JP4136954B2 - エアゾール組成物 - Google Patents
エアゾール組成物 Download PDFInfo
- Publication number
- JP4136954B2 JP4136954B2 JP2004016609A JP2004016609A JP4136954B2 JP 4136954 B2 JP4136954 B2 JP 4136954B2 JP 2004016609 A JP2004016609 A JP 2004016609A JP 2004016609 A JP2004016609 A JP 2004016609A JP 4136954 B2 JP4136954 B2 JP 4136954B2
- Authority
- JP
- Japan
- Prior art keywords
- foam
- aerosol composition
- group
- surfactants
- silicone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims description 41
- 239000000443 aerosol Substances 0.000 title claims description 37
- 229920001296 polysiloxane Polymers 0.000 claims description 25
- 239000000839 emulsion Substances 0.000 claims description 20
- 150000001412 amines Chemical class 0.000 claims description 16
- 239000011347 resin Substances 0.000 claims description 16
- 229920005989 resin Polymers 0.000 claims description 16
- 239000004094 surface-active agent Substances 0.000 claims description 12
- -1 long-chain fatty acid acrylic ester Chemical class 0.000 claims description 11
- 229920001577 copolymer Polymers 0.000 claims description 8
- 239000003093 cationic surfactant Substances 0.000 claims description 7
- 239000003380 propellant Substances 0.000 claims description 7
- 239000003945 anionic surfactant Substances 0.000 claims description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 6
- 239000002280 amphoteric surfactant Substances 0.000 claims description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 2
- 239000000470 constituent Substances 0.000 claims 1
- ODOJGQVXHIPDLF-UHFFFAOYSA-N ethyl(oxido)azanium;2-methylprop-2-enoic acid Chemical compound CC[NH2+][O-].CC(=C)C(O)=O ODOJGQVXHIPDLF-UHFFFAOYSA-N 0.000 claims 1
- 239000006260 foam Substances 0.000 description 50
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
- 239000002537 cosmetic Substances 0.000 description 10
- 230000015572 biosynthetic process Effects 0.000 description 8
- 238000011156 evaluation Methods 0.000 description 8
- 230000002688 persistence Effects 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 7
- 238000013329 compounding Methods 0.000 description 6
- 239000003915 liquefied petroleum gas Substances 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 229910003460 diamond Inorganic materials 0.000 description 5
- 239000010432 diamond Substances 0.000 description 5
- 230000001953 sensory effect Effects 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 4
- 230000003750 conditioning effect Effects 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 239000003205 fragrance Substances 0.000 description 4
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 4
- 239000008213 purified water Substances 0.000 description 4
- 229920005573 silicon-containing polymer Polymers 0.000 description 4
- 239000011550 stock solution Substances 0.000 description 4
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 4
- 238000011282 treatment Methods 0.000 description 4
- JTHZUSWLNCPZLX-UHFFFAOYSA-N 6-fluoro-3-methyl-2h-indazole Chemical compound FC1=CC=C2C(C)=NNC2=C1 JTHZUSWLNCPZLX-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 239000004359 castor oil Substances 0.000 description 3
- 235000019438 castor oil Nutrition 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 230000014759 maintenance of location Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000002736 nonionic surfactant Substances 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 235000019482 Palm oil Nutrition 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 2
- UCMIRNVEIXFBKS-UHFFFAOYSA-N beta-alanine Chemical compound NCCC(O)=O UCMIRNVEIXFBKS-UHFFFAOYSA-N 0.000 description 2
- 229960003237 betaine Drugs 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000008406 cosmetic ingredient Substances 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 239000003676 hair preparation Substances 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 description 2
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 2
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 2
- 229960002216 methylparaben Drugs 0.000 description 2
- 239000003595 mist Substances 0.000 description 2
- 239000002540 palm oil Substances 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 2
- 229960003080 taurine Drugs 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical compound C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 description 1
- FDCJDKXCCYFOCV-UHFFFAOYSA-N 1-hexadecoxyhexadecane Chemical compound CCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCC FDCJDKXCCYFOCV-UHFFFAOYSA-N 0.000 description 1
- HBXWUCXDUUJDRB-UHFFFAOYSA-N 1-octadecoxyoctadecane Chemical compound CCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCC HBXWUCXDUUJDRB-UHFFFAOYSA-N 0.000 description 1
- LEEDMQGKBNGPDN-UHFFFAOYSA-N 2-methylnonadecane Chemical compound CCCCCCCCCCCCCCCCCC(C)C LEEDMQGKBNGPDN-UHFFFAOYSA-N 0.000 description 1
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 1
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 1
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 1
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 description 1
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- XOBKSJJDNFUZPF-UHFFFAOYSA-N Methoxyethane Chemical compound CCOC XOBKSJJDNFUZPF-UHFFFAOYSA-N 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 108010077895 Sarcosine Proteins 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- WETDATKDGJUMJL-UHFFFAOYSA-M [Cl-].C(CCCCCCCCCCCCCCCCCCCCC)[N+](O)(O)CCCCCCCCCCCCCCCCCCCCCC Chemical compound [Cl-].C(CCCCCCCCCCCCCCCCCCCCC)[N+](O)(O)CCCCCCCCCCCCCCCCCCCCCC WETDATKDGJUMJL-UHFFFAOYSA-M 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 235000001014 amino acid Nutrition 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000003254 anti-foaming effect Effects 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 229940064004 antiseptic throat preparations Drugs 0.000 description 1
- 235000003704 aspartic acid Nutrition 0.000 description 1
- 229960005261 aspartic acid Drugs 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 229960000686 benzalkonium chloride Drugs 0.000 description 1
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 1
- 229940000635 beta-alanine Drugs 0.000 description 1
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 229940082500 cetostearyl alcohol Drugs 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011538 cleaning material Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005536 corrosion prevention Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- IUNMPGNGSSIWFP-UHFFFAOYSA-N dimethylaminopropylamine Chemical compound CN(C)CCCN IUNMPGNGSSIWFP-UHFFFAOYSA-N 0.000 description 1
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 150000002303 glucose derivatives Chemical class 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- 229960002989 glutamic acid Drugs 0.000 description 1
- 230000037308 hair color Effects 0.000 description 1
- UBHWBODXJBSFLH-UHFFFAOYSA-N hexadecan-1-ol;octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO.CCCCCCCCCCCCCCCCCCO UBHWBODXJBSFLH-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000007764 o/w emulsion Substances 0.000 description 1
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229940043230 sarcosine Drugs 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229940117986 sulfobetaine Drugs 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Cosmetics (AREA)
Description
(A)アミンオキシド基含有樹脂
(B)下記一般式(1):
(C)噴射剤
を含有することを特徴とするエアゾール組成物にある。
また本発明は、さらに(D)両性界面活性剤、アニオン性界面活性剤およびカチオン性界面活性剤からなる群より選ばれる一種又は二種以上の界面活性剤を含有する上記エアゾール組成物にある。
copolymerが特に好適に使用される。これらのアミンオキシド基含有樹脂は、「The Cosmetic Toiletry and Fragrance Association発行のInternational Cosmetic Ingredient Dictionary and Handbook」に記載されている。また、これらのアミンオキシド基含有樹脂は市販されており、クラリアント社から販売されているDiaformer Z711、Diaformer Z712、Diaformer Z731、Diaformer Z751、三菱化学社から販売されているダイヤフォーマーZ711、ダイヤフォーマーZ712、ダイヤフォーマーZ631、ダイヤフォーマーZ732、ダイヤフォーマーZ651、ダイヤフォーマーZ731、ダイヤフォーマーZ751等が挙げられる。
水性エマルジョンとする際には、低粘度の液状ジメチルポリシロキサン(例えば、粘度として200mPa・s以下のジメチルポリシロキサン)、オクタメチルシクロテトラシロキサン、デカメチルシクロペンタシロキサン、軽質イソパラフィンや軽質流動イソパラフィン等との混合物として提供されてエマルジョンに供される。また、水性エマルジョンの安定性、使用感や感触面の観点から、シリコーン重合体のnは500〜2,500が好ましい。
びカチオン性界面活性剤から選ばれる一種又は二種以上の界面活性剤を配合することによって、より泡の質、泡の持続性および低温下における泡の形成性を高めることができる。
20名の被験者によって25℃に保たれた室内で各試料を噴出させ手に取り、泡の質、泡の持続性の観察を行った。尚、評価基準は以下の通りである。
◎:非常に良好〔良いと答えた被験者が18名以上〕
○:良好〔良いと答えた被験者が15名以上18名未満〕
△:やや悪い〔良いと答えた被験者が10名以上15名未満〕
×:悪い〔良いと答えた被験者が10名未満〕
専門研究員が0℃に保たれた室内で各試料を噴出させ、目視により泡の形成性の観察を行った。尚、評価基準は以下の通りである。
◎:非常に良好
○:良好
△:やや悪い
×:悪い
20名の被験者によって試料を頭髪に使用し、整髪を実施した。その後被験者本人が、べたつきのなさ、ごわつきのなさ、自然なまとまりについて官能評価した。尚、評価基準は以下の通りである。
◎:非常に良好〔良いと答えた被験者が15名以上〕
○:良好〔良いと答えた被験者が10名以上15名未満〕
△:やや悪い〔良いと答えた被験者が5名以上10名未満〕
×:悪い〔良いと答えた被験者が5名未満〕
表1に記載の配合組成よりなる泡状整髪料を常法により調製し、前記各試験実施した。その結果を表1に併せて示す。
配合量(%)
(1)アミンオキシド基含有樹脂 8.0
(商品名:ダイヤフォーマーZ732、三菱化学社製)
(2)シリコーン水性エマルジョン (商品名:BY29−029 1.0
東レダウコーニングシリコーン社製)
(3)液化石油ガス(0.4MPa,25℃) 6.0
(4)グリセリン 5.0
(5)95度エタノール 15.0
(6)塩化ステアリルトリメチルアンモニウム 0.1
(7)セトステアリルアルコール 0.2
(8)POE(60)硬化ヒマシ油 0.3
(9)モノオレイン酸POE(20)ソルビタン 0.3
(10)ヤシ油脂肪酸ジエタノールアミド 0.2
(11)メチルパラベン 0.1
(12)シルク抽出液 0.5
(13)香料 0.1
(14)精製水 残 部
配合量(%)
(1)アミンオキシド基含有樹脂 2.0
(商品名:Diaformer Z751、クラリアント社製)
(2)アミンオキシド基含有樹脂 6.0
(商品名:ダイヤフォーマーZ732、三菱化学社製)
(3)シリコーン水性エマルジョン (商品名:BY29−007 3.0
東レダウコーニングシリコーン社製)
(4)液化石油ガス(0.4MPa,25℃) 6.0
(5)ジメチルエーテル 2.0
(6)アミドプロピルベタイン型界面活性剤 0.5
(商品名:レボン2000、三洋化成工業社製)
(7)メタクリロイルエチルベタイン・メタクリル酸エステル共重合体 3.0
(商品名:ユカフォーマーAM−75、三菱化学社製)
(8)95度エタノール 20.0
(9)ポリオキシエチレン・メチルシロキサン共重合体 0.5
(商品名:KF−6011、信越化学工業社製)
(10)POE(80)硬化ヒマシ油 0.3
(11)メチルパラベン 0.1
(12)エデト酸二ナトリウム 0.1
(13)精製水 残 部
配合量(%)
(1)アミンオキシド基含有樹脂 1.0
(商品名:Diaformer Z751、クラリアント社製)
(2)アミンオキシド基含有樹脂 1.0
(商品名:ダイヤフォーマーZ732、三菱化学社製)
(3)シリコーン水性エマルジョン 3.0
(商品名:KM−904、信越化学工業社製)
(4)液化石油ガス(0.4MPa,25℃) 7.0
(5)窒素 0.5
(6)N−アシルメチルタウリン型界面活性剤 0.3
(商品名:ダイヤポンK、日本油脂社製)
(7)エタノール 8.0
(8)POE(60)硬化ヒマシ油 0.3
(9)POE(15)セチルエーテル 0.3
(10)イソステアリン酸モノイソプロパノールアミド 0.5
(11)グリセリン 5.0
(12)セチルアルコール 0.1
(13)精製水 残 部
配合量(%)
(1)アミンオキシド基含有樹脂 4.0
(商品名:ダイヤフォーマーZ732、三菱化学社製)
(2)シリコーン水性エマルジョン 2.0
(商品名:KM−904、信越化学社工業製)
(3)液化石油ガス(0.3MPa,25℃) 40.0
(4)両性イオン性樹脂 2.0
(商品名:ユカフォーマーAM75RFN、三菱化学社製)
(5)エタノール 30.0
(6)POE(25)ステアリルエーテル 0.5
(7)ヤシ油脂肪酸ジエタノールアミド 0.5
(8)ジプロピレングリコール 3.0
(9)精製水 残 部
るセット性、セット保持性、コンディショニング性や風合い、使用感(べとつきのなさ、柔軟性、フレーキングのなさ、自然な仕上りなど)に優れ、特に、洗浄性に優れたエアゾール組成物を提供することができる。
Claims (2)
- さらに(D)両性界面活性剤、アニオン性界面活性剤およびカチオン性界面活性剤からなる群より選ばれる一種又は二種以上の界面活性剤を含有する請求項1記載の整髪用エアゾール組成物。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004016609A JP4136954B2 (ja) | 2004-01-26 | 2004-01-26 | エアゾール組成物 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004016609A JP4136954B2 (ja) | 2004-01-26 | 2004-01-26 | エアゾール組成物 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2005206555A JP2005206555A (ja) | 2005-08-04 |
JP4136954B2 true JP4136954B2 (ja) | 2008-08-20 |
Family
ID=34901709
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2004016609A Expired - Lifetime JP4136954B2 (ja) | 2004-01-26 | 2004-01-26 | エアゾール組成物 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP4136954B2 (ja) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4930683B2 (ja) * | 2006-02-23 | 2012-05-16 | ライオン株式会社 | 毛髪化粧料組成物 |
BRPI0923281A2 (pt) * | 2008-12-03 | 2020-11-03 | Shiseido Company, Ltd. | produto cosmetico à base de óleo em água e seu método de produção |
-
2004
- 2004-01-26 JP JP2004016609A patent/JP4136954B2/ja not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
JP2005206555A (ja) | 2005-08-04 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5215002B2 (ja) | 乳化型毛髪化粧料 | |
JP2008290973A (ja) | 泡沫状整髪用化粧料 | |
JP2009161488A (ja) | 毛髪化粧料 | |
JP2014043419A (ja) | 毛髪化粧料 | |
JP4704784B2 (ja) | 油性泡沫性クレンジング化粧料 | |
JP4136954B2 (ja) | エアゾール組成物 | |
JP4136967B2 (ja) | 毛髪化粧料 | |
JP2007031307A (ja) | 毛髪化粧料 | |
JP4180533B2 (ja) | 毛髪化粧料 | |
JP4136953B2 (ja) | エアゾール組成物 | |
JP2011037772A (ja) | エアゾール組成物 | |
JP4136952B2 (ja) | エアゾール組成物 | |
JP4136966B2 (ja) | 毛髪化粧料 | |
JP2005232117A (ja) | 毛髪化粧料 | |
JP2002161020A (ja) | 泡沫状化粧料 | |
JP5192871B2 (ja) | 洗浄剤組成物 | |
JP5856378B2 (ja) | 泡沫状毛髪クレンジング料 | |
JP2006028112A (ja) | 毛髪化粧料 | |
JPH08319212A (ja) | エアゾール組成物 | |
JP3652549B2 (ja) | 化粧料 | |
JPH0892044A (ja) | 毛髪化粧料 | |
JP2001302446A (ja) | エアゾール組成物 | |
JP2002308732A (ja) | エアゾール組成物 | |
JP2000095647A (ja) | 頭髪用化粧料 | |
JP2000169345A (ja) | 頭髪用化粧料 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A711 | Notification of change in applicant |
Free format text: JAPANESE INTERMEDIATE CODE: A711 Effective date: 20060328 |
|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20060822 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20080122 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20080129 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20080319 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20080527 |
|
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20080603 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 4136954 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20110613 Year of fee payment: 3 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20110613 Year of fee payment: 3 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120613 Year of fee payment: 4 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120613 Year of fee payment: 4 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130613 Year of fee payment: 5 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
EXPY | Cancellation because of completion of term |