JP3045615B2 - Foamy hair cosmetics - Google Patents

Foamy hair cosmetics

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Publication number
JP3045615B2
JP3045615B2 JP4207252A JP20725292A JP3045615B2 JP 3045615 B2 JP3045615 B2 JP 3045615B2 JP 4207252 A JP4207252 A JP 4207252A JP 20725292 A JP20725292 A JP 20725292A JP 3045615 B2 JP3045615 B2 JP 3045615B2
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JP
Japan
Prior art keywords
weight
smoothness
present
hair
formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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JP4207252A
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Japanese (ja)
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JPH0624944A (en
Inventor
龍雄 大島
Original Assignee
鐘紡株式会社
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  • Compositions Of Macromolecular Compounds (AREA)

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本発明は、泡沫状頭髪化粧料に関
し、更に詳しくは、毛髪に対し、艶,なめらかさ及び仕
上がりのさらさら感を大幅に改善するとともに泡安定性
に優れた泡沫状頭髪化粧料に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a foamed hair cosmetic, and more particularly, to a foamed hair having a significantly improved luster, smoothness and smoothness of the finish, and excellent foam stability. Related to cosmetics.

【0002】[0002]

【従来の技術及び発明が解決しようとする課題】近年、
頭髪用化粧料としては、塗布時の液だれがなく、均一に
塗布できしかも使用量の目測が容易であり使用者の好み
に応じ適量を使用することが可能であるとともに使用簡
便性を有するエアゾール式の泡沫状頭髪化粧料が一般化
されている。このような泡沫状頭髪化粧料には、毛髪に
艶,なめらかさを与える目的で炭化水素油,エステル
油,多価アルコール,シリコーン油等が用いられてい
る。
2. Description of the Related Art In recent years,
An aerosol that is easy to use as hair cosmetics can be applied uniformly without dripping at the time of application, easy to measure the amount of use, and easy to use according to the user's preference. Foam hair cosmetics of the formula have been generalized. In such foamy hair cosmetics, hydrocarbon oils, ester oils, polyhydric alcohols, silicone oils and the like are used for the purpose of giving gloss and smoothness to hair.

【0003】しかし、これらの油分等も限界があり、消
費者が連用する過程で毛髪が重くなり、脂ぎる欠点があ
った。
[0003] However, these oils and the like also have a limit, and the hair becomes heavy and greasy during the continuous use by consumers.

【0004】一方、なめらかさを付与する目的でカチオ
ン界面活性剤である第4級アンモニウム塩を有効成分と
するものも使用されているが、満足する結果は得られて
いない。
On the other hand, those containing a quaternary ammonium salt as a cationic surfactant as an active ingredient have been used for the purpose of imparting smoothness, but satisfactory results have not been obtained.

【0005】即ち、本発明は毛髪へ艶,なめらかさ及び
仕上がりのさらさら感を大幅に改善するとともに泡安定
性に優れた泡沫状頭髪化粧料を提供することを目的とし
ている。
[0005] That is, an object of the present invention is to provide a foamy hair cosmetic composition which has significantly improved luster, smoothness, and smoothness of the finish on hair and has excellent foam stability.

【0006】[0006]

【課題を解決するための手段】上記の目的を達成するた
めに、本発明の泡沫状頭髪化粧料は、次のような構成を
とっている。即ち、(A)一般式(I)
Means for Solving the Problems In order to achieve the above object, a foamy hair cosmetic composition of the present invention has the following constitution. That is, (A) general formula (I)

【化3】 (式中、R1 は総てがメチル基またはその一部がフェニ
ル基(ただし、R1 の総数の90%以上はメチル基)、
2 はメチル基または水酸基を示す。またmは1300
〜2200の整数を示す。)で表されるシリコーンの一
種または二種以上0.3〜3重量%と (B)一般式(II)
Embedded image (In the formula, all R 1 are methyl groups or a part thereof is a phenyl group (however, 90% or more of the total number of R 1 is a methyl group),
R 2 represents a methyl group or a hydroxyl group. M is 1300
整数 2200. (B) a general formula (II)

【化4】 (式中、R1 は総てがメチル基またはその一部がフェニ
ル基(ただし、R1 の総数の90%以上はメチル基)、
2 はメチル基または水酸基を示す。またnは100〜
300の整数を示す。)で表されるシリコーンの一種ま
たは二種以上1〜7重量%と (C)非イオン界面活性剤0.5〜5重量%と (D)水(残部)と (E)噴射剤2〜12重量%とを含有することを特徴と
する泡沫状頭髪化粧料である。
Embedded image (In the formula, all R 1 are methyl groups or a part thereof is a phenyl group (however, 90% or more of the total number of R 1 is a methyl group),
R 2 represents a methyl group or a hydroxyl group. Also, n is 100 to
Indicates an integer of 300. 1 to 7% by weight of one or more silicones represented by the formula (C), 0.5 to 5% by weight of a nonionic surfactant (C), water (remainder), and (E) a propellant 2 to 12 % By weight.

【0007】本発明における前記一般式(I)で表され
るシリコーンとしては、例えばジメチルポリシロキサ
ン,メチルフェニルポリシロキサン,末端水酸基含有ジ
メチルポリシロキサン,末端水酸基含有メチルフェニル
ポリシロキサンなどが挙げられる。
Examples of the silicone represented by the general formula (I) in the present invention include dimethylpolysiloxane, methylphenylpolysiloxane, dimethylpolysiloxane having a terminal hydroxyl group, and methylphenylpolysiloxane having a terminal hydroxyl group.

【0008】本発明の泡沫状頭髪化粧料には、これらの
シリコーンの一種または二種以上の混合物を総量を基準
として0.3〜3重量%(以下wt%と略記する)好ま
しくは、0.5〜2wt%配合される。配合量が0.3
wt%未満では、乾燥後のなめらかさ,さらさら感に良
好な結果が得られず、3wt%を超えると毛髪のなめら
かさが劣り好ましくない。
In the foamy hair cosmetic composition of the present invention, one or more of these silicones are mixed in an amount of 0.3 to 3% by weight (hereinafter abbreviated as wt%), preferably 0.1 to 3% by weight, based on the total amount. 5-2 wt% is blended. 0.3
If it is less than wt%, good results in smoothness and smoothness after drying cannot be obtained, and if it exceeds 3 wt%, the smoothness of the hair is inferior and is not preferable.

【0009】一方、本発明で使用するシリコーンの平均
重合度mは1300〜2200であり、好ましくは14
00〜2000である。平均重合度が1300に満たな
いものは効果がなく、平均重合度が2200を超えると
毛髪のなめらかさが劣り好ましくない。
On the other hand, the average degree of polymerization m of the silicone used in the present invention is from 1300 to 2200, preferably from 14 to 2200.
00 to 2000. Those having an average degree of polymerization of less than 1300 have no effect, and those having an average degree of polymerization of more than 2200 are not preferred because the smoothness of hair is poor.

【0010】本発明における前記一般式(II) で表され
るシリコーンとしては、例えばジメチルポリシロキサ
ン,メチルフェニルポリシロキサン,末端水酸基含有ジ
メチルポリシロキサン,末端水酸基含有メチルフェニル
ポリシロキサンなどが挙げられる。
The silicone represented by the general formula (II) in the present invention includes, for example, dimethylpolysiloxane, methylphenylpolysiloxane, dimethylpolysiloxane having a terminal hydroxyl group, and methylphenylpolysiloxane having a terminal hydroxyl group.

【0011】本発明の泡沫状頭髪化粧料には、これらの
シリコーンの一種または二種以上の混合物を総量を基準
として1〜7wt%好ましくは、2〜5wt%配合され
る。配合量が1wt%未満では、乾燥後のなめらかさ,
艶に良好な結果が得られず7wt%を超えると毛髪にべ
たつきが生じ好ましくない。
The foamy hair cosmetic composition of the present invention contains 1 to 7% by weight, preferably 2 to 5% by weight, based on the total amount, of one or a mixture of two or more of these silicones. If the compounding amount is less than 1 wt%, smoothness after drying,
Good results in gloss cannot be obtained, and if it exceeds 7% by weight, the hair becomes sticky, which is not preferable.

【0012】一方、本発明で使用するシリコーンの平均
重合度nは100〜300であり、好ましくは150〜
250である。平均重合度が100に満たないものは効
果がなく、平均重合度が300を超えるとなめらかさが
劣り好ましくない。これらの(A),(B)2成分の配
合重量比は1:2〜1:6が好ましい。
On the other hand, the average degree of polymerization n of the silicone used in the present invention is from 100 to 300, preferably from 150 to 300.
250. Those having an average degree of polymerization of less than 100 have no effect, and those having an average degree of polymerization of more than 300 are unfavorable due to poor smoothness. The weight ratio of these two components (A) and (B) is preferably from 1: 2 to 1: 6.

【0013】本発明の(C)成分である非イオン界面活
性剤としては、ポリオキシエチレン(20E.O.)セチル
エーテル,ポリオキシエチレン(20E.O.)ステアリル
エーテル等のポリオキシエチレンアルキルエーテル,モ
ノラウリン酸ポリオキシエチレン(20E.O.)ソルビタ
ン,モノオレイン酸ポリオキシエチレン(20E.O.)ソ
ルビタン,トリステアリン酸ポリオキシエチレン(20
E.O.)ソルビタン等のポリオキシエチレンソルビタン脂
肪酸エステル,モノステアリン酸ポリエチレングリコー
ル(20E.O.),モノオレイン酸ポリエチレングリコー
ル(20E.O.)等のポリエチレングリコール(10E.O.
〜50E.O.)脂肪酸エステル,ポリオキシエチレン(4
0E.O.〜100E.O.)硬化ヒマシ油誘導体等の非イオン
界面活性剤が挙げられ特に好ましくは、ポリオキシエチ
レン(80E.O.)硬化ヒマシ油が用いられる。
The nonionic surfactant which is the component (C) of the present invention includes polyoxyethylene alkyl ethers such as polyoxyethylene (20E.O.) cetyl ether and polyoxyethylene (20E.O.) stearyl ether. , Polyoxyethylene monolaurate (20E.O.) sorbitan, polyoxyethylene monooleate (20E.O.) sorbitan, polyoxyethylene tristearate (20E.O.)
EO) Polyoxyethylene sorbitan fatty acid esters such as sorbitan, polyethylene glycol monostearate (20E.O.) and polyethylene glycol (10E.O.) such as polyethylene glycol monooleate (20E.O.).
-50 E.O.) fatty acid ester, polyoxyethylene (4
Non-ionic surfactants such as a hardened castor oil derivative and the like are particularly preferable. Polyoxyethylene (80EO) hardened castor oil is particularly preferably used.

【0014】本発明の泡沫状頭髪化粧料には、これらの
非イオン界面活性剤の一種または二種以上の混合物を総
量を基準として0.5〜5wt%好ましくは、0.5〜
3wt%配合される。
The foamy hair cosmetic composition of the present invention contains 0.5 to 5% by weight, preferably 0.5 to 5% by weight, based on the total amount of one or a mixture of two or more of these nonionic surfactants.
3 wt% is blended.

【0015】本発明の(E)成分である噴射剤として
は、通常エアゾール製品に用いられるものが使用され
る。例えば、噴射剤としてはプロパン,イソブタン,ノ
ルマルブタンおよびその混合物である2.0〜6.0k
g/cm2 (at25℃)の液化石油ガス(以下LPG
と略す),ジメチルエーテルなどが挙げられる。
As the propellant which is the component (E) of the present invention, those usually used in aerosol products are used. For example, the propellant is propane, isobutane, normal butane and a mixture thereof, 2.0 to 6.0 k.
g / cm 2 (at 25 ° C.) liquefied petroleum gas (hereinafter LPG)
Dimethyl ether).

【0016】本発明の泡沫状頭髪化粧料には、これらの
噴射剤の一種または二種以上の混合物を総量を基準とし
て2〜12wt%特に好ましくは4〜8wt%であり、
噴射剤の種類により適宜選択される。
The foamy hair cosmetic composition of the present invention contains 2 to 12% by weight, particularly preferably 4 to 8% by weight, based on the total amount of one or a mixture of two or more of these propellants.
It is appropriately selected according to the type of the propellant.

【0017】本発明の泡沫状頭髪化粧料には、上述した
成分を必須の構成成分とするが、当該組成物には、本発
明の目的を達成する範囲で他の成分を適宜配合すること
ができる。即ち、ワセリン,スクワラン,低沸点イソパ
ラフィン,流動パラフィン等の炭化水素,イソプロピル
ミリステート,イソプロピルパルミテート等のエステル
油,ツバキ油,オリーブ油,アボカド油等の植物油,低
沸点シリコーン,環状シリコーン等のシリコーン油,メ
チルセルロース,ヒドロキシエチルセルロース,カチオ
ン化セルロース等のセルロース誘導体,プロピレングリ
コール,グリセリン,ポリグリセリン等の保湿剤,ポリ
ペプチド,その他殺菌剤,着色剤,香料などが挙げられ
これらの一種または二種以上を配合することができる。
The above-mentioned components are essential components in the foamy hair cosmetic of the present invention, and other components may be appropriately added to the composition within a range that achieves the object of the present invention. it can. Hydrocarbons such as petrolatum, squalane, low-boiling isoparaffin, and liquid paraffin; ester oils such as isopropyl myristate and isopropyl palmitate; vegetable oils such as camellia oil, olive oil and avocado oil; silicone oils such as low-boiling silicone and cyclic silicone , Cellulose derivatives such as methylcellulose, hydroxyethylcellulose, and cationized cellulose, humectants such as propylene glycol, glycerin, and polyglycerin, polypeptides, other fungicides, coloring agents, flavors, and the like. One or more of these are blended. can do.

【0018】[0018]

【実施例】次に実施例を挙げ本発明を説明するが、本発
明はこれらの実施例に限定されるものではない。なお、
本実施例中で用いた試験方法は、下記の通りである。
Next, the present invention will be described with reference to examples, but the present invention is not limited to these examples. In addition,
The test method used in this example is as follows.

【0019】(1)毛髪の艶,なめらかさ及び仕上がり
のさらさら感試験 各例における、毛髪の「艶」,「なめらかさ」,及び仕
上がりの「さらさら感」を女性20名の専門パネラーに
て連用後、官能的に比較し、下記基準で評価を行った。 ◎;良いと答えた人が18人以上の場合 ○; 〃 が14〜17人の場合 △; 〃 が8〜13人の場合 ×; 〃 が7人以下の場合
(1) Hair gloss, smoothness and smoothness test of finish In each case, the gloss, smoothness and smoothness of the finish of hair were continuously used by 20 female panelists. Thereafter, they were sensually compared and evaluated according to the following criteria. ◎; 18 or more answered good ○; 〃 14 to 17 △; 8 8 to 13 ×; 〃 7 or less

【0020】(2)泡の安定性試験 噴射剤と共に密封容器に充填された試料原料を500ml
メスシリンダー中に噴射して一定量の泡を採取し静置す
る。噴射直後の泡高さと静置5分後の泡高さから泡高さ
の変化率を求め、次の基準で泡の安定性を評価した。 A;変化率 1%未満 極めて安定な泡 B; 〃 1〜5% 安定な泡 C; 〃 5〜10% やや安定な泡 D; 〃 10%以上 非常に不安定な泡
(2) Foam stability test 500 ml of a sample material filled in a sealed container together with a propellant
Inject into a measuring cylinder to collect a certain amount of foam and let it stand still. The rate of change of the foam height was determined from the foam height immediately after the injection and the foam height after standing for 5 minutes, and the stability of the foam was evaluated according to the following criteria. A: rate of change less than 1% extremely stable foam B; 1〜 1 to 5% stable foam C; 5〜 5 to 10% slightly stable foam D; 10 10% or more very unstable foam

【0021】実施例1〜3,比較例1〜2 表1の上段に示す配合組成の泡沫状頭髪化粧料を通常の
方法(原液組成を均一に溶解,混合した後、所定のエア
ゾール容器(缶,バルブ,ボタン)に入れ、真空ポンプ
にて上部の空気を脱気しながら所定のバルブを取り付
け、噴射剤を圧入充填する。)で調製し、上記試験を行
い表1の下段にその結果を示した。
Examples 1 to 3 and Comparative Examples 1 to 2 A foamy hair cosmetic composition having the composition shown in the upper part of Table 1 was prepared by a conventional method (a uniform solution composition was uniformly dissolved and mixed, and then a predetermined aerosol container (can) , Valve, button), attach a predetermined valve while degassing the upper air with a vacuum pump, and press-fit and fill the propellant.) The above test is performed, and the results are shown in the lower row of Table 1. Indicated.

【0022】[0022]

【表1】 [Table 1]

【0023】実施例4〜6,比較例3〜8 表2の上段に示す配合組成の泡沫状頭髪化粧料を通常の
方法(前記実施例と同様)で調製し、上記試験を行い表
2の下段にその結果を示した。
Examples 4 to 6, Comparative Examples 3 to 8 Foamed hair cosmetics having the composition shown in the upper part of Table 2 were prepared by a usual method (similar to the above example), and the above test was carried out. The lower row shows the results.

【0024】[0024]

【表2】 [Table 2]

【0025】実施例1〜6より明らかなように、本発明
の泡沫状頭髪化粧料は、いずれも優れた性能を示した。
一方、必須成分である、シリコーンのどちらかを欠いた
場合(比較例1〜2)、またはこれらの配合量およびシ
リコーンの平均重合度(m,n)が本発明の範囲外の場
合(比較例3〜8)は、いずれも劣った性能を示し本発
明の目的を達成できなかった。
As is clear from Examples 1 to 6, all of the foamy hair cosmetics of the present invention exhibited excellent performance.
On the other hand, when either of the essential components, silicone, is missing (Comparative Examples 1 and 2), or when the blending amount thereof and the average polymerization degree (m, n) of the silicone are out of the range of the present invention (Comparative Example) All of 3 to 8) showed inferior performance and could not achieve the object of the present invention.

【0026】[0026]

【発明の効果】以上記載のごとく、本発明は毛髪に対
し、艶,なめらかさ及び仕上がりのさらさら感を大幅に
改善するとともに泡安定性に優れた泡沫状頭髪化粧料を
提供することは明らかである。
As described above, it is apparent that the present invention provides a foamy hair cosmetic composition which significantly improves gloss, smoothness, and smoothness of the finish on hair and has excellent foam stability. is there.

Claims (1)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 (A)一般式(I) 【化1】 (式中、R1 は総てがメチル基またはその一部がフェニ
ル基(ただし、R1 の総数の90%以上はメチル基)、
2 はメチル基または水酸基を示す。またmは1300
〜2200の整数を示す。)で表されるシリコーンの一
種または二種以上0.3〜3重量%と (B)一般式(II) 【化2】 (式中、R1 は総てがメチル基またはその一部がフェニ
ル基(ただし、R1 の総数の90%以上はメチル基)、
2 はメチル基または水酸基を示す。またnは100〜
300の整数を示す。)で表されるシリコーンの一種ま
たは二種以上1〜7重量%と (C)非イオン界面活性剤0.5〜5重量%と (D)水(残部)と (E)噴射剤2〜12重量%とを含有することを特徴と
する泡沫状頭髪化粧料。
(A) General formula (I) (In the formula, all R 1 are methyl groups or a part thereof is a phenyl group (however, 90% or more of the total number of R 1 is a methyl group),
R 2 represents a methyl group or a hydroxyl group. M is 1300
整数 2200. (B) one or more silicones represented by the formula (B): 0.3 to 3% by weight; (In the formula, all R 1 are methyl groups or a part thereof is a phenyl group (however, 90% or more of the total number of R 1 is a methyl group),
R 2 represents a methyl group or a hydroxyl group. Also, n is 100 to
Indicates an integer of 300. 1 to 7% by weight of one or more silicones represented by the formula (C), 0.5 to 5% by weight of a nonionic surfactant (C), water (remainder), and (E) a propellant 2 to 12 % By weight.
JP4207252A 1992-07-10 1992-07-10 Foamy hair cosmetics Expired - Lifetime JP3045615B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP4207252A JP3045615B2 (en) 1992-07-10 1992-07-10 Foamy hair cosmetics

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP4207252A JP3045615B2 (en) 1992-07-10 1992-07-10 Foamy hair cosmetics

Publications (2)

Publication Number Publication Date
JPH0624944A JPH0624944A (en) 1994-02-01
JP3045615B2 true JP3045615B2 (en) 2000-05-29

Family

ID=16536732

Family Applications (1)

Application Number Title Priority Date Filing Date
JP4207252A Expired - Lifetime JP3045615B2 (en) 1992-07-10 1992-07-10 Foamy hair cosmetics

Country Status (1)

Country Link
JP (1) JP3045615B2 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0736828A3 (en) * 1995-04-06 1997-11-12 Seiko Epson Corporation Battery driven electronic apparatus and method of controlling power supply in the apparatus
JP5164318B2 (en) * 2005-08-31 2013-03-21 株式会社アリミノ Hairdressing composition

Also Published As

Publication number Publication date
JPH0624944A (en) 1994-02-01

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