JP3057674B2 - How to prevent accidental eating of small articles - Google Patents
How to prevent accidental eating of small articlesInfo
- Publication number
- JP3057674B2 JP3057674B2 JP7039161A JP3916195A JP3057674B2 JP 3057674 B2 JP3057674 B2 JP 3057674B2 JP 7039161 A JP7039161 A JP 7039161A JP 3916195 A JP3916195 A JP 3916195A JP 3057674 B2 JP3057674 B2 JP 3057674B2
- Authority
- JP
- Japan
- Prior art keywords
- binder
- solvent
- emetic
- bitter
- toy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Toys (AREA)
- Medicinal Preparation (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Description
【０００１】[0001]
【産業上の利用分野】本発明は、幼児が小さな玩具など
の小型物品を口にした時、催吐感を感じさせて飲み込む
事故を未然に防止する誤食防止方法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for preventing accidental eating, which prevents an infant from feeling swallowed by feeling emetic when a small object such as a small toy is eaten.
【０００２】[0002]
【発明の背景】一般的に、誤飲、誤食による事故は幼児
に多く見られるが、事故をまとめたものとして図４の年
齢層別摂取経路（１９９３年４月〜１９９４年３月、
（財）日本中毒情報センター調べ）がある。この調査は
１９９３年度に、一般市民から上記情報センターが受信
した中毒に関するデータであるが、このデータによると
５才未満の幼児の経口による事故が圧倒的に多いことが
わかる。更に、同情報センターによれば起因物質別に年
齢層間の比較をすると、農薬、自然毒を除く家庭用品、
医薬品、工業用品などによる摂取事故が５才以下の乳幼
児で８０％〜９５％をしめているという報告もされてい
る。BACKGROUND OF THE INVENTION In general, accidents due to accidental ingestion and ingestion are often observed in infants, but the accidents are summarized as shown in FIG. 4 and taken by age group (April 1993 to March 1994,
According to the Japan Poisoning Information Center). This survey is data on poisoning received by the above-mentioned information center from the general public in 1993. According to this data, it is clear that oral accidents of infants under 5 years are predominant. Furthermore, according to the information center, a comparison between age groups by originating substance shows that household goods, excluding pesticides and natural poisons,
It has been reported that 80% to 95% of infants under 5 years of age have ingested accidents caused by drugs, industrial supplies and the like.
【０００３】従来から乳幼児の誤飲、誤食に関しては問
題が提起され、液体の場合には苦み催吐剤を液体に添加
することにより、口に含んだ時に苦みを感じて催吐感を
生じさせ、誤飲を防止する方法があるが、形状物（特に
幼児が扱う玩具）の場合は、誤食を防止する方法とし
て、なめても安全な塗料を使用するなど対策が取られて
いたが、飲み込むことを防止する積極的な対策が望まれ
ている。[0003] Conventionally, problems have been raised with regard to accidental ingestion and ingestion of infants. In the case of liquids, bitter emetics are added to the liquid, so that when they are contained in the mouth, they feel bitter and cause an emetic sensation. There is a method to prevent accidental ingestion, but in the case of shaped objects (especially toys handled by infants), measures have been taken to prevent accidental ingestion, such as using paint that is safe to lick. Active measures to prevent this are desired.
【０００４】[0004]
【発明の目的】本発明は、前記背景の下に成立したもの
であって、口に含んだ時に苦みを感じて催吐感を生じさ
せ、飲み込みを防止する小型物品における誤食防止方法
を提供することを目的とする。The object of the present invention is to provide a method for preventing accidental eating of small articles, which is established under the above background and which causes a feeling of bitterness when it is contained in the mouth to cause an emetic sensation and prevents swallowing. The purpose is to:
【０００５】[0005]
【課題を解決するための手段】前記目的を達成するた
め、本発明の小型物品における誤食防止方法は、溶剤中
に重量比３．６％のバインダと重量比０．４％の苦み催
吐剤とを溶かし込んだ薄い液状の機能性塗料を小型物品
の表面に付着させた後、上記溶剤を蒸発させて、上記苦
み催吐剤が上記バインダで接着された２〜３ミクロンの
半浸透状皮膜を上記小型物品の表面に形成したことを特
徴とする。To achieve the above object, according to an aspect of, accidental ingestion preventing method in a small article of the present invention, in a solvent
To 3.6% by weight binder and 0.4% by weight bitter
A thin liquid functional paint in which an emetic is dissolved is attached to the surface of a small article, and then the solvent is evaporated, and the bitter emetic is adhered by the binder to a 2-3 micron semi-permeable film. Is formed on the surface of the small article.
【０００６】[0006]
【発明の作用】前記構成によれば、苦み催吐剤とバイン
ダと溶剤とで機能性塗料を構成し、該機能性塗料を小型
物品に付着させ、その後乾燥させて溶剤を蒸発させる
と、上記小型物品の表面にバインダで苦み催吐剤が接着
された半浸透状皮膜が形成される。According to the above construction, a functional paint is constituted by a bitter emetic, a binder, and a solvent, and the functional paint is adhered to a small article, and then dried to evaporate the solvent. A semi-permeable film is formed on the surface of the article where the bitter emetic is adhered with a binder.
【０００７】[0007]
【実施例】本発明に係る小型物品の誤食防止方法におい
て、小型物品を小さな玩具として説明する。DESCRIPTION OF THE PREFERRED EMBODIMENTS In the method for preventing accidental eating of small articles according to the present invention, small articles will be described as small toys.
【０００８】この誤食防止方法は、苦み催吐剤とバイン
ダと溶剤とで機能性塗料を構成し、該機能性塗料で玩具
の表面に半浸透状皮膜を形成したもので、上記機能性塗
料は、玩具の素材に接着性のよいバインダを溶剤（有機
溶剤）でうすめて形成した溶液に、デナトニウムベンゾ
エイトからなる苦み催吐剤（例えばマクファーレン・ス
ミス社製のＢＩＴＲＥＸ（商標名）を使用すればよい）
を溶かしたものである。This method of preventing accidental eating includes a method in which a functional paint is composed of a bitter emetic, a binder, and a solvent, and a semi-permeable film is formed on the surface of the toy with the functional paint. When a bitter emetic made of denatonium benzoate (for example, BITREX (trade name) manufactured by McFarlane Smith Company) is used in a solution formed by diluting a binder having good adhesiveness to a toy material with a solvent (organic solvent), Good)
It is what melted.
【０００９】上記有機溶剤は炭化水素類の溶剤であれ
ば、例えばペンタン、へキサン、ヘプタン、石油エーテ
ル、石油ベンゼン、ケロシン、シクロヘキサン、トルエ
ン、キシレン、エチルベンゼン、クロロホルム、塩化メ
チル、塩化メチレン、四塩化炭素などを使用すればよ
い。If the organic solvent is a hydrocarbon solvent, for example, pentane, hexane, heptane, petroleum ether, petroleum benzene, kerosene, cyclohexane, toluene, xylene, ethylbenzene, chloroform, methyl chloride, methylene chloride, tetrachloride Carbon or the like may be used.
【００１０】アルコール類の溶剤であれば、例えばメタ
ノール、エタノール、プロパノール、ブタノール、アミ
ルアルコールなどを使用すればよく、エーテル類の溶剤
であれば、例えばエチルエーテル、ブチルエーテル、イ
ソアミルエーテルなどを使用すればよい。For alcohols, for example, methanol, ethanol, propanol, butanol, amyl alcohol, etc. may be used. For ethers, for example, ethyl ether, butyl ether, isoamyl ether, etc. may be used. Good.
【００１１】また、ケトン類の溶剤であれば、例えばア
セトン、メチルエチルケトン、メチルイソブチルケトン
などを使用し、エステル類の溶剤であれば、例えば酢酸
エチル、酢酸ブチルなどを使用すればよい。As a solvent for ketones, for example, acetone, methyl ethyl ketone, methyl isobutyl ketone, etc. may be used. For a solvent for esters, for example, ethyl acetate, butyl acetate, etc. may be used.
【００１２】上記バインダは、玩具の素材毎に接着性の
よいものを選択する。このバインダは、例えば素材がス
チロール、ＡＢＳ、ポリカーボネート、アクリル、硬質
塩化ビニールの場合にはアクリル樹脂系バインダ、軟質
塩化ビニールの場合には塩化ビニル樹脂系バインダ、ポ
リプロピレンの場合には塩素化ポリプロピレン樹脂系バ
インダを使用すればよい。As the binder, a binder having good adhesiveness is selected for each material of the toy. This binder is, for example, an acrylic resin binder when the material is styrene, ABS, polycarbonate, acrylic, hard vinyl chloride, a vinyl chloride resin binder when soft vinyl chloride, or a chlorinated polypropylene resin when polypropylene is used. A binder may be used.
【００１３】また、木の場合には繊維素系樹脂バイン
ダ、不飽和ポリエステル樹脂系バインダ、酸硬化アミノ
アルキッド樹脂系バインダ、ポリウレタン樹脂系バイン
ダ、ビニルブチラール樹脂バインダ、セラミック系バイ
ンダ、ニトロセルローズ系バインダを使用すればよい。In the case of wood, a cellulose resin binder, an unsaturated polyester resin binder, an acid-cured amino alkyd resin binder, a polyurethane resin binder, a vinyl butyral resin binder, a ceramic binder, and a nitrocellulose binder are used. Just use it.
【００１４】そして、金属又はガラスの場合には、エポ
キシ樹脂系バインダ、メラミン樹脂系バインダ、アミノ
アルキッド樹脂系バインダ、アクリル樹脂系バインダ、
シリコン樹脂系バインダ、フェノール樹脂系バインダ、
ウレタン樹脂系バインダ、アルキッド樹脂系バインダを
使用すればよい。In the case of metal or glass, an epoxy resin binder, a melamine resin binder, an amino alkyd resin binder, an acrylic resin binder,
Silicone resin binder, phenolic resin binder,
A urethane resin binder and an alkyd resin binder may be used.
【００１５】なお、上記バインダは素材によって複数の
バインダを混ぜ合わせて使用してもかまわない。The binder may be a mixture of a plurality of binders depending on the material.
【００１６】図１に示すように、上述の機能性塗料は、
容器１の中に入れた溶剤２に重量比３．６％の上記バイ
ンダ３と、重量比０．４％の上記苦み催吐剤４とを溶か
し込んだ、固形分（不揮発分）が２〜４％の薄い液状の
機能性塗料で、この液状の機能性塗料に玩具５を浸漬し
た後、溶剤２を蒸発させ乾燥するディップコーティング
により、上記玩具５の表面に１〜８ミクロンの半浸透状
皮膜６を形成することができる。As shown in FIG. 1, the above functional paint is
The binder 3 having a weight ratio of 3.6% and the bitter emetic 4 having a weight ratio of 0.4% are dissolved in a solvent 2 placed in a container 1, and the solid content (non-volatile content) is 2 to 4. % Of the toy 5 is immersed in the liquid functional paint with a thin liquid functional paint, and then the solvent 2 is evaporated and dried. 6 can be formed.
【００１７】なお、上記玩具５に上記機能性塗料を付着
する方法としては、機能性塗料に玩具を浸漬する以外
に、スプレー等による吹き付け、筆等による塗布でも構
わない。As a method for attaching the functional paint to the toy 5, the toy may be immersed in the functional paint, or may be sprayed or the like or applied with a brush.
【００１８】また、玩具５が平板な形状のものであれ
ば、図２に示すように、機能性塗料のついたローラー
７、７の間を通して、玩具５に機能性塗料を塗布し、半
浸透状皮膜６を形成するロールコーティングタイプによ
っても構わない。If the toy 5 has a flat shape, as shown in FIG. 2, the functional paint is applied to the toy 5 by passing it between the rollers 7 having the functional paint, and semi-penetrated. A roll coating type for forming the film 6 may be used.
【００１９】そして、上記溶剤２を蒸発させ乾燥して、
半浸透状皮膜６を形成するためには、基本的には常温乾
燥を行うが、乾燥を促進するために素材がプラスチック
系であれば、摂氏６０〜７０度で１０分〜３０分で乾燥
させることが考えられ、金属の場合には焼き付け塗布の
ために摂氏１５０度以下（ＢＩＴＲＥＸの融点が摂氏１
６０度以上のため）で乾燥することもある。Then, the solvent 2 is evaporated and dried.
In order to form the semi-permeable membrane 6, drying at room temperature is basically performed. However, if the material is a plastic material, the drying is performed at 60 to 70 degrees Celsius for 10 to 30 minutes to promote the drying. It is considered that in the case of metal, 150 ° C. or less (BITTREX has a melting point of 1 ° C.)
(60 degrees or more).
【００２０】なお、上記半浸透状皮膜６は、望ましくは
２〜３ミクロンに形成することが好ましい。これは、対
象の物品が玩具であるため、素材の色合いに影響を与え
る、不自然な光の反射が生じて玩具が光ってしまう、催
吐剤がバインダのなかに沈殿するようになり表面にバイ
ンダだけが現れ苦みを感じなくなる、素材の表面に細か
い彫りなどの細工がある場合不必要な丸みが出て表面が
滑らかになる等の点、及び小型の玩具の表面積は３０〜
４０平方センチメートル程度と考えられるが、万が一飲
み込んだ場合にも安全性が確保できる等の上記諸条件を
満足させながら催吐効果を発揮するため、適切な数値を
繰り返しテストにより求めた結果、上記数値に到達した
ものである。The semi-permeable membrane 6 is preferably formed to have a thickness of 2 to 3 microns. This is because the target article is a toy, which affects the color of the material, causes unnatural reflection of light, causing the toy to shine, and causes the emetic to precipitate in the binder, causing the binder to adhere to the surface. Only the appearance of the material makes it difficult to feel the bitterness. If the surface of the material is finely carved, unnecessary roundness appears and the surface becomes smooth.
Although it is considered to be about 40 square centimeters, the appropriate numerical value was repeatedly obtained by testing to achieve the emetic effect while satisfying the above conditions such as ensuring safety even if swallowed, and reaching the above value as a result It was done.
【００２１】上述のように半浸透状皮膜６は形成されて
いるので、図３の半浸透状皮膜の拡大図に示すように、
玩具５の素材表面５ａに上記半浸透状皮膜６を形成した
場合は、苦み催吐剤４同士がバインダ３で連結され、且
つ玩具５の素材表面５ａにバインダ３で付着しているの
で、苦み催吐剤４が素材の表面５ａから離脱し、手指に
付着することがなく、玩具５で遊んだ後に手指をなめる
ようなことがあっても苦みを感じることがなく、通常使
用時には苦みによるトラブルが発生することはない。Since the semi-permeable film 6 is formed as described above, as shown in the enlarged view of the semi-permeable film in FIG.
When the semi-permeable film 6 is formed on the material surface 5a of the toy 5, the bitter emetic agent 4 is connected to the material surface 5a of the toy 5 by the binder 3, and the bitter emetic agent 4 is attached. The agent 4 separates from the surface 5a of the material and does not adhere to the fingers. Even if the fingers are licked after playing with the toy 5, there is no feeling of bitterness. I will not do it.
【００２２】そして、催吐剤４、４をバインダで連結す
ると、図３のように催吐剤４、４間にはだ液の浸透空間
が形成されるので、このような半浸透状皮膜６を形成し
た玩具５を口に含んだ場合は、だ液は下層側の苦み催吐
剤４にも達して口内に溶け出し、強い苦みを感じさせる
ので催吐効果を発揮することができる。Then, the emetics 4, 4 are connected with a binder.
Then, as shown in FIG. 3, the permeation space between the emetics 4, 4
Is formed, such a semi-permeable film 6 is formed.
If the toy 5 is contained in the mouth, the saliva will be bitter
It reaches the agent 4 and dissolves in the mouth, giving a strong bitterness, so that an emetic effect can be exhibited.
【００２３】[0023]
【効果】本発明によれば溶剤中に重量比３．６％のバイ
ンダと重量比０．４％の苦み催吐剤とを溶かし込んだ薄
い液状の機能性塗料を小型物品の表面に付着させた後、
上記溶剤を蒸発させて皮膜として形成したもので、この
ように催吐剤をバインダで連結すると、催吐剤の粒子間
にはだ液の浸透空間が形成されるので、このような半浸
透状皮膜を形成した玩具を口に含んだ場合は、だ液は下
層側の苦み催吐剤にも達して強い苦みを感じて催吐感を
生じさせ、有効に誤食を防止することができる。また、
玩具等の小型物品を持った時に手指に催吐剤が付着する
不要な移染を抑え、誤食以外での苦みトラブルを最小限
に抑えることができる。そして、皮膜を２〜３ミクロン
にしたので、苦み催吐剤がバインダの中に神殿して物品
の表面にバインダだけが現れて苦みを感じなくなること
を回避することができるとともに、皮膜によって素材の
持つ色合いに影響を与えたり、不自然な光の反射を生じ
たり、素材の表面に不必要な丸みが出て滑らかになる等
の物品の外観的な特徴を損なうことがなくなる。しか
も、万一呑むようなことがあっても子どもが呑込める程
度の表面積の物品であれば安全も確保される。According to the present invention, 3.6% by weight of a solvent is contained in a solvent.
And 0.4% by weight of bitter emetic
After attaching a liquid functional paint to the surface of a small article,
The solvent was evaporated to form a film.
When the emetic is connected with the binder as in
A semi-soaked space is formed in the
If the mouth contains a toy with a permeable membrane, the saliva
It reaches the layer side bitter emetic and feels strong bitterness and makes you feel emetic
This can effectively prevent accidental eating. Also,
Emetic agent adheres to fingers when holding small articles such as toys
Suppresses unnecessary transfer and minimizes bitter troubles other than accidental ingestion
Can be suppressed. And, since the film is made to have a thickness of 2 to 3 microns, it is possible to avoid that the bitter emetic is shrine in the binder and only the binder appears on the surface of the article and does not feel bitter. or affect the hue, caused a reflection of unnatural light
In addition, the appearance characteristics of the article, such as unnecessary roundness on the surface of the material and smoothness, are not impaired. In addition, even if something should be swallowed, safety is ensured if the article has a surface area enough to be swallowed by children.
【図１】本発明の小型物品の表面に半浸透状皮膜を形成
する方法の一例を示す説明図FIG. 1 is an explanatory view showing an example of a method for forming a semi-permeable film on the surface of a small article of the present invention.
【図２】上記半浸透状皮膜を形成する方法の他の例を示
す説明図FIG. 2 is an explanatory view showing another example of the method for forming the semi-permeable membrane.
【図３】半浸透状皮膜の要部拡大図FIG. 3 is an enlarged view of a main part of a semi-permeable membrane.
【図４】一般市民における年齢層別摂取経路集計データFig. 4 Ingestion route total data by age group for general citizens
２ 溶剤 ３ バインダ ４ 苦み催吐剤 ５ 小型物品 ６ 半浸透状皮膜 2 solvent 3 binder 4 bitter emetic 5 small articles 6 semi-permeable film
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 ＦＩ Ｂ０５Ｄ 7/24 ３０１ Ｂ０５Ｄ 7/24 ３０１Ｚ (56)参考文献 特開 平４−312762（ＪＰ，Ａ) 特開 平２−127496（ＪＰ，Ａ) 特開 昭59−29353（ＪＰ，Ａ) 特開 昭59−211955（ＪＰ，Ａ) (58)調査した分野(Int.Cl.7，ＤＢ名) A63H 33/00 A61K 47/48 A63H 9/00 B05D 5/00,7/00 H01M 2/02 ──────────────────────────────────────────────────の Continuation of front page (51) Int.Cl. 7 identification code FI B05D 7/24 301 B05D 7/24 301Z (56) References JP-A-4-312762 (JP, A) JP-A-2-127496 (JP, A) JP-A-59-29353 (JP, A) JP-A-59-211955 (JP, A) (58) Fields investigated (Int. Cl. 7 , DB name) A63H 33/00 A61K 47 / 48 A63H 9/00 B05D 5 / 00,7 / 00 H01M 2/02
Claims (1)
量比０．４％の苦み催吐剤とを溶かし込んだ薄い液状の
機能性塗料を小型物品の表面に付着させた後、上記溶剤
を蒸発させて、上記苦み催吐剤が上記バインダで接着さ
れた２〜３ミクロンの半浸透状皮膜を上記小型物品の表
面に形成したことを特徴とする小型物品における誤食防
止方法。(1) 3.6% by weight of a binder and a solvent in a solvent.
0.4% bitter bitter emetic and dissolved in a thin liquid
After the functional paint was applied to the surface of the small article, the solvent was evaporated to form a 2-3 micron semi-permeable film on the surface of the small article to which the bitter emetic was adhered with the binder. A method for preventing accidental eating of small articles.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7039161A JP3057674B2 (en) | 1995-02-03 | 1995-02-03 | How to prevent accidental eating of small articles |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7039161A JP3057674B2 (en) | 1995-02-03 | 1995-02-03 | How to prevent accidental eating of small articles |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH08206368A JPH08206368A (en) | 1996-08-13 |
| JP3057674B2 true JP3057674B2 (en) | 2000-07-04 |
Family
ID=12545404
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7039161A Expired - Fee Related JP3057674B2 (en) | 1995-02-03 | 1995-02-03 | How to prevent accidental eating of small articles |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3057674B2 (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005108559A (en) * | 2003-09-29 | 2005-04-21 | Casio Comput Co Ltd | Fuel container |
| JP2011010725A (en) * | 2009-06-30 | 2011-01-20 | Nippon Koden Corp | Electrode for living body |
| EP2619826B1 (en) | 2010-09-21 | 2018-01-03 | Victoria Link Limited | Safety material and system |
| JP2014141258A (en) * | 2011-05-10 | 2014-08-07 | Nihon Yamamura Glass Co Ltd | Ptp packaging container |
| KR101205212B1 (en) * | 2011-10-31 | 2012-11-27 | 진명기 | Stationary having taste and manufacturing method thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04312762A (en) * | 1991-04-11 | 1992-11-04 | Nitto Denko Corp | Button cell |
-
1995
- 1995-02-03 JP JP7039161A patent/JP3057674B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH08206368A (en) | 1996-08-13 |
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