JP4327812B2 - Manufacturing method of carburized parts - Google Patents

Manufacturing method of carburized parts Download PDF

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JP4327812B2
JP4327812B2 JP2006059685A JP2006059685A JP4327812B2 JP 4327812 B2 JP4327812 B2 JP 4327812B2 JP 2006059685 A JP2006059685 A JP 2006059685A JP 2006059685 A JP2006059685 A JP 2006059685A JP 4327812 B2 JP4327812 B2 JP 4327812B2
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carburizing
oxide film
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JP2007238974A (en
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工 藤田
和寛 八木田
勝教 伊藤
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Description

本発明は、浸炭部品の製造法に関する。 The present invention also relates to the production how of carburized parts.

浸炭処理は、低炭素鋼または低炭素合金鋼などの加工性のよい鋼を機械加工した後、その鋼の表面層の炭素量を増加させ、表面層のみを焼入硬化する処理方法である。浸炭処理を施した鋼の内部は炭素量が少なく柔軟な組織のままであるために靭性が高く、また表面層は炭素量が多いために耐磨耗性が高い。浸炭処理が施された鋼はこのような利点を有するので、各種の機械部品に広く応用されている。浸炭処理の具体的な方法としては、浸炭性ガスを用いて行なわれるガス浸炭処理が主流であるが、ガス浸炭処理では、鋼の表面の位置によって浸炭層が形成される深さにムラが発生する場合がある。この浸炭の深さのムラを浸炭ムラという。   The carburizing treatment is a treatment method in which a steel having good workability such as low carbon steel or low carbon alloy steel is machined, and then the amount of carbon in the surface layer of the steel is increased to quench and harden only the surface layer. The carburized steel has high toughness because it has a low carbon content and a flexible structure, and the surface layer has high wear resistance because of its high carbon content. Since the carburized steel has such advantages, it is widely applied to various machine parts. As a specific method of carburizing treatment, gas carburizing treatment using carburizing gas is the mainstream, but in gas carburizing treatment, unevenness occurs in the depth at which the carburized layer is formed depending on the position of the steel surface. There is a case. This uneven carburization depth is called carburizing unevenness.

ところで、浸炭処理方法の一つとして真空浸炭処理がある。真空浸炭処理とは、減圧された浸炭性ガスを真空中(減圧雰囲気中)に導入することで浸炭処理を行なう浸炭処理方法である。真空浸炭処理に関しては、たとえば特許第3531736号(特許文献1)、特開2004−169101号公報(特許文献2)、または特許第3442737号(特許文献3)などに記載されている。一般に浸炭ムラができる原因は、鋼の表面に生成する酸化膜にあると考えられている。上記真空浸炭処理によれば、酸化膜の生成が抑止されるので、浸炭ムラの発生をある程度抑制することができる。   Incidentally, there is a vacuum carburizing process as one of the carburizing processes. The vacuum carburizing treatment is a carburizing treatment method in which carburizing treatment is performed by introducing a reduced carburizing gas into a vacuum (in a reduced pressure atmosphere). The vacuum carburizing process is described in, for example, Japanese Patent No. 3531736 (Patent Document 1), Japanese Patent Application Laid-Open No. 2004-169101 (Patent Document 2), or Japanese Patent No. 3442737 (Patent Document 3). In general, the cause of uneven carburization is considered to be an oxide film formed on the surface of steel. According to the vacuum carburizing process, since the formation of an oxide film is suppressed, the occurrence of carburizing unevenness can be suppressed to some extent.

また、鋼に含まれる成分の中でCr(クロム)は、特に酸化膜の生成が起こりやすい成分である。Crを多く含んでいる鋼ほど浸炭ムラが発生しやすい。一般に、Crを多く含むステンレス鋼では安定なCr酸化膜が生成される。このため、Crを多く含むステンレス鋼についてはガス浸炭処理が困難であることが知られており、真空浸炭処理が採用されている。
特許第3531736号(特開2002−212702号公報) 特開2004−169101号公報 特許第3442737号(特開2002−180235号公報)
Further, among the components contained in steel, Cr (chromium) is a component that is particularly likely to generate an oxide film. As the steel contains more Cr, carburization unevenness is more likely to occur. Generally, a stainless steel containing a large amount of Cr produces a stable Cr oxide film. For this reason, it is known that stainless steel containing a large amount of Cr is difficult to gas carburize, and vacuum carburizing is employed.
Japanese Patent No. 3531736 (Japanese Patent Laid-Open No. 2002-212702) JP 2004-169101 A Japanese Patent No. 3442737 (Japanese Patent Laid-Open No. 2002-180235)

しかしながら、上記の真空浸炭処理を行なっても、浸炭ムラの発生を十分抑止することができないという問題があった。また、真空浸炭処理には浸炭時に煤が発生する問題があるので、真空浸炭処理は浸炭処理方法の主流にはなっていない。   However, there has been a problem that even if the above-described vacuum carburizing treatment is performed, the occurrence of carburizing unevenness cannot be sufficiently suppressed. Moreover, since there is a problem that soot is generated during carburizing in the vacuum carburizing process, the vacuum carburizing process is not the mainstream carburizing method.

Crを多く含む鋼(Crの含有量3.5質量%以上の鋼)について浸炭ムラの発生を抑止し得る一つの方法として、浸炭処理前の鋼に大気中において900℃以上の温度で熱処理を施すことが行なわれている。しかし、この熱処理を施すと、浸炭処理後に得られた完成品(浸炭部品)において表面硬度が低下するという問題があった。   As one method that can suppress the occurrence of uneven carburization of steel containing a large amount of Cr (steel with a Cr content of 3.5% by mass or more), heat treatment is performed on the steel before carburizing at a temperature of 900 ° C. or higher in the atmosphere. It is done. However, when this heat treatment is performed, there is a problem that the surface hardness of the finished product (carburized part) obtained after the carburizing process is lowered.

したがって、本発明の目的は、浸炭ムラの発生および表面硬度の低下を抑止することのできる浸炭部品の製造法を提供することである。 Accordingly, an object of the present invention is to provide a manufacturing how the carburized component that can suppress the decrease in the generation and surface hardness of the carburized unevenness.

本発明の浸炭部品の製造方法は、3.5質量%以上のCrを含む鋼の表面に酸化膜を形成する酸化工程と、酸化工程後、鋼を浸炭する浸炭工程と、浸炭工程後、鋼の表面から酸化膜を除去する除去工程と、除去工程後、鋼を焼入れる焼入工程とを備えている。 The method of manufacturing a carburized component according to the present invention includes an oxidation process for forming an oxide film on the surface of steel containing 3.5 mass% or more of Cr, a carburization process for carburizing steel after the oxidation process, a carburization process, A removal step of removing the oxide film from the surface of the steel, and a quenching step of quenching the steel after the removal step.

本願発明者は、鋼が3.5質量%以上のCrを含む場合には、鋼の表面に形成された酸化膜が脱炭を助長し、浸炭部品の表面硬度の低下を招いていることを見出した。すなわち、予め鋼の表面に酸化膜を形成しておくことによって、浸炭時に浸炭ムラの発生を抑止することができる。一方で浸炭後に鋼を焼入れる際には、この酸化膜の成分(特に酸素)が鋼の表面に存在する炭素と結びつき、ガスとして放出される。その結果、焼入によって鋼が脱炭され、浸炭部品の表面硬度が低下する。   The inventor of the present application indicates that when steel contains 3.5 mass% or more of Cr, the oxide film formed on the surface of the steel promotes decarburization, leading to a decrease in the surface hardness of the carburized component. I found it. That is, by forming an oxide film on the surface of steel in advance, it is possible to suppress the occurrence of carburizing unevenness during carburizing. On the other hand, when the steel is quenched after carburizing, the components of the oxide film (especially oxygen) are combined with the carbon present on the surface of the steel and released as a gas. As a result, the steel is decarburized by quenching, and the surface hardness of the carburized component decreases.

そこで、本発明の浸炭部品の製造方法によれば、焼入工程前に酸化膜を除去するので、焼入工程における脱炭を抑止することができる。その結果、浸炭工程において酸化膜によって浸炭ムラの発生を抑止しつつ、表面硬度の低下を抑止することができる。 Then, according to the manufacturing method of the carburized component of this invention, since an oxide film is removed before a quenching process, the decarburization in a quenching process can be suppressed. As a result, it is possible to suppress the decrease in surface hardness while suppressing the occurrence of uneven carburization by the oxide film in the carburizing process.

本発明の浸炭部品の製造法によれば、浸炭ムラの発生および表面硬度の低下を抑止することができる。 According to the manufacturing how the carburized component of the present invention, it is possible to suppress the reduction in the generation and surface hardness of the carburized unevenness.

以下、本発明の一実施の形態について図面に基づいて説明する。
図1は、本発明の一実施の形態における浸炭部品の製造方法を工程順に示す図である。図1を参照して、始めに、3.5質量%以上のCrを含む鋼を準備し、この鋼に対して高温酸化処理を施す(ステップS1)。これにより、鋼の表面に酸化膜が形成される。高温酸化処理は、たとえば900℃以上1000℃以下の大気中に鋼を保持することにより行なわれる。
Hereinafter, an embodiment of the present invention will be described with reference to the drawings.
FIG. 1 is a diagram showing a method for manufacturing a carburized component according to an embodiment of the present invention in the order of steps. With reference to FIG. 1, first, steel containing 3.5 mass% or more of Cr is prepared, and this steel is subjected to high-temperature oxidation treatment (step S1). Thereby, an oxide film is formed on the surface of the steel. The high temperature oxidation treatment is performed, for example, by holding the steel in the atmosphere of 900 ° C. or higher and 1000 ° C. or lower.

次に、鋼を浸炭処理する(ステップS2)。浸炭処理は、たとえばCP(カーボンポテンシャル)が0.6の雰囲気で、960℃の温度で36時間行なわれる。浸炭処理方法は、固体浸炭、液体浸炭、ガス浸炭、または真空浸炭などいずれでもよい。浸炭処理の際には、鋼の表面に酸化膜が形成されているので、鋼の表面におけるどの位置からも均一な深さで炭素を侵入させることができ、浸炭ムラの発生を抑止することができる。その後、この鋼を浸炭処理温度から冷却することによって、鋼に対して1次焼入が施される。   Next, the steel is carburized (step S2). The carburizing process is performed for 36 hours at a temperature of 960 ° C. in an atmosphere having a CP (carbon potential) of 0.6, for example. The carburizing method may be any of solid carburizing, liquid carburizing, gas carburizing, or vacuum carburizing. During carburizing treatment, an oxide film is formed on the surface of the steel, so that carbon can penetrate at a uniform depth from any position on the surface of the steel, and the occurrence of carburizing unevenness can be suppressed. it can. Thereafter, the steel is cooled from the carburizing temperature to be subjected to primary quenching.

次に、鋼の表面に形成された酸化膜(スケール)を除去する(ステップS3)。スケールの除去方法としては、旋削、ラッピング、タンブラーなどの機械加工を用いる方法であってもよいし、電解研磨のような化学研磨を用いる方法であってもよい。   Next, the oxide film (scale) formed on the steel surface is removed (step S3). The scale removal method may be a method using machining such as turning, lapping, or tumbler, or a method using chemical polishing such as electrolytic polishing.

次に、鋼に対して2次焼入を施す(ステップS4)。2次焼入は、1100℃の真空炉において20分間保持した後で冷却することにより行なわれる。ここで、2次焼入の際に鋼の表面に酸化膜が形成されていると、酸化膜の成分が鋼の表面の炭素と結びつき、ガスとして放出される。その結果、鋼の脱炭が起こり、鋼の表面硬度の低下を招く。しかし本実施の形態では、酸化膜が除去された鋼に対して2次焼入を施すので、酸化膜による鋼の脱炭は起こらない。   Next, secondary quenching is performed on the steel (step S4). Secondary quenching is performed by holding for 20 minutes in a vacuum furnace at 1100 ° C. and then cooling. Here, if an oxide film is formed on the surface of the steel during the secondary quenching, components of the oxide film are combined with carbon on the surface of the steel and released as a gas. As a result, decarburization of the steel occurs and the surface hardness of the steel is reduced. However, in this embodiment, since the secondary quenching is performed on the steel from which the oxide film has been removed, the decarburization of the steel by the oxide film does not occur.

その後、鋼に焼戻を施してもよい。以上の工程により、本実施の形態の浸炭部品が得られる。   Thereafter, the steel may be tempered. Through the above steps, the carburized component of the present embodiment is obtained.

本実施の形態における浸炭方法は、3.5質量%以上のCrを含む鋼の表面に酸化膜を形成する酸化工程(ステップS1)と、酸化工程後、鋼を浸炭する浸炭工程(ステップS2)と、浸炭工程後、鋼の表面から酸化膜を除去する除去工程(ステップS3)と、除去工程後、鋼を焼入れる焼入工程(ステップS4)とを備えている。   The carburizing method according to the present embodiment includes an oxidation process (step S1) for forming an oxide film on the surface of steel containing 3.5% by mass or more of Cr, and a carburizing process for carburizing steel after the oxidation process (step S2). And a removal step (step S3) for removing the oxide film from the surface of the steel after the carburizing step, and a quenching step (step S4) for quenching the steel after the removal step.

本実施の形態における浸炭方法およびこれを用いて製造された浸炭部品によれば、鋼の表面に酸化膜を形成してから浸炭処理を施すので、浸炭ムラの発生を抑止することができる。加えて、酸化膜が除去された鋼に対して2次焼入を施すので、酸化膜の成分による鋼の脱炭を抑止することができ、鋼の表面硬度が低下するのを抑止することができる。   According to the carburizing method and the carburized parts manufactured using the carburizing method in the present embodiment, carburizing treatment is performed after forming an oxide film on the surface of the steel, so that occurrence of carburizing unevenness can be suppressed. In addition, since secondary quenching is performed on the steel from which the oxide film has been removed, decarburization of the steel due to the components of the oxide film can be suppressed, and the reduction in the surface hardness of the steel can be suppressed. it can.

本実施例では、試験片A(比較例)および試験片B(本発明例)に関して、2次焼入の際に鋼の表面から脱離するガスについて調べた。始めに、Crを含む鋼(C:0.15質量%、Ni:3.5質量%、Cr:4質量%、Mo:4質量%、V:1質量%、残部Fe)よりなる試験片Aおよび試験片Bを準備し、高温酸化処理、浸炭処理、および1次焼入を施した。高温酸化処理は950℃の大気中に鋼を保持することにより行なった。浸炭処理はガス浸炭により行ない、CPが0.6の雰囲気で、960℃の温度で36時間行なった。続いて、試験片Bについて鋼の表面に形成された酸化膜をラッピングにより除去した。試験片Aについては酸化膜を除去しなかった。以上のようにして得られた1次焼入後の試験片Aおよび試験片Bの各々に対して、昇温脱離ガス分析を行なった。図2は試験片Aの昇温脱離ガス分析の結果を示す図であり、図3は試験片Bの昇温脱離ガス分析の結果を示す図である。   In this example, the test piece A (comparative example) and the test piece B (present invention example) were examined for gases desorbed from the steel surface during secondary quenching. First, test piece A made of steel containing Cr (C: 0.15 mass%, Ni: 3.5 mass%, Cr: 4 mass%, Mo: 4 mass%, V: 1 mass%, balance Fe) And the test piece B was prepared and the high temperature oxidation process, the carburizing process, and the primary quenching were performed. The high temperature oxidation treatment was performed by holding the steel in the atmosphere at 950 ° C. The carburizing process was performed by gas carburizing, and was performed in an atmosphere having a CP of 0.6 at a temperature of 960 ° C. for 36 hours. Subsequently, the oxide film formed on the steel surface of the test piece B was removed by lapping. For the test piece A, the oxide film was not removed. A temperature-programmed desorption gas analysis was performed on each of the specimen A and specimen B after the primary quenching obtained as described above. FIG. 2 is a diagram showing the results of the temperature-programmed desorption gas analysis of the test piece A, and FIG. 3 is a diagram showing the results of the temperature-programmed desorption gas analysis of the test piece B.

図2を参照して、試験片Aでは試験片の温度上昇とともに大量のガスの脱離が観測された。具体的には、500℃付近、800℃付近および900℃付近で質量数44(二酸化炭素)の脱離ピークが観測され、800℃付近および900℃付近で質量数28(窒素・一酸化炭素)の脱離ピークが観測された。一方図3を参照して、試験片Bにおいて脱離したガスの量は、試験片Aにおいて脱離したガスの量に比べて非常に少なかった。これらの結果から、試験片Aの2次焼入の際には、酸化膜の酸素原子が鋼の表面に存在する炭素原子と結合して、一酸化炭素および二酸化炭素が発生し、その結果鋼の脱炭が発生していることが推測される。加えて、試験片Aでは300℃付近で質量数18(水)の脱離ピークが観測され、600℃付近で質量数2(水素)の脱離ピークが観測されたことから、酸化膜における酸素以外の成分も鋼に対して何らかの悪影響を与えているものと推測される。   Referring to FIG. 2, in test piece A, a large amount of gas desorption was observed as the temperature of the test piece increased. Specifically, desorption peaks with mass number 44 (carbon dioxide) are observed at around 500 ° C., 800 ° C. and 900 ° C., and mass number 28 (nitrogen / carbon monoxide) at around 800 ° C. and 900 ° C. The desorption peak of was observed. On the other hand, referring to FIG. 3, the amount of gas desorbed in test piece B was very small compared to the amount of gas desorbed in test piece A. From these results, during the secondary quenching of the test piece A, the oxygen atoms of the oxide film are combined with the carbon atoms present on the surface of the steel to generate carbon monoxide and carbon dioxide. As a result, the steel It is speculated that decarburization has occurred. In addition, in specimen A, a desorption peak with a mass number of 18 (water) was observed near 300 ° C., and a desorption peak with a mass number of 2 (hydrogen) was observed near 600 ° C., so that oxygen in the oxide film was observed. It is presumed that the other components have some adverse effects on the steel.

本実施の形態においては、2次焼入後の試験片Aおよび試験片Bに関して、深さ方向の硬度分布について調べた。すなわち、実施例1で得られた1次焼入後の試験片Aおよび試験片Bの各々に対して2次焼入を施した。2次焼入は1100℃の真空炉において20分間保持した後で冷却することにより行なった。以上のようにして試験片Aおよび試験片Bの各々の浸炭部品を得た。続いて、試験片Aおよび試験片Bの各々の断面において、深さ方向に沿ってビッカース硬度(HV)を測定した。図4は試験片Aの深さ方向の硬度分布を示す図であり、図5は試験片Bの深さ方向の硬度分布を示す図である。   In the present embodiment, the hardness distribution in the depth direction was examined for the test piece A and the test piece B after secondary quenching. That is, secondary quenching was performed on each of the specimen A and specimen B after the primary quenching obtained in Example 1. Secondary quenching was performed by holding in a vacuum furnace at 1100 ° C. for 20 minutes and then cooling. The carburized parts of each of the test piece A and the test piece B were obtained as described above. Subsequently, in each cross section of the test piece A and the test piece B, Vickers hardness (HV) was measured along the depth direction. 4 is a diagram showing the hardness distribution of the test piece A in the depth direction, and FIG. 5 is a diagram showing the hardness distribution of the test piece B in the depth direction.

図4および図5を参照して、試験片Aの硬度は、表面から約0.8mmの部分が最も高くなっており、表面に近づく程低下している。一方、試験片Bの硬度は、表面に最も近い部分が最も高くなっており、表面から離れる程低下している。これらの結果から、試験片Aでは2次焼入れの際の脱炭により表面硬度が低下しているのに対して、試験片Bでは表面硬度の低下が抑制されていることが分かる。   Referring to FIGS. 4 and 5, the hardness of test piece A is highest at a portion of about 0.8 mm from the surface, and decreases as it approaches the surface. On the other hand, the hardness of the test piece B is highest at the portion closest to the surface, and decreases as the distance from the surface increases. From these results, it can be seen that the test piece A has a reduced surface hardness due to decarburization during secondary quenching, whereas the test piece B has a reduced decrease in surface hardness.

以上に開示された実施の形態および実施例はすべての点で例示であって制限的なものではないと考慮されるべきである。本発明の範囲は、以上の実施の形態および実施例ではなく、特許請求の範囲によって示され、特許請求の範囲と均等の意味および範囲内でのすべての修正や変形を含むものと意図される。   The embodiments and examples disclosed above are to be considered in all respects as illustrative and not restrictive. The scope of the present invention is shown not by the above embodiments and examples but by the scope of claims, and is intended to include all modifications and variations within the meaning and scope equivalent to the scope of claims. .

本発明の浸炭方法およびそれによって製造された浸炭部品は、軸受部品の浸炭方法およびそれによって製造された軸受部品に適している。   The carburizing method of the present invention and the carburized part manufactured thereby are suitable for the carburizing method of the bearing part and the bearing part manufactured thereby.

本発明の一実施の形態における浸炭部品の製造方法を工程順に示す図である。It is a figure which shows the manufacturing method of the carburized component in one embodiment of this invention in process order. 本発明の実施例1における試験片Aの昇温脱離ガス分析の結果を示す図である。It is a figure which shows the result of the temperature-programmed desorption gas analysis of the test piece A in Example 1 of this invention. 本発明の実施例1における試験片Bの昇温脱離ガス分析の結果を示す図である。It is a figure which shows the result of the temperature-programmed desorption gas analysis of the test piece B in Example 1 of this invention. 本発明の実施例1における試験片Aの深さ方向の硬度分布を示す図である。It is a figure which shows the hardness distribution of the depth direction of the test piece A in Example 1 of this invention. 本発明の実施例1における試験片Bの深さ方向の硬度分布を示す図である。It is a figure which shows the hardness distribution of the depth direction of the test piece B in Example 1 of this invention.

Claims (3)

3.5質量%以上のCrを含む鋼の表面に酸化膜を形成する酸化工程と、
前記酸化工程後、前記鋼を浸炭する浸炭工程と、
前記浸炭工程後、前記鋼の表面から前記酸化膜を除去する除去工程と、
前記除去工程後、前記鋼を焼入れる焼入工程とを備える、浸炭部品の製造方法。
An oxidation step of forming an oxide film on the surface of steel containing 3.5 mass% or more of Cr;
After the oxidation step, carburizing step of carburizing the steel,
After the carburizing step, a removal step of removing the oxide film from the surface of the steel;
A carburized part manufacturing method comprising a quenching step of quenching the steel after the removing step.
前記焼入工程後に前記鋼を焼戻す工程を備える、請求項1に記載の浸炭部品の製造方法。The manufacturing method of the carburized component of Claim 1 provided with the process of tempering the steel after the quenching process. 前記焼入工程により前記浸炭部品の表面に最も近い部分の硬度が最も高くなるようにした、請求項1に記載の浸炭部品の製造方法。The method for manufacturing a carburized component according to claim 1, wherein the hardness of the portion closest to the surface of the carburized component is highest by the quenching step.
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