JP3582504B2 - Hot-press plated steel sheet - Google Patents

Hot-press plated steel sheet Download PDF

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Publication number
JP3582504B2
JP3582504B2 JP2001264591A JP2001264591A JP3582504B2 JP 3582504 B2 JP3582504 B2 JP 3582504B2 JP 2001264591 A JP2001264591 A JP 2001264591A JP 2001264591 A JP2001264591 A JP 2001264591A JP 3582504 B2 JP3582504 B2 JP 3582504B2
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Prior art keywords
steel sheet
plating
zinc
steel
hot
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JP2003073774A (en
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和仁 今井
保 土岐
幸宏 吉川
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Nippon Steel Corp
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Sumitomo Metal Industries Ltd
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/32Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer
    • C23C28/322Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer only coatings of metal elements only
    • C23C28/3225Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer only coatings of metal elements only with at least one zinc-based layer
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/34Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates
    • C23C28/345Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one oxide layer

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)
  • Coating With Molten Metal (AREA)

Description

【0001】
【発明の属する技術分野】
本発明は、熱間プレス用鋼材、特に自動車用の足廻り、シャ−シ、補強部品などの製造に使用される熱間プレス用鋼板および鋼材に関する。
【0002】
【従来の技術】
近年、自動車の軽量化のため、鋼材の高強度化を図り、使用する鋼材の厚みを減ずる努力が進んでいる。しかし、鋼材としての鋼板をプレス成形、例えば絞り形成を行うことを考えた場合、使用する鋼板の強度が高くなると絞り成形加工時に金型との接触圧力が高まり鋼板のカジリや鋼板の破断が発生したり、またそのような問題を少しでも軽減しようと鋼板の絞り成形時の材料の金型内への流入を高めるためブランク押さえ圧を下げると成形後の形状がばらつく等の問題点がある。
【0003】
また、形状安定性いわゆるスプリングバックも発生し、これに対しては例えば潤滑剤使用による改善対策等もあるが、780MPa級以上の高強度鋼板ではその効果が小さい。
【0004】
このように難加工材料としての高強度鋼のプレス成形には問題点が多いのが現状である。なお、以下、この種の材料を「難プレス成形材料」という。
【0005】
【発明が解決しようとする課題】
ところで、このような難プレス成形材料をプレス成形する技術として、成形すべき材料を予め加熱して成形する方法が考えられる。いわゆる熱間プレス成形および温間プレス成形である。以下、単に熱間プレス成形と総称する。
【0006】
しかし、熱間プレス成形は、加熱した鋼板を加工する成形方法であるため、表面酸化は避けられず、たとえ鋼板を非酸化性雰囲気中で加熱しても、例えば加熱炉からプレス成形のため取り出すときに大気にふれると表面に鉄酸化物が形成される。この鉄酸化物がプレス時に脱落して金型に付着して生産性を低下させたり、あるいはプレス後の製品にそのような酸化皮膜が残存して外観が不良となるという問題がある。しかも、このような酸化皮膜が残存すると、次工程で塗装する場合に鋼板との塗膜密着性が劣ることになる。またスケールが残存する場合、次工程で塗装してもスケール/鋼板間の密着性不芳のせいで塗膜密着性が劣る。
【0007】
そこで熱間プレス成形後は、ショットブラストを行ってそのようなスケールを構成する鉄酸化層を除去することが必要となるが、これではコスト増は免れない。
【0008】
また加熱時にそのようなスケールを形成させないために低合金鋼やステンレス鋼を用いてもスケール発生は完全に防止できないばかりか、普通鋼に比較して大幅にコスト高となる。
【0009】
このような熱間プレス成形時の表面酸化の問題に対する対策として加熱時の雰囲気とプレス工程全体の雰囲気をともに非酸化性雰囲気にすることも理論上有効ではあるが設備上大幅な高コストとなる。
【0010】
このような事情からも、今日でも熱間プレスについては多くの提案はされているが、実用的な段階には至っていないのが現状である。
ここに、特許出願として提案されている現状の技術について概観すると次のようである。
【0011】
例えば、熱間プレスの利点としては、プレス成形とともに熱処理を行えることが挙げられるが、その際にさらに同時に表面処理をも行うことが、特開平7−116900号公報に提案されている。もちろん、このような技術にも前述のような表面酸化の問題もあるが、複雑な形状の金型に防錆剤等の表面処理剤を均一に塗布することは難しく、またそのように金型に予め塗布した表面処理剤をプレス成形時に製品に均一に転写させることも難しい。もちろん、プレス成形後の処理としてめっき処理等の防錆処理を個別に行うことは自明であるが、生産性が低く、大幅なコスト増をもたらすことは明らかである。
【0012】
このように高強度の鋼板を成形するために熱間でプレス成形する方法があるが生成した鉄酸化物を除去する工程が必要であるのと、たとえ鉄酸化物を除去しても鋼板のみでは防錆性に劣るのが現状である。
【0013】
防錆性あるいは耐食性改善という面だけからでは、特開平6−240414号公報で提案されているように、例えばドア内のインパクトバーのような自動車用部品では、ドア内に浸入した腐食因子の水分が焼入鋼管の管内無塗装部を腐食させることがあるため、そのような焼入鋼管を構成する鋼材の鋼成分にCr、Mo等の元素を添加して耐食性を向上させている例もある。しかし、このような対策では、Cr、Mo添加でコスト高となるばかりでなく、プレス成形用の材料の場合、同合金成分の添加によるプレス成形性の劣化の問題がある。
【0014】
ここに、本発明の課題は、いわゆる難プレス成形材料について熱間プレスを行っても所定の耐食性を確保でき、外観劣化が生じない熱間プレス用の鋼材を提供することである。
【0015】
さらに本発明の具体的課題は、耐食性確保のための後処理を必要とせずに、例えば難プレス成形材料である高張力鋼板の熱間プレス成形を可能とし、同時に耐食性をも確保できる技術を提供することである。
【0016】
【課題を解決するための手段】
本発明者らは、かかる課題を解決する手段について種々の角度から鋭意検討の結果、前記のような難プレス成形材料をそのままプレス成形するのではなく、変形抵抗を低減させるべく高温状態でプレス成形を行い、同時にそのときに、後処理を行うことなく優れた耐食性を確保すべく、もともと耐食性に優れるめっき鋼板を用いてその熱間プレス成形を行うというアイデアを得た。そして、これに基づき、耐食性湿潤環境において鋼板の犠牲防食作用のある亜鉛系めっき鋼板に熱間プレスを適用することを着想した。しかし、熱間プレスは700 〜1000℃という温度で加熱することを意味するのであって、この温度は、亜鉛系めっき金属の融点以上の温度であって、そのような高温に加熱した場合、めっき層は溶融し、表面より流失し、あるいは溶融・蒸発して残存しないか、残存しても表面性状は著しく劣ったものとなることが予測された。
【0017】
しかしながら、さらに、その後種々の検討を重ねる内に、加熱することによりめっき層と鋼板とが合金化することで何らかの変化が見られるのではないかとの見解を得て予備試験として各種めっき組成および各種雰囲気で、実際に700 〜1000℃の温度に加熱を行い、次いで熱間プレスを行ったところ、それまでの予測に反して、一部の材料について問題なく熱間プレスを行うことができることが判明した。
【0018】
そこで、700 〜1000℃の温度で加熱してから熱間プレスを行っても表面性状が良好であるための条件を求めたところ、めっき層表面に亜鉛の酸化皮膜が、下層の亜鉛の蒸発を防止する一種のバリア層として全面的に形成されていることが判明した。このバリア層は、熱間プレスに先立つ加熱前にある程度形成されていることが必要で、その後700 〜1000℃に加熱されることによっても形成が進むと推測している。
【0019】
さらに、めっき層の分析を行ったところ、かなり合金化が進んでおり、それにより、めっき層が高融点化してめっき層表面からの亜鉛の蒸発を防止しており、かつ鋼板の鉄酸化物形成を抑制していることが判明した。しかも、このようにして加熱されためっき層は熱間プレス成形後においてめっき層と母材である鋼板との密着性が良好であることが判明した。
【0020】
上記の鋼板を亜鉛めっき鋼板として利用すれば、高張力鋼板でも熱間プレス成形が行える可能性があることが分かり、さらに実用性ある技術として利用可能か否かについて検討を重ね、ここにその効果を確認し、実用性ある技術であることを確信し、本発明を完成した。
【0021】
このように本発明において、めっき層の融点付近の温度域に加熱してもめっき層が残存する理由は、めっき層表面にめっき層よりも耐熱性を有する密着性良好な酸化皮膜層が亜鉛の蒸発を阻止するバリア層として形成されるためと考えられる。さらに、かかる作用が十分に発揮されるためには、めっき層と鋼板の合金化が進行しめっき層の融点が高くなることも影響しており、好ましくはこれらの両者の作用効果によって、めっき層を構成する亜鉛の沸点以上である950 ℃に加熱しても鋼板素地の酸化を抑制していると推定される。
【0022】
かかる知見を基に完成された本発明は、次の通りである。
(1) 表層に加熱時の亜鉛の蒸発を防止する酸化皮膜を備えた亜鉛または亜鉛系合金のめっき層を鋼板表面に有することを特徴とする700 1000 ℃に加熱されてプレスされる熱間プレス用鋼板。
【0023】
(2) 前記酸化皮膜が亜鉛の酸化物層から成る上記(1) 記載の熱間プレス用鋼板。
(3) 前記めっき層の片面当たりの付着量が90g/m2以下である上記(1) または(2) 記載の熱間プレス用鋼板。
【0024】
(4)前記めっき層を鋼板表面に直接設けた熱間プレス用鋼板であって、該めっき層におけるFe含有量が80質量%以下である上記(1) ないし(3) のいずれかに記載の熱間プレス用鋼板。
【0025】
(5) 前記鋼板のC含有量が 0.1 %以上、 3.0 %以下である上記 (1) ないし(4) のいずれかに記載の熱間プレス用鋼板。
(6) 前記鋼板が 780MPa 級以上の高強度鋼板である上記 (1) ないし (4) のいずれかに記載の熱間プレス用鋼板。
【0026】
(7) 表層に加熱時の亜鉛の蒸発を防止する酸化皮膜を備えた亜鉛または亜鉛系合金のめっき層を鋼材表面に有することを特徴とする700 1000 ℃に加熱されてプレスされる熱間プレス用鋼材。
【0027】
【発明の実施の形態】
次に、本発明において上述のように限定する理由について詳述する。なお、本明細書において鋼組成およびめっき組成を規定する「%」は「質量%」である。
【0028】
本発明によれば、溶融亜鉛系めっき鋼板を酸化性雰囲気下で加熱して表面に酸化皮膜を設けることで、これがバリア層として作用し、例えば900 ℃以上に加熱しても、表面の亜鉛系めっき層の蒸発が防止され、加熱後に熱間プレスを行うことができる。しかも、プレス成形後は亜鉛系めっき皮膜を備えていることから、それ自体すでに優れた耐食性を備えており、後処理としての防錆処理を必要としないというすぐれた効果を発揮することができる。
【0029】
素地鋼材
本発明にかかる熱間プレス用の素地鋼材は、溶融亜鉛系めっき時のめっき濡れ性、めっき後のめっき密着性が良好であれば特に限定しないが、熱間プレスの特性として、熱間成形後に急冷して高強度、高硬度となる焼き入れ鋼、たとえば下掲の表1にあるような鋼化学成分の高張力鋼板が実用上は特に好ましい。
【0030】
例えば、Si含有鋼やステンレス鋼のようにめっき濡れ性、めっき密着性に問題のある鋼種でもプレめっき処理等のめっき密着性向上手法を用いてめっき密着性を改善することで本発明に用いることができる。
【0031】
鋼板の焼き入れ後の強度は主に含有炭素(C) 量によってきまるため、高強度の成型品が必要な場合は、C含有量0.1 %以上、3.0 %以下とすることが望ましい。このときに上限を超えると、靭性が低下するおそれがある。
【0032】
特に、本発明の場合、プレス成形が難しいと言われている難プレス成形材である高張力鋼板、Si、Mn、Ni、Cr、Mo、V等を添加した機械構造用鋼板、高硬度鋼板等についてその実用上の意義が大きい。
【0033】
素材としてのプレス成形母材の形態は、一般には板材であるが、本発明の対象とする熱間プレスの形態として曲げ加工、絞り成型、張出し成型、穴拡げ成型、フランジ成型等があるから、その場合には、棒材、線材、管材などを素材として用いてもよい。
【0034】
【表1】

Figure 0003582504
【0035】
亜鉛系めっき層/バリア層
本発明において、バリア層を備えた亜鉛系めっき層を設けるには、例えば通常の溶融亜鉛めっき処理を行ったのち、酸化性雰囲気中での加熱、つまり通常の合金化処理を行えばよい。このような合金化処理はガス炉等で再加熱することにより行われるが、そのときめっき層表面の酸化ばかりでなく、めっき層と母材の鋼板との間で金属拡散が行われる。通常このときの加熱温度は550 〜650 ℃である。
【0036】
本発明による具体的なめっき操作としては、溶融した亜鉛および亜鉛合金めっき浴に鋼板を浸漬して引き上げる。めっき付着量の制御は引き上げ速度やノズルより吹き出すワイピングガスの流量調整により行う。合金化処理はめっき処理後にガス炉や誘導加熱炉などで追加的に加熱して行う。かかるめっき操作は、コイルの連続めっき法あるいは切り板単板めっき法のいずれによってめっきを行ってもよい。
【0037】
もちろん、所定厚みのめっき層が得られるのであれば、例えば、電気めっき、溶射めっき、蒸着めっき等その他いずれの方法でめっき層を設けてもよい。
亜鉛合金めっきとしては、次のような系が開示されている。
【0038】
例えば亜鉛−鉄合金めっき、亜鉛−12%ニッケル合金めっき、亜鉛−1%コバルト合金めっき、55%アルミニウム−亜鉛合金めっき、亜鉛−5%アルミニウム合金めっき、亜鉛−クロム合金めっき、亜鉛−アルミニウム−マグネシウム合金めっき、スズ−8%亜鉛合金めっき、亜鉛−マンガン合金めっきなどである。
【0039】
めっき付着量は90g/m以下が良好である。これを超えるとバリア層としての亜鉛酸化層の形成が不均一となり外観上問題がある。下限は特に制限しないが、薄過ぎるとプレス成形後に所要の耐食性を確保できなくなったり、あるいは加熱の際に鋼板の酸化を抑制するのに必要な酸化亜鉛層を形成できなくなったりすることから、通常は20g/m程度以上は確保する。加熱温度が高くなるなど、より過酷な加熱の場合、望ましくは40〜80g/mの範囲で性能良好となる。
【0040】
亜鉛系めっき層の組成は特に制限がなく、純亜鉛めっき層であっても、Al、Mn、Ni、Cr、Co、Mg、Sn、Pbなどの合金元素をその目的に応じて適宜量添加した亜鉛合金めっき層であってもよい。その他原料等から不可避的に混入することがあるBe、B、Si、P、S、Ti、V、W、Mo、Sb、Cd、Nb、Cu、Sr等のうちのいくつかが含有されることもある。
【0041】
しかし、純亜鉛めっき層または合金化亜鉛めっき層の方が低コストで望ましい。
通常、溶融亜鉛めっき浴には、Alが含有されており、本発明の場合にも、めっき皮膜中Al含有量は0.08〜0.4 %の範囲であれば良い。さらに望ましくは0.08〜0.3 %である。めっき皮膜中のFe含有量を高くするにはAl濃度が低いほうがよい。
【0042】
鋼板の加熱/熱間プレス成形
上述のようにして用意された表層にバリア層を備えた亜鉛系めっき鋼板を次いで所定温度にまで加熱し、プレス成形を行う。本発明の場合、熱間プレス成形を行うことから、通常700 〜1000℃に加熱するが、素材鋼板の種類によっては、プレス成形性がかなり良好なものがあり、その場合にはもう少し低い温度に加熱するだけでよい。本発明の場合、鋼種によってはいわゆる温間プレスの加熱領域に加熱する場合も包含されるが、いわゆる難プレス成形材料に適用するときに本発明の効果が効果的に発揮されることから、通常は、上述のように700 〜1000℃に加熱する。
【0043】
この場合の加熱方法としは電気炉、ガス炉や火炎加熱、通電加熱、高周波加熱、誘導加熱等が挙げられる。また加熱時の雰囲気も特に制限はないが、予めバリア層が形成されている材料の場合には、そのようなバリア層の維持に悪影響を与えない限り、特に制限はない。
【0044】
このときのプレス成形に先立つ加熱温度は焼き入れ鋼であれば目標とする硬度となる焼入温度に加熱したのち一定時間保持し高温のままプレス成形を行い、その際に金型で急冷する。通常の鋼種、条件では、このときに加熱の際の最高到達温度はおよそ700 ℃から1000℃の範囲であればよい。
【0045】
ところで、本発明によれば、亜鉛系めっき層の表面には、加熱時の亜鉛の蒸発を防止するバリア層として作用する酸化皮膜が形成されており、通常、その量は、厚さ0.01〜5.0 μm 程度で十分である。
【0046】
また、加熱処理後のめっき層におけるFe含有量は、めっき皮膜の融点に影響するので高い方が有利である。常温のプレス成形では皮膜中Fe量が増加するとめっき皮膜の加工性が低下するのでFe含有量は高くても13%前後であった。しかし、本発明においては熱間プレス成形では常温よりも鋼板およびめっき皮膜が軟質のためFe含有量が高くても成形が可能である。Fe含有量は80%以下である。望ましくはFe含有量は5〜80%の範囲であり、さらに望ましくは10〜30%である。Fe含有量が下限未満では加熱後の酸化皮膜に不均一さが生じ、上限を超えるとZn−Fe合金化に時間がかかり生産性が低下しコストアップとなる。
【0047】
かかるバリア層およびFe含有量は、熱間プレス成形の際に問題となるのであって、したがって、前述のように予めめっき層形成時の合金化処理によってバリア層が形成され、さらにプレス成形前に加熱が行われる場合には、合金化処理時の加熱条件はプレス成形直前の加熱処理を考慮した条件で行うことが好ましい。
【0048】
このようにして加熱され、表面にバリア層が形成された本発明にかかる熱間プレス用鋼板には、次いで、熱間プレス成形が行われるが、このときの熱間プレス成形は特に制限はなく、通常行われているプレス成形を行えばよい。熱間プレス成形の特徴として成形と同時に焼入れを行うことから、そのような焼入れを可能とする鋼種を用いることが好ましい。もちろん、プレス型を加熱しておいて、焼き入れ温度を変化させ、プレス後の製品特性を制御してもよい。
【0049】
次に、実施例によって本発明の作用効果をさらに具体的に説明する。
【0050】
【実施例】
[実施例1]
本例では、板厚み1.0mm の表2に示す鋼種Aの溶融亜鉛めっき鋼板を650 ℃で合金化処理を行い、次いで大気雰囲気の加熱炉内で950 ℃×5分加熱して、加熱炉より取り出し、このままの高温状態で円筒絞りの熱間プレス成形を行った。このときの熱間プレス成形条件は、絞り高さ25mm、肩部丸み半径R5mm、ブランク直径90mm、パンチ直径50mm、ダイ直径53mmで実施した。成形後のめっき層の密着状態をめっき層の剥離の有無を目視判定して成形性として評価した。なお、本例においては、鋼板の温度はほぼ2分で900 ℃に到達していた。
【0051】
このようにして得られた熱間プレス成形品について下記要領で塗膜密着性、塗装後耐食性( 単に耐食性という) をぞれぞれ評価した。
塗膜密着性試験
本例で得た円筒絞り体から切り出した試験片に、日本パーカライジング (株) 製PBL−3080で通常の化成処理条件により燐酸亜鉛処理したのち関西ペイント製電着塗料GT−10 を電圧200Vのスロープ通電で電着塗装し、焼き付け温度150 ℃で20分焼き付け塗装した。塗膜厚みは20μm であった。
【0052】
試験片を50℃のイオン交換水に浸漬し240 時間後に取り出して、カッターナイフで1mm 幅の碁盤目状に傷を入れ、ニチバン製のポリエステルテープで剥離テストを行い、塗膜の残存マス数を比較し、塗膜密着性を評価した。なお、全マス数は100 個とした。
【0053】
評価基準は残存マス数 90〜100 個を良好:評価記号○、0 〜89個を不良:評価記号×とした。
塗装後耐食性試験
本例で得た円筒絞り体から切り出した試験片に、日本パーカライジング (株) 製PBL−3080で通常の化成処理条件により燐酸亜鉛処理を行ったのち関西ペイント製電着塗料GT−10 を電圧200Vのスロープ通電で電着塗装し、焼き付け温度150 ℃で20分焼き付け塗装した。塗膜厚みは20μm であった。
【0054】
試験片の塗膜にカッターナイフで素地に達するスクラッチ傷を入れた後、JIS Z2371 に規定された塩水噴霧試験を480 時間行った。傷部からの塗膜膨れ幅もしくは錆幅を測定し、塗装後耐食性を評価した。
【0055】
評価基準は錆幅、塗膜膨れ幅のいずれか大きい方の値で Omm以上〜4mm 未満を良好:評価記号○、4mm 以上を不良:評価記号×とした。
これらの試験結果を表2にまとめて示す。
【0056】
比較例として、冷延鋼板およびステンレス鋼板について950 ℃×5分の加熱を行ってから同様の熱間プレス成形を行い、上述のような特性評価を行った。
結果は表2にまとめて示すが、合金化溶融亜鉛めっき鋼板を用いた場合は良好な特性を示すが、ステンレス鋼板や冷延鋼板を用いた場合は、酸化物が形成され、黒色化し、この酸化物が剥離し、プレス成形時押し込み疵が生じた。また、塗膜密着性、耐食性も不合格であった。
【0057】
【表2】
Figure 0003582504
【0058】
[実施例2]
本例では、鋼種Aについて実施例1と同様の試験を繰り返したが、表3に示すとおり、めっき付着量を種々に変え、まためっき直後の合金化処理の条件を変えることによってめっき皮膜中のFe含有量を変えた。本例では合金化処理めっき鋼板にさらに熱間プレス成形に先立って (A) 大気雰囲気加熱炉950 ℃×5分加熱と、(B) 大気雰囲気加熱炉850 ℃×3分加熱による加熱を行った。例No.9〜23では、めっき層のFe含有量を変化させているが、これは熱間プレスに先立つ加熱以前に、合金化処理温度(500〜800 ℃) や時間(30 分以下) を変化させることにより行った。また、No.18 〜23は、熱間プレスに先立つ加熱時の時間を3分から6分間に延長し、より過酷な条件で熱間プレスを行った。
【0059】
結果を表3にまとめて示す。
いずれの例も、加熱後外観、成形性、塗膜密着性および耐食性ともに良好な結果であった。
【0060】
【表3】
Figure 0003582504
【0061】
[実施例3]
本例では、表1の各鋼種について実施例1と同様の試験を繰り返し、得られた試験片について成形性、塗膜密着性、耐食性の評価試験を行った。結果を表4にまとめて示す。
【0062】
いずれの例も、加熱後外観、成形性、塗膜密着性および耐食性ともに良好な結果であった。
【0063】
【表4】
Figure 0003582504
【0064】
[実施例4]
表1に示す鋼種Aの成分をもち、厚さ1.0mm の鋼板を使用し、実験室でめっきを施した。電気めっきは実際の製造ラインで使用されているめっき浴を用い、実験室でめっきを施した。溶融めっきは実際の製造ラインで用いられる浴を実験室で再現して溶融めっきを行った。亜鉛−鉄めっきの合金化処理は550 ℃の溶融塩浴に浸漬する方法を用いた。得られためっき鋼板は実施例1と同様の熱間成形、評価を実施した。熱間プレスに先立つ加熱は、大気炉で850 ℃、3分間行った。
【0065】
得られた結果を、表5に示すが、めっき方法、めっき層の組成に関係なく、良好な特性が得られている。
【0066】
【表5】
Figure 0003582504
【0067】
これらの結果からも分かるように、本発明によれば、いずれの場合にあっても、プレス成形性のすぐれた材料が得られ、成形品としてすぐれた塗膜密着性および耐食性を示すことが分かる。
【0068】
【発明の効果】
以上説明してきたように、本発明によれば、例えば高張力鋼板およびステンレス鋼板などの難プレス成形材料の熱間プレス成形が可能となり、その際に、加熱炉の雰囲気制御設備が不要となるほか、プレス成形時の鋼板酸化物の剥離処理工程も不要となり生産工程を簡素化できる。また犠牲防食効果のある亜鉛めっき層を有するためプレス成形製品の耐食性も向上する。[0001]
TECHNICAL FIELD OF THE INVENTION
TECHNICAL FIELD The present invention relates to a steel material for hot pressing, particularly to a steel plate and a steel material for hot pressing used in the manufacture of undercarriage, chassis, reinforcing parts and the like for automobiles.
[0002]
[Prior art]
In recent years, efforts have been made to increase the strength of steel materials and reduce the thickness of steel materials used in order to reduce the weight of automobiles. However, when considering the press forming, for example, drawing, of a steel sheet as a steel material, when the strength of the steel sheet used increases, the contact pressure with the mold during drawing forming increases, causing galling of the steel sheet and breakage of the steel sheet. In order to reduce such a problem as much as possible, there is a problem that the shape after molding varies if the blank holding pressure is reduced in order to increase the flow of material into the metal mold during drawing of the steel sheet.
[0003]
In addition, shape stability, so-called springback, also occurs. For example, there is an improvement measure by using a lubricant, but the effect is small in a high-strength steel sheet of 780 MPa class or more.
[0004]
As described above, there are many problems in press forming of high-strength steel as a difficult-to-work material. In the following, this type of material is referred to as “hard-press-forming material”.
[0005]
[Problems to be solved by the invention]
By the way, as a technique for press-molding such a difficult-to-press material, a method in which a material to be molded is heated in advance and molded can be considered. So-called hot press forming and warm press forming. Hereinafter, it is collectively referred to simply as hot press forming.
[0006]
However, since hot press forming is a forming method for processing a heated steel sheet, surface oxidation is inevitable. Even if the steel sheet is heated in a non-oxidizing atmosphere, for example, it is removed from a heating furnace for press forming. Sometimes when exposed to the atmosphere, iron oxides form on the surface. There is a problem that the iron oxide falls off during pressing and adheres to a mold to reduce the productivity, or such an oxide film remains on the product after pressing, resulting in poor appearance. In addition, if such an oxide film remains, the adhesion of the coating film to the steel sheet will be poor when coating in the next step. When the scale remains, the adhesion of the coating film is poor due to the poor adhesion between the scale and the steel sheet even in the next step of coating.
[0007]
Therefore, after hot press molding, it is necessary to perform shot blasting to remove the iron oxide layer constituting such a scale, but this does not avoid an increase in cost.
[0008]
Further, since such a scale is not formed at the time of heating, even if a low alloy steel or stainless steel is used, the generation of scale cannot be completely prevented, and the cost is significantly higher than that of ordinary steel.
[0009]
As a countermeasure against the problem of surface oxidation at the time of hot press forming, it is theoretically effective to make both the atmosphere at the time of heating and the atmosphere of the entire pressing process a non-oxidizing atmosphere. .
[0010]
Under such circumstances, many proposals have been made on hot presses even today, but at present they have not reached a practical stage.
Here, an overview of the current technology proposed as a patent application is as follows.
[0011]
For example, an advantage of the hot press is that heat treatment can be performed together with press forming. At that time, it is proposed in Japanese Patent Application Laid-Open No. 7-116900 that a surface treatment is further performed at the same time. Of course, such a technique also has the problem of surface oxidation as described above, but it is difficult to uniformly apply a surface treatment agent such as a rust preventive agent to a mold having a complicated shape. It is also difficult to uniformly transfer the surface treatment agent previously applied to the product at the time of press molding. Obviously, it is obvious that rust prevention treatment such as plating treatment is individually performed as a treatment after press molding, but it is obvious that productivity is low and cost is greatly increased.
[0012]
In order to form a high-strength steel sheet in this way, there is a method of hot press forming, but a step of removing the generated iron oxide is necessary, and even if the iron oxide is removed, the steel sheet alone At present, it is inferior in rust prevention.
[0013]
In terms of rust prevention and corrosion resistance alone, as proposed in Japanese Patent Application Laid-Open No. 6-240414, for example, in the case of automobile parts such as impact bars in doors, the moisture of corrosion factors penetrating into the doors. May corrode the unpainted portion of the quenched steel pipe, so there is an example in which elements such as Cr and Mo are added to the steel component of the steel material constituting such a quenched steel pipe to improve the corrosion resistance. . However, such measures not only increase the cost due to the addition of Cr and Mo, but also in the case of a material for press molding, there is a problem of the deterioration of press moldability due to the addition of the same alloy component.
[0014]
Here, an object of the present invention is to provide a steel material for a hot press which can ensure a predetermined corrosion resistance even when a so-called difficult-to-press material is subjected to a hot press and does not cause deterioration in appearance.
[0015]
Furthermore, a specific object of the present invention is to provide a technology that enables hot press forming of, for example, a high-strength steel sheet, which is a difficult-to-press forming material, without requiring post-treatment for ensuring corrosion resistance, and at the same time, ensures corrosion resistance. It is to be.
[0016]
[Means for Solving the Problems]
Means for Solving the Problems The present inventors have conducted intensive studies from various angles on means for solving such problems, and as a result, rather than press-molding the above difficult-to-press material as it is, press molding at a high temperature to reduce deformation resistance. At the same time, at the same time, in order to ensure excellent corrosion resistance without performing post-treatment, the idea of performing hot press forming using a plated steel sheet which is originally excellent in corrosion resistance was obtained. Then, based on this, the idea of applying a hot press to a galvanized steel sheet having a sacrificial anticorrosion action of the steel sheet in a corrosion-resistant wet environment was conceived. However, hot pressing means heating at a temperature of 700 to 1000 ° C., which is higher than the melting point of the zinc-based plated metal. It was predicted that the layer would be melted and run off from the surface, or would not melt and evaporate and remain, or even if it did, the surface properties would be extremely poor.
[0017]
However, after further studying variously, after obtaining the opinion that some change may be seen due to alloying between the plating layer and the steel sheet by heating, we obtained various plating compositions and various In the atmosphere, when heating was actually performed to a temperature of 700 to 1000 ° C. and then hot pressing was performed, it was found that, contrary to the predictions so far, hot pressing could be performed on some materials without any problem. did.
[0018]
Therefore, the condition for obtaining good surface properties even after hot pressing at a temperature of 700 to 1000 ° C. and then performing hot pressing was determined. It has been found that the barrier layer is formed over the entire surface as a kind of barrier layer to prevent such a problem. It is necessary that this barrier layer be formed to some extent before heating prior to hot pressing, and it is presumed that formation will proceed by heating to 700 to 1000 ° C. thereafter.
[0019]
Furthermore, when the plating layer was analyzed, it was found that alloying had progressed considerably, which caused the plating layer to have a high melting point, prevent zinc from evaporating from the plating layer surface, and form iron oxide on the steel sheet. Was found to be suppressed. Moreover, it has been found that the plated layer heated in this way has good adhesion between the plated layer and the base steel sheet after hot press forming.
[0020]
If the above steel sheets were used as galvanized steel sheets, it was found that hot press forming could be performed even with high-strength steel sheets. After confirming that the technology was practical, the present invention was completed.
[0021]
As described above, in the present invention, the reason that the plating layer remains even when heated to a temperature range near the melting point of the plating layer is that the oxide film layer having better heat resistance than the plating layer and having good adhesion to the plating layer surface is made of zinc. It is considered that the barrier layer is formed as a barrier layer for preventing evaporation. Further, in order for this effect to be sufficiently exhibited, the alloying of the plating layer and the steel sheet progresses and the melting point of the plating layer increases, which is also affected. It is presumed that even when heated to 950 ° C., which is equal to or higher than the boiling point of zinc constituting the steel, the oxidation of the steel sheet base is suppressed.
[0022]
The present invention completed based on such knowledge is as follows.
(1) is heated plated layer of zinc or a zinc-based alloy having an oxide film to prevent evaporation of zinc during heating the surface layer to 700 ~ 1000 ° C. characterized by having the steel sheet surface between heat press Steel plate for press.
[0023]
(2) The steel sheet for hot pressing according to the above (1), wherein the oxide film comprises a zinc oxide layer.
(3) The steel sheet for hot pressing according to the above (1) or (2), wherein the coating amount per one side of the plating layer is 90 g / m 2 or less.
[0024]
(4) The steel sheet for hot pressing in which the plating layer is provided directly on the surface of the steel sheet according to any one of (1) to (3), wherein the Fe content in the plating layer is 80% by mass or less. Steel plate for hot pressing.
[0025]
(5) The steel sheet for hot pressing according to any one of (1) to (4), wherein the C content of the steel sheet is 0.1 % or more and 3.0 % or less .
(6) The steel sheet for hot pressing as described in any of (1) to (4) above, wherein the steel sheet is a high-strength steel sheet of 780 MPa class or higher .
[0026]
(7) a plating layer of zinc or a zinc-based alloy having an oxide film to prevent evaporation of zinc during heating the surface layer is heated to 700 ~ 1000 ° C. characterized by having a steel surface between heat press Steel for press.
[0027]
BEST MODE FOR CARRYING OUT THE INVENTION
Next, the reason why the present invention is limited as described above will be described in detail. In this specification, “%” for defining the steel composition and the plating composition is “% by mass”.
[0028]
According to the present invention, a hot-dip galvanized steel sheet is heated in an oxidizing atmosphere to provide an oxide film on the surface, which acts as a barrier layer. Evaporation of the plating layer is prevented, and hot pressing can be performed after heating. In addition, since the zinc-based plating film is provided after the press molding, it already has excellent corrosion resistance itself, and can exhibit an excellent effect of not requiring rust prevention treatment as a post-treatment.
[0029]
Base steel material The base steel material for hot pressing according to the present invention is not particularly limited as long as the plating wettability during hot-dip zinc-based plating and the plating adhesion after plating are good. For practical use, hardened steel which rapidly cools after hot forming to have high strength and high hardness, for example, a high-tensile steel sheet having a steel chemical composition as shown in Table 1 below is particularly preferable.
[0030]
For example, even in the case of a steel type having a problem with plating wettability and plating adhesion, such as a Si-containing steel and a stainless steel, the plating adhesion is improved by using a plating adhesion improvement method such as a pre-plating process, and the invention is used in the present invention. Can be.
[0031]
Since the strength of a steel sheet after quenching is determined mainly by the amount of carbon (C) contained, when a high-strength molded product is required, it is desirable that the C content be 0.1% or more and 3.0% or less. . If the upper limit is exceeded at this time, the toughness may decrease.
[0032]
In particular, in the case of the present invention, a high-strength steel sheet which is a difficult-to-press-formed material which is said to be difficult to press-form, a steel sheet for a machine structure added with Si, Mn, Ni, Cr, Mo, V, etc., a high-hardness steel sheet, etc. Is of great practical significance.
[0033]
The form of the press-formed base material as a raw material is generally a plate material, but the form of the hot press targeted by the present invention includes bending, drawing, overhanging, hole expanding, and flange forming. In that case, a rod, a wire, a pipe, or the like may be used as the material.
[0034]
[Table 1]
Figure 0003582504
[0035]
Zinc-based plating layer / barrier layer In the present invention, in order to provide a zinc-based plating layer having a barrier layer, for example, after performing a normal hot-dip galvanizing treatment, heating in an oxidizing atmosphere, that is, A normal alloying process may be performed. Such alloying treatment is performed by reheating in a gas furnace or the like. At this time, not only oxidation of the plating layer surface, but also metal diffusion between the plating layer and the base steel sheet. Usually, the heating temperature at this time is 550 to 650 ° C.
[0036]
As a specific plating operation according to the present invention, a steel sheet is immersed in a molten zinc and zinc alloy plating bath and pulled up. The amount of plating is controlled by adjusting the lifting speed and the flow rate of the wiping gas blown out from the nozzle. The alloying treatment is performed by additionally heating in a gas furnace or an induction heating furnace after the plating treatment. Such a plating operation may be performed by either a continuous plating method of a coil or a single plate plating method of a cut plate.
[0037]
Of course, as long as a plating layer having a predetermined thickness can be obtained, the plating layer may be provided by any other method such as electroplating, thermal spray plating, and vapor deposition plating.
The following systems are disclosed as zinc alloy plating.
[0038]
For example, zinc-iron alloy plating, zinc-12% nickel alloy plating, zinc-1% cobalt alloy plating, 55% aluminum-zinc alloy plating, zinc-5% aluminum alloy plating, zinc-chromium alloy plating, zinc-aluminum-magnesium Alloy plating, tin-8% zinc alloy plating, zinc-manganese alloy plating, and the like.
[0039]
The plating adhesion amount is preferably 90 g / m 2 or less. If it exceeds this, the formation of a zinc oxide layer as a barrier layer becomes uneven, and there is a problem in appearance. The lower limit is not particularly limited, but if it is too thin, the required corrosion resistance cannot be secured after press forming, or the zinc oxide layer required to suppress oxidation of the steel sheet during heating cannot be formed, so that it is usually used. Is about 20 g / m 2 or more. In the case of more severe heating, such as an increase in the heating temperature, the performance is desirably good in the range of 40 to 80 g / m 2 .
[0040]
The composition of the zinc-based plating layer is not particularly limited, and even in the case of a pure zinc plating layer, alloy elements such as Al, Mn, Ni, Cr, Co, Mg, Sn, and Pb are appropriately added according to the purpose. It may be a zinc alloy plating layer. Some of Be, B, Si, P, S, Ti, V, W, Mo, Sb, Cd, Nb, Cu, Sr, etc. which may be inevitably mixed from other raw materials, etc. There is also.
[0041]
However, a pure galvanized layer or an alloyed galvanized layer is desirable at a lower cost.
Usually, the hot dip galvanizing bath contains Al, and in the case of the present invention, the Al content in the plating film may be in the range of 0.08 to 0.4%. More preferably, the content is 0.08 to 0.3%. To increase the Fe content in the plating film, the lower the Al concentration, the better.
[0042]
Heating / Hot pressing of steel sheet The galvanized steel sheet provided with the barrier layer on the surface layer prepared as described above is then heated to a predetermined temperature and press-formed. In the case of the present invention, since hot press forming is performed, the temperature is usually heated to 700 to 1000 ° C., but depending on the type of the material steel sheet, there is a type having considerably good press formability. All you need to do is heat it. In the case of the present invention, depending on the type of steel, a case where heating is performed in a so-called warm press heating region is also included.However, since the effect of the present invention is effectively exerted when applied to a so-called difficult-to-press molding material, it is usually used. Is heated to 700-1000 ° C. as described above.
[0043]
Examples of the heating method in this case include an electric furnace, a gas furnace, flame heating, electric heating, high-frequency heating, and induction heating. The atmosphere at the time of heating is not particularly limited. However, in the case of a material in which a barrier layer is formed in advance, there is no particular limitation as long as the maintenance of such a barrier layer is not adversely affected.
[0044]
In this case, if the heating temperature prior to the press forming is quenched steel, the steel is heated to a quenching temperature having a target hardness, then is held for a certain period of time, press-formed at a high temperature, and quenched by a mold at that time. Under ordinary steel grades and conditions, the maximum temperature at the time of heating at this time may be in the range of about 700 ° C. to 1000 ° C.
[0045]
By the way, according to the present invention, on the surface of the zinc-based plating layer, an oxide film acting as a barrier layer for preventing evaporation of zinc at the time of heating is formed. About 5.0 μm is sufficient.
[0046]
Further, since the Fe content in the plated layer after the heat treatment affects the melting point of the plated film, a higher one is advantageous. In press molding at room temperature, when the amount of Fe in the film increases, the workability of the plating film decreases, so that the Fe content was about 13% at most. However, in the present invention, hot press forming enables forming even if the Fe content is high because the steel sheet and the plating film are softer than normal temperature. The Fe content is 80% or less. Preferably, the Fe content is in the range of 5 to 80%, more preferably 10 to 30%. If the Fe content is less than the lower limit, the oxide film after heating becomes non-uniform. If the Fe content exceeds the upper limit, Zn-Fe alloying takes a long time, the productivity is reduced, and the cost is increased.
[0047]
Such a barrier layer and the Fe content are problematic during hot press forming. Therefore, as described above, the barrier layer is formed in advance by an alloying process at the time of forming the plating layer. When the heating is performed, it is preferable that the heating condition at the time of the alloying process is performed in consideration of the heating process immediately before the press forming.
[0048]
Heated in this manner, the steel sheet for hot pressing according to the present invention having a barrier layer formed on the surface is then subjected to hot press forming, but the hot press forming at this time is not particularly limited. What is necessary is just to perform the usual press molding. Since quenching is performed simultaneously with forming as a feature of hot press forming, it is preferable to use a steel type that enables such quenching. Of course, the press mold may be heated, and the quenching temperature may be changed to control the product characteristics after pressing.
[0049]
Next, the operation and effect of the present invention will be described more specifically with reference to examples.
[0050]
【Example】
[Example 1]
In this example, a hot-dip galvanized steel sheet of steel type A shown in Table 2 having a sheet thickness of 1.0 mm was alloyed at 650 ° C., and then heated at 950 ° C. × 5 minutes in a heating furnace in an air atmosphere. The cylinder was then hot pressed under a high temperature condition. The hot press molding conditions at this time were a draw height of 25 mm, a shoulder radius R5 mm, a blank diameter of 90 mm, a punch diameter of 50 mm, and a die diameter of 53 mm. The state of adhesion of the plated layer after the molding was evaluated by visually judging the presence or absence of peeling of the plated layer as moldability. In this example, the temperature of the steel plate reached 900 ° C. in approximately 2 minutes.
[0051]
The hot press-molded product thus obtained was evaluated for coating film adhesion and post-coating corrosion resistance (hereinafter simply referred to as corrosion resistance) in the following manner.
Coating film adhesion test A test piece cut out from the cylindrical drawn body obtained in this example was subjected to zinc phosphate treatment with PBL-3080 (manufactured by Nippon Parkerizing Co., Ltd.) under ordinary chemical conversion conditions, and then electrodeposited by Kansai Paint. The paint GT-10 was electrodeposited by applying a voltage of 200 V on a slope and baked at a baking temperature of 150 ° C. for 20 minutes. The coating thickness was 20 μm.
[0052]
The test piece was immersed in ion-exchanged water at 50 ° C., taken out after 240 hours, cut in a 1 mm-wide grid with a cutter knife, subjected to a peeling test with Nichiban polyester tape, and measured for the number of remaining squares of the coating film. For comparison, the coating film adhesion was evaluated. The total number of cells was 100.
[0053]
The evaluation criteria were as follows: the number of residual cells of 90 to 100 was evaluated as good: evaluation symbol ○, and 0 to 89 was evaluated as poor: evaluation symbol x.
Corrosion resistance test after coating A test piece cut out from the cylindrical drawn body obtained in this example was subjected to zinc phosphate treatment with PBL-3080 manufactured by Nippon Parkerizing Co., Ltd. under ordinary chemical conversion conditions, and then Kansai Paint Co., Ltd. The coating paint GT-10 was electrodeposited by applying a slope voltage of 200 V, and baked at a baking temperature of 150 ° C. for 20 minutes. The coating thickness was 20 μm.
[0054]
After making a scratch on the coating film of the test piece to reach the substrate with a cutter knife, a salt spray test specified in JIS Z2371 was performed for 480 hours. The swollen width or rust width of the coating film from the scratch was measured, and the corrosion resistance after coating was evaluated.
[0055]
The evaluation criterion was the larger value of the rust width and the swelling width of the coating film, whichever was greater.
Table 2 summarizes the test results.
[0056]
As a comparative example, a cold-rolled steel plate and a stainless steel plate were heated at 950 ° C. for 5 minutes, and then subjected to the same hot press forming, and the above-described characteristics were evaluated.
The results are summarized in Table 2. As shown in Table 2, when the alloyed hot-dip galvanized steel sheet is used, good characteristics are exhibited. However, when a stainless steel sheet or a cold-rolled steel sheet is used, an oxide is formed, and the blackening occurs. The oxide was exfoliated and indentation flaws occurred during press molding. The coating film adhesion and corrosion resistance were also rejected.
[0057]
[Table 2]
Figure 0003582504
[0058]
[Example 2]
In this example, the same test as in Example 1 was repeated for steel type A, but as shown in Table 3, the amount of plating was changed variously, and the conditions of the alloying treatment immediately after plating were changed to change the plating film. The Fe content was changed. In this example, prior to hot press forming, the alloyed plated steel sheet was further heated by (A) heating in an atmosphere heating furnace at 950 ° C. × 5 minutes and (B) heating by heating in an atmosphere atmosphere heating furnace at 850 ° C. × 3 minutes. . Example No. In Nos. 9 to 23, the Fe content of the plating layer was changed by changing the alloying temperature (500 to 800 ° C.) and the time (30 minutes or less) before heating prior to hot pressing. It was performed by. No. In Nos. 18 to 23, the time for heating prior to hot pressing was extended from 3 minutes to 6 minutes, and hot pressing was performed under more severe conditions.
[0059]
The results are summarized in Table 3.
All of the examples showed good results in appearance, moldability, coating film adhesion and corrosion resistance after heating.
[0060]
[Table 3]
Figure 0003582504
[0061]
[Example 3]
In this example, the same test as in Example 1 was repeated for each steel type in Table 1, and the obtained test pieces were subjected to evaluation tests of moldability, coating film adhesion, and corrosion resistance. The results are summarized in Table 4.
[0062]
All of the examples showed good results in appearance, moldability, coating film adhesion and corrosion resistance after heating.
[0063]
[Table 4]
Figure 0003582504
[0064]
[Example 4]
A steel sheet having a composition of steel type A shown in Table 1 and having a thickness of 1.0 mm was plated in a laboratory. The electroplating was performed in a laboratory using a plating bath used in an actual production line. For the hot-dip plating, the bath used in the actual production line was reproduced in the laboratory and hot-dip plating was performed. For the zinc-iron plating alloying treatment, a method of immersion in a molten salt bath at 550 ° C. was used. The obtained plated steel sheet was subjected to the same hot forming and evaluation as in Example 1. The heating prior to the hot pressing was performed in an atmospheric furnace at 850 ° C. for 3 minutes.
[0065]
The obtained results are shown in Table 5, and good characteristics were obtained regardless of the plating method and the composition of the plating layer.
[0066]
[Table 5]
Figure 0003582504
[0067]
As can be seen from these results, according to the present invention, in any case, a material having excellent press moldability is obtained, and it is understood that the molded article exhibits excellent coating film adhesion and corrosion resistance. .
[0068]
【The invention's effect】
As described above, according to the present invention, for example, hot press forming of difficult-to-press forming materials such as high-strength steel plate and stainless steel plate becomes possible, and at that time, atmosphere control equipment of a heating furnace becomes unnecessary. In addition, there is no need for a steel plate oxide stripping process at the time of press forming, and the production process can be simplified. Further, the corrosion resistance of the press-formed product is improved due to the presence of the galvanized layer having a sacrificial corrosion prevention effect.

Claims (7)

表層に加熱時の亜鉛の蒸発を防止する酸化皮膜を備えた亜鉛または亜鉛系合金のめっき層を鋼板表面に有することを特徴とする700 1000 ℃に加熱されてプレスされる熱間プレス用鋼板。A steel sheet for hot pressing, which is heated to 700 to 1000 ° C. and has a coating layer of zinc or a zinc-based alloy having an oxide film on its surface layer to prevent evaporation of zinc during heating. . 前記酸化皮膜が亜鉛の酸化物層から成る請求項1記載の熱間プレス用鋼板。The steel sheet for hot pressing according to claim 1, wherein the oxide film comprises a zinc oxide layer. 前記めっき層の片面当たりの付着量が90g/m2以下である請求項1または2記載の熱間プレス用鋼板。The steel sheet for hot pressing according to claim 1 or 2, wherein the coating amount of one side of the plating layer is 90 g / m2 or less. 前記めっき層を鋼板表面に直接設けた熱間プレス用鋼板であって、該めっき層におけるFe含有量が80質量%以下である請求項1ないし3のいずれかに記載の熱間プレス用鋼板。The steel sheet for hot pressing according to any one of claims 1 to 3, wherein the steel sheet is a steel sheet for hot pressing in which the plating layer is provided directly on the surface of the steel sheet, and the Fe content in the plating layer is 80% by mass or less. 前記鋼板のC含有量が 0.1 %以上、 3.0 %以下である請求項1ないし4のいずれかに記載の熱間プレス用鋼板。The steel sheet for hot pressing according to any one of claims 1 to 4, wherein the C content of the steel sheet is 0.1 % or more and 3.0 % or less . 前記鋼板が 780MPa 級以上の高強度鋼板である請求項1ないし4のいずれかに記載の熱間プレス用鋼板。 The steel sheet for hot pressing according to any one of claims 1 to 4, wherein the steel sheet is a high-strength steel sheet of 780 MPa class or higher . 表層に加熱時の亜鉛の蒸発を防止する酸化皮膜を備えた亜鉛または亜鉛系合金のめっき層を鋼材表面に有することを特徴とする700 1000 ℃に加熱されてプレスされる熱間プレス用鋼材。A steel material for hot pressing which is heated to 700 to 1000 ° C. and has a plating layer of zinc or a zinc-based alloy provided with an oxide film on its surface to prevent evaporation of zinc during heating. .
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JP2012073871A (en) 2010-09-29 2012-04-12 Kubota Corp Tractor
KR101447408B1 (en) 2011-06-07 2014-10-06 제이에프이 스틸 가부시키가이샤 Steel sheet for hot pressing and process for manufacturing hot pressed member using the steel sheet
CN102744575A (en) * 2012-07-23 2012-10-24 武汉钢铁(集团)公司 Method for preparing steel helmet shell

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