JP3023688B2 - Cosmetics - Google Patents
CosmeticsInfo
- Publication number
- JP3023688B2 JP3023688B2 JP2099844A JP9984490A JP3023688B2 JP 3023688 B2 JP3023688 B2 JP 3023688B2 JP 2099844 A JP2099844 A JP 2099844A JP 9984490 A JP9984490 A JP 9984490A JP 3023688 B2 JP3023688 B2 JP 3023688B2
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- Prior art keywords
- cosmetics
- cosmetic
- present
- foamed resin
- solid
- Prior art date
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Description
【発明の詳細な説明】 ［産業上の利用分野］ 本発明は、中空発泡樹脂球体を含有せしめることによ
り、優れた使用感と使用性を付与せしめた化粧料に関す
る。[Detailed description of the invention] [Industrial application field] The present invention relates to a cosmetic which is imparted with excellent feeling and usability by containing a hollow foamed resin sphere.
［従来の技術及びその課題］ 従来、化粧料用粉体としては種々のものが知られてお
り、化粧料に配合して利用されている。特にメーキャッ
プ化粧料には、白色顔料、着色顔料、体質顔料等をはじ
めとする種々の無機粉体、有機粉体等が、メーキャップ
効果、使用感、使用性等を考慮して配合されている。[Prior art and its problems] Conventionally, various powders for cosmetics have been known and used by being blended into cosmetics. In particular, make-up cosmetics are blended with various inorganic powders, organic powders and the like, including white pigments, colored pigments, extender pigments, and the like, in consideration of the makeup effect, feeling of use, usability, and the like.
これら化粧料用粉体のうち、酸化チタン、酸化亜鉛、
硫酸バリウム等の白色無機顔料は、肌を被覆する目的
で、また化粧料の肌への付着性、密着性を高めるために
メーキャップ化粧料によく配合されている。しかし、こ
れら白色無機顔料は粉体間の凝集力が強いため、塗布時
に重く感じたり、延び拡がりが悪いと共に、固形粉体メ
ーキャップ化粧料の場合には、化粧料表面の固化を招
き、塗布体での取れが悪くなる、所謂ケーキング現象を
起こす原因となることがあった。このため、これら粉体
を球状化し、延展性を良くすることが行なわれている。Among these cosmetic powders, titanium oxide, zinc oxide,
BACKGROUND ART White inorganic pigments such as barium sulfate are often blended with makeup cosmetics for the purpose of coating the skin and for enhancing the adhesion and adhesion of the cosmetic to the skin. However, since these white inorganic pigments have a strong cohesive force between powders, they feel heavy at the time of application and spread poorly, and in the case of a solid powder makeup cosmetic, the solidification of the cosmetic surface is caused, and In some cases, it may cause a so-called caking phenomenon. For this reason, these powders are made spherical to improve spreadability.
また、使用時の肌への延び延がり、スライド感、固形
粉体メーキャップ化粧料のケーキング防止及び塗布体へ
の取れを良好とするには、タルク、マイカ等の体質無機
顔料を用いるのが一般的であるが、最近これにナイロン
パウダー、ポリスチレンパウダー、ポリエチレンパウダ
ー、ポリメチルメタクリレートパウダー等の球状有機粉
体又は無水シリカ等の球状無機粉体を添加することが行
われている。In addition, in order to extend the skin to the skin at the time of use, to provide a feeling of sliding, to prevent caking of the solid powder make-up cosmetics, and to obtain a good take-off on the applied body, it is common to use a constitutional inorganic pigment such as talc or mica. Recently, spherical organic powders such as nylon powder, polystyrene powder, polyethylene powder and polymethyl methacrylate powder or spherical inorganic powders such as anhydrous silica have been recently added.
このように、延展性、塗布感等の使用感、塗布体での
取れ、持続性等の使用性を向上させるために、球状粉体
特有の粉体特性を活かした技術が提案されている。As described above, in order to improve the usability such as spreadability, application feeling and the like, and the usability such as removal from a coated body and sustainability, a technique utilizing the powder characteristics specific to spherical powders has been proposed.
一方、球状の外形をもち、かつ内部が中空の樹脂粉体
を化粧料に応用した技術としては、例えば各種の成分を
内包した圧縮崩壊性軟質球状カプセルを配合する技術
（特開昭59−73510号）、特定の粒径かつ比重の球状の
空胞を有する球状重合体を配合する技術（特開昭60−18
4004号）、中空樹脂球体の球状集合体を配合する技術
（特開昭63−119411号）が報告されている。On the other hand, as a technique of applying a resin powder having a spherical outer shape and having a hollow inside to a cosmetic, for example, a technique of blending a compressible collapsible soft spherical capsule containing various components (Japanese Patent Application Laid-Open No. 59-73510) ), A technique of blending a spherical polymer having spherical vacuoles with a specific particle size and specific gravity (Japanese Patent Laid-Open No. 60-18 / 1985)
No. 4004), and a technique of blending a spherical aggregate of hollow resin spheres (JP-A-63-119411) has been reported.
しかし、これらの中空樹脂球体を用いた化粧料は、従
来のものに比べある程度の使用感、使用性が改善された
が、まだ充分満足し得るものではなく、更に一層の改善
が望まれていた。However, cosmetics using these hollow resin spheres have improved the feeling of use and usability to some extent as compared with conventional ones, but they are not yet satisfactory enough, and further improvements have been desired. .
［課題を解決するための手段］ 斯かる実情に鑑み、本発明者らは、鋭意研究を行った
結果、特定の中空発泡樹脂球体を混合することにより、
上記中空樹脂球体では得られなかった、使用時の延展性
がよく、ソフトな感触を有し、化粧後の肌への負担感が
なく、仕上り状態が良好で、ケーキング現象がない等の
優れた特徴を有する化粧料が得られることを見出し、本
発明を完成した。[Means for Solving the Problems] In view of such circumstances, the present inventors have conducted intensive studies and as a result, by mixing a specific hollow foamed resin sphere,
It was not obtained with the above hollow resin spheres, has good spreadability during use, has a soft feel, has no burden on the skin after makeup, has a good finished state, and has excellent caking phenomena. The present inventors have found that a cosmetic having characteristics can be obtained, and completed the present invention.
すなわち、本発明は、平均粒径10〜100μ、みかけ比
重0.02〜0.09、３〜5kg/cm2の加圧により体積が70％以
下に圧縮され、加圧解除後の体積が50％以上復元する中
空発泡樹脂球体を含有することを特徴とする圧縮した又
はワックスにより固化した固形状化粧料を提供するもの
である。That is, according to the present invention, the volume is compressed to 70% or less by pressurization with an average particle size of 10 to 100 μm, an apparent specific gravity of 0.02 to 0.09, and 3 to 5 kg / cm 2 , and the volume after depressurization is restored to 50% or more. It is intended to provide a compressed or wax-solidified solid cosmetic characterized by containing hollow foamed resin spheres.
本発明において、中空発泡樹脂球体とは、加熱により
気化する揮発性液体発泡剤を内包した熱可塑性樹脂球体
を加熱、膨張せしめて得られるものをいう。In the present invention, the hollow foamed resin sphere is obtained by heating and expanding a thermoplastic resin sphere containing a volatile liquid foaming agent that evaporates by heating.
この中空発泡樹脂球体の外殻を形成する樹脂として
は、塩化ビニル、塩化ビニリデン、メチルメタクリレー
ト等のメタクリレート、アクリロニトリル、スチレン等
の単独又は共重合物等が好ましく、揮発性液体発泡剤と
しては特に限定されないが、ブタン、イソブタン、イソ
ペンタン、ネオペンタン、ネオヘキサン、フロン類等が
好適に用いられる。As the resin forming the outer shell of the hollow foamed resin sphere, methacrylates such as vinyl chloride, vinylidene chloride, and methyl methacrylate, acrylonitrile, styrene and the like, or homopolymers or the like are preferable, and volatile liquid foaming agents are particularly limited. However, butane, isobutane, isopentane, neopentane, neohexane, chlorofluorocarbons and the like are preferably used.
この中空発泡樹脂球体は、例えば特公昭59−53290号
に開示されている如く、揮発性液体発泡剤を内包した熱
可塑性樹脂球体、例えば、市販されているエクスパンセ
ル（エクスパンセル社製、商品名）を加熱、発泡させる
方法により製造される。As disclosed in JP-B-59-53290, this hollow foamed resin sphere is a thermoplastic resin sphere containing a volatile liquid foaming agent, for example, a commercially available Expancel (manufactured by Expancel, Inc.). It is manufactured by a method of heating and foaming (trade name).
本発明の中空発泡樹脂球体は揮発性液体発泡剤を内包
した熱可塑性樹脂球体を充分加熱、発泡せしめたものが
好ましい。本発明の中空発泡樹脂球体は、平均粒径が10
〜100μであることが必要であり、特に10〜50μが好ま
しい。平均粒径が10μ未満では目的とする粒子の弾性特
性が得られないため、良好な延展性、ソフトは感触等の
特徴が発揮されず、また100μを越えると粒子感を感じ
るようになり好ましくない。The hollow foamed resin sphere of the present invention is preferably obtained by sufficiently heating and foaming a thermoplastic resin sphere containing a volatile liquid foaming agent. The hollow foamed resin sphere of the present invention has an average particle size of 10
100100 μm is required, and particularly preferably 10-50 μm. If the average particle diameter is less than 10μ, the elastic properties of the target particles cannot be obtained, so that good spreadability and softness do not exhibit characteristics such as touch, and if it exceeds 100μ, a particle feeling is felt, which is not preferable. .
また、中空発泡樹脂球体のみかけ比重は0.02〜0.09の
範囲内にあるものが好ましい。The apparent specific gravity of the hollow foamed resin sphere is preferably in the range of 0.02 to 0.09.
更に、本発明の中空発泡樹脂球体は、本発明の上記効
果をなお一層発揮させるために、加圧による圧縮後、加
圧解除によってある程度もとの形に戻る復元性を有する
ことが好ましい。中空発泡樹脂球体、未発泡樹脂球体及
び発泡不充分の樹脂球体を、流動パラフィンで湿潤後、
加圧及び加圧解除による体積変化を調べる試験を行っ
た。その結果は第１図に示すとおりであり、３〜5kg/cm
2の加圧による体積が70％以下、好ましくは60％以下に
圧縮され、かつ加圧解除後の体積が50％以上、好ましく
は80％以上に復元するものが良好なものであった。Furthermore, in order to further exert the above-mentioned effects of the present invention, the hollow foamed resin sphere of the present invention preferably has a resilience to a certain degree of returning to the original shape by releasing the pressure after the compression by the pressure. Hollow foamed resin spheres, unfoamed resin spheres and insufficiently foamed resin spheres are wetted with liquid paraffin,
A test was conducted to examine the volume change due to pressurization and depressurization. The results are as shown in FIG. 1 and 3-5 kg / cm
The one which was compressed to a volume of 70% or less, preferably 60% or less by pressurization, and the volume of which was restored to 50% or more, preferably 80% or more after depressurization was good.
本発明の圧縮した又はワックスにより固化した固形状
化粧料としては、具体的には、ファンデーション、ほほ
紅、白粉、アイシャドウ等が挙げられる。Specific examples of the solid cosmetics compressed or wax-solidified of the present invention include foundations, blushers, white powders, and eye shadows.
これら化粧料への中空発泡樹脂球状の配合料は化粧料
の種類により異なるが、0.1〜10重量％が好ましい。配
合量が多すぎると、化粧後のかさつき感や化粧膜の粉っ
ぽさが感じられたり固形粉末メーキャップ化粧料の場合
には成形が難しくなったりすることがあり、また少なす
ぎると、充分な効果が奏されない。The spherical foamed resin composition for these cosmetics varies depending on the type of cosmetic, but is preferably 0.1 to 10% by weight. If the compounding amount is too large, the bulkiness after makeup and the powderiness of the cosmetic film may be felt, or in the case of solid powder makeup cosmetics, molding may be difficult, and if the amount is too small, sufficient No effect.
本発明の化粧料の製造は、従来の化粧料用粉体の代り
に中空発泡樹脂球体を使用する以外は自体公知の製造方
法によって行うことができ、特にその手法は問わない。The production of the cosmetic of the present invention can be carried out by a production method known per se except that a hollow foamed resin sphere is used instead of the conventional powder for cosmetics, and the method is not particularly limited.
本発明化粧料には、更に通常化粧料に使用されている
成分、例えば着色顔料、体質顔料、パール剤、有機粉末
等の化粧料用粉体；固形、半固形、液体状の油剤；界面
活性剤、高分子化合物、多価アルコール類、アルカリ
剤、酸化防止剤、紫外線吸収剤、防腐剤、香料、美容成
分、水等を必要に応じて適宜配合することができる。The cosmetics of the present invention further include ingredients commonly used in cosmetics, for example, powders for cosmetics such as coloring pigments, extender pigments, pearlescent agents, and organic powders; solid, semi-solid, and liquid oils; An agent, a polymer compound, a polyhydric alcohol, an alkali agent, an antioxidant, an ultraviolet absorber, a preservative, a fragrance, a cosmetic ingredient, water and the like can be appropriately compounded as required.
［発明の効果］ 本発明化粧料は、含有する中空発泡樹脂球体の外殻が
薄い中空の樹脂であり、軽く軟らかで弾性があるため、
ソフトな感触を有し、化粧後の肌への負担感がなく、仕
上り状態が良好であり、形状が球状であるため延展性が
非常によいという優れた特徴を有する。更に、固形化粧
料にあっては、使用時及び使用後の化粧膜に粉っぽさが
なく、ケーキング現象を起こさずに塗布体への取具合が
良好であり、また油性化粧料にあっては、使用時及び使
用後の化粧膜に油性感が感じられないというような優れ
た特徴を有する。[Effects of the Invention] The cosmetic of the present invention is a hollow resin foam containing a thin hollow resin outer shell, which is light and soft and elastic,
It has an excellent feature that it has a soft touch, does not feel a burden on the skin after makeup, has a good finish, and has a very good spreadability due to its spherical shape. Furthermore, in the case of solid cosmetics, the cosmetic film at the time of use and after use is not powdery, has good caulking properties without causing a caking phenomenon, and has an oily cosmetic. Has excellent characteristics such that no oiliness is felt in the cosmetic film at the time of use and after use.
［実施例］ 次に実施例を挙げて本発明を更に詳細に説明するが本
発明はこれらに限定されるものではない。[Examples] Next, the present invention will be described in more detail with reference to examples, but the present invention is not limited thereto.
実施例１〜３ 固形状油性ファンデーション： 下記製法により表１の成分の本発明固形状油性ファン
デーション及び比較例の固形状油性ファンデーションを
製造し、使用感及び使用性を下記評価基準により評価し
た。結果を表１に示す。Examples 1 to 3 Solid oily foundation: The solid oily foundations of the present invention having the components shown in Table 1 and the solid oily foundations of Comparative Examples were produced by the following production methods, and the usability and usability were evaluated according to the following evaluation criteria. Table 1 shows the results.
＜製 法＞ 成分（１）〜（４）を混合、粉砕し、均一にする。こ
れを予じめ混合、加熱溶解した成分（９）〜（15）中に
加え、三本ロールにて均一にし、次いで成分（５）〜
（８）各々を添加して混合、均一にする。これを容器に
溶融充填して固形状油性ファンデーションを得た。 <Production method> Components (1) to (4) are mixed, pulverized, and made uniform. This is previously added to the components (9) to (15) which have been mixed and dissolved by heating.
(8) Add each to mix and uniform. This was melt-filled in a container to obtain a solid oily foundation.
＜評価基準＞ ◎：比較例１より非常に優れる ○：比較例１より良好 △：比較例１と同等 ×：比較例１より悪い 表１の評価結果に認められる如く、本発明品（実施例
１〜３）は、比較品（比較例２〜４）に比較し、塗布体
での擦取時及び肌への塗布時にソフトであり、肌への延
び拡がりがよく、仕上りの化粧膜に油っぽさや負担感が
感じられず、優れた使用感、使用性を有するものであっ
た。<Evaluation Criteria> ：: Very superior to Comparative Example 1 ：: Excellent than Comparative Example 1 △: Equal to Comparative Example 1 ×: Worse than Comparative Example 1 As shown in the evaluation results in Table 1, the product of the present invention (Example) 1-3) are softer at the time of rubbing with an applied body and at the time of application to the skin than the comparative products (Comparative Examples 2 to 4), have good spread and spread to the skin, and have an oil on the finished cosmetic film. No feeling of feeling or burden was felt, and it had excellent usability and usability.
実施例４ 固形状パウダーファンデーション： 下記製法により表２の成分の本発明固形状パウダーフ
ァンデーション及び比較例の固形状パウダーファンデー
ションを製造し、使用感及び使用性を実施例１〜３の評
価基準と同様にして評価した。結果を表２に示す。Example 4 Solid powder foundation: The solid powder foundation of the present invention having the components shown in Table 2 and the solid powder foundation of the comparative example were produced by the following production method, and the usability and usability were the same as the evaluation criteria of Examples 1 to 3. Was evaluated. Table 2 shows the results.
＜製 法＞ 成分（１）〜（７）を混合、粉砕し、均一にする。こ
れに予じめ混合、加熱溶解した成分（10）〜（15）を加
えて混合し、次いで成分（８）〜（９）各々を添加して
混合、均一にする。これを容器に充填、プレス成型して
固形状パウダーファンデーションを得た。 <Production method> Components (1) to (7) are mixed, pulverized, and made uniform. The components (10) to (15) previously mixed and dissolved by heating are added thereto and mixed, and then the components (8) to (9) are added and mixed and made uniform. This was filled in a container and press-molded to obtain a solid powder foundation.
表２の評価結果に認められる如く、本発明品（実施例
４）は、比較品（比較例６）に比較し、より一層使用時
にソフトな感触を有し、肌への延び拡がりがよく、化粧
後肌に負担感を感じさせないものであった。また本発明
品は、塗布体への取れ具合がよく、ケーキング現象を起
こすこともなかった。As can be seen from the evaluation results in Table 2, the product of the present invention (Example 4) has a softer feel when used and has better spread and spread to the skin, compared to the comparative product (Comparative Example 6). It did not make the skin feel a burden after makeup. In addition, the product of the present invention was easily removed to the coated body and did not cause a caking phenomenon.
実施例５ スティック状口紅： 以下に示す成分で下記製法によりスティック状口紅を
得た。Example 5 Stick-shaped lipstick: A stick-shaped lipstick was obtained from the following components by the following method.
（成分） （重量％） （１） 酸化チタン 3.0 （２） 着色顔料 2.5 （３） 中空発泡樹脂球体＊ 1.0 （４） セレシン 10.0 （５） ジペンタエリトリット脂肪酸エステル 5.0 （６） ジグリセリントリイソステアレート 49.4 （７） ２−エチルヘキサン酸セチル 20.0 （８） マイクロクリスタリン末 9.0 （９） 香料 0.1 ＊塩化ビニリデン／メチルメタクリレート共重合物： 平均粒径50μ、みかけ比重0.03 ＜製 法＞ 成分（１）〜（２）及び予め加温溶解した成分（４）
〜（９）を混合し、三本ロールにて均一分散し、次いで
成分（３）を加えて混合する。これを容器に溶融充填、
成型してスティック状口紅を得た。(Ingredient) (% by weight) (1) Titanium oxide 3.0 (2) Color pigment 2.5 (3) Hollow foamed resin sphere * 1.0 (4) Selesin 10.0 (5) Dipentaerythritol fatty acid ester 5.0 (6) Diglycerin triiso Stearate 49.4 (7) Cetyl 2-ethylhexanoate 20.0 (8) Microcrystalline powder 9.0 (9) Fragrance 0.1 * Vinylidene chloride / methyl methacrylate copolymer: average particle size 50μ, apparent specific gravity 0.03 <Production method> Component (1) ) To (2) and the component (4) previously heated and dissolved
And (9) are mixed, uniformly dispersed with a three-roll mill, and then the component (3) is added and mixed. This is melt-filled in a container,
A stick-like lipstick was obtained by molding.
実施例６ 固形アイシャドウ： 以下に示す成分が下記製法により固形状アイシャドウ
を得た。Example 6 Solid eye shadow: The following components were used to obtain a solid eye shadow by the following method.
（成分） （重量％） （１） 雲母チタン 45.0 （２） マイカ 29.9 （３） タルク 10.0 （４） 着色顔料 4.0 （５） 中空発泡樹脂球体＊ 1.0 （６） ワセリン 2.5 （７） スクワラン 5.0 （８） ジメチルポリシロキサン（20cs） 2.5 （９） 香料 0.1 ＊塩化ビニリデン／アクリロニトリル共重合物： 平均粒径40μ、みかけ比重0.09 （製法） 成分（１）〜（４）を混合、粉砕し、均一にする。こ
れに予じめ混合、加熱溶解した成分（６）〜（９）を加
えて混合し、次いで成分（５）を添加して混合、均一に
する。これを容器に充填、プラス成型して固形状アイシ
ャドウを得た。(Ingredient) (% by weight) (1) Titanium mica 45.0 (2) Mica 29.9 (3) Talc 10.0 (4) Color pigment 4.0 (5) Hollow foamed resin sphere * 1.0 (6) Vaseline 2.5 (7) Squalane 5.0 (8) ) Dimethylpolysiloxane (20cs) 2.5 (9) Fragrance 0.1 * Vinylidene chloride / acrylonitrile copolymer: average particle size 40μ, apparent specific gravity 0.09 (Production method) Mix components (1) to (4), pulverize and homogenize . The components (6) to (9) previously mixed and dissolved by heating are added thereto and mixed, and then the component (5) is added to mix and homogenize. This was filled in a container and molded into a positive shape to obtain a solid eye shadow.
以上の如くして得た実施例４〜６の本発明化粧料は、
いずれも使用時にソフトな感触を有し、肌への延び拡が
りが良く、化粧仕上がりが良好なものであった。The cosmetics of the present invention of Examples 4 to 6 obtained as described above,
All had a soft touch when used, had good spread and spread to the skin, and had a good cosmetic finish.
第１図は種々の中空の樹脂球体の圧力による体積変化を
示す図面である。FIG. 1 is a drawing showing changes in volume of various hollow resin spheres due to pressure.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 福倉 逸雄 東京都北区栄町48番18号 株式会社小林 コーセー株式会社内 (56)参考文献 特開 昭63−33318（ＪＰ，Ａ) ──────────────────────────────────────────────────続 き Continuation of front page (72) Inventor Itsuo Fukukura 48-18 Sakaemachi, Kita-ku, Tokyo Inside Kobayashi Kose Co., Ltd. (56) References JP-A-63-33318 (JP, A)
Claims (1)
9、３〜5kg/cm2の加圧により体積が70％以下に圧縮さ
れ、加圧解除後の体積が50％以上復元する中空発泡樹脂
球体を含有することを特徴とする圧縮した又はワックス
により固化した固形状化粧料。(1) an average particle diameter of 10 to 100 μ, an apparent specific gravity of 0.02 to 0.0
9,3～5Kg / volume by the pressure of cm 2 is compressed to less than 70% by compressed or wax volume after depressurization is characterized by containing a hollow foamed resin spheres to restore 50% Solidified solid cosmetic.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2099844A JP3023688B2 (en) | 1989-04-17 | 1990-04-16 | Cosmetics |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9516089 | 1989-04-17 | ||
| JP1-95160 | 1989-04-17 | ||
| JP2099844A JP3023688B2 (en) | 1989-04-17 | 1990-04-16 | Cosmetics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0347110A JPH0347110A (en) | 1991-02-28 |
| JP3023688B2 true JP3023688B2 (en) | 2000-03-21 |
Family
ID=26436436
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2099844A Expired - Lifetime JP3023688B2 (en) | 1989-04-17 | 1990-04-16 | Cosmetics |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3023688B2 (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2658720B1 (en) * | 1990-02-28 | 1994-09-09 | Oreal | COSMETIC COMPOSITION IN THE FORM OF COMPACTED POWDER CONTAINING HOLLOW MICROSPHERES OF SYNTHETIC THERMOPLASTIC MATERIAL. |
| FR2699815B1 (en) * | 1992-12-24 | 1995-02-24 | Oreal | Solid or pasty makeup composition and process for the preparation of this composition. |
| US5679361A (en) * | 1992-12-24 | 1997-10-21 | L'oreal | Solid or pasty make-up composition |
| JPH07112912A (en) * | 1993-10-14 | 1995-05-02 | Kose Corp | Water-based cosmetic |
| FR2722102B1 (en) * | 1994-07-11 | 1996-08-23 | Cird Galderma | USE OF DEFORMABLE HOLLOW PARTICLES IN A COSMETIC AND / OR DERMATOLOGICAL COMPOSITION CONTAINING FAT MATERIALS |
| FR2722097B1 (en) * | 1994-07-11 | 1997-05-16 | Oreal | COSMETIC AND / OR DERMATOLOGICAL GEL COMPOSITION, RICH IN SOLVENT AND CONTAINING HOLLOW PARTICLES, ITS APPLICATION |
| FR2727312B1 (en) * | 1994-11-24 | 1997-05-23 | Oreal | COSMETIC COMPOSITION IN THE FORM OF COMPACT POWDER AND PREPARATION METHOD |
| JP2008056637A (en) * | 2006-09-01 | 2008-03-13 | Nippon Shikizai Inc | Stick-like oily solid cosmetic |
-
1990
- 1990-04-16 JP JP2099844A patent/JP3023688B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0347110A (en) | 1991-02-28 |
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