JP4198642B2 - 毛髪化粧料 - Google Patents
毛髪化粧料 Download PDFInfo
- Publication number
- JP4198642B2 JP4198642B2 JP2004168250A JP2004168250A JP4198642B2 JP 4198642 B2 JP4198642 B2 JP 4198642B2 JP 2004168250 A JP2004168250 A JP 2004168250A JP 2004168250 A JP2004168250 A JP 2004168250A JP 4198642 B2 JP4198642 B2 JP 4198642B2
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- Prior art keywords
- hair
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- acid
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- RBBHGNBWKGCPAF-XEKXCHJCSA-N [27-oxo-27-[[(2s,3s,4r)-1,3,4-trihydroxyoctadecan-2-yl]amino]heptacosyl] (9z,12z)-octadeca-9,12-dienoate Chemical compound CCCCCCCCCCCCCC[C@@H](O)[C@@H](O)[C@H](CO)NC(=O)CCCCCCCCCCCCCCCCCCCCCCCCCCOC(=O)CCCCCCC\C=C/C\C=C/CCCCC RBBHGNBWKGCPAF-XEKXCHJCSA-N 0.000 description 1
- HMDDXIMCDZRSNE-UHFFFAOYSA-N [C].[Si] Chemical group [C].[Si] HMDDXIMCDZRSNE-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
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- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 159000000032 aromatic acids Chemical class 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
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- 229960000686 benzalkonium chloride Drugs 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 229940099417 ceramide 2 Drugs 0.000 description 1
- 229940044176 ceramide 3 Drugs 0.000 description 1
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 230000001427 coherent effect Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 235000018417 cysteine Nutrition 0.000 description 1
- XUJNEKJLAYXESH-UHFFFAOYSA-N cysteine Natural products SCC(N)C(O)=O XUJNEKJLAYXESH-UHFFFAOYSA-N 0.000 description 1
- 150000001470 diamides Chemical class 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- IUNMPGNGSSIWFP-UHFFFAOYSA-N dimethylaminopropylamine Chemical compound CN(C)CCCN IUNMPGNGSSIWFP-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- 229960004275 glycolic acid Drugs 0.000 description 1
- 239000008266 hair spray Substances 0.000 description 1
- 230000003699 hair surface Effects 0.000 description 1
- HNDVDQJCIGZPNO-UHFFFAOYSA-N histidine Natural products OC(=O)C(N)CC1=CN=CN1 HNDVDQJCIGZPNO-UHFFFAOYSA-N 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229960000448 lactic acid Drugs 0.000 description 1
- 150000002605 large molecules Chemical class 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 229930182817 methionine Natural products 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- RVRFYZGKUZFYAH-UHFFFAOYSA-N n',n'-dimethylpropane-1,3-diamine;octadecanoic acid Chemical compound CN(C)CCCN.CCCCCCCCCCCCCCCCCC(O)=O RVRFYZGKUZFYAH-UHFFFAOYSA-N 0.000 description 1
- PUGFCQQOYJMKOO-UHFFFAOYSA-N n-(3-hexadecoxy-2-hydroxypropyl)-n-(2-hydroxyethyl)hexadecanamide Chemical compound CCCCCCCCCCCCCCCCOCC(O)CN(CCO)C(=O)CCCCCCCCCCCCCCC PUGFCQQOYJMKOO-UHFFFAOYSA-N 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- 229940066842 petrolatum Drugs 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- 229930000756 phytoceramide Natural products 0.000 description 1
- 150000003038 phytosphingosines Chemical class 0.000 description 1
- 235000021118 plant-derived protein Nutrition 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- 102000004196 processed proteins & peptides Human genes 0.000 description 1
- 230000002633 protecting effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000003531 protein hydrolysate Substances 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 210000004761 scalp Anatomy 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 210000003491 skin Anatomy 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 235000019710 soybean protein Nutrition 0.000 description 1
- WWUZIQQURGPMPG-KRWOKUGFSA-N sphingosine Chemical group CCCCCCCCCCCCC\C=C\[C@@H](O)[C@@H](N)CO WWUZIQQURGPMPG-KRWOKUGFSA-N 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 125000000547 substituted alkyl group Chemical group 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 229960003495 thiamine Drugs 0.000 description 1
- DPJRMOMPQZCRJU-UHFFFAOYSA-M thiamine hydrochloride Chemical compound Cl.[Cl-].CC1=C(CCO)SC=[N+]1CC1=CN=C(C)N=C1N DPJRMOMPQZCRJU-UHFFFAOYSA-M 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 235000019155 vitamin A Nutrition 0.000 description 1
- 239000011719 vitamin A Substances 0.000 description 1
- 235000010374 vitamin B1 Nutrition 0.000 description 1
- 239000011691 vitamin B1 Substances 0.000 description 1
- 235000019166 vitamin D Nutrition 0.000 description 1
- 239000011710 vitamin D Substances 0.000 description 1
- 150000003710 vitamin D derivatives Chemical class 0.000 description 1
- 229940045997 vitamin a Drugs 0.000 description 1
- 229940046008 vitamin d Drugs 0.000 description 1
- 229940043810 zinc pyrithione Drugs 0.000 description 1
- PICXIOQBANWBIZ-UHFFFAOYSA-N zinc;1-oxidopyridine-2-thione Chemical compound [Zn+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S PICXIOQBANWBIZ-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Cosmetics (AREA)
Description
(a)一般式(1)で表されるアミドアミン(以下アミドアミン(1)という)
(b)一般式(2)で表されるジアミド化合物(以下ジアミド化合物(2)という)
(c)炭素数8〜30の脂肪族アルコール
(d)有機酸
(B)高重合ジメチルポリシロキサン
高重合ジメチルポリシロキサンを本発明の毛髪化粧料中に配合する場合、液状油に溶解して配合するか、予めアミドアミン(1)の酸塩等の陽イオン性界面活性剤やポリオキシエチレンアルキルエーテルなどの非イオン性界面活性剤水溶液中で調製した分散液を配合することが好ましい。液状油としては先に記載した(A)のジメチルポリシロキサンオイルや、下記(E)の環状シリコーン又はイソパラフィン系炭化水素等を挙げることができる。
アミノ変性シリコーンを水性乳濁液として用いる場合、該水性乳濁液中に含まれるアミノ変性シリコーンの量は20〜60重量%が好ましく、30〜50重量%が更に好ましい。
(E)環状シリコーン
(F)フッ素変性シリコーン
(G)アルキル変性シリコーン
(H)一般式(5)で表されるアミノ変性シロキサン−ポリオキシアルキレンブロック共重合体
これらシリコーン成分の中では、(A)ジメチルポリシロキサンオイル、(B)高重合ジメチルポリシロキサン、(E)環状シリコーン、或いはそれらの混合物、(C)アミノ変性シリコーン、(H)アミノ変性シロキサン−ポリオキシアルキレンブロック共重合体が好ましく、その中でも(C)アミノ変性シリコーン、(H)アミノ変性シロキサン−ポリオキシアルキレンブロック共重合体が特に好ましい。
表1に示す組成の毛髪化粧料(ヘアコンディショナー)を以下の方法で調製し、以下の方法で使用感及び枝毛・切れ毛の発生状態を評価した。結果を表1に示す。
1)100mlのビーカーにイオン交換水、酸以外の成分を最終製造量が300gとなる所要量を入れ、65℃に加熱して、均一に溶解させた。
2)500mlのビーカーにイオン交換水、酸を最終製造量が300gとなる所要量を入れ、65℃に加熱し、1)で得た混合物を添加し乳化して、ヘアコンディショナーを調製した。
パネラー10名が、陰イオン性界面活性剤を主体とする市販のシャンプーを用いて洗髪後、各ヘアコンディショナーを使用した。これを1日1回2週間繰り返した。各ヘアコンディショナーの塗布時の滑らかさ、柔らかさ、濯ぎ時の滑らかさ、柔らかさ、及び乾燥後の櫛通りの良さ、仕上がり感について、下記基準で官能評価した。
A:8人以上が効果あると回答
B:6〜7人が効果あると回答
C:4〜5人が効果あると回答
D:3人以下が効果あると回答
<枝毛・切れ毛の発生状態の評価法>
長さ15cm、およそ100本のトレスを各ヘアコンディショナー中に室温で10分間浸漬した後、流水下で30秒間余分な剤をすすぎ流し、自然乾燥した。処理を終えたトレスを、モーターに連動した回転ブラシにより、回転数100rpmの条件で約60分ブラッシング刺激を与えた。その後目視によりトレス先端の状態を観察し、発生した枝毛・切れ毛の本数を確認した。基準トレス(比較例1)の枝毛・切れ毛の本数に対する比率を枝毛・切れ毛発生率とし、下記基準で評価した。
A:枝毛・切れ毛発生率50%未満
B:枝毛・切れ毛発生率50%以上70%未満
C:枝毛・切れ毛発生率70%以上90%未満
D:枝毛・切れ毛発生率90%以上
アミドアミン(1)として、花王(株)製ルナックBAとジメチルアミノプロピルアミンから合成した、下記式(A)で表されるアミドアミン[純度99.6%(その他、未反応脂肪酸、未反応アミン、水分等を含有)、以下アミドアミンAという]を用い、下記組成のヘアコンディショナーを調製した。このヘアコンディショナーは、塗布時、濯ぎ時のリッチ感とその持続性、柔軟性、平滑性、及び乾燥後の柔らか感、櫛通り感が良好で、枝毛・切れ毛の抑制効果も良好であった。
<ヘアコンディショナー組成>
アミドアミンA 1.5%
ステアリルアルコール*1 4.0%
グリセリン 1.0%
ベンジルオキシエタノール 0.3%
ジアミド(N) 0.3%
シリコーン*2 2.0%
アミノ変性シリコーン−ポリオキシアルキレンブロック共重合体*3 0.5%
乳酸 0.5%
ジペンタエリスルトール脂肪酸エステル*4 0.2%
ヒドロキシエチルセルロース*5 0.2%
高重合ポリエチレングリコール*6 0.05%
酢酸トコフェロール 0.1%
香料、メチルパラベン 適量
精製水 残量
(pH4.5)
*1 花王(株)製 カルコール8098
*2 東レ・ダウコーニング・シリコーン(株)製 BY00−003
*3 日本ユニカー(株)製 FZ−3789
*4 日清製油(株)製 コスモール168AR
*5 ダイセル化学工業(株)製 SE−850
*6 ユニオンカーバイド(株)製 ポリオックスWSRN−60K。
下記組成のヘアトリートメントを調製した。このヘアトリートメントは、塗布時、濯ぎ時のリッチ感とその持続性、柔軟性、平滑性、及び乾燥後の柔らか感、櫛通り感が良好で、枝毛・切れ毛の抑制効果も良好であった。
アミドアミンA 2.0%
塩化ベヘニルトリメチルアンモニウム 0.3%
ステアリルアルコール 4.5%
ベヘニルアルコール*1 1.5%
ジアミド(F) 0.5%
シリコーン*2 1.0%
アミノ変性シリコーン*3 0.5%
グリコール酸 0.5%
リンゴ酸 0.1%
ジプロピレングリコール 3.0%
ベンジルアルコール 0.3%
アルギニン 0.2%
パントテニルエチルエーテル 0.1%
香料、メチルパラベン 適量
精製水 残量
(pH4.0)
*1 花王(株)製 カルコール22080
*2 東レ・ダウコーニング・シリコーン(株)製 SH200C-5000cs
*3 東レ・ダウコーニング・シリコーン(株)製 SM8704C。
下記組成のヘアコンディショナーを調製した。このヘアコンディショナーは、塗布時、濯ぎ時のリッチ感とその持続性、柔軟性、平滑性、及び乾燥後の柔らか感、櫛通り感が良好で、枝毛・切れ毛の抑制効果も良好であった。
アミドアミンA 1.5%
ステアリルアルコール*1 4.0%
プロピレングリコール 0.5%
ベンジルオキシエタノール 0.3%
ジアミド(A) 0.5%
シリコーン*2 2.0%
アミノ変性シリコーン−ポリオキシアルキレンブロック共重合体*3 0.5%
乳酸 0.5%
オレイン酸グリセリド 0.2%
セラミド1*4 0.1%
小麦タンパク加水分解物*5 0.3%
香料、メチルパラベン 適量
精製水 残量
(pH4.5)
*1 花王(株)製 カルコール8098
*2 東レ・ダウコーニング・シリコーン(株)製 BY00−003
*3 日本ユニカー製 FZ−3789
*4 Gist-brocades/Cosmoferm社,Phytoceramide 1
*5 セイワ化成社製 プロモイストWG
Claims (4)
- 下記(a)成分、(b)成分、(c)成分及び(d)成分を含有する毛髪化粧料。
(a)一般式(1)で表されるアミドアミン
(b)一般式(2)で表されるジアミド化合物
(c)炭素数8〜30の脂肪族アルコール
(d)有機酸 - 一般式(2)で表されるジアミド化合物において、R4が炭素数11〜22の直鎖若しくは分岐鎖のアルキレン基である請求項1記載の毛髪化粧料。
- 一般式(2)で表されるジアミド化合物において、R4が1〜4個の二重結合を有する、炭素数11〜22の直鎖若しくは分岐鎖のアルケニレン基である請求項1記載の毛髪化粧料。
- 更に、芳香族アルコールを含有する請求項1〜3のいずれかに記載の毛髪化粧料。
Priority Applications (1)
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JP2004168250A JP4198642B2 (ja) | 2004-06-07 | 2004-06-07 | 毛髪化粧料 |
Applications Claiming Priority (1)
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JP2004168250A JP4198642B2 (ja) | 2004-06-07 | 2004-06-07 | 毛髪化粧料 |
Publications (2)
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JP2005343861A JP2005343861A (ja) | 2005-12-15 |
JP4198642B2 true JP4198642B2 (ja) | 2008-12-17 |
Family
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Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
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JP4964428B2 (ja) * | 2005-04-11 | 2012-06-27 | 花王株式会社 | 毛髪化粧料 |
JP4806543B2 (ja) * | 2005-06-30 | 2011-11-02 | 花王株式会社 | 毛髪弾性改善剤 |
JP4979132B2 (ja) * | 2007-11-16 | 2012-07-18 | クラシエホームプロダクツ株式会社 | ヘアリンス組成物 |
WO2009158439A2 (en) * | 2008-06-25 | 2009-12-30 | The Procter & Gamble Company | Hair conditioning composition containing behenyl trimethyl ammonium chloride, and having higher yield point |
WO2020250966A1 (ja) * | 2019-06-11 | 2020-12-17 | 花王株式会社 | 乳化組成物 |
EP4248940A1 (en) | 2022-03-25 | 2023-09-27 | Wella Germany GmbH | Composition for enhancing keratin fibers |
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