JP3136195B2 - Resin composition and electrical equipment - Google Patents
Resin composition and electrical equipmentInfo
- Publication number
- JP3136195B2 JP3136195B2 JP04149912A JP14991292A JP3136195B2 JP 3136195 B2 JP3136195 B2 JP 3136195B2 JP 04149912 A JP04149912 A JP 04149912A JP 14991292 A JP14991292 A JP 14991292A JP 3136195 B2 JP3136195 B2 JP 3136195B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- resin
- parts
- inorganic filler
- resin composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Landscapes
- Polyesters Or Polycarbonates (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Insulating Of Coils (AREA)
- Inorganic Insulating Materials (AREA)
- Organic Insulating Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
【０００１】[0001]
【産業上の利用分野】本発明は、低粘度で、密着性、柔
軟性に優れた樹脂組成物及びこれを用いた電気機器に関
する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a resin composition having a low viscosity, excellent adhesion and flexibility, and an electric device using the same.
【０００２】[0002]
【従来の技術】含酸素芳香族炭化水素ホルムアルデヒド
樹脂と不飽和多塩基酸を反応させた変性芳香族炭化水素
樹脂や、不飽和ポリエステル樹脂と反応性単量体を混合
した無溶剤の樹脂組成物は、柔軟性、電気絶縁性、耐候
性、金属との密着性等に優れているため、さらに無機質
充填剤を混合させて熱伝導率向上、低コスト用として、
安定器のトランス等の電気機器等に使用されている。2. Description of the Related Art Solvent-free resin compositions in which a modified aromatic hydrocarbon resin obtained by reacting an oxygen-containing aromatic hydrocarbon formaldehyde resin with an unsaturated polybasic acid, or an unsaturated polyester resin and a reactive monomer are mixed. Is excellent in flexibility, electrical insulation, weather resistance, adhesion to metal, etc., and further mixed with inorganic filler to improve thermal conductivity, for low cost,
It is used for electrical equipment such as ballast transformers.
【０００３】しかしながら、従来ユーザーにおいて、液
状である樹脂組成物と、粉末状の無機充填剤と混合して
使用するため、作業環境が悪化するのは避けられない状
況にあった。また、その無機充填剤は沈降しやすいた
め、混合後速やかに使用しなければならないという制約
もあった。これらの理由から、樹脂組成物と無機充填剤
との混合作業から、注入、硬化に至るまでの工程は、機
械による自動ライン化が遅れているのが実情であった。[0003] However, in the past, for users, since the liquid resin composition and the powdered inorganic filler were used in a mixed state, the working environment was inevitably deteriorated. In addition, since the inorganic filler tends to settle, there is a restriction that the inorganic filler must be used immediately after mixing. For these reasons, in the process from the work of mixing the resin composition and the inorganic filler to the injection and curing, the automatic line by machine has been delayed.
【０００４】[0004]
【発明が解決しようとする課題】本発明は、上記の欠点
を解消するためになされたもので、低粘度で無機質充填
剤の沈降が少なく、柔軟性、電気絶縁性、耐候性、金属
との密着性等に優れた、自動化ラインに対応した樹脂組
成物及び電気機器を提供しようとするものである。SUMMARY OF THE INVENTION The present invention has been made to solve the above-mentioned disadvantages, and has low viscosity, low sedimentation of an inorganic filler, flexibility, electrical insulation, weather resistance, and a reduction in metal. An object of the present invention is to provide a resin composition and an electric device which are excellent in adhesion and are compatible with an automation line.
【０００５】[0005]
【課題を解決するための手段】本発明者は、上記の目的
を達成しようと鋭意研究を重ねた結果、特定の不飽和ポ
リエステル樹脂と特定量の無機質充填剤を用いることに
よって、上記の目的を達成できることを見いだし、本発
明を完成したものである。Means for Solving the Problems As a result of diligent research aimed at achieving the above object, the present inventor has achieved the above object by using a specific unsaturated polyester resin and a specific amount of an inorganic filler. The inventors have found what can be achieved and completed the present invention.
【０００６】即ち、本発明は、 （Ａ）（a ）エポキシ樹脂エステル 5〜20重量％、（b
）含酸素芳香族炭化水素ホルムアルデヒド樹脂10〜40
重量％で変性した変性不飽和ポリエステル樹脂 （Ｂ）反応性単量体 （Ｃ）無機質充填剤 を必須成分とし、前記樹脂成分［（Ａ）＋（Ｂ）］ 100
重量部に対し、前記（Ｃ）の無機質充填剤を 200〜350
重量部の割合で配合してなることを特徴とする樹脂組成
物及びそれを含浸硬化されてなることを特徴とする電気
機器である。That is, the present invention relates to (A) (a) 5 to 20% by weight of an epoxy resin ester, (b)
) Oxygenated aromatic hydrocarbon formaldehyde resin 10-40
The modified unsaturated polyester resin (B) reactive monomer (C) inorganic filler is an essential component, and the resin component [(A) + (B)]
200 to 350 parts by weight of the inorganic filler (C)
A resin composition characterized by being blended in parts by weight, and an electric device characterized by being impregnated and cured with the resin composition.
【０００７】以下、本発明を詳細に説明する。Hereinafter, the present invention will be described in detail.
【０００８】本発明に用いる（Ａ）変性不飽和ポリエス
テル樹脂は、（a ）エポキシ樹脂エステル 5〜20重量
％、（b ）含酸素芳香族炭化水素ホルムアルデヒド樹脂
10〜40重量％で変性したものである。The modified unsaturated polyester resin (A) used in the present invention comprises (a) 5 to 20% by weight of an epoxy resin ester, and (b) an oxygen-containing aromatic hydrocarbon formaldehyde resin.
Modified at 10 to 40% by weight.
【０００９】変性不飽和ポリエステル樹脂の変性成分で
ある（a ）エポキシ樹脂エステルとしては、ビスフェノ
ールＡ型、ビスフェノールＦ型、ポリフェノール型、ハ
ロゲン化のビスフェノール型、多価グリシジルエステル
型等の単独又は 2種以上のエポキシ樹脂のエポキシ基
を、酸成分でエステル変性したものである。この酸成分
としては、アジピン酸、無水フタル酸、無水テトラヒド
ロフタル酸、ヒドロキシメタアクリル酸、無水マレイン
酸、マレイン酸、フマール酸、大豆油脂肪酸、アマニ油
脂肪酸、トール油脂肪酸等が挙げられ、これらは単独ま
たは 2種以上混合して使用することができる。エポキシ
樹脂のエポキシ当量は、1000を超えない範囲であるとが
好ましく、より好ましくは 500を超えない範囲である。
エポキシ当量が1000を超えると反応性単量体に対する溶
解性が低下して、粘度が増加し好ましくない。エポキシ
樹脂エステルの配合割合は、変性不飽和ポリエステル樹
脂に対して 5〜20重量％含有するように配合することが
望ましい。この割合が 5重量％未満では、十分な金属と
の密着性、電気絶縁性、熱的特性が得られず、また、20
重量％を超えると粘度が低下せず、無機質充填剤を混合
した際の粘度が上昇し好ましくない。As the epoxy resin ester (a) which is a modifying component of the modified unsaturated polyester resin, bisphenol A type, bisphenol F type, polyphenol type, halogenated bisphenol type, polyhydric glycidyl ester type and the like can be used alone or in combination. The epoxy group of the above epoxy resin is ester-modified with an acid component. Examples of the acid component include adipic acid, phthalic anhydride, tetrahydrophthalic anhydride, hydroxymethacrylic acid, maleic anhydride, maleic acid, fumaric acid, soybean oil fatty acid, linseed oil fatty acid, and tall oil fatty acid. Can be used alone or in combination of two or more. The epoxy equivalent of the epoxy resin is preferably within a range not exceeding 1000, more preferably within a range not exceeding 500.
If the epoxy equivalent exceeds 1000, the solubility in the reactive monomer decreases, and the viscosity increases, which is not preferable. It is desirable that the epoxy resin ester is blended so as to contain 5 to 20% by weight based on the modified unsaturated polyester resin. If this proportion is less than 5% by weight, sufficient adhesion to metal, electrical insulation and thermal properties cannot be obtained.
If the amount exceeds 10% by weight, the viscosity does not decrease and the viscosity when the inorganic filler is mixed increases, which is not preferable.
【００１０】また、他の変性成分である（b ）含酸素芳
香族炭化水素ホルムアルデヒド樹脂は、芳香族炭化水
素、例えばメシチレンとホルムアルデヒドを反応させて
メチレンエーテルを含む重合鎖を与えた含酸素の樹脂で
あって、具体的なものとして、例えば、ニカノールＭ
（三菱瓦斯化学社製、商品名）、ゼネライト３１５０
（ゼネラル石油化学社製、商品名）等が挙げられ、これ
らは単独または 2種以上混合して使用することができ
る。（b ）含酸素芳香族炭化水素ホルムアルデヒド樹脂
の配合割合は、変性不飽和ポリエステル樹脂に対して10
〜40重量％含有するように配合することが望ましい。こ
の割合が10重量％未満では、硬化物の柔軟性が十分得ら
れず、また、40重量％を超えると、コスト面、密着性の
点で好ましくない。The oxygen-containing aromatic hydrocarbon formaldehyde resin (b), which is another modified component, is an oxygen-containing resin obtained by reacting an aromatic hydrocarbon such as mesitylene with formaldehyde to give a polymer chain containing methylene ether. And as a specific example, for example, Nicanol M
(Mitsubishi Gas Chemical Company, trade name), Generalite 3150
(Manufactured by General Petrochemical Co., Ltd., trade name) and the like, and these can be used alone or in combination of two or more. (B) The mixing ratio of the oxygen-containing aromatic hydrocarbon formaldehyde resin is 10% with respect to the modified unsaturated polyester resin.
It is desirable to mix them so as to contain up to 40 wt%. If this ratio is less than 10% by weight, the cured product will not have sufficient flexibility, and if it exceeds 40% by weight, it is not preferable in terms of cost and adhesion.
【００１１】上述した（a ）エポキシ樹脂エステルと、
（b ）含酸素芳香族炭化水素ホルムアルデヒド樹脂とを
反応させて、変性不飽和ポリエステル樹脂を得ることが
できる。(A) the epoxy resin ester described above;
(B) A modified unsaturated polyester resin can be obtained by reacting with an oxygen-containing aromatic hydrocarbon formaldehyde resin.
【００１２】本発明に用いる（Ｂ）反応性単量体として
は、スチレン、スチレン誘導体、アクリル酸エステル、
メタクリル酸エステル、各種アリールエステル等が挙げ
られ、これらは単独または 2種以上混合して使用するこ
とができる。反応性単量体の配合割合は、前述した
（Ａ）変性不飽和ポリエステル樹脂 100重量部に対して
30〜140 重量部配合することが望ましい。配合量が30重
量部未満では、粘度が高く、作業性を損ない、また 140
重量部を超えると金属との密着性、柔軟性等が得られず
好ましくない。The reactive monomer (B) used in the present invention includes styrene, styrene derivatives, acrylates,
Examples include methacrylic acid esters and various aryl esters, and these can be used alone or in combination of two or more. The proportion of the reactive monomer is based on 100 parts by weight of the above-mentioned (A) modified unsaturated polyester resin.
It is desirable to add 30 to 140 parts by weight. If the amount is less than 30 parts by weight, the viscosity is high and the workability is impaired.
If the amount is more than the weight part, adhesion to metal, flexibility and the like cannot be obtained, which is not preferable.
【００１３】本発明に用いる（Ｃ）無機質充填剤として
は、シリカ、硅砂、炭酸カルシウム、水和アルミナ、ア
ルミナ、タルク等が挙げられ、これらは単独または 2種
以上混合して使用することができる。平均粒径 6μm の
シリカ、平均粒径40〜60μmの硅砂、平均粒径 1μm の
炭酸カルシウム、平均粒径 1μm の水和アルミナもしく
はアルミナ等が好ましく使用され、これらの範囲を外れ
ると沈降性が悪くなり好ましくない。無機質充填剤の配
合割合は、前述した樹脂成分［（Ａ）＋（Ｂ）］ 100重
量部に対し 200〜350 重量部の割合で配合することが望
ましい。この割合が 200重量部未満では十分硬化するこ
とができず、また 350重量部を超えると高粘度となり作
業性が悪くなるので好ましくいない。The inorganic filler (C) used in the present invention includes silica, silica sand, calcium carbonate, hydrated alumina, alumina, talc and the like, and these can be used alone or in combination of two or more. . Silica having an average particle size of 6 μm, silica sand having an average particle size of 40 to 60 μm, calcium carbonate having an average particle size of 1 μm, hydrated alumina or alumina having an average particle size of 1 μm are preferably used. It is not preferable. The inorganic filler is desirably compounded at a ratio of 200 to 350 parts by weight with respect to 100 parts by weight of the resin component [(A) + (B)]. If the proportion is less than 200 parts by weight, curing cannot be sufficiently performed, and if it exceeds 350 parts by weight, the viscosity becomes high and workability deteriorates, which is not preferable.
【００１４】本発明の樹脂組成物は、変性不飽和ポリエ
ステル樹脂、反応性単量体および無機充填剤を必須成分
とするが、本発明の目的に反しない範囲において、また
必要に応じて他の成分例えば、消泡剤、減粘剤、硬化剤
等を添加配合することができる。この硬化剤としては、
有機過酸化物例えば、ラウロイルパーオキサイド、ベン
ゾイルパーオキサイド等のジアシルパーオキサイド等を
添加配合することもできる。また必要に応じて硬化促進
剤として、ナフテン酸又はオクテン酸金属塩（コバル
ト、マンガン、亜鉛、ジルコニウム等の金属塩）等が挙
げられ、これらは単独又は 2種以上混合して使用するこ
とができる。また、重合禁止剤としては、ハイドロキノ
ン、パラターシャリーブチルカテコール、ピロガロール
等のキノン類等が挙げられ、これらは単独又は 2種以上
混合して使用することができる。The resin composition of the present invention contains a modified unsaturated polyester resin, a reactive monomer and an inorganic filler as essential components, but may contain other components as far as it does not contradict the object of the present invention. Ingredients, for example, an antifoaming agent, a viscosity reducing agent, a curing agent and the like can be added and blended. As this curing agent,
Organic peroxides, for example, diacyl peroxides such as lauroyl peroxide and benzoyl peroxide can also be added and blended. If necessary, examples of the curing accelerator include metal salts of naphthenic acid or octenoic acid (metal salts such as cobalt, manganese, zinc, and zirconium), and these can be used alone or in combination of two or more. . Examples of the polymerization inhibitor include quinones such as hydroquinone, p-tert-butylcatechol, and pyrogallol, and these can be used alone or in combination of two or more.
【００１５】本発明の樹脂組成物は、変性不飽和ポリエ
ステル樹脂、反応性単量体および無機質充填剤、その他
の成分を配合して均一に混合して容易に製造することが
できる。そしてこの組成物を用いて含浸硬化させて電気
機器を製造することができる。含浸方法については特に
制限はなくいかなる方法でもよい。The resin composition of the present invention can be easily produced by blending a modified unsaturated polyester resin, a reactive monomer, an inorganic filler, and other components and mixing them uniformly. The composition can be impregnated and cured to produce an electrical device. The impregnation method is not particularly limited, and any method may be used.
【００１６】[0016]
【作用】本発明の樹脂組成物及び電気機器は、特定の変
性不飽和ポリエステル樹脂と、特定の無機質充填剤を特
定量用いることによって、低粘度で無機充填剤の沈降が
少なく、柔軟性、電気絶縁性、耐候性、金属との密着性
等に優れた、自動化ラインに対応した樹脂組成物及び電
気機器を提供することができたものである。The resin composition and the electric equipment of the present invention are low in viscosity, have low sedimentation of the inorganic filler, have low flexibility, and have high electrical and electrical properties, by using a specific amount of the specific modified unsaturated polyester resin and the specific inorganic filler. An object of the present invention is to provide a resin composition and an electric device which are excellent in insulation property, weather resistance, adhesion to a metal, etc. and are compatible with an automation line.
【００１７】[0017]
【実施例】次に本発明を実施例によって説明するが、本
発明はこれらの実施例によって限定されるものではな
い。実施例及び比較例において「部」とは特に説明のな
い限り「重量部」を意味する。Ａ ［変性不飽和ポリエ
ステル樹脂の製造］Ａ−１ Ａ−１を欠番とする。 Next, the present invention will be described with reference to examples, but the present invention is not limited to these examples. In the examples and comparative examples, “parts” means “parts by weight” unless otherwise specified. A [Production of Modified Unsaturated Polyester Resin ] A-1 A-1 is omitted.
【００１８】Ａ−２ エポキシ樹脂のエピコート＃８２
８（シェル社製商品名、エポキシ当量 184〜194 ）15
部、トリフェニルホスフィン 0.07 部、大豆油脂肪酸20
部を 140〜150 ℃で 2時間反応させた後、含酸素芳香族
炭化水素ホルムアルデヒド樹脂の、ゼネライト３１５０
（ゼネラル石油化学社製、商品名）30部、ハイドロキノ
ン 0.01 部、水 6部、無水マレイン酸 4部を加え 190〜
200 ℃で反応させて酸価10の樹脂を得た。その樹脂50部
に、反応性単量体としてスチレン50部を加えて攪拌溶解
し、変性不飽和ポリエステル樹脂を製造した。A-2 Epoxy coat # 82 of epoxy resin
8 (Product name of shell company, epoxy equivalent 184-194) 15
Parts, triphenylphosphine 0.07 parts, soybean oil fatty acid 20
After reacting at 140-150 ° C. for 2 hours, oxygen-containing aromatic hydrocarbon formaldehyde resin, Generalite 3150
(General Petrochemical Co., Ltd., trade name) 30 parts, hydroquinone 0.01 parts, water 6 parts, maleic anhydride 4 parts and added 190 ~
The reaction was carried out at 200 ° C. to obtain a resin having an acid value of 10. To 50 parts of the resin, 50 parts of styrene as a reactive monomer was added and dissolved by stirring to produce a modified unsaturated polyester resin.
【００１９】実施例１実施例１を欠番とする。 Embodiment 1 Embodiment 1 is omitted.
【００２０】実施例２ Ａ−２で製造した変性不飽和ポリエステル樹脂 100部
に、 6％ナフテン酸コバルト 0.2部、無機質充填剤であ
るシリカＡ−３（丸山砿業社製硅砂、商品名） 210部お
よびソフトン２２００（備北粉化工業社製炭酸カルシウ
ム、商品名）90部を加えて混合、攪拌して樹脂組成物を
製造した。Example 2 0.2 part of 6% cobalt naphthenate, 100 parts of the modified unsaturated polyester resin produced in A-2, and 210 parts of silica A-3 (silica sand, trade name, manufactured by Maruyama Mining Co., Ltd.) as an inorganic filler And 90 parts of Softon 2200 (calcium carbonate, trade name, manufactured by Bihoku Powder Chemical Industry Co., Ltd.) were added, mixed and stirred to produce a resin composition.
【００２１】比較例１比較例１を欠番とする。 Comparative Example 1 Comparative Example 1 is a missing number.
【００２２】比較例３比較例３を欠番とする。 Comparative Example 3 Comparative Example 3 is omitted.
【００２３】実施例２及び比較例２で製造した樹脂組成
物を用いて、粘度、沈降性を試験した。また、これらの
樹脂組成物を用いてトランスに含浸させ、密着性、騒音
レベルを試験した。その結果を表１に示したが、本発明
は、いずれの特性においても優れており、本発明の効果
を確認することができた。これらの試験は次のようにし
て行った。Using the resin compositions produced in Example 2 and Comparative Example 2 , the viscosity and sedimentation were tested. Transformers were impregnated with these resin compositions and tested for adhesion and noise level. The results are shown in Table 1. The present invention was excellent in any of the characteristics, and the effect of the present invention could be confirmed. These tests were performed as follows.
【００２４】粘度は、Ｂ型粘度計（４番ローター／30rp
m ）を25℃において測定した。沈降性試験は、直径12c
m、高さ15cmのブリキ製丸缶に、樹脂組成物の 1.5kgを
入れ室温で 1日、 1ケ月間静置保管した後のそれぞれの
沈降状態を測定した。密着性の試験は、縦5cm 、横4cm
、高さ17cmの金属ケースに、縦4cm 、横2cm 、高さ12c
mのトランスを入れ、樹脂組成物 100部に硬化剤として
パーメックＮ（日本油脂社製、商品名） 0.5部を加えて
混合したものを金属ースに注入し、温度80℃で 1時間加
熱硬化させたものを室温まで冷却させる。これを温度−
20℃で 1時間乃至温度 130℃で 1時間のヒートサイクル
試験を30サイクル行い、金属ケースと樹脂組成物の密着
状態を観察した。即ち、トランス入り金属ケースを、赤
インク中に浸漬した後洗浄し、ケースを引き剥がし、樹
脂組成物とケースとが剥離した部分に侵入した赤インク
部分の面積が、全体の70％以上有るものを不合格と判定
した。騒音レベルは、樹脂組成物を注入、硬化したトラ
ンスに所定の電圧，電流値を通電して、 5分後の騒音値
を無音室で測定し、25 dＢ以上のものを不合格と判定し
た。The viscosity was measured using a B-type viscometer (No. 4 rotor / 30 rp).
m) was measured at 25 ° C. Sedimentation test, diameter 12c
1.5 kg of the resin composition was placed in a tin round can having a height of 15 cm and a height of 15 cm, and left standing at room temperature for one day and one month to measure the sedimentation state of each. Adhesion test is 5cm long, 4cm wide
, 17cm high metal case, 4cm long, 2cm wide, 12c high
m Transformer, 100 parts of resin composition, 0.5 part of Permec N (trade name, manufactured by NOF Corporation) as a curing agent was added and mixed, and the mixture was poured into metal powder and cured at 80 ° C for 1 hour. The let is allowed to cool to room temperature. This is the temperature-
A heat cycle test at 20 ° C. for 1 hour to a temperature of 130 ° C. for 1 hour was performed 30 times, and the adhesion between the metal case and the resin composition was observed. That is, the transformer-containing metal case is washed after being immersed in red ink, the case is peeled off, and the area of the red ink portion that has penetrated into the portion where the resin composition and the case have peeled is 70% or more of the whole. Was rejected. As for the noise level, a predetermined voltage and current value were applied to the transformer in which the resin composition was injected and cured, the noise value after 5 minutes was measured in a silent room, and a noise level of 25 dB or more was judged to be unacceptable.
【００２５】[0025]
【表１】（単位） [Table 1] (Unit)
【００２６】[0026]
【発明の効果】以上の説明および表１から明らかなよう
に、本発明の樹脂組成物は、低粘度で無機質充填剤の沈
降が少なく、柔軟性、電気絶縁性、耐候性、金属との密
着性等に優れた、自動化ラインに対応した含浸用樹脂
で、これを機械による自動化ラインで含浸、硬化させる
ことによって、生産性、信頼性の高い電気機器を製造す
ることができた。As is clear from the above description and Table 1, the resin composition of the present invention has low viscosity, little sedimentation of the inorganic filler, flexibility, electric insulation, weather resistance, adhesion to metal. An impregnating resin with excellent properties, etc., compatible with an automation line. By impregnating and curing the resin in an automated line using a machine, highly productive and highly reliable electrical equipment could be manufactured.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 ＦＩ Ｈ０１Ｆ 41/12 Ｈ０１Ｆ 41/12 Ｂ (58)調査した分野(Int.Cl.7，ＤＢ名) C08F 283/00 - 283/01 C08F 290/00 - 290/14 C08F 299/00 - 299/08 C08G 63/00 - 63/91 C08L 67/00 - 67/08 H01B 3/00 H01B 3/42 H01F 41/12 ──────────────────────────────────────────────────の Continuation of the front page (51) Int.Cl. 7 identification symbol FI H01F 41/12 H01F 41/12 B (58) Field surveyed (Int.Cl. 7 , DB name) C08F 283/00-283 / 01 C08F 290/00-290/14 C08F 299/00-299/08 C08G 63/00-63/91 C08L 67/00-67/08 H01B 3/00 H01B 3/42 H01F 41/12
Claims (2)
20重量％、（b ）含酸素芳香族炭化水素ホルムアルデヒ
ド樹脂10〜40重量％で変性した変性不飽和ポリエステル
樹脂 （Ｂ）反応性単量体 （Ｃ）無機質充填剤 を必須成分とし、前記樹脂成分［（Ａ）＋（Ｂ）］ 100
重量部に対し、前記（Ｃ）の無機質充填剤を 200〜350
重量部の割合で配合してなることを特徴とする樹脂組成
物。(A) (a) an epoxy resin ester 5 to
20% by weight, (b) a modified unsaturated polyester resin modified with 10 to 40% by weight of an oxygen-containing aromatic hydrocarbon formaldehyde resin, (B) a reactive monomer, and (C) an inorganic filler. [(A) + (B)] 100
200 to 350 parts by weight of the inorganic filler (C)
A resin composition characterized by being compounded in parts by weight.
20重量％、（b ）含酸素芳香族炭化水素ホルムアルデヒ
ド樹脂10〜40重量％で変性した変性不飽和ポリエステル
樹脂 （Ｂ）反応性単量体 （Ｃ）無機質充填剤 を必須成分とし、前記樹脂成分［（Ａ）＋（Ｂ）］ 100
重量部に対し、前記（Ｃ）の無機質充填剤を 200〜350
重量部の割合で配合した樹脂組成物を、含浸硬化させて
なることを特徴とする電気機器。(A) (a) an epoxy resin ester 5 to
20% by weight, (b) a modified unsaturated polyester resin modified with 10 to 40% by weight of an oxygen-containing aromatic hydrocarbon formaldehyde resin, (B) a reactive monomer, and (C) an inorganic filler. [(A) + (B)] 100
200 to 350 parts by weight of the inorganic filler (C)
An electric device characterized by being impregnated and cured with a resin composition blended in parts by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP04149912A JP3136195B2 (en) | 1992-05-18 | 1992-05-18 | Resin composition and electrical equipment |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP04149912A JP3136195B2 (en) | 1992-05-18 | 1992-05-18 | Resin composition and electrical equipment |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH05320285A JPH05320285A (en) | 1993-12-03 |
| JP3136195B2 true JP3136195B2 (en) | 2001-02-19 |
Family
ID=15485311
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP04149912A Expired - Lifetime JP3136195B2 (en) | 1992-05-18 | 1992-05-18 | Resin composition and electrical equipment |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3136195B2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5135532B2 (en) * | 2006-06-29 | 2013-02-06 | 新日鐵住金株式会社 | Method for coating an insulating coating on the surface of a laminated motor core |
-
1992
- 1992-05-18 JP JP04149912A patent/JP3136195B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH05320285A (en) | 1993-12-03 |
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