JP3228986B2 - Manufacturing method of high strength steel sheet - Google Patents

Manufacturing method of high strength steel sheet

Info

Publication number
JP3228986B2
JP3228986B2 JP02503092A JP2503092A JP3228986B2 JP 3228986 B2 JP3228986 B2 JP 3228986B2 JP 02503092 A JP02503092 A JP 02503092A JP 2503092 A JP2503092 A JP 2503092A JP 3228986 B2 JP3228986 B2 JP 3228986B2
Authority
JP
Japan
Prior art keywords
less
steel sheet
tempering
strength
quenching
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP02503092A
Other languages
Japanese (ja)
Other versions
JPH05222450A (en
Inventor
政昭 藤岡
淳彦 吉江
崇史 藤田
泰光 尾上
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Nippon Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Steel Corp filed Critical Nippon Steel Corp
Priority to JP02503092A priority Critical patent/JP3228986B2/en
Publication of JPH05222450A publication Critical patent/JPH05222450A/en
Application granted granted Critical
Publication of JP3228986B2 publication Critical patent/JP3228986B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本発明は焼き入れ焼き戻しにより
生産性の高い強度、靱性に優れた低降伏比高張力鋼板製
造方法に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for manufacturing a high yield strength steel sheet having a low yield ratio and excellent strength and toughness by quenching and tempering.

【0002】[0002]

【従来の技術】近年、建築用構造物等に使用される鋼材
(鋼板、鋼管、形鋼など)においては耐震性の優れた低
降伏比高張力鋼板が求められている。このような要求に
対して、例えば特開昭55−41927号公報あるいは
特開昭55−97425号公報記載の方法が提案されて
いる。前者の方法は制御圧延、制御冷却を用いた方法で
あり、後者の方法は焼き入れ、焼き戻しによる方法であ
るが、いずれの場合も引っ張り強度が60kgf/mm
2 級の鋼に適用される方法であり、60kgf/mm2
を超える鋼に対して一般的に適用されるものではない。
2. Description of the Related Art In recent years, for steel materials (steel plates, steel pipes, shaped steels, etc.) used for building structures and the like, low yield ratio high tensile strength steel plates having excellent earthquake resistance have been demanded. In response to such a demand, for example, a method described in Japanese Patent Application Laid-Open No. 55-41927 or Japanese Patent Application Laid-Open No. 55-97425 has been proposed. The former method is a method using controlled rolling and controlled cooling, and the latter method is a method using quenching and tempering. In each case, the tensile strength is 60 kgf / mm.
This method is applied to grade 2 steel, and is 60 kgf / mm 2
It does not generally apply to steels exceeding.

【0003】[0003]

【発明が解決しようとする課題】本発明は、これら従来
法の問題点を排除し、60kgf/mm2 を超える強度
の鋼に対しても適用できる強度、靱性に優れた低降伏比
高張力鋼板の容易なる製造方法を提供することにある。
SUMMARY OF THE INVENTION The present invention eliminates the problems of the conventional methods and provides a low yield ratio high tensile strength steel sheet having excellent strength and toughness applicable to steel having a strength exceeding 60 kgf / mm 2. It is to provide a manufacturing method which makes it easy.

【0004】[0004]

【課題を解決するための手段】本発明の要旨とするとこ
ろは (1)重量%で、 C :0.02〜0.5%、 Mn:0.02〜10.0%、 Si:0.01〜1.0%、 Al:0.1%以下、 を含有し、残部がFeおよび不可避的不純物からなる鋼
板を直接焼き入れあるいは再加熱後に焼き入れし、その
後、焼き戻しを行って高張力鋼板を製造する方法におい
て、焼き入れ後の金属組織が主にベイナイト、マルテン
サイトあるいはこの混合組織であって、焼き戻し時の昇
温速度を1℃/秒以上、焼き戻し温度をAc1 点以上の
温度とし、さらに保持を15分以内で終了し、その後、
放冷もしくは強制冷却を行うことを特徴とする生産性の
高い高強度、高靱性低降伏比高張力鋼板の製造方法。 (2)重量%で、 C :0.02〜0.5%、 Mn:0.02〜10.0%、 Si:0.01〜1.0%、 Al:0.1%以下、 が基本成分であり、 Mo:3.0 %以下、 Ni:10.0 %以下、 Cr:3.0 %以下、 V :0.1 %以下、 Nb:0.1 %以下、 Ti:0.1 %以下、 B :0.003 %以下、 Cu:10.0 %以下、 Co:10.0 %以下、 W :3.0 %以下 のいずれか1種、または2種以上をさらに含有する残部
がFeおよび不可避的不純物からなる鋼板を直接焼き入
れあるいは再加熱後に焼き入れし、その後焼き戻しを行
って高張力鋼板を製造する方法において、焼き入れ後の
組織が主にマルテンサイト、ベイナイトあるいはこの混
合組織であって、焼き戻し時の昇温速度を1℃/秒以
、焼き戻し温度をAc1 点以上の温度とし、さらに保
持時間を15分以内で終了し、その後放冷もしくは強制
冷却を行うことを特徴とする生産性の高い高強度、高靱
性低降伏比高張力鋼板の製造方法にある。これにより焼
き戻しマルテンサイトあるいは焼き戻しベイナイトの微
細な金属組織状態を損なうこと無く、その組織中に微細
なマルテンサイト、残留オーステナイトあるいはセメン
タイトを分散させ、強度、靱性にすぐれた低降伏比高張
力鋼板を製造し得る。
The gist of the present invention is as follows. (1) By weight%, C: 0.02 to 0.5%, Mn: 0.02 to 10.0%, Si: 0. Quenched directly or after reheating, and then tempered to obtain a high tensile strength steel sheet containing 0.1 to 1.0%, Al: 0.1% or less, and the balance being Fe and unavoidable impurities. In the method for producing a steel sheet, the metal structure after quenching is mainly bainite, martensite or a mixed structure thereof, and the temperature rising rate during tempering is 1 ° C./sec or more , and the tempering temperature is 1 point or more at Ac. , And the holding is completed within 15 minutes.
A method for producing a high-strength, high-toughness, low-yield-ratio, high-strength steel sheet with high productivity, characterized by performing cooling or forced cooling. (2) C: 0.02 to 0.5%, Mn: 0.02 to 10.0%, Si: 0.01 to 1.0%, Al: 0.1% or less by weight% Mo: 3.0% or less, Ni: 10.0% or less, Cr: 3.0% or less, V: 0.1% or less, Nb: 0.1% or less, Ti: 0.1% In the following, B: 0.003% or less, Cu: 10.0% or less, Co: 10.0% or less, W: 3.0% or less, and the balance further contains Fe or more. And a method of manufacturing a high-strength steel sheet by directly quenching or reheating a steel sheet consisting of unavoidable impurities and then performing tempering, wherein the structure after quenching is mainly martensite, bainite or a mixed structure of these. And the rate of temperature rise during tempering is 1 ° C / second or less.
Furthermore, tempering temperature to a temperature of more than 1 point Ac, further holding time was completed within 15 minutes, then a high strength of productivity and performing cooling or forced cooling, high toughness low yield ratio It is in the manufacturing method of high strength steel sheet. As a result, fine martensite, retained austenite or cementite is dispersed in the microstructure of tempered martensite or tempered bainite without impairing the microstructure of the microstructure, and a low yield ratio high-tensile steel sheet having excellent strength and toughness. Can be manufactured.

【0005】以下、本発明について詳細に説明する。本
発明の基本となる考え方は以下の通りである。まず、金
属学的な見地から直接焼き入れを含む焼き入れ、焼き戻
しで製造される鋼の強度、靱性は第一に金属組織の微細
さに依存している。通常、焼き入れ後の鋼の金属組織は
マルテンサイトとベイナイトからなり、その結晶粒は微
細である。従って、その強度は高い。しかしながら、焼
き入れままの金属組織は過飽和の炭素原子を多く含有し
ており、強度は高いが延性や靱性が充分ではない。そこ
で、通常、焼き入れ後には焼き戻し処理が行われる。一
般に焼き戻し処理は焼き戻し処理を行う温度に設定され
た熱処理炉内に鋼板を挿入し、Ac1 点以下の所定の温
度に到達せしめ、その後に数10分程度の保持を行うこ
とで行われており、昇温の為の時間を含めると極めて長
時間の焼き戻し処理が行われる。このため焼き戻し後の
金属組織は焼き戻しマルテンサイトあるいは焼き戻しベ
イナイトとなる。このような鋼の降伏比は、焼き戻しに
より析出したセメンタイト等の炭化物が可動転位を固着
するために降伏強度が高く、90%を超えることが多
い。
Hereinafter, the present invention will be described in detail. The basic concept of the present invention is as follows. First, the strength and toughness of steel produced by quenching and tempering, including direct quenching, from a metallurgical point of view depend primarily on the fineness of the metal structure. Usually, the metal structure of the steel after quenching is composed of martensite and bainite, and its crystal grains are fine. Therefore, its strength is high. However, the as-quenched metal structure contains many supersaturated carbon atoms and has high strength but insufficient ductility and toughness. Therefore, a tempering process is usually performed after quenching. Generally, the tempering process is performed by inserting a steel sheet into a heat treatment furnace set to a temperature at which the tempering process is to be performed, allowing the steel plate to reach a predetermined temperature of one point or less of Ac, and then holding for several tens of minutes. Therefore, when the time for raising the temperature is included, an extremely long tempering process is performed. Therefore, the metal structure after tempering becomes tempered martensite or tempered bainite. The yield ratio of such steel is high because the carbides such as cementite precipitated by tempering fix mobile dislocations, and often have a yield strength of more than 90%.

【0006】一方、焼き入れままのマルテンサイトや残
留オーステナイトは結晶粒内に転位を多く含有するなど
のために降伏強度が低く、低降伏比となる。さらに残留
オーステナイト部分にはマルテンサイト(フェライト)
との固溶度の差に基づいて、固溶原子を吸収し、マルテ
ンサイト中で降伏強度の上昇をもたらす固溶原子等を低
減する効果もある。そこで鋼を低降伏比とするには、残
留オーステナイトを生成せしめることや焼き戻し処理中
にマルテンサイトや残留オーステナイトの転位の回復を
制御することが必要であると思われる。従って、焼き戻
し処理温度をAc1 点温度以上とし金属組織の一部をオ
ーステナイト化し、冷却中にそのまま残留させるか再び
マルテンサイトにすることによって、焼き戻しマルテン
サイト、焼き戻しベイナイトとの混合組織を形成し、降
伏比の低い鋼板を製造できると考えられる。
On the other hand, as-quenched martensite and retained austenite have a low yield strength and a low yield ratio due to the fact that many dislocations are contained in crystal grains. Furthermore, martensite (ferrite) is used in the retained austenite part
On the basis of the difference between the solid solubility and the solid solution atoms, there is also an effect of absorbing the solid solution atoms and reducing the solid solution atoms and the like which increase the yield strength in martensite. Therefore, in order to reduce the yield ratio of steel, it is necessary to control the recovery of martensite and the recovery of dislocations of martensite and retained austenite during tempering. Therefore, the tempering treatment temperature is set to the Ac 1 point temperature or higher, a part of the metal structure is austenitized, and is left as it is during cooling or is converted to martensite again, so that the mixed structure of tempered martensite and tempered bainite is obtained. It is considered that a steel sheet having a low yield ratio can be produced.

【0007】しかしながら、従来法のごとき焼き戻し方
法でこれを行えば、オーステナイト化部分が粗大とな
り、冷却後は粗大炭化物や粗大なマルテンサイトを含む
金属組織となるので強度、靱性の観点から好ましくな
い。また、オーステナイト化しなかった部分についても
焼き戻し温度が高いためにマルテンサイトの転位が著し
く減少したり、場合によっては再結晶により粗大なフェ
ライトが生成し、強度、靱性が著しく低下する。そこ
で、本発明者らは種々の熱処理条件を検討し、焼き戻し
温度をAc1 点温度以上としながらも急速加熱、短時間
保持により強度、靱性を向上した上で鋼の降伏比を容易
に低下することを見いだした。
However, if this is carried out by a conventional tempering method such as the conventional method, the austenitized portion becomes coarse, and after cooling, it becomes a metal structure containing coarse carbides and coarse martensite, which is not preferable from the viewpoint of strength and toughness. . In addition, since the tempering temperature is high, the dislocation of martensite is remarkably reduced even in a part that has not been austenitized, and in some cases, coarse ferrite is generated by recrystallization, and the strength and toughness are significantly reduced. Therefore, the present inventors examined various heat treatment conditions and, while maintaining the tempering temperature at or above the Ac 1 point temperature, improved the strength and toughness by rapid heating and holding for a short time, and then easily lowered the yield ratio of the steel. I found something to do.

【0008】本発明法による効果は、Ac1 点温度以上
での焼き戻しによって生じたオーステナイト部分をマル
テンサイトラス境界上などに微細に現出し(Ac1 点温
度以下でマルテンサイトラス境界上などに析出したセメ
ンタイトがオーステナイトの核となる)、それに引き続
く冷却中にこれがマルテンサイト、残留オーステナイ
ト、セメンタイトあるいはこれらの混合物となること、
およびこのようにして生じたマルテンサイト、残留オー
ステナイト部分が転位の豊富さなどの為に降伏点の低下
と引っ張り強度の上昇に寄与するために生じると考えら
れる。一方、オーステナイト化しなかった部分について
も、急速加熱、短時間焼き戻しによって、金属組織中に
存在する炭化物は微細に分散し、マルテンサイト変態な
どの変態により導入された転位や加工されたオーステナ
イトから引き継がれた転位が金属組織中に多く残存する
事によって強度が上昇し、場合によっては可動転位が延
性を促進することによって鋼の靱性を増すのである。
[0008] The effect of the method of the present invention is that the austenite portion generated by tempering at a temperature higher than the Ac 1 point temperature appears finely on the martensite lath boundary and the like (precipitates on the martensite lath boundary and the like below the Ac 1 point temperature). Cementite is the core of austenite), and during subsequent cooling it becomes martensite, residual austenite, cementite or mixtures thereof,
Further, it is considered that the martensite and retained austenite generated in this manner are generated because they contribute to the reduction of the yield point and the increase of the tensile strength due to the abundance of dislocations. On the other hand, even in the parts that did not become austenite, carbides present in the metal structure were finely dispersed by rapid heating and tempering for a short time, and were inherited from dislocations introduced by transformation such as martensitic transformation and processed austenite. The large number of dislocations remaining in the metal structure increases the strength, and in some cases, the mobile dislocations promote ductility and increase the toughness of the steel.

【0009】さらに、降伏点の低下に付いてはオーステ
ナイト化した際にオーステナイト部分がマルテンサイト
(フェライト)との固溶度の差に基づいて、残部金属組
織の固溶元素を吸収、低減するという効果も期待でき、
このような効果は一度オーステナイト化した部分がフェ
ライトとセメンタイトとなった場合でも有効である。以
上のような考え方によって、本発明法によれば、マルテ
ンサイトあるいはベイナイトの微細な金属組織状態を損
なうこと無く、その組織中の極めて微少な部分を一度オ
ーステナイト化し、この部分を冷却中に再び微細なマル
テンサイト、残留オーステナイト、セメンタイトもしく
はこの混合物として、焼き戻しマルテンサイトあるいは
ベイナイト中に分散させることにより、強度、靱性にす
ぐれた低降伏比高張力鋼板を製造し得るのである。
[0009] Further, the lowering of the yield point means that when austenite is formed, the austenite portion absorbs and reduces solid solution elements of the remaining metal structure based on the difference in solid solubility with martensite (ferrite). The effect can be expected,
Such an effect is effective even when the austenitized portion becomes ferrite and cementite. Based on the above-mentioned concept, according to the method of the present invention, an extremely minute portion in the microstructure of austenite is once converted to austenite without impairing the fine metal structure of martensite or bainite, and this portion is again refined during cooling. By dispersing such martensite, retained austenite, cementite or a mixture thereof in tempered martensite or bainite, a low-yield-ratio high-tensile steel sheet having excellent strength and toughness can be produced.

【0010】次に、生産性の見地からは図1に示すよう
に昇温速度を増加させ、保持を15分以内の短時間とす
ることにより、焼き戻しに要する実処理時間を大幅に減
少させることができ、生産性を著しく向上することが可
能となるのである。即ち、本発明法を適用する事によっ
て、従来法に比してきわめて短時間で、強度、靱性に優
れた低降伏比鋼板の製造が可能なのである。このような
新しい発見に基づき本発明法における鋼の化学成分、製
造条件を詳細に調査した結果本発明者らは特許請求の範
囲の第1項、第2項に示したような強靱な厚鋼板の製造
方法を創案した。
Next, from the viewpoint of productivity, the actual processing time required for tempering is greatly reduced by increasing the heating rate as shown in FIG. 1 and keeping the temperature within 15 minutes. It is possible to significantly improve productivity. That is, by applying the method of the present invention, it is possible to produce a low yield ratio steel sheet having excellent strength and toughness in a very short time as compared with the conventional method. Based on such a new discovery, a detailed investigation was made on the chemical composition and production conditions of steel in the method of the present invention. As a result, the present inventors found that a tough steel plate as described in claims 1 and 2 of the claims was obtained. Of the manufacturing method of

【0011】以下に製造方法の限定の理由について述べ
る。Cは鋼の強化を行うのに有効な元素であり0.02
%未満では十分な強度が得られない。一方、その含有量
が0.5%を越えると、溶接性を劣化させる。Siは脱
酸元素として、また、鋼の強化元素として有効である
が、0.01%未満の含有量ではその効果がない。一
方、1.0%を越えると、鋼の表面性状を損なう。Mn
は鋼の強化に有効な元素であり、0.02%未満では十
分な効果が得られない。一方、その含有量が10.0%
を越えると鋼の加工性を劣化させる。Alは脱酸元素と
して添加されるが、0.10%を越えると、鋼の表面性
状を劣化させる。
The reason for limiting the manufacturing method will be described below. C is an element effective for strengthening steel and is 0.02%.
%, Sufficient strength cannot be obtained. On the other hand, if the content exceeds 0.5%, the weldability deteriorates. Although Si is effective as a deoxidizing element and as a strengthening element for steel, it is not effective at a content of less than 0.01%. On the other hand, if it exceeds 1.0%, the surface properties of the steel are impaired. Mn
Is an element effective for strengthening steel, and if it is less than 0.02%, a sufficient effect cannot be obtained. On the other hand, the content is 10.0%
If it exceeds, the workability of the steel is deteriorated. Al is added as a deoxidizing element, but if it exceeds 0.10%, the surface properties of the steel deteriorate.

【0012】TiおよびNbはいずれも微量の添加で結
晶粒の微細化と析出強化の面で有効に機能するので溶接
部の靱性を劣化させない範囲で使用しても良い。このよ
うな観点からその添加量の上限を0.1%とする。C
u,Ni,Cr,Mo,Co,Wはいずれも鋼の焼き入
れ性を向上させる元素であり、本発明の場合、その添加
により鋼の強度を高めることが出来る。しかし、過度の
添加は鋼の靱性および溶接性を損なうため、Cu≦1
0.0%、Ni≦10.0%、Cr≦3.0%、Mo≦
3.0%、Co≦10.0%、W≦3.0%に限定す
る。Vは析出強化により鋼の強度を高めるのに有効であ
るが、過度の添加は鋼の靱性を損なうために、その上限
を0.10%とする。Bは鋼の焼き入れ性を向上させる
元素である。本発明における場合、その添加により鋼の
強度を高めることができるが、過度の添加はBの析出物
を増加させ鋼の靱性を損ねるのでその含有量の上限を
0.003%とする。
[0012] Since both Ti and Nb function effectively in terms of grain refinement and precipitation strengthening when added in a small amount, they may be used in a range that does not deteriorate the toughness of the welded portion. From such a viewpoint, the upper limit of the addition amount is set to 0.1%. C
u, Ni, Cr, Mo, Co, and W are all elements that improve the hardenability of steel. In the case of the present invention, the addition of u, Ni, Cr, Mo, Co, and W can increase the strength of steel. However, since excessive addition impairs the toughness and weldability of the steel, Cu ≦ 1
0.0%, Ni ≦ 10.0%, Cr ≦ 3.0%, Mo ≦
3.0%, Co ≦ 10.0%, W ≦ 3.0%. V is effective in increasing the strength of the steel by precipitation strengthening, but excessive addition impairs the toughness of the steel, so the upper limit is made 0.10%. B is an element that improves the hardenability of steel. In the case of the present invention, the strength of the steel can be increased by its addition, but excessive addition increases the precipitation of B and impairs the toughness of the steel, so the upper limit of the content is made 0.003%.

【0013】次に、本発明における製造条件に付いて述
べる。本発明はいかなる鋳造条件で鋳造された鋼片につ
いても有効であるので、特に鋳造条件を特定する必要は
ない。また、鋳片を冷却すること無くそのまま熱間圧延
を開始しても一度冷却した鋳片をAc3 点以上に再加熱
した後に圧延を開始しても良い。なお、本発明において
は圧延あるいは圧延後の冷却の条件に付いては特に規定
するものではないが、それはいかなる圧延、冷却を行っ
ても本発明の有効性が失われないからである。ただし、
本発明では焼き戻しにより鋼中の結晶粒、炭化物を微細
に分散させるという目的があるので本発明の効果を最大
限に利用するためには、焼き入れ後に金属組織がマルテ
ンサイトあるいはベイナイトで、結晶粒が微細であるこ
とが望ましい。
Next, the manufacturing conditions in the present invention will be described. Since the present invention is effective for billets cast under any casting conditions, there is no need to specify the casting conditions. Alternatively, hot rolling may be started as it is without cooling the slab, or rolling may be started after the slab once cooled is reheated to three or more Ac points. In the present invention, conditions for rolling or cooling after rolling are not particularly specified, because the effectiveness of the present invention is not lost even if any rolling or cooling is performed. However,
In the present invention, there is an object of finely dispersing the crystal grains and carbides in the steel by tempering.In order to make the most of the effect of the present invention, after quenching, the metal structure is martensite or bainite, and It is desirable that the grains are fine.

【0014】次に、焼き戻し条件についてであるが、焼
き戻し温度をAc1 点以上としたのはこれ未満では炭化
物をオーステナイト化することができないからである。
焼き戻し中の昇温速度を1℃/秒以上、Ac1 点以上の
温度域での保持を15分以内としたのは、昇温速度が遅
く、保持時間が長ければ昇温中に転位の回復、組織・析
出物の粗大化、固溶炭素原子の析出が生じてしまい強
度、靱性を高めることができないこととオーステナイト
の粗大化が進み、冷却後の組織が粗大で不均一となり、
靱性を劣化させるからである。
[0014] Next, although the tempering conditions, the the temperature tempering was Ac 1 point or more than this it is not possible to austenite the carbides.
The reason why the rate of temperature rise during tempering was 1 ° C./sec or more and the holding in the temperature range of 1 point or more of Ac was 15 minutes or less was that the rate of temperature rise was slow, and if the holding time was long, dislocation during the temperature rising Recovery, coarsening of structure and precipitates, precipitation of solid solution carbon atoms occur, strength and toughness can not be increased and austenite coarsening progresses, the structure after cooling becomes coarse and non-uniform,
This is because toughness is deteriorated.

【0015】[0015]

【実施例】次に本発明の実施例によって本発明の有効性
を示す。表1及び表2は実施例の鋼の成分を示すもので
ある。このような成分の鋼を表2及び表3に示す製造条
件で製造した場合に、同じく表2及び表3に示すような
強度、靱性、焼き戻しに要した処理時間が得られた。表
3、表4では本発明の条件に合致しない項目に下線をつ
けて示して有る。これによれば、本発明法は比較法に比
べ明らかに生産性が高く、引っ張り強度・靱性に優れた
低降伏比鋼板を製造することが可能であり、本発明は有
効である。
EXAMPLES Next, the effectiveness of the present invention will be shown by examples of the present invention. Tables 1 and 2 show the components of the steels of the examples. When steels having such components were manufactured under the manufacturing conditions shown in Tables 2 and 3, the strength, toughness, and processing time required for tempering as shown in Tables 2 and 3 were also obtained. In Tables 3 and 4, items that do not meet the conditions of the present invention are underlined. According to this, the method of the present invention is clearly higher in productivity than the comparative method, and it is possible to produce a low yield ratio steel sheet excellent in tensile strength and toughness, and the present invention is effective.

【0016】[0016]

【表1】 [Table 1]

【0017】[0017]

【表2】 [Table 2]

【0018】[0018]

【表3】 [Table 3]

【0019】[0019]

【表4】 [Table 4]

【0020】[0020]

【発明の効果】以上述べたように、本発明の実施によっ
て、従来法に比較して極めて短時間で、かつ強度、靱性
に優れた低降伏比鋼板が製造可能となり、生産性を著し
く向上することが出来た。
As described above, by implementing the present invention, it is possible to produce a low yield ratio steel sheet having excellent strength and toughness in an extremely short time as compared with the conventional method, and the productivity is remarkably improved. I was able to do it.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明中の焼き戻し処理の説明図である。FIG. 1 is an explanatory diagram of a tempering process in the present invention.

───────────────────────────────────────────────────── フロントページの続き (72)発明者 尾上 泰光 千葉県富津市新富20−1 新日本製鐵株 式会社 技術開発本部内 (56)参考文献 特開 昭53−23817(JP,A) 特開 昭54−74221(JP,A) (58)調査した分野(Int.Cl.7,DB名) C21D 6/00 C21D 8/00 - 8/02 C22C 38/00 - 38/60 ────────────────────────────────────────────────── ─── Continuing from the front page (72) Inventor Yasumitsu Onoe 20-1 Shintomi, Futtsu-shi, Chiba Nippon Steel Corporation Technology Development Division (56) References JP-A-53-23817 (JP, A) 1979-74221 (JP, A) (58) Fields investigated (Int. Cl. 7 , DB name) C21D 6/00 C21D 8/00-8/02 C22C 38/00-38/60

Claims (2)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 重量%で、 C :0.02〜0.5%、 Mn:0.02〜10.0%、 Si:0.01〜1.0%、 Al:0.1%以下、 を含有し、残部がFeおよび不可避的不純物からなる鋼
板を直接焼き入れあるいは再加熱後に焼き入れし、その
後、焼き戻しを行って高張力鋼板を製造する方法におい
て、焼き入れ後の金属組織が主にベイナイト、マルテン
サイトあるいはこの混合組織であって、焼き戻し時の昇
温速度を1℃/秒以上、焼き戻し温度をAc1 点以上の
温度とし、さらに保持を15分以内で終了し、その後、
放冷もしくは強制冷却を行うことを特徴とする生産性の
高い高強度、高靱性低降伏比高張力鋼板の製造方法。
C .: 0.02 to 0.5%, Mn: 0.02 to 10.0%, Si: 0.01 to 1.0%, Al: 0.1% or less by weight%. In a method of directly quenching or reheating and quenching a steel sheet containing Fe and inevitable impurities, and then quenching the steel sheet to produce a high-tensile steel sheet, the metal structure after quenching is mainly The tempering rate during tempering is 1 ° C./sec or more , the tempering temperature is 1 point or more, and the holding is completed within 15 minutes. ,
A method for producing a high-strength, high-toughness, low-yield-ratio, high-strength steel sheet with high productivity, characterized by performing cooling or forced cooling.
【請求項2】 重量%で、 C: 0.02〜0.5%、 Mn:0.02〜10.0%、 Si:0.01〜1.0%、 Al:0.1%以下、 が基本成分であり、 Mo:3.0 %以下、 Ni:10.0 %以下、 Cr:3.0 %以下、 V :0.1 %以下、 Nb:0.1 %以下、 Ti:0.1 %以下、 B :0.003 %以下、 Cu:10.0 %以下、 Co:10.0 %以下、 W :3.0 %以下 のいずれか1種、または2種以上をさらに含有する残部
がFeおよび不可避的不純物からなる鋼板を直接焼き入
れあるいは再加熱後に焼き入れし、その後焼き戻しを行
って高張力鋼板を製造する方法において、焼き入れ後の
組織が主にマルテンサイト、ベイナイトあるいはこの混
合組織であって、焼き戻し時の昇温速度を1℃/秒以
、焼き戻し温度をAc1 点以上の温度とし、さらに保
持時間を15分以内で終了し、その後放冷もしくは強制
冷却を行うことを特徴とする生産性の高い高強度、高靱
性低降伏比高張力鋼板の製造方法。
2. In% by weight, C: 0.02 to 0.5%, Mn: 0.02 to 10.0%, Si: 0.01 to 1.0%, Al: 0.1% or less, Are the basic components, Mo: 3.0% or less, Ni: 10.0% or less, Cr: 3.0% or less, V: 0.1% or less, Nb: 0.1% or less, Ti: 0. 1% or less, B: 0.003% or less, Cu: 10.0% or less, Co: 10.0% or less, W: 3.0% or less. Is directly quenched or quenched after reheating a steel sheet comprising Fe and unavoidable impurities, and then tempered to produce a high-tensile steel sheet, the structure after quenching is mainly martensite, bainite or It is a mixed structure, and the temperature rise rate during tempering is 1 ° C / sec or less.
Furthermore, tempering temperature to a temperature of more than 1 point Ac, further holding time was completed within 15 minutes, then a high strength of productivity and performing cooling or forced cooling, high toughness low yield ratio Manufacturing method of high strength steel sheet.
JP02503092A 1992-02-12 1992-02-12 Manufacturing method of high strength steel sheet Expired - Lifetime JP3228986B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP02503092A JP3228986B2 (en) 1992-02-12 1992-02-12 Manufacturing method of high strength steel sheet

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP02503092A JP3228986B2 (en) 1992-02-12 1992-02-12 Manufacturing method of high strength steel sheet

Publications (2)

Publication Number Publication Date
JPH05222450A JPH05222450A (en) 1993-08-31
JP3228986B2 true JP3228986B2 (en) 2001-11-12

Family

ID=12154518

Family Applications (1)

Application Number Title Priority Date Filing Date
JP02503092A Expired - Lifetime JP3228986B2 (en) 1992-02-12 1992-02-12 Manufacturing method of high strength steel sheet

Country Status (1)

Country Link
JP (1) JP3228986B2 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69601340T2 (en) * 1995-04-12 1999-08-26 Mitsubishi Heavy Ind Ltd HIGH-STRENGTH, HIGH-STRENGTH HEAT-RESISTANT STEEL AND METHOD FOR THE PRODUCTION THEREOF
JP3352938B2 (en) * 1998-03-19 2002-12-03 株式会社神戸製鋼所 High-strength hot-rolled steel sheet excellent in impact resistance and method for producing the same
WO2004106574A1 (en) * 2003-05-27 2004-12-09 Koyo Seiko Co., Ltd. Steel bar for steering rack, method for producing the same, and steering rack using the same
KR101376683B1 (en) * 2011-09-15 2014-03-26 국방과학연구소 High~strength high~tensile steel and manufacturing method thereof
CN104789892B (en) * 2015-03-20 2017-03-08 宝山钢铁股份有限公司 There is low yield strength ratio high toughness thick steel plate and its manufacture method of superior low temperature impact flexibility
KR101917444B1 (en) * 2016-12-20 2018-11-09 주식회사 포스코 Steel plate for pressure vessel having excellent resistance for high-temperature tempering and post weld heat treatment, and method for manufacturing same
CN109652733B (en) * 2019-01-07 2021-01-26 南京钢铁股份有限公司 690 MPa-grade super-thick steel plate and manufacturing method thereof

Also Published As

Publication number Publication date
JPH05222450A (en) 1993-08-31

Similar Documents

Publication Publication Date Title
JP4529549B2 (en) Manufacturing method of high-strength cold-rolled steel sheets with excellent ductility and hole-expansion workability
JP2876968B2 (en) High-strength steel sheet having high ductility and method for producing the same
JPH08176659A (en) Production of high tensile strength steel with low yield ratio
JPH07278656A (en) Production of low yield ratio high tensile strength steel
JP3015923B2 (en) Manufacturing method for tough steel
KR20010060760A (en) structural steel having High strength and method for menufactreing it
JP3228986B2 (en) Manufacturing method of high strength steel sheet
JP3015924B2 (en) Manufacturing method for tough steel
JP3422864B2 (en) Stainless steel with excellent workability and method for producing the same
JPH09256037A (en) Production of thick high tensile strength steel plate for stress relieving annealing treatment
JP3246993B2 (en) Method of manufacturing thick steel plate with excellent low temperature toughness
KR20000043762A (en) Method of manufacturing super high-strength cold-rolled steel sheet improved in ductility
JPH06128631A (en) Production of high manganese ultrahigh tensile strength steel excellent in low temperature toughness
JP3267653B2 (en) Manufacturing method of high strength steel sheet
JP3229107B2 (en) Manufacturing method of low yield ratio high strength steel sheet with excellent uniform elongation
JP3462922B2 (en) Manufacturing method of high strength steel sheet with excellent strength and toughness
JPS6137333B2 (en)
JPH0813028A (en) Production of precipitation hardening steel material having high tensile strength and high toughness
JPH09256038A (en) Heat treatment before stress relieving annealing treatment for thick steel plate
JPH08283838A (en) Production of low yield ratio, high ductility steel excellent in strength, toughness and ductility
JPH1192860A (en) Steel having ultrafine ferritic structure
JPH05230531A (en) Production of high tensile strength steel plate having low yield ratio
JP3502809B2 (en) Method of manufacturing steel with excellent toughness
JPH05271756A (en) Manufacture of thick steel plate for welded structure excellent in toughness at low temperature
JPH1121625A (en) Production of thick steel plate excellent in strength and toughness

Legal Events

Date Code Title Description
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20010828

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20070907

Year of fee payment: 6

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20080907

Year of fee payment: 7

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20090907

Year of fee payment: 8

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20100907

Year of fee payment: 9

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20100907

Year of fee payment: 9

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20110907

Year of fee payment: 10

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20120907

Year of fee payment: 11

EXPY Cancellation because of completion of term
FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20120907

Year of fee payment: 11