JP4092373B2 - Sludge treatment method - Google Patents

Sludge treatment method Download PDF

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JP4092373B2
JP4092373B2 JP2001056606A JP2001056606A JP4092373B2 JP 4092373 B2 JP4092373 B2 JP 4092373B2 JP 2001056606 A JP2001056606 A JP 2001056606A JP 2001056606 A JP2001056606 A JP 2001056606A JP 4092373 B2 JP4092373 B2 JP 4092373B2
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soil
sludge
water
mixed
granular
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JP2002254097A (en
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幸彦 山田
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石井 秀雄
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Description

【0001】
【発明の属する技術分野】
本発明は、浄水処理の過程で処理場から多量に排出されるスラッジの処理方法に関する。
【0002】
【従来の技術】
浄水処理場の処理過程で、多量の沈殿物がこれら処理場に堆積する。この堆積した沈殿物はスラッジ、あるいは汚泥と言われ、含水率が極めて高い物質である。スラッジの堆積は処理場の処理効率を低下させるため、逐次排出されるが、含水率が高いため処理が困難であった。このため、大部分のスラッジは、脱水処理工程を経て、あるいは経ることなく埋め立てなどで処理されているのが現状である。
【0003】
しかし、首都圏を始めとして、各地方自治体がスラッジを埋め立て廃棄処分する最終処分場の確保が年々困難になってきており、スラッジを再資源として有効に活用できる画期的な活用策の開発が期待されている。そこで、下水処理場等から採取した下水汚泥を一般廃棄物、産業廃棄物と共に焼却し、得た焼却灰を加水して含水比率を調製した後、カルボキシル基を有する高分子化合物を添加し砂状に粒状化する方法が開発されている(特開平10−2979948号公報参照)。
しかし、この方法では、下水汚泥を一度焼却した後、加水調製する工程が必要となるため、工程が複雑な上に焼却炉や加水調製装置等が必要になり経済的ではなかった。
【0004】
【発明が解決しようとする課題】
そこで、本発明は、浄水処理場から排出されるスラッジを加工処理することなく、そのままの状態で再資源として活用した新たなスラッジの処理方法の提供を目的とする。
【0005】
【課題を解決するための手段】
本発明は、浄水処理場から発生するスラッジ、及び土木建設現場から発生する粘性及び含水比の高い土壌の物性を鋭意研究した結果、土壌にスラッジを添加混合した混合土にカルボキシル基含有水溶性重合体を添加して撹拌混合すると、スラッジの細かい粒子が土壌の粒子と結合して、粘性の強い土壌が細かい粒の粒状土に変性することを見い出してなされたものである。
【0006】
具体的に述べると、本発明の処理方法は、スラッジに土壌を混合させた混合土に、径40mmの砕石もしくは原石とカルボキシル基含有水溶性重合体を添加し、前記砕石もしくは原石で前記混合土をカットしながら攪拌混合し粒状化した後、固化材を添加混合することを特徴とする。生石灰粉末等の固化材を添加し混合すると、粒状土中の水分と反応して粒状土の表面に消石灰の被膜が形成され、より強固な粒状土を得ることができる。
【0007】
【発明の実施の形態】
以下、本発明を詳細に説明する。本発明で使用するスラッジは、粒度が0.1mm以下の通常のスラッジでも使用できるが、浄水処理場に堆積した浄水汚泥は、周知なように水酸化アルミニュウムを主原料とする微細な固形粒状物質を含有する含水比率が98%以上の泥質物であり、カドミウム、鉛等の有害物質を含まないので好ましい。また下水処理場から排出される下水汚泥を使用する場合は、予め、下水汚泥に含まれるカドミウム、鉛、六価クロムのような有害物質を化学的処理等の手段により除去することが望ましい。
【0008】
また、本発明に使用する土壌は、ビル建設工事、宅地造成工事、地中埋設管工事等の一般の土木・建築工事に伴って工事現場から多量に発生する柔軟で粘着性が強く、かつ含水比の高い建設発生土、建設残土である。
【0009】
本発明は、土木.建築工事現場から採取した土壌に、スラッジを添加して撹拌機で撹拌混合する。スラッジを土壌に添加して撹拌混合すると、スラッジを構成する細かい固形粒状物は、解砕された土壌の土粒子と結合するため、土壌はスラッジを含んだ粒状化しやすい粒状土に変性する。
【0010】
スラッジを土壌に添加する割合は、スラッジと土壌との総和に対して30重量%を越えないことが好ましい。混合の割合が30重量%を越えると、撹拌混合してもスラッジが塊として残存し、土壌とスラッジとの結合性が生じない。このため、スラッジは、含水性を帯びない細かい固化粒状物の状態で土壌中に残存するため、後述するカルボキシル基含有水溶性重合体を添加混合してもスラッジと反応しないので、粒状土を生成することができない。
【0011】
本発明は、スラッジの細かい粒子が土壌の粒子と結合して、粘性の強い土壌が細かい粒の粒状土に変性することを確実なものとするため、土壌とスラッジとの混合土にカルボキシル基含有水溶性重合体を添加混合する。この際、混合土に対して径40mmの砕石もしくは原石を10重量%以下加えることにより、土壌とスラッジとの混合土とカルボキシル基含有水溶性重合体との混合が均一となる。該重合体は、親水基としてカルボキシル基を有するものであり、重合体を構成する全単量体単位のうちカルボキシル基を有する単量体が、通常1〜80モル%、好ましくは5〜60モル%含まれる。
【0012】
また、カルボキシル基は、遊離酸または塩の形のどちらで存在してもよい。塩の種類としては、例えばナトリウム、カリウムなどのアルカリ金属の塩、カルシウム、マグネシウムなどのアルカリ土類金属の塩、アンモニウム塩、炭素数1〜18のアルキルアミン、アルカノールアミンなどのアミン塩、およびこれら2種以上の混合物があるが、好ましくはアルカリ金属の塩類である。
【0013】
かかる水溶性重合体としては、(メタ)アクリル酸またはその塩と(メタ)アクリルアミドとの共重合体、マレイン酸またはその塩と酢酸ビニルとの共重合体、イタコン酸またはその塩と(メタ)アクリルアミドとの共重合体などの合成水溶性重合体、アラビヤガム、カラヤガム、トラントガム、アルギン酸などの天然水溶性重合体、及び、カルボキシメチルセルロース、カルボキシハイドロエチルセルロース、グアーガム変性物のような半合成水溶性重合体が例示される。
【0014】
以上のカルボキシル基含有水溶性重合体のうち、好ましくは(メタ)アクリル酸またはその塩と(メタ)アクリルアミドとの共重合体である。(メタ)アクリル酸またはその塩を含有する(メタ)アクリルアミド系重合体としては、(メタ)アクリル酸またはその塩と(メタ)アクリルアミドを共重合したもののほか、(メタ)アクリルアミドの単独重合体を部分加水分解したものでもよい。
【0015】
更に、以上のカルボキシル基含有水溶性重合体には、親水性基としてスルホン酸基を含む単量体、例えばビニルスルホン酸、アクリルスルホン酸、2−アクリルアミド−2−メチルプロパンスルホン酸およびこれらの塩などを含めて共重合してもよい。また、水溶性を阻害しない程度であればオレフィン、アクリル酸エステル、ビニルエステルのような疎水性単量体を含んでもよい。
【0016】
カルボキシル基含有水溶性重合体の添加量は、スラッジの添加割合や土壌の含水比などに応じて異なるが、30重量%のスラッジを土壌に混合した混合土の場合は、混合土に対して0.07〜0.1重量%添加する。また、カルボキシル基含有水溶性重合体と混合土との撹拌混合は、撹拌機を用いて緩やかな撹拌を通常0.8〜2分程度行うのが望ましい。
【0017】
混合土にカルボキシル基含有水溶性重合体を上記の割合で添加し、撹拌機で約0.8〜2分程度緩やかに撹拌混合すると、カルボキシル基含有水溶性重合体は、粒状土の表面を均一に被覆し、粒状土内部の土粒子やスラッジの固形粒子間の遊離水分を吸引して溶解する。このため、カルボキシル基含有水溶性重合体に吸引された土壌内部の水分は、遊離水としての性質を失い、疑似固定水(吸着水)として粒状土の表面に固定されることになり、粒状土は互いに付着せず、撹拌混合されることにより、球状に造粒される。
【0018】
本発明は、生成された粒状土の表面に固定された被膜を安定化させ、長期に亘って粒状に保持するため、石灰等の固化材を粒状土の表面に均一に付着させる。本発明に使用する固化材は、粒状土の表面に付着し易いものがよく、平均粒径が0.5mm以下の石灰粉末を用いるのが好ましい。固化材としての石灰には、酸化カルシウム、水酸化カルシウムを含むもので、具体的には、消石灰、生石灰、水硬セメント、石灰系改良材、セメント系改良材などを適用できるが、脱水および固化速度が速い生石灰の粉末が好ましい。固化材の添加量は、混合土に対して、1〜10重量%が好ましい。
【0019】
水分を吸引し溶解したカルボキシル基含有水溶性重合体の被膜で被覆された粒状土の表面に、生石灰等の固化材が付着すると、被膜中の水分は固形材と反応して発熱しながら消石灰となるため、被膜中の水分を蒸発させながら、石灰分布の高い表面から浸透しつつポゾラン反応によって、強度が発現する。
粒状土の強度は生石灰の量により変化するので、粒状土の使用目的に応じて生石灰の量を増やすことができる。例えば、埋め戻し用にしようする粒状土の場合は生石灰の量は混合土に対して3重量%程度とする。
なお、粒状土の強度を更に発現させるために養生を行うこともできる。養生は、通常、常温下で1〜7日、好ましくは3〜6日程度放置することで行う。
【0020】
本発明の処理方法により製造された粒状土の粒度は、東京都の基準を充分に満たす範囲内に収まり、また粒度の大小は砕石または原石の量によって変化させることができ、粒径も幅広く均衡が保たれるため、従来の粒状改良土と同等の地盤支持力、強度特性、粒土特性を有し透水性に優れた粒状土を得ることができる。
【0021】
【実施例】
以下、本発明の具体例として、実施例を述べるが本発明はこれら実施例に限定されるものでない。
実施例
建築現場から採取した含水比98%の関東ロームが主体な含水土壌7kgと、浄水処理場から採取したスラッジ3kgとを容量20リットルのミキサーに入れて約60秒間撹拌混合して粒状化しやすい混合土を得た。
次に、上記工程で得た混合土10kgにアクリルアミドとアクリル酸ナトリウムの共重合体10g(混合土に対して0.1重量%)を添加し約90秒間緩やかに撹拌混合した後、生石灰粉末300gを添加し、更に30秒間ほとんど外圧を加えないで撹拌すると消石灰で被覆された粒状土を得た。
【0022】
この粒状土をふるいわけ試験機にかけ粒径等を計測した。測定結果を表1に示す。このふるいわけ試験機は、目開き13.2mmで重量576.6g、目開き9.5mmで重量545.6g、目開き6.7mmで重量479.6g、目開き4.75mmで重量527.6g、目開き2.36mmで重量498.4g、目開き1.18mmで重量460.7g、目開き0.425mmで重量403.3g、目開き0.075mmで重量361g及び目開き0mmで重量356.1gの網ふるいを上方からこの順序に重合し、上方から795.7gの粒状土を供給して行った。
【0023】
【表1】
ふるいわけ測定結果

Figure 0004092373
(注)百分率C÷合計×100%
すなわち、最上段のふるいに供給された粒状土はすべて目開き13.2mmの網目より2段目のふるいに落下し、2段目の目開き9.5mmのふるいの上には1.6gの残留土を残して3段目に落下する。
このようにして、最下段の目開き0mmのふるい上には1.1gの粒状土が残留する。また、表中の百分率は各ふるい上に残留した粒状土の供給粒状土に対するものである。
【0024】
上記の測定結果や試験結果から明らかなように、本発明によって得られた粒状土の粒度は、0.425〜9.5mmの範囲内のものが大多数を示め、東京都基準(粒度13.0mm以下)に適合し、良質な砂と同等の粒径、粒度分布を有していた。なお、平均粒径は2.6mmであった。
【0025】
以上のことから、単独では細粒分が多すぎるスラッジでも予め土壌に混合させておけば、カルボキシル基含有水溶液重合体の浸透性を促進させ、従来の粒状改良土と同等の地盤支持力、せん断強度特性を備えた粒状土を得ることができることが分かる。
【0026】
【発明の効果】
本発明によれば、予め、土壌にスラッジを添加混合することにより、土壌は添加されたスラッジの粒子を含んだ細かい粒状の含水土壌になるため、カルボルキシル基含有水溶性重合体の浸透が良好になり、生成された粒状土はより川砂に近いものとなる。
また、粘性が強い土壌は、撹拌するのが困難であったが、スラッジを添加することにより、スラッジが撹拌補助剤的な役割を果たすため、撹拌機に対する負荷を軽減でき耐久性を向上することができる。
【0027】
また、従来、その大部分が埋め立て廃棄物として埋め立て処理されていたスラッジを再生粒状土の再生資源として利用できるため、スラッジの利用性を高め、環境問題に貢献するところが大きい。また、スラッジを再生利用するにあたり、スラッジ自体に特別な加工処理工程を介在する必要がないため、再生処理に要する費用を軽減できる。
さらに、混合土に対して径40mmの砕石もしくは原石を10重量%以下加えることにより、粘性の強い混合土がこれら砕石もしくは原石でカットされてカルボキシル基含有水溶性重合体の混合を容易に且つ均一にし、耐久力が向上すると共に、砕石もしくは原石の量によって粒度の大小を変化させることができる。[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a method for treating sludge discharged in a large amount from a treatment plant in the course of water purification treatment.
[0002]
[Prior art]
A large amount of sediment accumulates in these treatment plants during the treatment process of the water treatment plant. This deposited sediment is called sludge or sludge and is a substance with a very high water content. The sludge accumulation is sequentially discharged to reduce the treatment efficiency of the treatment plant, but the treatment is difficult due to the high water content. For this reason, most sludge is currently processed in landfills through or without a dehydration process.
[0003]
However, it has become difficult year by year to secure a final disposal site where local governments, including the Tokyo metropolitan area, landfill and dispose of sludge. Expected. Therefore, sewage sludge collected from sewage treatment plants, etc. is incinerated with general waste and industrial waste, and the water content is adjusted by adding the incinerated ash, and then a polymer compound having a carboxyl group is added to form sand. A method of granulating the material has been developed (see JP-A-10-2997948).
However, this method requires a step of adding water after incineration of the sewage sludge, so that the process is complicated and an incinerator, a water preparation device, and the like are required, which is not economical.
[0004]
[Problems to be solved by the invention]
Then, this invention aims at provision of the processing method of the new sludge utilized as a resource as it is, without processing the sludge discharged | emitted from a water purification plant.
[0005]
[Means for Solving the Problems]
As a result of intensive studies on the physical properties of sludge generated from a water treatment plant and soil having a high viscosity and moisture content generated from a civil engineering construction site, a carboxyl group-containing water-soluble heavy weight is added to the mixed soil obtained by adding sludge to the soil. It was found by adding the coalesced mixture and stirring and mixing that the fine particles of the sludge were combined with the particles of the soil, and the highly viscous soil was denatured into fine granular soil.
[0006]
Specifically, in the treatment method of the present invention, a crushed stone or rough stone having a diameter of 40 mm and a carboxyl group-containing water-soluble polymer are added to mixed soil obtained by mixing soil with sludge, and the mixed soil is mixed with the crushed stone or raw stone. after granulated by stirring and mixing while cutting, and wherein the admixing solidifying material. When a solidifying material such as quick lime powder is added and mixed, it reacts with moisture in the granular soil to form a slaked lime coating on the surface of the granular soil, thereby obtaining a stronger granular soil.
[0007]
DETAILED DESCRIPTION OF THE INVENTION
Hereinafter, the present invention will be described in detail. The sludge used in the present invention can be used with ordinary sludge having a particle size of 0.1 mm or less, but the purified water sludge deposited in the water treatment plant is a fine solid particulate material mainly composed of aluminum hydroxide as is well known. It is preferable because it is a mud having a water content of 98% or more and does not contain harmful substances such as cadmium and lead. In addition, when using sewage sludge discharged from a sewage treatment plant, it is desirable to previously remove harmful substances such as cadmium, lead, and hexavalent chromium contained in the sewage sludge by means of chemical treatment or the like.
[0008]
In addition, the soil used in the present invention is a flexible, sticky and water-containing material that is generated in large quantities from the construction site due to general civil engineering and construction work such as building construction work, residential land preparation work, underground pipe construction, etc. This is the soil with a high ratio of construction and construction.
[0009]
The present invention relates to civil engineering. Sludge is added to the soil collected from the construction site and mixed with a stirrer. When the sludge is added to the soil and mixed with stirring, the fine solid particles constituting the sludge are combined with the soil particles of the crushed soil, so that the soil is denatured into a granular soil containing sludge and easily granulated.
[0010]
The proportion of sludge added to the soil is preferably not more than 30% by weight with respect to the sum of sludge and soil. When the mixing ratio exceeds 30% by weight, sludge remains as a lump even when stirring and mixing, and the bond between soil and sludge does not occur. For this reason, sludge remains in the soil in the form of fine solid particles that do not have water content, so even if the carboxyl group-containing water-soluble polymer described later is added and mixed, it does not react with the sludge. Can not do it.
[0011]
In order to ensure that fine particles of sludge are combined with soil particles and the viscous soil is denatured into fine granular soil, the present invention contains a carboxyl group in the mixed soil of soil and sludge. Add water-soluble polymer and mix. In this case, the crushed stone or rough diameter 40mm by adding 10 wt% or less of the mixed soil, a mixed GaHitoshi one mixed soil and the carboxyl group-containing water-soluble polymer of soil and sludge. The polymer has a carboxyl group as a hydrophilic group, and the monomer having a carboxyl group among all the monomer units constituting the polymer is usually 1 to 80 mol%, preferably 5 to 60 mol. %included.
[0012]
Also, the carboxyl group may be present in either a free acid or salt form. Examples of the salt include alkali metal salts such as sodium and potassium, alkaline earth metal salts such as calcium and magnesium, ammonium salts, amine salts such as alkyl amines having 1 to 18 carbon atoms, alkanolamines, and the like. There are two or more mixtures, but alkali metal salts are preferred.
[0013]
Such water-soluble polymers include (meth) acrylic acid or a salt thereof and (meth) acrylamide copolymer, maleic acid or a salt thereof and vinyl acetate, itaconic acid or a salt thereof and (meth). Synthetic water-soluble polymers such as copolymers with acrylamide, natural water-soluble polymers such as arabic gum, karaya gum, tolanto gum, alginic acid, and semi-synthetic water-soluble polymers such as carboxymethylcellulose, carboxyhydroethylcellulose, and guar gum modified products Is exemplified.
[0014]
Of the above water-soluble carboxyl group-containing polymers, a copolymer of (meth) acrylic acid or a salt thereof and (meth) acrylamide is preferable. The (meth) acrylamide polymer containing (meth) acrylic acid or a salt thereof includes a copolymer of (meth) acrylic acid or a salt thereof and (meth) acrylamide, or a homopolymer of (meth) acrylamide. It may be partially hydrolyzed.
[0015]
Further, the above-mentioned water-soluble polymer containing carboxyl groups includes monomers containing sulfonic acid groups as hydrophilic groups, such as vinyl sulfonic acid, acrylic sulfonic acid, 2-acrylamido-2-methylpropane sulfonic acid, and salts thereof. Etc. may be copolymerized. Further, hydrophobic monomers such as olefins, acrylic acid esters, and vinyl esters may be included as long as they do not inhibit water solubility.
[0016]
The addition amount of the carboxyl group-containing water-soluble polymer varies depending on the addition ratio of sludge, the moisture content of the soil, etc., but in the case of mixed soil in which 30% by weight of sludge is mixed with soil, it is 0 with respect to the mixed soil. Add 0.07 to 0.1 wt%. Moreover, it is desirable that the stirring and mixing of the carboxyl group-containing water-soluble polymer and the mixed soil is carried out by using a stirrer and generally performing gentle stirring for about 0.8 to 2 minutes.
[0017]
When the carboxyl group-containing water-soluble polymer is added to the mixed soil in the above ratio and gently stirred and mixed for about 0.8 to 2 minutes with a stirrer, the carboxyl group-containing water-soluble polymer has a uniform surface of the granular soil. The free water between the soil particles inside the granular soil and the solid particles of the sludge is sucked and dissolved. For this reason, the water inside the soil sucked into the carboxyl group-containing water-soluble polymer loses its properties as free water and is fixed on the surface of the granular soil as pseudo-fixed water (adsorbed water). Do not adhere to each other and are granulated into a spherical shape by stirring and mixing.
[0018]
The present invention stabilizes the coating fixed on the surface of the generated granular soil and holds the solidified material such as lime uniformly on the surface of the granular soil in order to keep it in a granular shape for a long time. The solidified material used in the present invention should be easy to adhere to the surface of the granular soil, and it is preferable to use lime powder having an average particle size of 0.5 mm or less. The lime as a solidifying material includes calcium oxide and calcium hydroxide. Specifically, slaked lime, quick lime, hydraulic cement, lime-based improving material, cement-based improving material, etc. can be applied, but dehydration and solidification. Fast lime powder is preferred. The addition amount of the solidifying material is preferably 1 to 10% by weight with respect to the mixed soil.
[0019]
When solidified material such as quicklime adheres to the surface of the granular soil coated with a coating of a carboxyl group-containing water-soluble polymer that has absorbed and dissolved moisture, the moisture in the coating reacts with the solid material and generates heat while generating heat. Therefore, the strength is expressed by the pozzolanic reaction while penetrating from the surface having a high lime distribution while evaporating the moisture in the film.
Since the intensity | strength of granular soil changes with the quantity of quick lime, the quantity of quick lime can be increased according to the intended purpose of granular soil. For example, in the case of granular soil to be used for backfilling, the amount of quicklime is about 3% by weight with respect to the mixed soil.
Curing can also be performed to further develop the strength of the granular soil. Curing is usually performed by leaving it to stand at room temperature for 1 to 7 days, preferably about 3 to 6 days.
[0020]
The particle size of the granular soil produced by the treatment method of the present invention falls within a range that sufficiently satisfies the standards of Tokyo, and the size of the particle size can be changed depending on the amount of crushed stone or raw stone, and the particle size is also widely balanced. Therefore, it is possible to obtain a granular soil having the same ground supporting force, strength characteristics, and granular soil characteristics as those of conventional granular improved soils and excellent in water permeability.
[0021]
【Example】
Hereinafter, examples will be described as specific examples of the present invention, but the present invention is not limited to these examples.
Example 7 kg of water-containing soil mainly composed of Kanto loam with a water content ratio of 98% collected from a construction site and 3 kg of sludge collected from a water treatment plant are placed in a mixer with a capacity of 20 liters and mixed for about 60 seconds to be easily granulated. A mixed soil was obtained.
Next, 10 g of a copolymer of acrylamide and sodium acrylate (0.1% by weight with respect to the mixed soil) is added to 10 kg of the mixed soil obtained in the above step, and after gently stirring and mixing for about 90 seconds, 300 g of quick lime powder is added. And stirring for 30 seconds with almost no external pressure applied, a granular soil coated with slaked lime was obtained.
[0022]
This granular soil was sieved and passed through a testing machine, and the particle size was measured. The measurement results are shown in Table 1. This sieve testing machine has an opening of 13.2 mm and a weight of 576.6 g, an opening of 9.5 mm and a weight of 545.6 g, an opening of 6.7 mm and a weight of 479.6 g, and an opening of 4.75 mm and a weight of 527.6 g. , A weight of 348.4 g with an aperture of 2.36 mm, a weight of 460.7 g with an aperture of 1.18 mm, a weight of 403.3 g with an aperture of 0.425 mm, a weight of 361 g with an aperture of 0.075 mm, and a weight of 356. A 1-g screen sieve was polymerized in this order from above, and 795.7 g of granular soil was supplied from above.
[0023]
[Table 1]
Sieve reason measurement result
Figure 0004092373
(Note) Percentage C / total x 100%
That is, all of the granular soil supplied to the uppermost sieve falls from the 13.2 mm mesh to the second sieve, and 1.6 g of the second sieve opens to the 9.5 mm sieve. It falls to the third stage leaving the residual soil.
In this way, 1.1 g of granular soil remains on the lowermost sieve having a mesh opening of 0 mm. In addition, the percentages in the table are relative to the supplied granular soil of the granular soil remaining on each sieve.
[0024]
As apparent from the above measurement results and test results, the grain size of the granular soil obtained by the present invention is mostly in the range of 0.425 to 9.5 mm, indicating the Tokyo standard (grain size 13 0.03 mm or less) and had a particle size and particle size distribution equivalent to that of good quality sand. The average particle size was 2.6 mm.
[0025]
From the above, if the sludge containing too much fine particles alone is mixed with the soil in advance, it promotes the permeability of the carboxyl group-containing aqueous polymer, and provides the same ground bearing capacity and shear as conventional granular improved soil. It can be seen that a granular soil having strength characteristics can be obtained.
[0026]
【The invention's effect】
According to the present invention, by adding and mixing the sludge in the soil in advance, the soil becomes a fine granular water-containing soil containing the added sludge particles, so that the penetration of the carboxyl group-containing water-soluble polymer is good. Thus, the generated granular soil becomes closer to river sand.
In addition, soil with strong viscosity was difficult to stir, but by adding sludge, sludge plays the role of a stirrer, thus reducing the load on the stirrer and improving durability. Can do.
[0027]
In addition, since sludge that has been mostly landfilled as landfill waste can be used as a reclaimed resource for reclaimed granular soil, the sludge utilization is greatly improved, contributing to environmental problems. Further, when sludge is recycled, it is not necessary to intervene a special processing process in the sludge itself, so that the cost required for the regeneration process can be reduced.
Furthermore , by adding 10% by weight or less of crushed stone or raw stone having a diameter of 40 mm to the mixed soil, the highly viscous mixed soil is cut with these crushed stone or raw stone, so that the carboxyl group-containing water-soluble polymer can be mixed easily and uniformly. In addition, the durability can be improved and the particle size can be changed depending on the amount of crushed stone or raw stone .

Claims (4)

スラッジに土壌を混合させた混合土に、径40mmの砕石もしくは原石とカルボキシル基含有水溶性重合体を添加し、前記砕石もしくは原石で前記混合土をカットしながら攪拌混合し粒状化した後、固化材を添加混合することを特徴とするスラッジの処理方法。A mixed soil which is mixed with soil sludge, was added crushed stone or ore and a carboxyl group-containing water-soluble polymer of diameter 40 mm, it was granulated by stirring and mixing while cutting the mixed soil in the crushed stone or ore, A method for treating sludge, comprising adding and mixing a solidifying material. 前記固化材が石灰の粉末であることを特徴とする請求項1に記載のスラッジの処理方法。  The sludge treatment method according to claim 1, wherein the solidifying material is lime powder. 前記混合土の前記スラッジ量は前記混合土の30重量%を越えないことを特徴とする請求項1又は2記載のスラッジの処理方法。  The sludge treatment method according to claim 1 or 2, wherein the amount of the sludge of the mixed soil does not exceed 30% by weight of the mixed soil. 前記カルボキシル基含有水溶性重合体は前記混合土の0.07〜0.1重量%であることを特徴とする請求項1又3のいずれかに記載のスラッジの処理方法。  4. The sludge treatment method according to claim 1, wherein the carboxyl group-containing water-soluble polymer is 0.07 to 0.1% by weight of the mixed soil.
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JP2005246141A (en) * 2004-03-01 2005-09-15 Ishii Hideo Improvement method for water-containing fine-grained soil
JP5120005B2 (en) * 2008-03-25 2013-01-16 Jfeエンジニアリング株式会社 Treatment method of organic sludge

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06310191A (en) * 1993-04-28 1994-11-04 Kinki Denki Kk Linear sleeve cover

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