JP3062283B2 - Hair cosmetics - Google Patents
Hair cosmeticsInfo
- Publication number
- JP3062283B2 JP3062283B2 JP3109195A JP10919591A JP3062283B2 JP 3062283 B2 JP3062283 B2 JP 3062283B2 JP 3109195 A JP3109195 A JP 3109195A JP 10919591 A JP10919591 A JP 10919591A JP 3062283 B2 JP3062283 B2 JP 3062283B2
- Authority
- JP
- Japan
- Prior art keywords
- hair
- integer
- group
- osi
- gloss
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
【０００１】[0001]
【産業上の利用分野】本発明は毛髪に対し、優れた光沢
を与え、滑らかな感触及びしっとりした感触を付与し、
かつ良好な紫外線からの毛髪の保護効果を有する毛髪化
粧料に関するものである。BACKGROUND OF THE INVENTION The present invention provides hair with excellent gloss, smooth feel and moist feel,
The present invention also relates to a hair cosmetic having good hair protection from ultraviolet rays.
【０００２】[0002]
【従来の技術及び発明が解決しようとする課題】従来、
毛髪化粧料には、毛髪に光沢を与え、滑らかでしっとり
とした感触を付与し、良好なくし通り性を与える目的
で、ジメチルポリシロキサンに代表される油分を用いる
ことが一般的であった。2. Description of the Related Art
For hair cosmetics, oils represented by dimethylpolysiloxane are generally used for the purpose of imparting gloss to hair, imparting a smooth and moist feel, and giving good elimination.
【０００３】しかしながら、これら油分を多量に用いた
り、長期間使用すると油性感が増大し好ましくなく、ま
た光沢、滑らかさ、くし通り性等も必ずしも満足できる
ものではなかった。However, when these oils are used in a large amount or used for a long period of time, the oiliness increases, which is not preferable, and gloss, smoothness, combability and the like are not always satisfactory.
【０００４】一方、近年においては、紫外線による毛髪
の損傷が問題とされている。このため毛髪化粧料に紫外
線吸収剤を配合せしめ、毛髪を保護せんとしている。し
かし、紫外線防止効果の十分なものはなく、特に紫外線
を経時的に照射した場合の効果は不十分であった。更に
紫外線吸収剤を多量に用いると安全性が問題となる。従
って、髪に光沢、滑らかさ、良好なくし通り性を与え、
しかも紫外線による毛髪の損傷を防止することのできる
毛髪化粧料が望まれていた。On the other hand, in recent years, damage to hair due to ultraviolet rays has become a problem. For this reason, hair cosmetics are compounded with an ultraviolet absorber to protect the hair. However, the effect of preventing ultraviolet rays was not sufficient, and the effect in the case of irradiating ultraviolet rays with time was insufficient. Further, when a large amount of the ultraviolet absorber is used, safety becomes a problem. Therefore, it gives the hair gloss, smoothness, good combability,
In addition, there has been a demand for a hair cosmetic that can prevent damage to hair due to ultraviolet rays.
【０００５】[0005]
【発明が解決しようとする課題】本発明者らは、斯かる
実情に鑑み鋭意研究を行なった結果、アミノ変性シリコ
ーン誘導体と紫外線吸収剤を組み合せた毛髪化粧料が、
髪に光沢、滑らかさ、良好なくし通り性を与え、しかも
紫外線による毛髪の損傷を防止することを見出し本発明
を完成した。SUMMARY OF THE INVENTION The present inventors have conducted intensive studies in view of such circumstances, and as a result, have found that hair cosmetics combining an amino-modified silicone derivative and an ultraviolet absorbent have been developed.
The present invention has been found to impart gloss, smoothness and good combability to hair, and to prevent damage to the hair due to ultraviolet rays, and completed the present invention.
【０００６】すなわち、本発明は、（ａ）後記一般式
（１）で表わされるアミノ変性シリコーン誘導体及び
（ｂ）紫外線吸収剤を含有することを特徴とする、すす
がないで使用するタイプの毛髪化粧料を提供するもので
ある。That is, the present invention provides a soot-free type of hair comprising (a) an amino-modified silicone derivative represented by the following general formula (1) and (b) an ultraviolet absorber. Provide cosmetics.
【０００７】本発明に用いられるアミノ変性シリコーン
誘導体（ａ）は次の一般式（１）で表わされる。 (R1 aA(3-a))-Si-(OSi(A)2)m-[OSi-(AbR1 (2-b))]n-OSi(R
1 aA(3-a)) （１） 〔式中、Ａは水素原子、フェニル基、水酸基又は炭素数
１〜８のアルキル基を示し、ａは０〜３の整数を示し、
ｂは０又は１の整数を示し、ｍは０〜１９９９の整数を
示し、ｎは１〜２０００の整数を示すが、ｍ＋ｎは１〜
２０００の整数であり、Ｒ1 は基-CfH2fL（式中、ｆは
２〜８の整数であり、Ｌは基The amino-modified silicone derivative (a) used in the present invention is represented by the following general formula (1). (R 1 a A (3-a) ) -Si- (OSi (A) 2 ) m- [OSi- (A b R 1 (2-b) )] n -OSi (R
1 a A (3-a) ) (1) wherein A represents a hydrogen atom, a phenyl group, a hydroxyl group or an alkyl group having 1 to 8 carbon atoms, a represents an integer of 0 to 3,
b represents an integer of 0 or 1; m represents an integer of 0 to 1999; n represents an integer of 1 to 2000;
An integer of 2000; R 1 is a group —C f H 2f L (where f is an integer of 2 to 8, and L is a group
【０００８】[0008]
【化２】 Embedded image
【０００９】[0009]
【００１０】かかるアミノ変性シリコーン誘導体（ａ）
のうち、より好適にはCTFA Cosmetic Ingredient Dicti
onary （３rd Edition The Cosmetic Toiletry and Fra
grance Association Inc.,（1982））に記載されている
次の式（２）[0010] The amino-modified silicone derivative (a)
Among them, more preferably CTFA Cosmetic Ingredient Dicti
onary (3rd Edition The Cosmetic Toiletry and Fra
grance Association Inc., (1982))
【００１１】[0011]
【化３】 Embedded image
【００１２】（式中、ｐ及びｑは、分子量3000〜50,000
を満たす数を示す）(Wherein p and q have a molecular weight of 3,000 to 50,000)
Indicates the number that satisfies)
【００１３】で表わされるアモジメチコーン（AMODIMET
HICONE）又はこの水酸基をアルコキシ基で置換したもの
が挙げられる。またアミノ変性シリコーン誘導体はエマ
ルジョンの形態であっても良く、この例としては、SM 8
702C（東レシリコーン（株））、DC 929（ダウ・コーニ
ング（株））等が挙げられる。An amodimethicone represented by the formula (AMODIMET
HICONE) or those obtained by substituting this hydroxyl group with an alkoxy group. The amino-modified silicone derivative may be in the form of an emulsion.
702C (Toray Silicone Co., Ltd.) and DC 929 (Dow Corning Co., Ltd.).
【００１４】（ａ）成分の配合量は0.01〜10重量％（以
下単に「％」という）が好ましく、特に0.05〜５％とす
ることが好ましい。配合量が0.01％未満であると毛髪の
滑らかさが不十分であり、10％を超えるとべたつきが生
じ好ましくない。The amount of the component (a) is preferably 0.01 to 10% by weight (hereinafter simply referred to as "%"), particularly preferably 0.05 to 5%. If the amount is less than 0.01%, the smoothness of the hair is insufficient, and if it exceeds 10%, stickiness is undesirably caused.
【００１５】（ｂ）成分の紫外線吸収剤としては、例え
ばパラアミノ安息香酸エチル、パラジメチルアミノ安息
香酸エチルヘキシルエステル〔例えば、エスカロール
（ESCALOL ）507 （VANDYK社）〕、シノキサート、パラ
メトキシ桂皮酸エチルヘキシルエステル〔例えば、パー
ソール（Parsol）MCX （GIVAUDAN社）〕、２−（２−ヒ
ドロキシ−５−メチルフェニル）ベンゾトリアゾール、
オキシベンゾン〔例えば、スペクトラソルブ（Spectra-
Solb）UV９（American Cyanamid 社）〕、ウロカニン
酸、ウロカニン酸エチル、テトラヒドロキシベンゾフェ
ノン〔例えば、コビナールD50 （BASF社）〕等が挙げら
れる。これらは１種でも２種以上を混合して用いてもよ
く、配合量は、0.01〜５％が好ましく、特に0.05〜２％
が好ましい。As the ultraviolet absorber of the component (b), for example, ethyl paraaminobenzoate, ethylhexyl paradimethylaminobenzoate [eg, ESCALOL 507 (VANDYK)], sinoxate, ethylhexyl paramethoxycinnamate [ For example, Parsol MCX (GIVAUDAN)], 2- (2-hydroxy-5-methylphenyl) benzotriazole,
Oxybenzone [for example, Spectra-solve (Spectra-
Solb) UV9 (American Cyanamid)], urocanic acid, ethyl urocanate, tetrahydroxybenzophenone [for example, Kobinal D50 (BASF)] and the like. These may be used alone or as a mixture of two or more kinds. The compounding amount is preferably 0.01 to 5%, particularly 0.05 to 2%.
Is preferred.
【００１６】本発明には、上記必須成分の他、本発明の
効果を損なわない限り、界面活性剤、高分子化合物、そ
の他毛髪化粧料に一般的に用いられる添加物を配合する
ことができる。In the present invention, in addition to the above essential components, a surfactant, a polymer compound, and other additives generally used in hair cosmetics can be added as long as the effects of the present invention are not impaired.
【００１７】具体的にアニオン活性剤としては、直鎖／
分岐鎖アルキルベンゼンスルホン酸塩、EO／PO付加型ア
ルキル／アルケニルエーテル硫酸塩、アルキル／アルケ
ニル硫酸塩、オレフィンスルホン酸塩、アルカンスルホ
ン酸塩、飽和／不飽和脂肪酸塩、EO／PO付加型アルキ
ル、アルケニルエーテルカルボン酸塩、α−スルホ脂肪
酸塩／エステル、スルホコハク酸型活性剤、リン酸エス
テル型活性剤、アミノ酸型活性剤等が、ノニオン活性剤
としては、EO／PO／BO付加型ノニオン活性剤、高級脂肪
酸アルカノールアミド／そのアルキレンオキサイド付加
物、糖系ノニオン活性剤等が挙げられ、カチオン活性剤
としてはジ長鎖アルキル第４級アンモニウム塩、モノ長
鎖アルキル第４級アンモニウム塩、ジ長鎖アルキルポリ
オキシエチレン第４級アンモニウム塩、モノ長鎖アルキ
ルポリオキシエチレン第４級アンモニウム塩、ビス（ヒ
ドロキシアルキル）第４級アンモニウム塩、アミド／エ
ステル結合を有する第４級アンモニウム塩等が、両性活
性剤としては、アルキルアミノオキサイド、ベタイン型
（例えばカルボベタイン、アミドベタイン、スルホベタ
イン、ヒドロキシスルホベタイン、アミドスルホベタイ
ン）、イミダゾリン型、アミドアミン型等が挙げられ
る。また、高分子化合物としては、ポリビニルピロリド
ン系高分子化合物、酸性ビニルエーテル系高分子化合
物、酸性アクリル系高分子化合物、アルカリ性アクリル
系高分子化合物、カチオン性セルロース誘導体、カチオ
ン性デンプン、ジアリル第４級アンモニウム／アクリル
アミド共重合体、４級化ポリビニルピロリドン、ポリグ
リコールポリアミン縮合物、カチオン化グアーガム、ア
ルギン酸誘導体、カラギーナン、アラビアゴム、トラガ
ントゴム、セルロース誘導体、ポリビニルアルコール誘
導体、ポリビニルアルキルエーテル誘導体、ポリエチレ
ンオキシド誘導体、カルボキシベタイン型誘導体等が挙
げられる。毛髪化粧料に一般的に用いられる添加物とし
ては多価アルコール、油脂類、炭化水素油、アルコール
類、シリコーン油、ワックス、ワックスエステル、植物
抽出エキス、酸化防止剤、防腐剤、ビタミン、金属イオ
ン封鎖剤、pH調整剤、酸化剤、還元剤、色素、香料等が
挙げられる。Specifically, as the anionic activator, linear /
Branched alkyl benzene sulfonate, EO / PO addition type alkyl / alkenyl ether sulfate, alkyl / alkenyl sulfate, olefin sulfonate, alkane sulfonate, saturated / unsaturated fatty acid salt, EO / PO addition type alkyl, alkenyl Ether carboxylate, α-sulfo fatty acid salt / ester, sulfosuccinic acid type activator, phosphate ester type activator, amino acid type activator, etc., as nonionic activators, EO / PO / BO addition type nonionic activator, Higher fatty acid alkanolamides / alkylene oxide adducts thereof, sugar-based nonionic activators, and the like, and examples of cationic activators include di-long-chain alkyl quaternary ammonium salts, mono-long-chain alkyl quaternary ammonium salts, and di-long-chain alkyls. Polyoxyethylene quaternary ammonium salt, mono long chain alkyl polyoxyethylene quaternary Quaternary ammonium salts, bis (hydroxyalkyl) quaternary ammonium salts, quaternary ammonium salts having an amide / ester bond and the like, as amphoteric activators, alkylamino oxides, betaine type (for example, carbobetaine, amidobetaine, sulfo) Betaine, hydroxysulfobetaine, amidosulfobetaine), imidazoline type, amidoamine type and the like. Examples of the polymer compound include a polyvinylpyrrolidone polymer compound, an acidic vinyl ether polymer compound, an acidic acrylic polymer compound, an alkaline acrylic polymer compound, a cationic cellulose derivative, a cationic starch, and diallyl quaternary ammonium. / Acrylamide copolymer, quaternized polyvinylpyrrolidone, polyglycolpolyamine condensate, cationized guar gum, alginic acid derivative, carrageenan, gum arabic, tragacanth gum, cellulose derivative, polyvinyl alcohol derivative, polyvinyl alkyl ether derivative, polyethylene oxide derivative, carboxybetaine Type derivatives and the like. Additives commonly used in hair cosmetics include polyhydric alcohols, oils and fats, hydrocarbon oils, alcohols, silicone oils, waxes, wax esters, plant extracts, antioxidants, preservatives, vitamins, metal ions Examples include a blocking agent, a pH adjusting agent, an oxidizing agent, a reducing agent, a coloring matter, and a fragrance.
【００１８】本発明毛髪化粧料は常法に従って製造する
ことができ、ヘアクリーム、ヘアフォーム、ヘアオイ
ル、ヘアジェル等毛髪に直接塗布し、すすがないタイプ
の剤型とする。The hair cosmetic composition of the present invention can be produced according to a conventional method, and is directly applied to the hair such as a hair cream, a hair foam, a hair oil, a hair gel, etc. to obtain a soot-free type.
【００１９】[0019]
【発明の効果】本発明の毛髪化粧料は髪に光沢、滑らか
さ、良好なくし通り性を与え、しかも紫外線による毛髪
の損傷を防止することができる。Industrial Applicability The hair cosmetic composition of the present invention gives gloss, smoothness, good combability to hair, and can prevent damage to the hair due to ultraviolet rays.
【００２０】[0020]
【実施例】次に、実施例を挙げて本発明を更に詳細に説
明するが、本発明はこれらに限定されるものではない。
実施例１下記表１に示す毛髪化粧料を調製し、各々を20
ｇの毛束に塗布し、毛髪の光沢、くし通り性、感触を下
記評価基準により評価した。結果を同表に示す。Next, the present invention will be described in more detail with reference to examples, but the present invention is not limited to these examples.
Example 1 Hair cosmetics shown in Table 1 below were prepared, and
g of hair tresses, and the gloss, combability, and feel of the hair were evaluated according to the following evaluation criteria. The results are shown in the same table.
【００２１】 評価基準： 光沢 光沢がある ○ やや光沢がある △ 光沢がない × くし通り性 くし通りが滑らかである ○ ややくし通りが滑らかである △ くし通りが悪い × 髪の感触 20ｇの毛束に各サンプルを塗布し、その後、日光照射
し、毛束の感触を下記基準で評価した。 滑らかでしっとりする ○ やや滑らかで、ややしっとりする △ 滑らかでなく、しっとりしない ×Evaluation criteria: Glossy Glossy ○ Slightly shiny △ No gloss × Comb passing Smooth comb passing ○ Smooth comb passing △ Bad comb passing × Feeling of hair 20g hair bundle Each sample was applied thereto, and then irradiated with sunlight, and the feel of the hair bundle was evaluated according to the following criteria. Smooth and moist ○ Slightly smooth and slightly moist △ Not smooth and moist ×
【００２２】[0022]
【表１】 [Table 1]
【００２３】実施例２ ヘアフォーム SM 8702C（東レシリコーン製） 0.5（％） ポリオキシエチレン（EO20）ステアリルエーテル （花王（株）製エマルゲン320P） 2 牛脂（C8,C16)ジアルキルジメチルアンモニウム （花王（株）製コータミンD86P） 0.5 バーチエキストラクト 1 パーソルMCX 1 メチルパラベン 0.1 エタノール 10 イオン交換水 74.9 液化石油ガス 7 ジメチルエーテル 3 得られたヘアフォームは滑らかさ、光沢、髪の感触に優
れる。Example 2 Hair foam SM 8702C (manufactured by Toray Silicone) 0.5% Polyoxyethylene (EO20) stearyl ether (Emulgen 320P manufactured by Kao Corporation) 2 Tallow (C 8 , C 16 ) dialkyldimethylammonium (Kao 0.5 Birch extract 1 Persol MCX 1 Methyl paraben 0.1 Ethanol 10 Ion-exchanged water 74.9 Liquefied petroleum gas 7 Dimethyl ether 3 The resulting hair foam is excellent in smoothness, gloss, and hair feel.
【００２４】実施例３ ヘアオイル DC 929（ダウ・コーニング（株）製） 5（％） ポリオキシエチレン硬化ヒマシ油（EO40） 5 エスカロール507 2 軽質流動イソパラフィン 60 エタノール 28 得られたヘアオイルは滑らかさ、光沢、髪の感触に優れ
る。Example 3 Hair oil DC 929 (manufactured by Dow Corning) 5% Polyoxyethylene hydrogenated castor oil (EO40) 5 Escalol 507 2 Light liquid isoparaffin 60 Ethanol 28 The resulting hair oil has a smoothness, Excellent gloss and hair feel.
【００２５】実施例４ ジェル SM 8702C（東レシリコーン製） 2（％） ユビナールD-50（BASF製） 3 ポリビニルピロリドン（GAF 製 PVP90） 10 エタノール 25 イオン交換水 60 得られたジェルは滑らかさ、光沢、髪の感触及びセット
力に優れる。Example 4 Gel SM 8702C (manufactured by Toray Silicone) 2% (%) Ubinal D-50 (manufactured by BASF) 3 Polyvinylpyrrolidone (PVP90 manufactured by GAF) 10 Ethanol 25 ion-exchanged water 60 The obtained gel is smooth and glossy Excellent hair feel and setting power.
Claims (1)
1 aA(3-a)) （１） 〔式中、Ａは水素原子、フェニル基、水酸基又は炭素数
１〜８のアルキル基を示し、ａは０〜３の整数を示し、
ｂは０又は１の整数を示し、ｍは０〜１９９９の整数を
示し、ｎは１〜２０００の整数を示すが、ｍ＋ｎは１〜
２０００の整数であり、Ｒ1 は基-CfH2fL（式中、ｆは
２〜８の整数であり、Ｌは基 【化１】 で表わされるアミノ変性シリコーン誘導体、及び （ｂ）紫外線吸収剤 を含有することを特徴とする、すすがないで使用するタ
イプの毛髪化粧料。(A) The following general formula (1): (R 1 a A (3-a) ) -Si- (OSi (A) 2 ) m- [OSi- (A b R 1 (2-b ) )] n -OSi (R
1 a A (3-a) ) (1) wherein A represents a hydrogen atom, a phenyl group, a hydroxyl group or an alkyl group having 1 to 8 carbon atoms, a represents an integer of 0 to 3,
b represents an integer of 0 or 1; m represents an integer of 0 to 1999; n represents an integer of 1 to 2000;
R 1 is a group —C f H 2f L (where f is an integer of 2 to 8, and L is a group represented by the following formula: A hair cosmetic of the type used without soot, comprising: an amino-modified silicone derivative represented by the formula: and (b) an ultraviolet absorber.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3109195A JP3062283B2 (en) | 1991-05-14 | 1991-05-14 | Hair cosmetics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3109195A JP3062283B2 (en) | 1991-05-14 | 1991-05-14 | Hair cosmetics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH04338317A JPH04338317A (en) | 1992-11-25 |
| JP3062283B2 true JP3062283B2 (en) | 2000-07-10 |
Family
ID=14504036
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3109195A Expired - Fee Related JP3062283B2 (en) | 1991-05-14 | 1991-05-14 | Hair cosmetics |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3062283B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3111923A1 (en) | 2015-07-02 | 2017-01-04 | Shin-Etsu Chemical Co., Ltd. | Organopolysiloxane and hair cosmetic and method for producing thereof |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2706766B1 (en) * | 1993-06-21 | 1995-08-18 | Oreal | FILTERING COSMETIC COMPOSITIONS CONTAINING A HYDROPHILIC AGENT CONTAINING AT LEAST ONE RADICAL ACID |
| AU4486397A (en) * | 1997-09-17 | 1999-04-05 | Procter & Gamble Company, The | Hair care compositions comprising optical brighteners and polymeric suspending agents |
| WO1999013830A1 (en) * | 1997-09-17 | 1999-03-25 | The Procter & Gamble Company | Shampoo composition comprising triazoles |
-
1991
- 1991-05-14 JP JP3109195A patent/JP3062283B2/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3111923A1 (en) | 2015-07-02 | 2017-01-04 | Shin-Etsu Chemical Co., Ltd. | Organopolysiloxane and hair cosmetic and method for producing thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH04338317A (en) | 1992-11-25 |
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