようにする。
図1は、本発明で用いる記録消去のための発光波形である。照射パワーとして、ピークパワー(Pp)、消去パワー(Pe)、バイアスパワー(Pb)があり、ピークパワーを照射して記録層を加熱するための先頭部のピークパワー(加熱パルス)印加時間Ttop、中間部のピークパワー(加熱パルス)印加時間Tmp、後端部のピークパワー(加熱パルス)印加時間Tmpと、バイアスパワーを照射するバイアスパワー(冷却パルス)印加時間があり、更に、中間部のピークパワー印加時間Tmpと、バイアスパワー印加時間の和がウインドウ幅Twになっている。パルスの数はマーク長nTw(n=3〜14)に対し、(n−1)又は(n−2)個である。
CAV記録に対応するため、ピークパワー印加時間を各線速に対応したウィンドウ幅Twに比例する時間と固定された時間で制御することにより、ウィンドウ幅Twに比例させて制御すると、時間を固定する場合に比べて、実際のピークパワー印加時間を線速変化に対し連続的に増加させることができ、ある途中の線速からパルス時間を不連続にすることなく記録できる。
The optical recording medium which is the subject of the present invention is a medium capable of such recording, and in order to obtain good characteristics by the recording method, the emission waveform is as follows.
FIG. 1 shows a light emission waveform for recording and erasing used in the present invention. The irradiation power includes peak power (Pp), erasing power (Pe), and bias power (Pb). The peak power (heating pulse) application time Ttop for heating the recording layer by irradiating the peak power, There is a peak power (heating pulse) application time Tmp in the middle part, a peak power (heating pulse) application time Tmp in the rear end part, and a bias power (cooling pulse) application time for irradiating the bias power. The sum of the power application time Tmp and the bias power application time is the window width Tw. The number of pulses is (n−1) or (n−2) for the mark length n Tw (n = 3 to 14).
In order to support CAV recording, the peak power application time is controlled by a time proportional to the window width Tw corresponding to each linear velocity and a fixed time, thereby controlling the time proportional to the window width Tw. In comparison with the above, the actual peak power application time can be continuously increased with respect to the change in linear velocity, and recording can be performed without making the pulse time discontinuous from a certain linear velocity.

従来は、1倍速〜2.4倍速の範囲で記録する場合、ピークパワー印加時間をウィンドウ幅Twに比例する時間と固定された時間の和で制御する以外に、先頭部のピークパワー印加開始時間は線速に依らず一定とし、最後部のバイアスパワーの印加終了時間を線速毎に変えて最適なマークを形成することができた。
しかし、4倍速記録と下位互換が両立できる記録媒体の場合、1.65倍速〜4倍速の線速範囲では、この方法をそのまま適用しても、CAV記録において良好な特性を得られなくなる。4倍速記録を基準にして先頭部のピークパワー印加開始時間を決めてしまうと、低線速側で短いマークが所定のマーク長より短くなる傾向があるからである。そのため、短いマークの再生エラーが起き易くなる。
Conventionally, when recording in the range of 1 × to 2.4 × speed, in addition to controlling the peak power application time by the sum of the time proportional to the window width Tw and the fixed time, the peak power application start time at the head portion It was possible to form an optimum mark by changing the end time of applying the bias power at the last part for each linear velocity, regardless of the linear velocity.
However, in the case of a recording medium compatible with 4 × speed recording and backward compatibility, in the linear velocity range of 1.65 × to 4 × speed, even if this method is applied as it is, good characteristics cannot be obtained in CAV recording. This is because if the peak power application start time at the head portion is determined based on the quadruple speed recording, a short mark tends to be shorter than a predetermined mark length on the low linear velocity side. Therefore, a reproduction error of a short mark is likely to occur.

これに対し、本発明では、図1における先頭部のピークパワーの印加を開始するまでの時間(dTtop)を、各線速毎に、形成しようとする少なくとも2つの長さのマークについて、ウインドウ幅Twの(k/16)倍(kは整数)とすることにより、低線速から高線速まで良好な記録特性を得ることができる。また、この場合、低線速側は、先頭部のピークパワー印加開始時間を基準(図1のa)より速くし(手前とし)、高線速になるほど遅くするように連続性を持たせると良い。
同時に最後部のバイアスパワー印加終了時間を、基準(図1のb)より、低線速側では遅く(バイアスパワー印加時間が長くなる)、高線速側では速く(バイアスパワー印加時間が短くなる)なるようにウィンドウ幅Twに比例する部分を連続的に変える。これは、光記録媒体にも依るが、本発明で対象とする媒体においては最適な方法になる。特に最高線速である4倍速記録では、最後部のバイアスパワー印加時間を0にするか又は限りなく0に近付け、低線速側、特に1倍速においてウィンドウ幅Tw程度の時間印加することが好ましい。これらの方法に特に有効な線速範囲は、1.65倍速〜4倍速である。
On the other hand, in the present invention, the time (dTtop) until the start of application of the peak power at the head in FIG. 1 is set to the window width Tw for at least two lengths of marks to be formed for each linear velocity. (K / 16) times (k is an integer), good recording characteristics can be obtained from a low linear velocity to a high linear velocity. Also, in this case, the low linear velocity side has a continuity so that the peak power application start time at the beginning is made faster (front) than the reference (a in FIG. 1), and becomes slower as the linear velocity becomes higher. good.
At the same time, the bias power application end time at the last part is slower on the low linear velocity side (the bias power application time is longer) and faster on the high linear velocity side (the bias power application time is shorter than the reference (b in FIG. 1)). ) So that the portion proportional to the window width Tw is continuously changed. This depends on the optical recording medium, but is an optimum method for the medium targeted by the present invention. In particular, in quadruple speed recording, which is the highest linear velocity, it is preferable to apply the bias power application time at the last part to 0 or as close as possible to zero, and to apply the time of about the window width Tw on the low linear velocity side, particularly at 1 × speed. . A linear velocity range particularly effective for these methods is 1.65 times speed to 4 times speed.

ウィンドウ幅Twに比例する係数は、4倍速記録の場合の記録装置で制御可能な時間から決められる。例えば0.5ナノ秒であれば、9.56ナノ秒×c=0.5ナノ秒から、c≒1/20(=0.05)となり、Tw/20が最小制御時間になる。媒体に応じて係数i(0,1,2,3,…)を決め、i×Tw/20で制御する。
一方、固定時間も同様に線速に応じて連続的にパルス時間を制御できるように記録装置で制御可能な時間から決められる。0.5ナノ秒を最小とすれば、0.5×j(j=1,2,3,…)で表される時間で制御する。加熱パルス時間は、i×(Tw/20)+0.5×jという時間で記録線速が変わると共に、線速に対応したウインドウ幅Twが変化するため、CAV記録が可能になる。
更に、先頭のピークパワー印加時間とその後の中間部や後端部のピークパワー印加時間とが異なるようにしても良い。即ち、Ttop≠Tmpとしてもよい。Ttop、Tmpは、時間幅としては、0.2×Tw〜0.8×Twの範囲が好ましい。
The coefficient proportional to the window width Tw is determined from the time controllable by the recording apparatus in the case of quadruple speed recording. For example, in the case of 0.5 nanoseconds, from 9.56 nanoseconds × c = 0.5 nanoseconds, c≈1 / 20 (= 0.05), and Tw / 20 is the minimum control time. The coefficient i (0, 1, 2, 3,...) Is determined according to the medium, and is controlled by i × Tw / 20.
On the other hand, the fixed time is also determined from the time controllable by the recording apparatus so that the pulse time can be continuously controlled according to the linear velocity. If 0.5 nanosecond is set to the minimum, the time is controlled by 0.5 × j (j = 1, 2, 3,...). The heating pulse time is i × (Tw / 20) + 0.5 × j. The recording linear velocity changes and the window width Tw corresponding to the linear velocity changes, so that CAV recording is possible.
Furthermore, the peak power application time at the beginning may be different from the peak power application time at the subsequent intermediate or rear end. That is, Ttop ≠ Tmp may be set. Ttop and Tmp preferably have a time width of 0.2 × Tw to 0.8 × Tw.

また、c=1/16とし、dTtopはk×(Tw/16)とした場合、位置aに対し遅れる側を(−)側、速く開始する側を(+)側とすれば、4倍速は、−(3×Tw/16)、1.65倍速は(3×Tw/16)、中間線速2.83倍速は0×Tw/16が良く、係数を比較するとこれらは線形に変化しているので、CAV記録が可能である。
また、dTeraに係る最後部のバイアスパワー印加終了時間(図1ではdTeraの左端の位置)は、位置bに対し、速くする場合は(+)側、遅くする場合、即ちバイアスパワー印加時間を長くする場合は(−)側とする。4倍速、2.83倍速、1.65倍速の順にdTeraは+(8Tw/16)、+(2Tw/16)、+0とする。
dTtopの範囲は、−0.5〜1Twがよいが、好ましくは、−0.25〜0.5Twがよい。
dTeraは、−1.0〜+0.7Twがよいが、好ましくは、−0.5〜+0.6Twがよい。
Also, when c = 1/16 and dTtop is k × (Tw / 16), if the side delayed with respect to the position a is the (−) side and the side that starts fast is the (+) side, the quadruple speed is ,-(3 × Tw / 16), 1.65 times speed is (3 × Tw / 16), medium linear speed 2.83 times speed is 0xTw / 16, and comparing coefficients, these change linearly Therefore, CAV recording is possible.
In addition, the last bias power application end time related to dTera (the position of the left end of dTera in FIG. 1) is (+) side when making it faster than the position b, and when making it slower, that is, the bias power application time is made longer. When doing so, it shall be on the (-) side. DTera is set to + (8Tw / 16), + (2Tw / 16), and +0 in the order of 4 × speed, 2.83 × speed, and 1.65 × speed.
The range of dTtop is preferably -0.5 to 1 Tw, but is preferably -0.25 to 0.5 Tw.
dTera is preferably −1.0 to +0.7 Tw, and preferably −0.5 to +0.6 Tw.

このようにして発光パルス時間を調整することで十分な記録特性が得られる。
特に、dTtopを線速毎にピークパワー、消去パワー、バイアスパワーは、ディスクの盤面で、それぞれ最大22mW、12mW、1mWである。線速が最大8.5m/s、最大ピークパワーが16mWの下位記録再生装置に対してのCAV記録に対しても同様である。
これらの記録方法に適し、かつ低線速から高線速まで広い範囲で記録が可能な光記録媒体の条件は、記録を行うための最大ピークパワーの20%以上に相当する消去パワーを連続的に照射することにより、最高線速で未記録状態よりも反射率が減少し、かつ最低線速では少なくとも減少しないことである。
ピークパワーが最大22mWの場合、その50%にあたる11mWの消去パワーを連続的に照射した後、本発明の対象となる光記録媒体は、線速が8〜11m/s以上で反射率が未記録状態よりも下がる。反射率が下がり始める好ましい線速範囲は9.5〜11m/sである。記録線速14m/sでは、反射率が未記録状態よりも30〜70%減少する。一方、記録線速3.5m/sでは、未記録状態と同じか或いは未記録状態よりも反射率が高くなる。これにより、低い記録線速範囲を低いピークパワーで記録でき、かつ高線速でも記録が可能になる。
Thus, sufficient recording characteristics can be obtained by adjusting the light emission pulse time.
In particular, the peak power, erasing power, and bias power of dTtop for each linear velocity are 22 mW, 12 mW, and 1 mW at the maximum on the disk surface, respectively. The same applies to CAV recording for a lower level recording / reproducing apparatus having a maximum linear velocity of 8.5 m / s and a maximum peak power of 16 mW.
An optical recording medium suitable for these recording methods and capable of recording over a wide range from a low linear velocity to a high linear velocity is a continuous erasing power corresponding to 20% or more of the maximum peak power for recording. , The reflectance is reduced more than the unrecorded state at the highest linear velocity, and at least does not decrease at the lowest linear velocity.
When the peak power is 22 mW at the maximum, the erasing power of 11 mW corresponding to 50% of the peak power is continuously irradiated, and the optical recording medium targeted by the present invention has a linear velocity of 8 to 11 m / s or more and an unrecorded reflectance. Lower than the state. A preferable linear velocity range in which the reflectance starts to decrease is 9.5 to 11 m / s. At a recording linear velocity of 14 m / s, the reflectance is reduced by 30 to 70% as compared to the unrecorded state. On the other hand, at a recording linear velocity of 3.5 m / s, the reflectance is the same as that in the unrecorded state or higher than that in the unrecorded state. As a result, a low recording linear velocity range can be recorded with a low peak power, and recording can be performed even at a high linear velocity.

図2に示すのは本発明の対象となる光記録媒体の基本的層構成の一例であり、基板1上に、下部保護層2、界面層7、結晶相と非晶質相の可逆的相変化をする相変化記録層3、上部保護層4、硫化防止層5、反射層6の順に積層したものである。界面層は必要に応じて設ければよく、記録層と上部保護層の間にも設けることができる。
基板材料としては、記録再生光に対し透明な、ポリカーボネート(PC)、ポリメタアクリル酸(PMMA)などのプラスチック、或いはガラスを用いる。
下部保護層及び上部保護層の材料としては、各種誘電体を用いることができ、例えば、SiOx、ZnO、SnO、Al、TiO、In、MgO、ZrO、Ta等の金属酸化物;Si、AlN、TiN、BN、ZrN等の窒化物;ZnS、TaS等の硫化物;SiC、TaC、BC、WC、TiC、ZrC等の炭化物が挙げられる。
これらの材料は、単体だけでなく混合物として用いることもできる。中でも、ZnSとSiOの混合物が相変化型光記録媒体で一般的に用いられており、その混合比は80:20(モル比)が良い。
FIG. 2 shows an example of a basic layer structure of an optical recording medium that is an object of the present invention. On the substrate 1, a lower protective layer 2, an interface layer 7, a reversible phase of a crystalline phase and an amorphous phase. A phase change recording layer 3 that changes, an upper protective layer 4, an antisulfurization layer 5, and a reflective layer 6 are laminated in this order. The interface layer may be provided as necessary, and can also be provided between the recording layer and the upper protective layer.
As the substrate material, a plastic such as polycarbonate (PC) or polymethacrylic acid (PMMA) or glass transparent to recording / reproducing light is used.
As the material of the lower protective layer and upper protective layer, it is possible to use various dielectric, for example, SiOx, ZnO, SnO 2, Al 2 O 3, TiO 2, In 2 O 3, MgO, ZrO 2, Ta 2 Metal oxides such as O 5 ; nitrides such as Si 3 N 4 , AlN, TiN, BN, and ZrN; sulfides such as ZnS and TaS 4 ; carbides such as SiC, TaC, B 4 C, WC, TiC, and ZrC Is mentioned.
These materials can be used not only as a simple substance but also as a mixture. Among these, a mixture of ZnS and SiO 2 is generally used in phase change optical recording media, and the mixing ratio is preferably 80:20 (molar ratio).

下部保護層は、熱伝導率が低く、比熱が小さく、オーバーライトにより結晶化せず、加熱と急冷の多数回の履歴によるクラックの発生、元素の拡散などがないものが良い。ZnS・SiO(80:20)はこれらの条件を満たしており、上部保護層にも好ましく用いられる。
を3〜6モル%含むZrOも、屈折率がZnS・SiOとほぼ同じかそれよりも大きいので好ましい。ZrO単体では高温環境下に放置された場合、記録マークが結晶化により劣化し易い。
ZrO・Y(3モル%)とTiOとの混合物も好ましい。混合比は20:80(モル%)が良いが、TiO量は多くても70モル%とする。TiOのみの場合には、酸化物の膜としての安定性が良くなく、記録膜の構成元素と反応し易い。
酸化物としてはAlも良い。
The lower protective layer preferably has a low thermal conductivity, a low specific heat, does not crystallize due to overwriting, and does not generate cracks due to numerous history of heating and quenching, and does not diffuse elements. ZnS.SiO 2 (80:20) satisfies these conditions and is preferably used for the upper protective layer.
ZrO 2 containing 3 to 6 mol% of Y 2 O 3 is also preferable because its refractive index is almost the same as or larger than that of ZnS · SiO 2 . When ZrO 2 alone is left in a high temperature environment, the recording mark is likely to deteriorate due to crystallization.
A mixture of ZrO 2 .Y 2 O 3 (3 mol%) and TiO 2 is also preferable. The mixing ratio is preferably 20:80 (mol%), but the TiO 2 content is at most 70 mol%. In the case of only TiO 2 , the stability as an oxide film is not good, and it easily reacts with the constituent elements of the recording film.
Al 2 O 3 may also be used as the oxide.

界面層は、記録マーク端部の結晶成長を助けて消去比を高めオーバーライト特性を良くするために設けられる。その膜厚は、1〜5nmの範囲であれば効果を保ち且つ保存信頼性の劣化もかなり抑制されることが分った。
下部保護層の膜厚は、40〜250nmの範囲とし、45〜80nmが好ましい。40nmより薄くなると、耐環境保護機能の低下、放熱効果の低下を招き、繰り返しオーバーライト特性の劣化が大きくなる。250nmより厚くなると、スパッタ法等による製膜過程において、膜温度の上昇により膜剥離やクラックが生じる。
上部保護層の膜厚は、5〜50nmの範囲とし、8〜20nmが好ましい。5nmより薄いと記録感度が低下する。50nmより厚くなると、温度上昇による変形、放熱性の低下により繰り返しオーバーライト特性が悪くなる。
The interface layer is provided to assist crystal growth at the end of the recording mark to increase the erase ratio and improve the overwrite characteristics. It has been found that if the film thickness is in the range of 1 to 5 nm, the effect is maintained and deterioration of storage reliability is considerably suppressed.
The thickness of the lower protective layer is in the range of 40 to 250 nm, preferably 45 to 80 nm. If the thickness is less than 40 nm, the environmental resistance protection function and the heat dissipation effect are lowered, and the deterioration of the overwrite characteristic is increased repeatedly. When the thickness is greater than 250 nm, film peeling or cracking occurs due to an increase in film temperature in the film formation process by sputtering or the like.
The film thickness of the upper protective layer is in the range of 5 to 50 nm, preferably 8 to 20 nm. If it is thinner than 5 nm, the recording sensitivity is lowered. If it is thicker than 50 nm, the overwrite characteristics are deteriorated repeatedly due to deformation due to temperature rise and a decrease in heat dissipation.

反射層には、Al、Ag、Cu、Pd、Cr、Tiなどの金属材料又はそれらの合金が用いられるが、中でも熱伝導率が高いAg又はAg合金が好ましい。
しかし、Ag又はAg合金を用いる場合には、上部保護層中に含まれる硫黄によるAgの腐食を防止するため、反射層と上部保護層の間に硫化防止層を設ける必要がある。硫化防止層の材料については、これまでの検討の結果、Si、SiCが好ましいことが分った。ZrO、MgO、TiOxも適している。
SiCは、膜厚を3nm位に薄くしてもその効果が高いが、少なくとも2nmは必要であり、上限は10nmである。これ以上厚くすると、反射層との距離が離れるため、放熱効率が下がってしまうし、吸収係数が高いために反射率が低下してしまう。
反射層の膜厚は、50〜250nmが良い。膜厚が厚くなり過ぎると放熱性は向上するが、薄膜を作製する間に媒体の温度上昇により基板の変形が起きてしまう。薄すぎると放熱性が悪くなり記録特性が劣化する。
The reflective layer is made of a metal material such as Al, Ag, Cu, Pd, Cr, or Ti, or an alloy thereof. Among them, Ag or an Ag alloy having a high thermal conductivity is preferable.
However, when Ag or an Ag alloy is used, it is necessary to provide a sulfidation preventive layer between the reflective layer and the upper protective layer in order to prevent corrosion of Ag by sulfur contained in the upper protective layer. As a result of the examination so far, it has been found that Si and SiC are preferable for the material of the sulfidation prevention layer. ZrO 2 , MgO, TiOx are also suitable.
Although the effect of SiC is high even if the film thickness is reduced to about 3 nm, at least 2 nm is necessary and the upper limit is 10 nm. If it is thicker than this, the distance from the reflective layer is increased, so that the heat radiation efficiency is lowered, and the reflectance is lowered because the absorption coefficient is high.
The thickness of the reflective layer is preferably 50 to 250 nm. If the film thickness becomes too thick, the heat dissipation is improved, but the substrate is deformed by the temperature rise of the medium during the production of the thin film. If it is too thin, the heat dissipation will deteriorate and the recording characteristics will deteriorate.

相変化記録層には、これまでSb70Te30付近の共晶組成を基本とし、Ag、In、更にはGeを添加したAgInSbTe系、AgInSbTeGe系が高線速かつ高密度記録に適した材料系であるため用いられてきた。SbのTeに対する比率が大きくなるほど結晶化速度が速くなり、また、Sb量が80原子%を超えると結晶化速度は速くなるものの、保存性が極端に悪くなり、しかも非晶質相を形成し難くなる。従って、高線速記録に対応するための好ましい量は65〜80原子%の範囲である。一方、Teは、15〜25原子%が良い。
Geは記録したマークの高温環境下での保存性を向上させるのに必須の元素である。GeとTeの結合エネルギーが大きく、しかもGe添加量が増加する程、結晶化温度が高くなるため保存性が良くなると考えられる。しかし、あまり多く入れると結晶化温度が更に高くなり、結晶化速度が遅くなるのでGeの添加量は5原子%以下がよい。
For phase change recording layers, AgInSbTe and AgInSbTeGe systems that have been based on a eutectic composition near Sb 70 Te 30 so far, and that contain Ag, In, and Ge are suitable for high linear velocity and high density recording. Has been used. As the ratio of Sb to Te increases, the crystallization speed increases. When the Sb content exceeds 80 atomic%, the crystallization speed increases, but the storage stability becomes extremely poor and an amorphous phase is formed. It becomes difficult. Therefore, a preferable amount for dealing with high linear velocity recording is in the range of 65 to 80 atomic%. On the other hand, Te is preferably 15 to 25 atomic%.
Ge is an essential element for improving the storage stability of recorded marks in a high temperature environment. It is considered that as the binding energy of Ge and Te is larger and the Ge addition amount is increased, the crystallization temperature becomes higher and the storage stability is improved. However, if too much is added, the crystallization temperature is further increased and the crystallization rate is lowered, so the addition amount of Ge is preferably 5 atomic% or less.

Agは記録したマークを安定化させるが、結晶化温度を高くする作用はあまりない。しかし、多く入れ過ぎると、結晶化速度を下げてしまうため、あまり多く入れることはできない。従って、Agの添加量は3原子%以下が良い。
Inは、結晶化速度を上げると共に、結晶化温度を上げるので保存性も向上させるが、多く入れると偏析し易く、繰り返しオーバーライト特性の劣化と再生光パワーに対する劣化が起きるので、その添加量は5原子%以下が良い。
In以外に結晶化速度を速くするものとしてGa、Mnがある。Gaは同量のInに比べ、結晶化速度をより速くするが、結晶化温度もより高くなるため、5原子%以下の範囲で添加するのが良い。Mnは多くても5原子%添加すれば充分である。更に、Gaを添加し結晶化速度と保存性を向上させる系も有効である。
相変化記録層の膜厚は、10〜20nmがよく、10nmより薄いと結晶相と非晶質相の反射率差が小さくなり、20nmより厚いと記録感度、繰り返しオーバーライト特性が悪くなる。
Ag stabilizes the recorded marks, but has little effect on increasing the crystallization temperature. However, if too much is added, the crystallization speed is lowered, so that much cannot be added. Therefore, the addition amount of Ag is preferably 3 atomic% or less.
In increases the crystallization speed and increases the crystallization temperature, which improves the storage stability. However, if it is added in a large amount, it tends to segregate and repeatedly deteriorates the overwrite characteristics and the reproduction light power. 5 atomic% or less is good.
In addition to In, there are Ga and Mn to increase the crystallization speed. Ga makes the crystallization speed faster than the same amount of In, but the crystallization temperature becomes higher, so it is preferable to add it in the range of 5 atomic% or less. It is sufficient to add Mn at most 5 atomic%. Furthermore, a system in which Ga is added to improve the crystallization speed and storage stability is also effective.
The film thickness of the phase change recording layer is preferably 10 to 20 nm, and if it is thinner than 10 nm, the difference in reflectance between the crystalline phase and the amorphous phase becomes small, and if it is thicker than 20 nm, the recording sensitivity and repetitive overwriting characteristics deteriorate.

以上のことから、本発明の対象となる相変化型光記録媒体の各層の好ましい膜厚は、界面層2〜4nm、相変化記録層11〜13nm、上部保護層10〜15nm、硫化防止層3〜5nm、Ag反射層120〜160nmである。この場合に、下部保護層の膜厚は、40〜80nmの範囲が良く、55nm付近で反射率が最も低くなり、この膜厚に対し、±5nmの範囲で特に特性が良い。
基板は、マークが書き込まれる溝部と溝部のピッチ0.74μm、溝深さ15〜45nm、溝幅0.2〜0.3μmとする。溝は、約820kHzの周期を持つ蛇行状の溝とする。アドレス部は、蛇行溝の周波数の位相を変調させ、この位相変化部分を検出し、2値化信号に変換してアドレス(番地)を読み取る。この蛇行部の振幅は、5〜20nmである。記録線密度は、0.267μm/bitで、(8−16)変調方式で記録する。
From the above, the preferred film thicknesses of the respective layers of the phase change optical recording medium to be the subject of the present invention are 2 to 4 nm for the interface layer, 11 to 13 nm for the phase change recording layer, 10 to 15 nm for the upper protective layer, and the antisulfurization layer 3. -5 nm, Ag reflection layer 120-160 nm. In this case, the thickness of the lower protective layer is preferably in the range of 40 to 80 nm, the reflectance is the lowest in the vicinity of 55 nm, and the characteristics are particularly good in this range of ± 5 nm.
The substrate has a groove-to-mark groove pitch of 0.74 μm, a groove depth of 15 to 45 nm, and a groove width of 0.2 to 0.3 μm. The groove is a serpentine groove having a period of about 820 kHz. The address part modulates the phase of the frequency of the meandering groove, detects this phase change part, converts it into a binary signal, and reads the address (address). The amplitude of the meandering portion is 5 to 20 nm. The recording linear density is 0.267 μm / bit, and recording is performed by the (8-16) modulation method.

低いピークパワー範囲で低線速記録可能で且つ高いピークパワー範囲で高線速記録可能な相変化型光記録媒体に対して、媒体の内周部から外周部に亘って線速が低線速から高線速まで連続的に変化するCAV記録を行うのに適した光記録方法を提供できる。中でも、書き換え型DVD媒体であって、最高線速がDVDの4倍速であり、かつ1倍速〜2.4倍速で記録するドライブとの下位互換が可能な光記録媒体に対して有効な光記録方法を提供できる。更に、上記光記録方法に対応可能な相変化型光記録媒体を提供できるCompared to phase change optical recording media that can record at low linear velocity in the low peak power range and record at high linear velocity in the high peak power range, the linear velocity is low from the inner periphery to the outer periphery of the medium. An optical recording method suitable for performing CAV recording that continuously changes from a high linear velocity to a high linear velocity can be provided. In particular, optical recording is effective for an optical recording medium that is a rewritable DVD medium and has a maximum linear velocity of 4 times that of DVD and can be backward compatible with a drive that records at 1 to 2.4 times speed. Can provide a method. Furthermore, it is possible to provide a phase change type optical recording medium that can cope with the above optical recording method.

以下、実施例により本発明を更に具体的に説明するが、本発明はこれらの実施例により限定されるものではない。   EXAMPLES Hereinafter, although an Example demonstrates this invention further more concretely, this invention is not limited by these Examples.

実施例1
相変化型光記録媒体を以下のようにして作製した。
溝にマークを記録するための溝ピッチ0.74μm、溝幅0.25μm、溝深さ25nm、厚さ0.6mmのポリカーボネート製基板を用い、この上にスパッタリング方式により各層を積層した。
まず、ZnS:SiO=80:20(モル%)のターゲットを使用し、膜厚54nmの下部保護層を設けた。
次に、Ge:Ag:In:Sb:Te=3.8:0.3:3.5:72:20.4という組成のターゲットを使用し、膜厚12nmの相変化記録層を設けた。
次に、ZrO・Y(3モル%)・TiO(20モル%)複合酸化物ターゲットを使用し、膜厚3nmの界面層を設けた。
次に、ZnS:SiO=80:20(モル%)のターゲットを使用し、膜厚11nmの上部保護層を設けた。
次に、膜厚4nmのSiC層(硫化防止層)と膜厚140nmのAg反射層を設けた後、耐環境性を向上させるために、大日本インキ製SD318紫外線硬化樹脂を5μmの厚さで塗布後、硬化し、耐環境保護膜とした。
最後に、膜を設けていない上記と同一のもう一枚の基板を、厚さ40μmの紫外線硬化樹脂(アクリル製、日本化薬 DVD003)を用いて貼合わせ、相変化型光記録媒体を得た。
その後、波長810nmの大口径LD(ビーム径;トラック方向1μm×半径方向75μm)を用い、線速10m/s、パワー1300mW、ヘッドの送り速度36μm/回転で記録層を結晶化(初期化)させた。
Example 1
A phase change optical recording medium was prepared as follows.
A polycarbonate substrate having a groove pitch of 0.74 μm, a groove width of 0.25 μm, a groove depth of 25 nm, and a thickness of 0.6 mm for recording marks in the grooves was used, and each layer was laminated thereon by a sputtering method.
First, a lower protective layer having a film thickness of 54 nm was provided using a target of ZnS: SiO 2 = 80: 20 (mol%).
Next, a target having a composition of Ge: Ag: In: Sb: Te = 3.8: 0.3: 3.5: 72: 20.4 was used, and a phase change recording layer having a thickness of 12 nm was provided.
Next, a ZrO 2 · Y 2 O 3 (3 mol%) · TiO 2 (20 mol%) composite oxide target was used to provide an interface layer having a thickness of 3 nm.
Next, an upper protective layer having a film thickness of 11 nm was provided using a target of ZnS: SiO 2 = 80: 20 (mol%).
Next, after providing a 4 nm thick SiC layer (sulfurization prevention layer) and a 140 nm thick Ag reflective layer, in order to improve environmental resistance, an SD318 UV curable resin made by Dainippon Ink with a thickness of 5 μm is used. After application, it was cured to obtain an environmental protection film.
Finally, another substrate identical to the above without a film was bonded using a 40 μm-thick UV curable resin (acrylic, Nippon Kayaku DVD003) to obtain a phase change optical recording medium. .
Thereafter, the recording layer is crystallized (initialized) at a linear velocity of 10 m / s, power of 1300 mW, and head feed speed of 36 μm / rotation using a large-diameter LD (beam diameter: 1 μm in the track direction × 75 μm in the radial direction) with a wavelength of 810 nm. It was.

この光記録媒体を、上記記録ヘッドで、線速を変えながらDC光11mWを照射していったところ、線速10m/s付近から反射率が減少し始めた。
記録再生は波長662nm、対物レンズNA0.65のピックアップヘッドを用いて、最高線速14m/sで記録密度が0.267μm/bitとなるように記録した。ピークパワーは最大21mW、バイアスパワーは5mW、消去パワーはピークパワーの30%になるようにして記録した。各マーク長のパルスの数は(n−1)個;n=3〜14である。
14m/s(4倍速)から5.8m/s(1.65倍速)の線速範囲でCAV記録する場合の記録条件を表1に示す。表1に示されているパラメータは基本的に図1の記号と同じであるが、図1にない記号との関係については、Ttop≡OP1、Tmp≡(OPj、OPm)、ε=Pe/Ppである。
表1のように、パルス時間を決めて、パルスの開始時間、終了時間をdTtop、dTeraにより制御することで、良好な特性が得られる。特に、パルスの先頭部のピークパワー印加開始時間を調整し、しかも、記録データ領域の内周部の最低線速から最外周部の最高線速の範囲で、線形に変化させることにより、従来のようにここを一定にしていた場合に比べてCAV記録の特性が向上した。中でも、再生信号に影響を及ぼす最短マーク(非晶質相)の反射信号とマーク間(結晶相)の反射率の差の半分の反射率と、最長マークの反射率と最長マークのマーク間の反射率の差の半分の反射率が同じになるようにすることが好ましく、これをアシンメトリーという信号特性の項目で評価している。このdTtopの制御はアシンメトリーをどの線速でもゼロから5%になるようにすることが有効であり、他の特性が良い場合でもこの特性は再生信号エラーに大きな影響を及ぼす。本実施例では図3に示すように線速に依らずアシンメトリーがほぼゼロ近傍になっている。

Figure 0004376927
When this optical recording medium was irradiated with 11 mW of DC light while changing the linear velocity with the recording head, the reflectance began to decrease from around the linear velocity of 10 m / s.
Recording / reproduction was performed using a pickup head having a wavelength of 662 nm and an objective lens NA of 0.65 at a maximum linear velocity of 14 m / s so that the recording density was 0.267 μm / bit. Recording was performed such that the maximum peak power was 21 mW, the bias power was 5 mW, and the erase power was 30% of the peak power. The number of pulses of each mark length is (n-1); n = 3-14.
Table 1 shows the recording conditions for CAV recording in the linear velocity range from 14 m / s (4 × speed) to 5.8 m / s (1.65 × speed). The parameters shown in Table 1 are basically the same as those in FIG. 1, but the relationship with symbols not in FIG. 1 is as follows: Ttop≡OP1, Tmp≡ (OPj, OPm), ε = Pe / Pp It is.
As shown in Table 1, good characteristics can be obtained by determining the pulse time and controlling the start time and end time of the pulse by dTtop and dTera. In particular, by adjusting the peak power application start time at the beginning of the pulse, and by changing linearly in the range from the lowest linear velocity at the inner periphery to the highest linear velocity at the outermost periphery, Thus, the characteristics of CAV recording were improved as compared with the case where this was kept constant. Above all, the reflectance of half of the difference between the reflectance of the shortest mark (amorphous phase) that affects the reproduction signal and the reflectance between the marks (crystalline phase), and the reflectance of the longest mark and the longest mark It is preferable that the reflectance of half of the difference in reflectance is the same, and this is evaluated by an item of signal characteristics called asymmetry. This dTtop control is effective to make asymmetry from zero to 5% at any linear speed, and this characteristic has a great influence on the reproduction signal error even when other characteristics are good. In this embodiment, asymmetry is almost in the vicinity of zero regardless of the linear velocity as shown in FIG.
Figure 0004376927

比較例1
比較としてdTtopを4倍速の条件で固定し、2.83倍速、1.65倍速で記録した結果を図4に示す。
図4から分るように、dTopを変えずに記録速度を変えると、低線速側でアシンメトリーが−5%(−0.05)より小さくなる。従って、再生時にデータエラー率が高くなり易い。
Comparative Example 1
As a comparison, FIG. 4 shows the results of recording at 2.83 times speed and 1.65 times speed with dTtop fixed at 4 times speed conditions.
As can be seen from FIG. 4, when the recording speed is changed without changing dTop, the asymmetry becomes smaller than −5% (−0.05) on the low linear velocity side. Therefore, the data error rate tends to be high during reproduction.

実施例2
実施例1と同じ光記録媒体を用い、記録条件を表2に示す条件に変えた点以外は実施例1と同様にして記録再生を行った。最高線速2.40倍速(8.4m/s)、最低線速1.0倍速(3.5m/s)、中間線速1.7倍速(6m/s)である。
ピークパワー15mWにおける記録特性の内、ジッター、アシンメトリーを評価した結果、図5に示すように、線速に対し殆ど依存性がなく良好な特性が得られた。上記線速範囲において、パルスの先頭部のピークパワー印加開始時間は、線速に依らずウィンドウ幅Twに対し一定の係数とした。ジッターはダイレクトオーバーライト(DOW)10回目の結果である。

Figure 0004376927
Example 2
Recording and reproduction were performed in the same manner as in Example 1 except that the same optical recording medium as in Example 1 was used and the recording conditions were changed to the conditions shown in Table 2. The maximum linear velocity is 2.40 times (8.4 m / s), the lowest linear velocity is 1.0 times (3.5 m / s), and the intermediate linear velocity is 1.7 times (6 m / s).
Of the recording characteristics at a peak power of 15 mW, jitter and asymmetry were evaluated. As a result, as shown in FIG. In the above linear velocity range, the peak power application start time at the head of the pulse is a constant coefficient with respect to the window width Tw regardless of the linear velocity. Jitter is the result of the 10th direct overwrite (DOW).
Figure 0004376927

実施例3〜5
実施例1と同じ光記録媒体を用い、DC光を盤面11mWの消去パワーで照射しながら、線速を3.5m/sから最大14m/sまで0.5m/s刻みで変えていったところ、反射率が減少し始める線速は、10.5m/s付近であった(表3の実施例4参照)。
次に、記録層の材料を、Ag:In:Sb:Te:Ge=0.5:5:68:24.5:2(実施例3)、Ag:In:Sb:Te:Ge=0.3:4:73:19.7:3(実施例5)の組成のものに変えた点以外は、実施例1と同様にして光記録媒体を作製し、実施例4と同様にして測定を行ったところ、反射率はそれぞれ8.5m/s、11.5m/s付近から下がり始めた。
各媒体に対し、2.4倍速ではピークパワー15mW、4倍速では19mWで記録し、DOW1回目のジッターを測定した結果、共に9%以下になったのは実施例4のみであった。
本実施例で使用した評価装置のピークパワーは最大で21mWであり、その約50%の消去パワーを用いた。特に、2.4倍速を15mW以下で記録した特性と、4倍速の記録特性が共に良好な線速は、反射率低下が10〜11m/s付近である。

Figure 0004376927
Examples 3-5
The same optical recording medium as in Example 1 was used, and the linear velocity was changed from 3.5 m / s to a maximum of 14 m / s in 0.5 m / s increments while irradiating DC light with an erasing power of 11 mW of the board surface. The linear velocity at which the reflectance starts to decrease was around 10.5 m / s (see Example 4 in Table 3).
Next, the material of the recording layer is Ag: In: Sb: Te: Ge = 0.5: 5: 68: 24.5: 2 (Example 3), Ag: In: Sb: Te: Ge = 0. An optical recording medium was prepared in the same manner as in Example 1 except that the composition was changed to 3: 4: 73: 19.7: 3 (Example 5), and measurement was performed in the same manner as in Example 4. As a result, the reflectances began to decrease from around 8.5 m / s and 11.5 m / s, respectively.
For each medium, recording was performed at a peak power of 15 mW at 2.4 times speed and 19 mW at 4 times speed, and the jitter of the first DOW was measured. As a result, both were 9% or less only in Example 4.
The peak power of the evaluation apparatus used in this example was 21 mW at maximum, and about 50% of the erasing power was used. In particular, in the linear velocity in which the 2.4 × speed recording at 15 mW or less and the 4 × speed recording property are both good, the reflectivity decrease is around 10 to 11 m / s.
Figure 0004376927

実施例6
実施例1と同じ光記録媒体を用い、記録条件として、表1の4倍速記録条件の内、dTeraを変化させた点以外は実施例1と同様にして記録再生を行った場合の、DOW1回目のジッターに関する最後部のバイアスパワー印加終了時間(dTeraの左端に相当)依存性を示す。dTeraは、図1の位置bに対して、最後部のバイアスパワー印加終了時間が位置bより速くなる場合を(+)側、遅くなる側を(−)側とした。
図6にその結果を示す。図6の横軸はdTera=k×(Tw/16)であり、横軸の目盛りはkの値である。
図6から分るように、バイアスパワー印加時間が8Tw/16の条件に近いほど、即ちバイアスパワー印加時間がゼロに近いほど、ジッター9%以下の良好な特性が得られる。
Example 6
The first DOW when recording / reproduction was performed in the same manner as in Example 1 except that the same optical recording medium as in Example 1 was used and dTera was changed as the recording condition in the quadruple speed recording conditions in Table 1. The bias power application end time (corresponding to the left end of dTera) at the end of the jitter is shown. For the dTera, the case where the last bias power application end time is faster than the position b with respect to the position b in FIG.
The result is shown in FIG. The horizontal axis in FIG. 6 is dTera = k × (Tw / 16), and the scale on the horizontal axis is the value of k.
As can be seen from FIG. 6, the closer the bias power application time is to 8Tw / 16, that is, the closer the bias power application time is to zero, the better the jitter is 9% or less.

本発明で用いる記録消去のための発光波形を説明する図。The figure explaining the light emission waveform for the recording erasing used by this invention. 本発明の対象となる光記録媒体の基本的層構成の一例を示す図。1 is a diagram illustrating an example of a basic layer configuration of an optical recording medium that is an object of the present invention. 実施例1におけるピークパワーとアシンメトリーとの関係を示す図。FIG. 3 is a diagram showing the relationship between peak power and asymmetry in Example 1. 比較例1におけるピークパワーとアシンメトリーとの関係を示す図。The figure which shows the relationship between the peak power and the asymmetry in the comparative example 1. 実施例2における線速とジッター及びアシンメトリーとの関係を示す図。FIG. 6 is a diagram showing the relationship between the linear velocity, jitter, and asymmetry in Example 2. 実施例6におけるDOW1回目のジッターの、最後部のバイアスパワー印加時間(dTera)依存性を示す図。The figure which shows the bias power application time (dTera) dependence of the last part of the jitter of the DOW 1st time in Example 6. FIG.

符号の説明Explanation of symbols

Tw ウインドウ幅(基本クロック周期)
Pp ピークパワー
Pe 消去パワー
Pb バイアスパワー
Ttop 先頭部のピークパワー印加時間
Tmp 中間部、後端部のピークパワー印加時間
dTtop 基準aに対する先頭部のピークパワーの印加を開始するまでの時間
dTera 基準bに対する最後部のバイアスパワーの印加を終了するまでの時間
a 開始基準位置〔記録マーク信号の先頭(立ち上がり)から、1Tシフトした時間〕
b 終了基準位置〔記録マーク信号の後端(立ち下がり)に相当する時間〕
Tw Window width (basic clock cycle)
Pp Peak power Pe Erase power Pb Bias power Ttop Top peak power application time Tmp Middle power and rear end peak power application time dTtop Time until start of peak power application to the reference a Reference to the dTera reference b Time until the end of bias power application at the end a Start reference position [time shifted by 1T from the beginning (rising edge ) of the recording mark signal]
b End reference position [time corresponding to trailing edge (falling) of recording mark signal]

Claims (6)

相変化型光記録媒体に対し、記録可能な最低線速と最高線速の範囲内の線速を用い、ピークパワー(Pp)、消去パワー(Pe)及びバイアスパワー(Pb)の3値で照射パワーを制御し、マーク形成時はピークパワー(Pp)とバイアスパワー(Pb)をパルス状に交互に印加し、前記マーク形成のためのパルス印加時間を、内周部から外周部に向けて変化する線速に対応したウインドウ幅Twで変化させる記録方法(CAV記録)において、先頭部のピークパワー印加開始時間の基準〔記録マーク信号の先頭(立ち上がり)から1Twシフトした時間〕をa、最後部のバイアスパワー印加終了時間の基準〔記録マーク信号の後端(立ち下がり)に相当する時間〕をbとして、変化する各線速毎に基準aに対する先頭部のピークパワーの印加を開始するまでの時間(dTtop)を、ウインドウ幅Twの(k/16)倍(kは整数)とすることを特徴とする光記録方法。 Irradiate the phase change optical recording medium with three values of peak power (Pp), erasing power (Pe), and bias power (Pb) using a linear velocity within the range of the lowest linear velocity that can be recorded and the highest linear velocity. The power is controlled, and peak power (Pp) and bias power (Pb) are alternately applied in the form of pulses during mark formation, and the pulse application time for forming the mark changes from the inner periphery to the outer periphery. In the recording method (CAV recording) in which the window width Tw corresponding to the linear velocity to be changed is changed, the reference of the peak power application start time at the head portion (time shifted by 1 Tw from the head (rising edge) of the recording mark signal) is a, the last portion reference bias power application end time [trailing edge of the recording mark signal time corresponding to (fall)] as b, and each each linear velocity which varies, the peak power of the head portion relative to the reference a Time (dTtop) until the start of pressurization, optical recording method characterized in that a window width Tw (k / 16) times (k is an integer). ピークパワー印加時間(Ttop)、中間部の印加時間(Tmp)、及び、基準bに対する最後部のバイアスパワーの印加を終了するまでの時間(dTera)のうちの少なくとも一つを、ウインドウ幅Twの(k/16)倍(kは整数)で変化させることを特徴とする請求項1記載の光記録方法。 At least one of the peak power application time (Ttop), the intermediate application time (Tmp), and the time (dTera) until the application of the bias power at the last part with respect to the reference b is determined by the window width Tw. 2. The optical recording method according to claim 1, wherein the optical recording method is changed by (k / 16) times (k is an integer). ピークパワー印加時間(Ttop)及び中間部の印加時間(Tmp)が、固定された時間(定数項)を有することを特徴とする請求項2記載の光記録方法。   3. The optical recording method according to claim 2, wherein the peak power application time (Ttop) and the intermediate application time (Tmp) have a fixed time (constant term). 線速が速くなるに従い、前記(dTtop)を減少させ、前記(dTera)を増加させる(即ち、最後部のバイアスパワー印加時間を減少させる)ことを特徴とする請求項1〜3の何れかに記載の光記録方法。   4. (dTtop) is decreased and (dTera) is increased (that is, the last bias power application time is decreased) as the linear velocity increases. The optical recording method described. 記録可能な線速の範囲が、基準線速の1.0倍以上、4.00倍以下であることを特徴とする請求項1〜の何れかに記載の光記録方法。 Range of recordable linear velocity, or 1.0 times the reference linear velocity, the optical recording method according to any one of claims 1-4, characterized in that not more than 4.00 times. 最低線速が基準線速に対して1.65倍速、最高線速と最低線速の間の速度が基準線速に対して2.83倍速、最高線速が基準線速に対して4.00倍速である各線速毎の(dTtop)、(Ttop)、(Tmp)及び(dTera)の情報が予め記録されていることを特徴とする請求項1〜の何れかに記載の記録方法に対応可能な相変化型光記録媒体。 The minimum linear speed is 1.65 times the reference linear speed, the speed between the highest linear speed and the lowest linear speed is 2.83 times the reference linear speed, and the highest linear speed is 4.3 times the reference linear speed. 00 is a speed each linear velocity for each of the (dTtop), (Ttop), a recording method according to any one of claims 1 to 5, characterized in that is recorded in advance information (Tmp) and (dTera) Phase change optical recording media that can be used.
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