JP3022973B2 - Base material for wood floor - Google Patents

Base material for wood floor

Info

Publication number
JP3022973B2
JP3022973B2 JP7349590A JP7349590A JP3022973B2 JP 3022973 B2 JP3022973 B2 JP 3022973B2 JP 7349590 A JP7349590 A JP 7349590A JP 7349590 A JP7349590 A JP 7349590A JP 3022973 B2 JP3022973 B2 JP 3022973B2
Authority
JP
Japan
Prior art keywords
foam
base material
weight
polyolefin
parts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP7349590A
Other languages
Japanese (ja)
Other versions
JPH03275862A (en
Inventor
英一 廣田
博 中澤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lion Corp
Original Assignee
Lion Corp
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Filing date
Publication date
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Priority to JP7349590A priority Critical patent/JP3022973B2/en
Publication of JPH03275862A publication Critical patent/JPH03275862A/en
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Publication of JP3022973B2 publication Critical patent/JP3022973B2/en
Anticipated expiration legal-status Critical
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Description

【発明の詳細な説明】 産業上の利用分野 本発明は、荷重に対する緩衝性、回復性が良好で、か
つ断熱性にも優れる木質床用下地材に関するものであ
る。
Description: BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a base material for a wooden floor, which has good buffering and recovery properties against load and excellent heat insulation.

従来の技術 近年、共同住宅用床材として木質床が風合やダニ、カ
ビの発生防止等の衛生面から、広く普及してきており、
この施工に当っては、木質表面材の下部に緩衝材を貼り
合わせる、いわゆる直貼り工法が安価でしかも施工が容
易であることから急速に実用化されている。
2. Description of the Related Art In recent years, wooden floors have become widespread as floor materials for apartments, from the aspect of hygiene such as texture, ticks, and prevention of mold.
In this construction, a so-called direct pasting method, in which a cushioning material is attached to a lower portion of a wooden surface material, is inexpensive and easy to construct, and thus has been rapidly put into practical use.

この工法で用いられる緩衝材は、モルタルからの湿気
防止等の耐湿性、断熱性、床暖房時の熱的寸法安定性、
施工時の接着性、床材に仕上げるための切削加工性、加
工時に排出される端材の焼却処理における低発熱性等の
性能が要求され、これには無機物を高充てんしたポリオ
レフィン系独立気泡発泡体が好適で、現在広く実用化さ
れている。
The cushioning material used in this method is moisture-resistant, such as preventing moisture from mortar, heat insulation, thermal dimensional stability during floor heating,
Performance such as adhesiveness during construction, cutting workability for finishing floor materials, and low heat generation in incineration of scrap materials discharged during processing are required, such as polyolefin-based closed cell foam filled with high levels of inorganic substances. The body is preferred and is currently widely practiced.

しかしながら、木質床用下地材として好適なこの発泡
体もまだ多くの改善すべき点があり十分満足しうるもの
とはいえない。
However, this foam suitable as a base material for a wooden floor still has many points to be improved and cannot be said to be sufficiently satisfactory.

すなわち、樹脂単品のポリオレフィン系発泡体と比べ
て無機物を高充てんしているため、高荷重に対する歪の
回復が劣る、大荷重に対する緩衝性は優れているが、比
較的小荷重に体するそれが劣る、さらには比熱が小さい
ため熱伝導率が大きく断熱性に劣るといった傾向があ
り、高機能化のニーズに対応してさらなる改善が強く望
まれていた。
In other words, because it is more filled with inorganic materials than polyolefin-based foams made of resin alone, the recovery of strain under high loads is inferior, and the buffering property against large loads is excellent, but it is relatively small load. In addition, there is a tendency that the thermal conductivity is large and the heat insulating property is inferior because the specific heat is small, and further improvement has been strongly desired in response to the need for higher functionality.

発明が解決しようとする課題 本発明は、このような事情の下、従来の木質床用下地
材としてのポリオレフィン系無機物充てん発泡体の長所
を維持したまま、さらに荷重に対する良好な歪回復性、
小荷重から大荷重にわたる高緩衝性及び優れた断熱性を
有する木質床用下地材を提供することを目的とするもの
である。
PROBLEM TO BE SOLVED BY THE INVENTION Under such circumstances, the present invention maintains the advantages of a polyolefin-based inorganic-filled foam as a base material for a conventional wooden floor, and further has a good strain recovery property against a load.
It is an object of the present invention to provide a base material for a wooden floor, which has a high cushioning property from a small load to a large load and excellent heat insulation.

課題を解決するための手段 本発明者らは、上記の目的を達成するために、鋭意研
究を重ねた結果、ポリオレフィン系樹脂に、所定の粒子
径を有する無機物と界面活性剤を所定組成比で配合して
発泡成形することにより、所定の均一微小な独立気泡を
有するポリオレフィン系無機物充てん発泡体が得られ、
これが木質床用下地材として好適であることを見出し、
この知見に基いて本発明をなすに至った。
Means for Solving the Problems The present inventors have conducted intensive studies in order to achieve the above object, and as a result, a polyolefin-based resin, an inorganic substance having a predetermined particle diameter and a surfactant in a predetermined composition ratio. By blending and foam molding, a polyolefin-based inorganic-filled foam having predetermined uniform and minute closed cells is obtained,
It has been found that this is suitable as a base material for wooden floors,
The present invention has been accomplished based on this finding.

すなわち、本発明は、(a)ポリオレフィン系樹脂及
び(b)0.05〜15μの平均粒子径を有する無機物充填材
を、a/a+b=0.25〜0.70、b/a+b=0.75〜0.30の組成
比で含有すると共に、界面活性剤を(a)ポリオレフィ
ン系樹脂と(b)前記無機物充てん剤の合計量100重量
部に対して0.1〜5.0重量部含有し、かつ気泡の70%以上
が気泡径0.03〜0.2mmの範囲内にある均一微細な独立気
泡を有するポリオレフィン系無機物充填発泡体で構成さ
れたことを特徴とする木質床用下地材を提供するもので
ある。
That is, the present invention comprises (a) a polyolefin-based resin and (b) an inorganic filler having an average particle diameter of 0.05 to 15 μ at a composition ratio of a / a + b = 0.25 to 0.70 and b / a + b = 0.75 to 0.30. In addition, the surfactant is contained in an amount of 0.1 to 5.0 parts by weight based on 100 parts by weight of the total of (a) the polyolefin resin and (b) the inorganic filler, and 70% or more of the bubbles have a bubble diameter of 0.03 to 0.2. An object of the present invention is to provide a base material for a wooden floor, comprising a polyolefin-based inorganic material-filled foam having uniformly fine closed cells within a range of mm.

以下、本発明を詳細に説明する。 Hereinafter, the present invention will be described in detail.

本発明で用いられるポリオレフィン系樹脂としては特
に制限はなく、例えば低密度ポリエチレン、直鎖状低密
度ポリエチレン、高密度ポリエチレン、エチレン−酢酸
ビニル共重合体などが挙げられ、これらは単独又は併用
して用いることができる。これらの中で低密度ポリエチ
レンが好ましい。
The polyolefin resin used in the present invention is not particularly limited, and includes, for example, low-density polyethylene, linear low-density polyethylene, high-density polyethylene, ethylene-vinyl acetate copolymer, and the like, alone or in combination. Can be used. Of these, low density polyethylene is preferred.

また、無機物充填材としては、例えば炭酸カルシウ
ム、カオリン、クレー、水酸化アルミニウム、酸化アル
ミニウム、硫酸アルミニウム、ケイ酸マグネシウムなど
が挙げられ、特に好ましくは炭酸カルシウム、水酸化ア
ルミニウムが使用される。これらは単独で又は併用して
用いてもよい。無機物充填材は0.05〜15μ、好ましくは
0.1〜10μの平均粒子径を有することが必要である。こ
の平均粒子径が0.05μ未満では二次凝集して発泡体の気
泡が不均一かつ粗大化し、発泡体の柔軟性が著しく低下
するし、また、15μを超えてもやはり、粗大で不均一な
気泡となり、本発明の目的とする荷重に対する良好な緩
衝性は得られない。
Examples of the inorganic filler include calcium carbonate, kaolin, clay, aluminum hydroxide, aluminum oxide, aluminum sulfate, magnesium silicate, and the like, and particularly preferably, calcium carbonate and aluminum hydroxide are used. These may be used alone or in combination. The inorganic filler is 0.05 to 15μ, preferably
It is necessary to have an average particle size of 0.1 to 10μ. If the average particle size is less than 0.05μ, the foam of the foam is non-uniform and coarse due to secondary agglomeration, the flexibility of the foam is significantly reduced, and, even if it exceeds 15μ, it is coarse and uneven. Air bubbles are formed, and good buffering properties against the load intended by the present invention cannot be obtained.

また、界面活性剤としては、樹脂と相容性が良好で、
かつ界面活性能の高いものが好ましく、例えば、アニオ
ン系界面活性剤としては、C8〜22のアルキル基を含有
するスルホン酸塩、硫酸エステル塩、すなわち、α−オ
レフィンスルホン酸塩、アルキルベンゼンスルホン酸
塩、アルキル硫酸エステル塩、パラフィンスルホン酸
塩、ポリオキシエチレンフェニルエーテル硫酸エステル
塩などであり、非イオン系界面活性剤としては、C
8〜22の高級一価〜多価アルコール、C8〜22の高級脂
肪酸多価アルコールエステル、C8〜22ポリオキシエチ
レンアルキルエーテルなどであり、カチオン系界面活性
剤としては、C8〜22のアルキルアミン、ポリオキシエ
チレンアルキルアミン、アルキルアミン、ポリオキシエ
チレンアミドなどである。
In addition, as a surfactant, the compatibility with the resin is good,
And those having high surface activity are preferable. For example, as anionic surfactants, sulfonates and sulfates containing C8-22 alkyl groups, that is, α-olefin sulfonates, alkylbenzenesulfonic acids Salts, alkyl sulfates, paraffin sulfonates, polyoxyethylene phenyl ether sulfates, and the like. Nonionic surfactants include C
8-22 of higher monohydric ~ polyhydric alcohols, higher fatty acid polyhydric alcohol esters of C 8-22, and the like C 8-22 polyoxyethylene alkyl ethers, examples of the cationic surfactant, the C 8-22 Alkylamine, polyoxyethylene alkylamine, alkylamine, polyoxyethyleneamide, and the like.

その中でも、C8〜22のアルキルスルホン酸塩、C
8〜22の高級一価アルコール、脂肪酸エステル、脂肪族
アミン、ポリオキシエチレンアルキルアミンなどが好ま
しい。
Among them, C 8-22 alkyl sulfonate, C
Preferred are 8 to 22 higher monohydric alcohols, fatty acid esters, aliphatic amines, polyoxyethylene alkylamines, and the like.

本発明のポリオレフィン系樹脂の使用量は、無機物充
填材との合計量に対して25〜70重量%、好ましくは40〜
60重量%の範囲で選ばれる。この量が25重量%未満で
は、成形不良となるし、また70重量%を超えると圧縮強
度が低下するので好ましくない。
The amount of the polyolefin resin used in the present invention is 25 to 70% by weight, preferably 40 to 70% by weight based on the total amount of the inorganic filler.
It is selected in the range of 60% by weight. If the amount is less than 25% by weight, molding failure will occur, and if it exceeds 70% by weight, the compressive strength will decrease, which is not preferable.

また、界面活性剤の使用量は、ポリオレフィン系樹脂
と無機物充てん剤の合計量100重量部に対して0.1〜5.0
重量部の範囲で選ばれる。この量が0.1重量部未満では
気泡の均一微小効果が十分ではなく、粗大な気泡が生成
してしまう上に、解圧した、すなわち荷重を除いた後の
発泡体の歪の回復が少なく圧縮永久歪等が大きすぎる
し、また5.0重量部を超えるとポリオレフィン系樹脂に
混練する際に滑性過剰となり、ロール巻付性が不良とな
る上に、発泡時の溶融粘度が低下して発泡成形性が不良
となるので好ましくない。
The amount of the surfactant used is 0.1 to 5.0 with respect to 100 parts by weight of the total amount of the polyolefin resin and the inorganic filler.
It is selected in the range of parts by weight. When the amount is less than 0.1 part by weight, the uniform and minute effect of the bubbles is not sufficient, and coarse bubbles are generated. In addition, the foam is decompressed, that is, the recovery of the distortion of the foam after removing the load is small and the compression is permanent. If the strain or the like is too large, and if it exceeds 5.0 parts by weight, the lubricating property will be excessive when kneading with the polyolefin resin, the roll wrapping property will be poor, and the melt viscosity at the time of foaming will decrease, and the foam moldability will increase. Is not preferable because it becomes defective.

さらに、本発明においては、ポリオレフィン系樹脂、
無機物充てん剤及び界面活性剤を配合してポリオレフィ
ン系無機物充てん発泡体が得られるが、この発泡体は独
立気泡を有し、かつその全気泡の70%以上、好ましくは
80%以上が0.03〜0.2mmの範囲の気泡径を有して気泡が
均一微小であることが必要である。この所定気泡径の気
泡が全気泡の70%未満になると外部からの荷重に対する
分散効果が十分ではなく、解圧した際、すなわち荷重を
除いた際の圧縮永久歪等の歪の回復性が劣り、床用下地
材とした場合、重量物移動時に床材同士の境目に段差が
生じるし、また、断熱性が不良となるので好ましくな
い。
Further, in the present invention, a polyolefin resin,
A polyolefin-based inorganic-filled foam can be obtained by blending an inorganic filler and a surfactant, and the foam has closed cells, and 70% or more of all the cells, preferably
It is necessary that 80% or more have a bubble diameter in the range of 0.03 to 0.2 mm and the bubbles are uniform and minute. If the bubbles having the predetermined bubble diameter are less than 70% of all the bubbles, the effect of dispersing against an external load is not sufficient, and when the pressure is released, that is, the recoverability of strain such as compression set when the load is removed is poor. In the case of using a floor base material, a step is generated at the boundary between floor materials when moving a heavy object, and the heat insulating property is unfavorably deteriorated.

この無機物充填発泡体は、木質床用下地材としては、
圧縮硬さが1.2kg/cm2以上、圧縮弾性率が12〜30kg/cm2
で、かつ圧縮永久歪が2.0%以下の物性を有するように
調整することが好ましい。
This inorganic-filled foam is used as a base material for wooden floors.
Compression hardness of 1.2 kg / cm 2 or more, compression modulus of 12 to 30 kg / cm 2
It is preferable to adjust the compression set such that the compression set has a physical property of 2.0% or less.

本発明のポリオレフィン系無機物充填発泡体を製造す
る際の発泡成形には熱分解型発泡剤及び架橋剤を用い
る。該発泡剤としては、アゾジカーボンアミド、ジフェ
ニルスルホン−3,3′−ジスルホンヒドラジドベンジル
スルホン酸ジフェニルヒドラジドなどが用いられる。そ
の際の熱分解型発泡剤の配合量は、ポリオレフィン系樹
脂と無機物充填材の合計量100部に対して1〜5重量部
用いられる。
In the foam molding for producing the polyolefin-based inorganic material-filled foam of the present invention, a pyrolytic foaming agent and a crosslinking agent are used. As the foaming agent, azodicarbonamide, diphenylsulfone-3,3'-disulfonehydrazide, benzylsulfonic acid diphenylhydrazide and the like are used. The amount of the thermal decomposition type foaming agent used at that time is 1 to 5 parts by weight based on 100 parts of the total amount of the polyolefin resin and the inorganic filler.

また、架橋剤としては、1,3−ビス(ターシャリブチ
ルパーオキシイソプロピル)ベンゼン、2,5−ジメチル
−2,5−ジ(ターシャリブチルパーオキシ)ヘキサン、
ジクミルパーオキシドなどが好適である。この架橋剤の
配合量はポリオレフィン系樹脂と無機物充填材の合計量
100部に対して0.1〜2重量部が好ましい。
Examples of the crosslinking agent include 1,3-bis (tert-butylperoxyisopropyl) benzene, 2,5-dimethyl-2,5-di (tert-butylperoxy) hexane,
Dicumyl peroxide and the like are preferred. The compounding amount of this cross-linking agent is the total amount of polyolefin resin and inorganic filler.
0.1 to 2 parts by weight per 100 parts is preferred.

なお、この他に添加剤として必要に応じ顔料、滑剤、
防カビ剤、酸化防止剤等を添加してもよい。
In addition, pigments, lubricants, and other additives as necessary.
A fungicide, an antioxidant and the like may be added.

次に本発明のポリオレフィン系無機物充填発泡体を製
造するには、先ず、ポリオレフィン系樹脂、無機物充填
材、界面活性剤、熱分解型発泡剤及び架橋剤、さらに必
要に応じて各種添加剤をインターナルミキサー、バンバ
リーミキサー、加圧ニーダー等の装置で均一に溶融、混
練し、次いでロール、押出機等の装置でシート状等の所
望の形状に成形する。次に上記工程で調製した混練シー
トを、例えば加圧プレス装置を用いて一段加圧、加熱発
泡方式により温度160〜190℃、圧力150〜200kg/cm2で架
橋発泡を行う。
Next, in order to produce the polyolefin-based inorganic-filled foam of the present invention, first, a polyolefin-based resin, an inorganic filler, a surfactant, a pyrolytic foaming agent and a cross-linking agent, and, if necessary, various additives, are added. The mixture is uniformly melted and kneaded by an apparatus such as a null mixer, a Banbury mixer, or a pressure kneader, and then formed into a desired shape such as a sheet by an apparatus such as a roll or an extruder. Next, the kneaded sheet prepared in the above step is subjected to cross-linking and foaming at a temperature of 160 to 190 ° C. and a pressure of 150 to 200 kg / cm 2 by a one-stage pressurization and a heat foaming method using, for example, a press machine.

このようにして、気泡径0.03〜0.2mmの範囲内のもの
が70%以上である均一微小な独立気泡を有するポリオレ
フィン系無機物充てん発泡体が得られる。
In this manner, a polyolefin-based inorganic material-filled foam having uniform and minute closed cells having a cell diameter in the range of 0.03 to 0.2 mm of 70% or more is obtained.

この発泡体は即木質床用下地材となる。 This foam immediately becomes a base material for a wooden floor.

発明の作用、効果 本発明においては、上記特定の平均粒子径を有する無
機物充填材に加えて界面活性剤を併用することにより、
先ず無機物充てん剤がポリオレフィン系樹脂中に均一に
分散し、発泡成形時に気泡調整の核剤及び発泡体の補強
材として作用して微小な気泡を形成し、さらに界面活性
剤の作用により発泡に最適な溶融粘度に調整されるとと
もに、ポリオレフィン系樹脂と無機物の相容性を向上
し、無機物の周囲の気泡の集合化を防止することがで
き、それによって、微小かつ均一な気泡形成が可能とな
る。こうして、気泡径0.03〜0.2mmの範囲内のものが全
気泡の70%以上である均一かつ微小な独立気泡を含む所
望の発泡体が得られる。
Actions and Effects of the Invention In the present invention, by using a surfactant in addition to the inorganic filler having the specific average particle diameter,
First, the inorganic filler is uniformly dispersed in the polyolefin resin, and acts as a nucleating agent for foam adjustment and a reinforcing material for the foam during foam molding to form fine bubbles, and is most suitable for foaming by the action of a surfactant. As well as improving the compatibility between the polyolefin resin and the inorganic substance, preventing the aggregation of bubbles around the inorganic substance, thereby enabling fine and uniform bubble formation. . In this manner, a desired foam containing uniform and fine closed cells having a cell diameter in the range of 0.03 to 0.2 mm, which is 70% or more of all cells, can be obtained.

この発泡体は、小荷重から大荷重にわたって荷重に対
する緩衝性及び歪回復性に優れ、かつ熱伝導率の低下に
より良好な断熱性を発揮する。また、界面活性剤の効果
として有効な帯電防止をも付与することができ、発泡体
加工時の摩擦帯電に伴う種々の問題も防止できる。
This foam has excellent shock absorbing properties and strain recovery from a small load to a large load, and exhibits good heat insulating properties due to a decrease in thermal conductivity. In addition, an effective antistatic effect can be provided as an effect of the surfactant, and various problems associated with triboelectric charging during foam processing can be prevented.

従って、本発明のこの発泡体で構成される木質床用下
地材は、ソフトでありながら、かつ腰のある感触を奏
し、心地好い歩行感をもたらすなど、現代生活にマッチ
した質感をもつ素材を与えるものである。
Accordingly, the wood flooring base material composed of this foam of the present invention provides a material that has a texture that matches the modern life, such as being soft and having a stiff feel and providing a comfortable walking feeling. Things.

実施例 次に、実施例及び比較例によって本発明をさらに詳細
に説明する。
Examples Next, the present invention will be described in more detail with reference to Examples and Comparative Examples.

なお、各発泡体の物性は以下の試験測定法により求め
た。
The physical properties of each foam were determined by the following test and measurement methods.

(1) 見掛け密度;JIS K 6767 (2) 気泡径;JIS K 6402に準じ、発泡体の任意の個
所の25mmの直線を横切る気泡について測定した。
(1) Apparent density; JIS K 6767 (2) Bubble diameter: According to JIS K 6402, measurement was made on bubbles crossing a 25 mm straight line at an arbitrary point of the foam.

(3) 圧縮硬さ;JIS K 6767(25%圧縮) (4) 圧縮弾性率;JIS K 6767 (5) 圧縮永久歪;JIS K 6767 (6) 熱伝導率;;JIS K 1412 実施例1 低密度ポリエチレン〔融点:110℃、密度:0.92g/cm3
メルトインデックス:12g/分(住友化学(株)製、商品
名スミカセンF−216−1〕を50重量部、無機物充填材
として三共製粉(株)製の重質炭酸カルシウム(エスカ
ロン#800、平均粒径1.7μm)を50重量部、界面活性剤
として直鎖アルキルスルホン酸ナトリウム〔バイエル社
製、商品名メルソラートH−95〕を1.0重量部、発泡剤
として大塚化学(株)製のアゾジカーボンアミド(ユニ
フォームAZ)3重量部、架橋剤として化薬アクゾ(株)
製の1,3−ビス(ターシャリーブチルパーオキシイソプ
ロピル)ベンゼン(パーカドックス14/40)を0.4重量部
使用し、これをインターナルミキサーで溶融混練後、2
本ロールでシート化し、発泡温度175℃にて一段加圧加
熱方式で発泡体を得た。得られた発泡体は第1表に示し
たように、0.03〜20mmの気泡占有率が85%であり、圧縮
硬さ1.4kg/cm2、圧縮弾性率14kg/cm2、圧縮永久歪1.1%
と歩行感が良好で、かつ熱伝導率が0.032Kcal/m.hr.℃
と断熱性に優れていた。
(3) Compression hardness; JIS K 6767 (25% compression) (4) Compression modulus; JIS K 6767 (5) Compression set; JIS K 6767 (6) Thermal conductivity; JIS K 1412 Example 1 Low Density polyethylene (melting point: 110 ° C, density: 0.92 g / cm 3 ,
Melt index: 12 g / min (Sumitomo Chemical Co., Ltd., trade name: Sumikasen F-216-1) 50 parts by weight, heavy calcium carbonate (Escalon # 800, average particle size) manufactured by Sankyo Flour Milling Co., Ltd. as an inorganic filler 1.7 μm), 1.0 part by weight of sodium linear alkyl sulfonate (manufactured by Bayer, trade name: Mersolate H-95) as a surfactant, and azodicarbonamide manufactured by Otsuka Chemical Co., Ltd. as a foaming agent (Uniform AZ) 3 parts by weight, chemical agent Akzo Co., Ltd. as a crosslinking agent
0.4 parts by weight of 1,3-bis (tertiary butylperoxyisopropyl) benzene (Percadox 14/40) was melt-kneaded with an internal mixer and then kneaded.
The roll was formed into a sheet, and a foam was obtained at a foaming temperature of 175 ° C. by a one-stage pressure heating method. As shown in Table 1, the obtained foam had a bubble occupancy of 0.03 to 20 mm of 85%, a compression hardness of 1.4 kg / cm 2 , a compression modulus of 14 kg / cm 2 , and a compression set of 1.1%.
Good walking feeling and thermal conductivity of 0.032Kcal / m.hr. ℃
And the insulation was excellent.

実施例2〜14 実施例1と同様にして第1表に示した配合組成(各成
分は全て重量部である)を有する発泡体を得、この物性
を求めた。得られた発泡体は木質床用下地材として好適
のものであった。
Examples 2 to 14 In the same manner as in Example 1, foams having the composition shown in Table 1 (all components are parts by weight) were obtained, and their physical properties were determined. The obtained foam was suitable as a base material for a wooden floor.

比較例1〜7 実施例1と同様にして第2表に示した配合組成(各成
分は全て重量部である)のものをシート成形処理に付し
たところ、比較例4のものは成形不良であり、比較例6
のものは成形不可であった。他の比較例のものは成形で
き、同様に発泡体も得られた。この物性を求めたとこ
ろ、得られた発泡体は気泡が不均一で、しかも広範囲の
気泡径を有し、木質床用下地材としては圧縮特性、特に
圧縮永久歪特性、断熱性のいずれも不十分であった。
Comparative Examples 1 to 7 In the same manner as in Example 1, those having the composition shown in Table 2 (all components are parts by weight) were subjected to sheet forming treatment. Yes, Comparative Example 6
Was not moldable. Other comparative examples could be molded and foams were obtained as well. When the physical properties were determined, the obtained foam had non-uniform cells and a wide range of cell diameters. As a base material for a wooden floor, none of the compression properties, especially the compression set properties and the heat insulation properties, were satisfactory. Was enough.

フロントページの続き (58)調査した分野(Int.Cl.7,DB名) E04F 15/18 601 E04F 15/16 E04F 15/02 C08L 23:00 C08J 9/06 Continuation of the front page (58) Field surveyed (Int.Cl. 7 , DB name) E04F 15/18 601 E04F 15/16 E04F 15/02 C08L 23:00 C08J 9/06

Claims (3)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】(a)ポリオレフィン系樹脂及び(b)0.
05〜15μの平均粒子径を有する無機物充填材を、a/a+
b=0.25〜0.70、b/a+b=0.75〜0.30の組成比で含有
すると共に、界面活性剤を(a)ポリオレフィン系樹脂
と(b)前記無機物充てん剤の合計量100重量部に対し
て0.1〜5.0重量部含有し、かつ気泡の70%以上が気泡径
0.03〜0.2mmの範囲内にある均一微細な独立気泡を有す
るポリオレフィン系無機物充填発泡体で構成されたこと
を特徴とする木質床用下地材。
(1) a polyolefin-based resin (b);
An inorganic filler having an average particle size of 05 to 15μ is a / a +
b = 0.25 to 0.70, b / a + b = 0.75 to 0.30, and a surfactant is used in an amount of 0.1 to 0.1 parts by weight based on 100 parts by weight of the total amount of (a) the polyolefin resin and (b) the inorganic filler. Contains 5.0 parts by weight and more than 70% of the bubbles have a bubble diameter
A base material for a wooden floor, comprising a polyolefin-based inorganic-filled foam having uniformly fine closed cells within a range of 0.03 to 0.2 mm.
【請求項2】界面活性剤が炭素数8〜22(C8〜22)の
アルキルスルホン酸塩、炭素数8〜22(C8〜22)の脂
肪族アルコール、脂肪酸エステル又は脂肪族アミン、あ
るいはポリオキシエチレンアルキルアミンである請求項
1記載の木質床用下地材。
Wherein alkyl sulfonate surfactant having from 8 to 22 carbon atoms (C 8-22), fatty alcohols, fatty acid esters or fatty amines having 8 to 22 carbon atoms (C 8-22), or, The base material for a wooden floor according to claim 1, which is a polyoxyethylene alkylamine.
【請求項3】発泡体の圧縮永久歪が2.0%以下である請
求項1記載の木質床用下地材。
3. The base material for a wooden floor according to claim 1, wherein the compression set of the foam is 2.0% or less.
JP7349590A 1990-03-26 1990-03-26 Base material for wood floor Expired - Fee Related JP3022973B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP7349590A JP3022973B2 (en) 1990-03-26 1990-03-26 Base material for wood floor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP7349590A JP3022973B2 (en) 1990-03-26 1990-03-26 Base material for wood floor

Publications (2)

Publication Number Publication Date
JPH03275862A JPH03275862A (en) 1991-12-06
JP3022973B2 true JP3022973B2 (en) 2000-03-21

Family

ID=13519899

Family Applications (1)

Application Number Title Priority Date Filing Date
JP7349590A Expired - Fee Related JP3022973B2 (en) 1990-03-26 1990-03-26 Base material for wood floor

Country Status (1)

Country Link
JP (1) JP3022973B2 (en)

Also Published As

Publication number Publication date
JPH03275862A (en) 1991-12-06

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