JP2842715B2 - Disinfectant cleaning composition - Google Patents
Disinfectant cleaning compositionInfo
- Publication number
- JP2842715B2 JP2842715B2 JP23008991A JP23008991A JP2842715B2 JP 2842715 B2 JP2842715 B2 JP 2842715B2 JP 23008991 A JP23008991 A JP 23008991A JP 23008991 A JP23008991 A JP 23008991A JP 2842715 B2 JP2842715 B2 JP 2842715B2
- Authority
- JP
- Japan
- Prior art keywords
- present
- cleaning composition
- chain
- composition
- examples
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Landscapes
- Apparatus For Disinfection Or Sterilisation (AREA)
- Detergent Compositions (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
【０００１】[0001]
【産業上の利用分野】本発明は殺菌洗淨剤組成物に関す
る。FIELD OF THE INVENTION The present invention relates to a germicidal detergent composition.
【０００２】[0002]
【従来の技術】病院、食品工場などで器具、設備及び作
業者の手指等を洗浄し、殺菌する必要がある。従来これ
らの場所ではアルキルジメチルベンジルアンモニウムク
ロリド、アルキルトリメチルアンモニウムブロミド等の
殺菌効力を有する陽イオン界面活性剤を含有する水溶液
からなる殺菌剤組成物が用いられている。2. Description of the Related Art In hospitals, food factories, etc., it is necessary to wash and sterilize instruments, equipment, and fingers of workers. Conventionally, in these places, a disinfectant composition comprising an aqueous solution containing a cationic surfactant having a disinfecting effect such as alkyldimethylbenzylammonium chloride and alkyltrimethylammonium bromide has been used.
【０００３】[0003]
【発明が解決しようとする課題】しかし、このものは十
分な洗浄力を持たず、通常の洗浄剤例えば陰イオン界面
活性剤と併用すると、その殺菌効力が著しく低下するこ
とが知られている。そのため病院、食品工場等では洗浄
と殺菌は２工程に分けて行わねばならないという問題が
あった。However, it is known that this product does not have a sufficient detergency and its bactericidal effect is remarkably reduced when used in combination with a usual detergent such as an anionic surfactant. Therefore, there has been a problem that cleaning and sterilization must be performed in two steps in hospitals and food factories.
【０００４】[0004]
【課題を解決するための手段】本発明者らは上記問題を
解決するため鋭意検討した結果、長鎖脂肪族炭化水素基
を２個有するジ低級アルキルアンモニウム塩に両性界面
活性剤を配合することにより、殺菌効力と、洗浄性の両
方を備えた殺菌洗浄剤組成物が得られることを見いだ
し、本発明に到達した。すなわち本発明はジ長鎖アルキ
ルジ短鎖アルキルアンモニウム塩(Ａ)と、両性界面活性
剤(Ｂ)を含有する水溶液からなる殺菌洗淨剤組成物（但
しヨウ素分子は含まない）である。Means for Solving the Problems The inventors of the present invention have conducted intensive studies to solve the above problems, and have found that an amphoteric surfactant is mixed with a di-lower alkylammonium salt having two long-chain aliphatic hydrocarbon groups. As a result, the present inventors have found that a germicidal detergent composition having both bactericidal efficacy and detergency can be obtained, and have reached the present invention. That is, the present invention is a disinfectant cleaning composition (but not containing iodine molecules) comprising an aqueous solution containing a dilong-chain alkyldi-short-chain alkylammonium salt (A) and an amphoteric surfactant (B).
【０００５】本発明において、ジ長鎖アルキルジ短鎖ア
ルキルアンモニウム塩(Ａ)としては、下記一般式(１)で
示される第４級アンモニウム塩が挙げられる。In the present invention, the di-long-chain alkyl-di-short-chain alkyl ammonium salt (A) includes a quaternary ammonium salt represented by the following general formula (1).
【化１】 [式中Ｒ1、Ｒ2は同一または異なる分枝を有していても
よい飽和または不飽和の長鎖アルキル基；Ｒ3およびＲ4
は同一または異なる短鎖アルキル基；］Ｒ1およびＲ2で
表わされる長鎖アルキル基は好ましくは炭素数８〜１８
のアルキル基、例えば２−エチルヘキシル、オクチル、
デシル、ドデシル、オクチル、ステアリル等であるが特
に好ましくは炭素数８〜１０のアルキル基である。Ｒ3
およびＲ4としてはメチルまたはエチル基が適してお
り、特にメチルが好ましい。本発明において長鎖アルキ
ル基は１分子中に２個有している必要がある。長鎖アル
キル基を１個有する、例えば従来から殺菌剤として知ら
れているアルキルトリメチルアンモニウムブロミド等で
はこれを両性界面活性剤と併用したとき十分な殺菌洗浄
力を発現し得ない。長鎖アルキル基の炭素数が８より小
さくても１８より大きくても十分な殺菌力を発現しな
い。両性界面活性剤と併用したとき特に高い殺菌効力を
発現し、かつ洗浄力を低下しないアルキル基は２−エチ
ルヘキシル、オクチルまたはデシルである。アニオンと
してはハロゲン(Ｃl-,Ｉ-,Ｂr-など)、無機酸対イオン
(ＨＳＯ4 -,ＮＯ3 -,Ｈ2ＰＯ4 -など)、及び有機酸対イオ
ン(ＣＨ3ＯＳＯ3 -,Ｃ2Ｈ5ＳＯ3 -,ＣＨ3ＣＯ2 -,ＣＨ3Ｃ6
Ｈ4ＳＯ3 -,ＣＨ3ＳＯ3 -など)が挙げられる]。(Ａ)の具
体例としては、ジオクチルジメチルアンモニウムクロラ
イド、オクチルデシルジメチルアンモニウムクロライド
及びジデシルジメチルアンモニウムクロライドなどが挙
げられる。これらのうち好ましいものはジデシルジメチ
ルアンモニウムクロライドである。Embedded image [Wherein R 1 and R 2 are the same or different and may have a saturated or unsaturated long-chain alkyl group; R 3 and R 4
Are the same or different short-chain alkyl groups; the long-chain alkyl groups represented by R 1 and R 2 preferably have 8 to 18 carbon atoms.
Alkyl group such as 2-ethylhexyl, octyl,
It is decyl, dodecyl, octyl, stearyl and the like, and particularly preferably an alkyl group having 8 to 10 carbon atoms. R 3
As R 4 and R 4 , a methyl or ethyl group is suitable, and methyl is particularly preferable. In the present invention, it is necessary to have two long-chain alkyl groups in one molecule. An alkyltrimethylammonium bromide having one long-chain alkyl group, for example, conventionally known as a bactericide, cannot exhibit sufficient germicidal detergency when used in combination with an amphoteric surfactant. If the carbon number of the long-chain alkyl group is smaller than 8 or larger than 18, sufficient bactericidal activity is not exhibited. Alkyl groups that exhibit particularly high germicidal efficacy when used in combination with amphoteric surfactants and do not reduce detergency are 2-ethylhexyl, octyl or decyl. Halogen Examples of the anion (Cl -, I -, Br - , etc.), an inorganic acid counterion
(HSO 4 − , NO 3 − , H 2 PO 4 − etc.) and organic acid counter ions (CH 3 OSO 3 − , C 2 H 5 SO 3 − , CH 3 CO 2 − , CH 3 C 6)
H 4 SO 3 -, CH 3 SO 3 - , etc.) and the like. Specific examples of (A) include dioctyldimethylammonium chloride, octyldecyldimethylammonium chloride, and didecyldimethylammonium chloride. Of these, preferred is didecyldimethylammonium chloride.
【０００６】両性界面活性剤(Ｂ)としては、例えばベタ
イン型両性界面活性剤；特に次のような一般式(２)；As the amphoteric surfactant (B), for example, a betaine-type amphoteric surfactant; in particular, the following general formula (2):
【化２】 [式中Ｒ5は平均炭素数が９〜１５の分枝を有していても
よい飽和または不飽和のアルキル基であり、Ｒ6,Ｒ7は
メチル基又はエチル基、mは２又は３を表す。];で示さ
れるアルキルアミドベタイン型両性界面活性剤(例えば
ヤシ油脂肪酸アミドプロピルジメチルアミノ酢酸ベタイ
ン、ラウリン酸アミドプロピルジメチルアミノ酢酸ベタ
イン)、一般式(３)；Embedded image [Wherein R 5 is a saturated or unsaturated alkyl group which may have a branch having an average carbon number of 9 to 15, R 6 and R 7 are a methyl group or an ethyl group, and m is 2 or 3 Represents An alkyl amido betaine type amphoteric surfactant represented by the formula (for example, coconut oil fatty acid amidopropyldimethylaminoacetic acid betaine, lauric acid amidopropyldimethylaminoacetic acid betaine), and a general formula (3)
【化３】 [式中Ｒ8は平均炭素数が９〜１５の分枝を有していても
よい飽和または不飽和のアルキル基であり、Ｒ9,Ｒ10は
メチル基又はエチル基である。]で示されるアルキルベ
タイン型両性界面活性剤(例えばヤシ油アルキルジメチ
ルアミノ酢酸ベタイン、ラウリルジメチルアミノ酢酸ベ
タイン)、一般式(４)；Embedded image [Wherein R 8 is a saturated or unsaturated alkyl group which may have a branch having an average carbon number of 9 to 15, and R 9 and R 10 are a methyl group or an ethyl group. Alkylbetaine-type amphoteric surfactants (eg, coconut oil alkyldimethylaminoacetate betaine, lauryldimethylaminoacetate betaine) represented by general formula (4):
【化４】 [式中Ｒ11は平均炭素数が９〜１５の分枝を有していて
もよい飽和または不飽和のアルキル基である。]で示さ
れるイミダゾリニウムベタイン型両性界面活性剤(例え
ば２−ヤシ油アルキル−１−カルボキシエチル−１−ヒ
ドロキシエチルイミダゾリニウムベタイン液);並びにア
ミノ酸型両性界面活性剤(例えばラウリルアミノプロピ
オン酸ナトリウム)が挙げられる。これらのうちで好ま
しいものはアルキルアミドベタイン型両性界面活性剤及
びアルキルベタイン型両性界面活性剤であるが特にアル
キルアミドベタイン型両性界面活性剤が好ましい。又本
発明の殺菌剤組成物には必要により次に挙げる非イオン
界面活性剤を含有させる事もできる。この非イオン界面
活性剤としては例えば下記(１)〜(３)が挙げられる。Embedded image [In the formula, R 11 is a saturated or unsaturated alkyl group which may have a branch having an average carbon number of 9 to 15. Imidazolinium betaine-type amphoteric surfactants (e.g., 2-coco oil-1-carboxyethyl-1-hydroxyethyl imidazolinium betaine solution); and amino acid-type amphoteric surfactants (e.g., laurylaminopropionic acid) Sodium). Of these, preferred are alkylamidobetaine-type amphoteric surfactants and alkylbetaine-type amphoteric surfactants, with alkylamidebetaine-type amphoteric surfactants being particularly preferred. The bactericide composition of the present invention may contain the following nonionic surfactants, if necessary. Examples of the nonionic surfactant include the following (1) to (3).
【０００７】(１)ポリオキシエチレンアルキルエーテ
ル;脂肪族アルコール(炭素数６〜２０、好ましくは炭素
数１２〜１８で直鎖又は分岐の天然又は合成アルコー
ル)のエチレンオキサイド(以下ＥＯという)付加物(ＥＯ
の付加モル数は通常２〜５０、好ましくは５〜２０)
で、例えばオクチルアルコールＥＯ(８)、ラウリルアル
コールＥＯ(９)が挙げられる。(1) Polyoxyethylene alkyl ether; ethylene oxide (hereinafter referred to as EO) adduct of aliphatic alcohol (natural or synthetic alcohol having 6 to 20 carbon atoms, preferably 12 to 18 carbon atoms, linear or branched, having straight or branched chain) (EO
Is usually 2 to 50, preferably 5 to 20).
Examples include octyl alcohol EO (8) and lauryl alcohol EO (9).
【０００８】(２)ポリオキシエチレンポリオキシプロピ
レンブロックコポリマー:プルロニックタイプの非イオ
ン界面活性剤。ポリプロピレングリコール(以下ＰＰＧ
という。平均分子量(ＭＷ):９００〜２９００)のＥＯ付
加物(ＥＯが分子中に１０〜８０重量％占める)で例えば
ＰＰＧ(ＭＷ:１２００)のＥＯ１０重量％付加物、ＰＰ
Ｇ(ＭＷ:１７５０)のＥＯ２０重量％付加物、ＰＰＧ(Ｍ
Ｗ:２０５０)のＥＯ４０重量％付加物が挙げられる。(2) Polyoxyethylene polyoxypropylene block copolymer: Pluronic type nonionic surfactant. Polypropylene glycol (hereinafter PPG)
That. EO adduct having an average molecular weight (MW) of 900 to 2900 (EO accounts for 10 to 80% by weight in the molecule), for example, PPG (MW: 1200) EO 10% by weight adduct, PP
G (MW: 1750) EO 20% by weight adduct, PPG (M
W: 2050).
【０００９】(３)アルキルジメチルアミンオキシド:ア
ルキル基の炭素数が６〜２０、好ましくは８〜１６で直
鎖又は分岐のアルキル基であり、例えばラウリルジメチ
ルアミンオキシド、ヤシ油アルキルジメチルアミンオキ
シドが挙げられる。その他、必要により含有させること
のできる他の添加剤としては例えば、トリポリリン酸ナ
トリウム、メタケイ酸ナトリウム、炭酸ナトリウムなど
のアルカリ性ビルダー、エチレンジアミンテトラアセテ
ート(ＥＤＴＡ)、Ｎ−ヒドロキシエチル−エチレンジア
ミントリアセテート(ＨＥＤＴＡ)などの有機金属イオン
封鎖剤、着色料、香料が挙げられる。(3) Alkyldimethylamine oxide: a linear or branched alkyl group having 6 to 20, preferably 8 to 16 carbon atoms in the alkyl group, such as lauryl dimethylamine oxide and coconut oil alkyldimethylamine oxide. No. In addition, as other additives that can be contained as needed, for example, sodium trifluorophosphate, sodium metasilicate, alkaline builders such as sodium carbonate, ethylenediaminetetraacetate (EDTA), N-hydroxyethyl-ethylenediaminetriacetate (HEDTA) and the like Organic metal ion sequestering agents, coloring agents, and fragrances.
【００１０】本発明の殺菌洗淨剤組成物は、上記各成分
を任意の割合に混合したものであるが、好ましくは(Ａ)
１モルに対し、(Ｂ)は１.２５〜２.５０モル、特に好ま
しくは(Ｂ)は１.４０〜２.００モルの範囲である。(Ｂ)
が上記範囲未満では本発明の組成物の安定性が低下し、
上記範囲を越えると殺菌効果が低下する傾向を示す。The germicidal detergent composition of the present invention is a mixture of the above-mentioned components in an optional ratio.
(B) is in the range of 1.25 to 2.50 mol, and particularly preferably (B) is in the range of 1.40 to 2.00 mol per mol. (B)
Is less than the above range, the stability of the composition of the present invention is reduced,
If it exceeds the above range, the bactericidal effect tends to decrease.
【００１１】本発明の殺菌洗淨剤組成物の濃度は特に限
定されないが、通常２〜５０重量％の水溶液として製剤
され、使用にあたり水に希釈して用いられる。必要によ
り含有させる非イオン界面活性剤は通常０〜２０％、上
記他の添加剤は通常０〜５％である。本発明の組成物の
製法を例示すると、(Ａ),(Ｂ)の各水溶液及び必要によ
り非イオン界面活性剤や上記他の添加剤を均一に混合す
るのみで容易に本発明の組成物が得られる。この際水溶
液濃度の調整は任意の段階で行うことができる。使用時
の濃度は対象によっても異なるが、通常(Ａ)が１〜１
０,０００ppmであり、好ましくは１００〜１,０００ppm
となる濃度で使用するとよい。本発明の殺菌洗淨剤組成
物は病院、食品工場、畜舎、ホテル、レストラン、学校
等の床や壁を殺菌洗浄する環境殺菌洗浄剤として有用で
ある。The concentration of the sterilizing composition of the present invention is not particularly limited, but it is usually formulated as an aqueous solution of 2 to 50% by weight, and is diluted with water before use. The nonionic surfactant to be contained as necessary is usually 0 to 20%, and the other additives are usually 0 to 5%. To illustrate the method for producing the composition of the present invention, the composition of the present invention can be easily prepared by simply uniformly mixing each of the aqueous solutions (A) and (B) and, if necessary, the nonionic surfactant and the other additives described above. can get. At this time, the concentration of the aqueous solution can be adjusted at any stage. The concentration at the time of use varies depending on the subject, but usually (A) is 1 to 1
000 ppm, preferably 100 to 1,000 ppm
It is recommended to use at a concentration such that The germicidal detergent composition of the present invention is useful as an environmental germicidal detergent for disinfecting and cleaning floors and walls of hospitals, food factories, barns, hotels, restaurants, schools and the like.
【００１２】[0012]
【実施例】以下、実施例により本発明をさらに説明する
が、本発明はこれにより限定されるものではない。実施
例中の部は重量部である。なお以下において、洗浄力は
リーナッツ式洗浄力評価方法(ＪＩＳ−Ｋ３３７０)によ
り試験した。試験条件は以下の通りである。 (試験条件) 濃度 : ０.１％ 温度 : ３０℃ 洗浄時間 : ３分 殺菌効力は各種殺菌を用いた最少発育阻止濃度により評
価した。 実施例１〜４,比較例１,２ 表−１に示す実施例１〜４及び比較例１,２の各成分の
比率となるよう均一に混合し調整した組成物Ｉ〜ＶＩを
得た。(表中の数字は()外は重量％を表し、()内はＡと
Ｂ−１もしくはＢ−２とのモル比を表す。）The present invention will be described in more detail with reference to the following examples, which, however, are not intended to limit the scope of the present invention. Parts in the examples are parts by weight. Note that, in the following, the detergency was tested according to a leanut-type detergency evaluation method (JIS K3370). The test conditions are as follows. (Test conditions) Concentration: 0.1% Temperature: 30 ° C Washing time: 3 minutes The bactericidal efficacy was evaluated by the minimum growth inhibitory concentration using various sterilizations. Examples 1 to 4 and Comparative Examples 1 and 2 Compositions I to VI were obtained by uniformly mixing and adjusting the components of Examples 1 to 4 and Comparative Examples 1 and 2 shown in Table 1 so as to have the respective ratios. (The numbers outside the parentheses indicate weight%, and the numbers in the parenthesis indicate the molar ratio of A to B-1 or B-2.)
【００１３】[0013]
【表１】 [Table 1]
【００１４】実施例５〜８、比較例３，４ 組成物Ｉ〜ＶＩを用いて洗浄力を試験した結果を表２に
示す。Examples 5 to 8 and Comparative Examples 3 and 4 Table 2 shows the results of tests on the detergency of the compositions I to VI.
【表２】 [Table 2]
【００１５】実施例９〜１２、比較例５,６ 組成物Ｉ〜ＶＩを用いて殺菌効力を評価した結果を表３
に示す。Examples 9 to 12 and Comparative Examples 5 and 6 The results of evaluating the bactericidal efficacy using the compositions I to VI are shown in Table 3.
Shown in
【表３】 [Table 3]
【００１６】[0016]
【発明の効果】本発明の組成物は下記効果を奏する。即
ち、 １．本発明の殺菌洗淨剤組成物は、高い洗浄力を示す。 ２．本発明の殺菌洗淨剤組成物は、優れた殺菌効力を示
す。The composition of the present invention has the following effects. That is, 1. The sterilizing composition of the present invention exhibits high detergency. 2. The germicidal detergent composition of the present invention exhibits excellent germicidal efficacy.
───────────────────────────────────────────────────── フロントページの続き (58)調査した分野(Int.Cl.6，ＤＢ名) A01N 33/12 A01N 25/30 ＣＡ（ＳＴＮ) ＲＥＧＩＳＴＲＹ（ＳＴＮ) ＷＰＩ（ＤＩＡＬＯＧ)──────────────────────────────────────────────────続 き Continued on the front page (58) Fields surveyed (Int.Cl. 6 , DB name) A01N 33/12 A01N 25/30 CA (STN) REGISTRY (STN) WPI (DIALOG)
Claims (4)
ウム塩(Ａ)と、両性界面活性剤(Ｂ)を含有する水溶液か
らなる殺菌洗淨剤組成物（但しヨウ素分子は含まな
い）。1. A germicidal detergent composition comprising an aqueous solution containing a dilong-chain alkyldi-short-chain alkylammonium salt (A) and an amphoteric surfactant (B) (but not containing iodine molecules).
ロライドである請求項１項記載の殺菌洗淨剤組成物。2. The composition according to claim 1, wherein (A) is didecyldimethylammonium chloride.
面活性剤である請求項１又は２記載の殺菌洗淨剤組成
物。3. The sterilizing and cleaning composition according to claim 1, wherein (B) is an alkyl amido betaine type amphoteric surfactant.
／２.５である請求項１〜３いずれかに記載の殺菌洗淨
剤組成物。4. The molar ratio of (A) to (B) is 1 / 1.25 to 1
The sterilizing and cleaning composition according to any one of claims 1 to 3, wherein the ratio is /2.5.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23008991A JP2842715B2 (en) | 1991-09-10 | 1991-09-10 | Disinfectant cleaning composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23008991A JP2842715B2 (en) | 1991-09-10 | 1991-09-10 | Disinfectant cleaning composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0565203A JPH0565203A (en) | 1993-03-19 |
| JP2842715B2 true JP2842715B2 (en) | 1999-01-06 |
Family
ID=16902378
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP23008991A Expired - Lifetime JP2842715B2 (en) | 1991-09-10 | 1991-09-10 | Disinfectant cleaning composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2842715B2 (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2733901B2 (en) * | 1994-10-14 | 1998-03-30 | 三菱化工機株式会社 | Rotary single-chamber filter |
| US6514458B1 (en) * | 2000-02-25 | 2003-02-04 | Ge Betz, Inc. | Method for removing microbes from surfaces |
| JP4558955B2 (en) * | 2001-01-18 | 2010-10-06 | 株式会社Ａｄｅｋａ | Bactericidal composition |
| JP2006069918A (en) * | 2004-08-31 | 2006-03-16 | Sanyo Chem Ind Ltd | Degerming and deodorizing cleanser |
| JP2010132611A (en) * | 2008-12-05 | 2010-06-17 | Johnson Diversey Co Ltd | Germicide composition for finger |
| JP2010132612A (en) * | 2008-12-05 | 2010-06-17 | Johnson Diversey Co Ltd | Germicide detergent composition for finger |
| JP5980479B2 (en) * | 2011-03-31 | 2016-08-31 | 小林製薬株式会社 | Biofilm removal composition |
-
1991
- 1991-09-10 JP JP23008991A patent/JP2842715B2/en not_active Expired - Lifetime
Non-Patent Citations (1)
| Title |
|---|
| Ｃｈｅｍｉｃａｌ Ａｂｓｔｒａｃｔ，Ｖｏｌ．７６，８１７９０，ｐ８６，１９７２ |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0565203A (en) | 1993-03-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5143992B2 (en) | disinfectant | |
| JP2516418B2 (en) | Disinfectant composition | |
| CA2458475C (en) | Cleaning composition | |
| CN109414026A (en) | For the seamless permanent seal cooling composition for hard-surface cleaning and sterilization | |
| JP6991959B2 (en) | Antibacterial cleaner composition | |
| JP2004534718A (en) | disinfectant | |
| JP2842715B2 (en) | Disinfectant cleaning composition | |
| JP6097639B2 (en) | Cleaning composition and method of using the same | |
| JP2004526833A (en) | Biocidal cleaning composition | |
| JP2019104793A (en) | Liquid detergent composition | |
| MXPA02000085A (en) | Disinfectants. | |
| JP5642429B2 (en) | Cleaning disinfectant composition | |
| JP2004315691A (en) | Germicidal detergent composition | |
| GB2172607A (en) | Rinse aid composition | |
| JP4558955B2 (en) | Bactericidal composition | |
| JP5337350B2 (en) | Disinfectant cleaning composition and disinfecting cleaning method using the same | |
| JP2004231594A (en) | Composition of germicidal detergent | |
| JP7144028B2 (en) | Cleaning and sanitizing agent composition | |
| JPH06122893A (en) | Detergent composition | |
| JP4468010B2 (en) | Disinfectant cleaning composition | |
| JP3860549B2 (en) | Disinfectant cleaning composition | |
| JP2001316209A (en) | Sterilizing cleanser composition | |
| WO2020223275A1 (en) | Sanitizing compositions | |
| JP6399704B2 (en) | Liquid detergent for textile products | |
| JP4165938B2 (en) | Composition comprising an amidoamine oxide compound and a quaternary nitrogen-containing cationic surfactant |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Year of fee payment: 10 Free format text: PAYMENT UNTIL: 20081023 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Year of fee payment: 11 Free format text: PAYMENT UNTIL: 20091023 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Year of fee payment: 12 Free format text: PAYMENT UNTIL: 20101023 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20111023 Year of fee payment: 13 |
|
| EXPY | Cancellation because of completion of term |