JP2799613B2 - Pressure-disintegrating spherical powder and cosmetics containing the same - Google Patents
Pressure-disintegrating spherical powder and cosmetics containing the sameInfo
- Publication number
- JP2799613B2 JP2799613B2 JP1337229A JP33722989A JP2799613B2 JP 2799613 B2 JP2799613 B2 JP 2799613B2 JP 1337229 A JP1337229 A JP 1337229A JP 33722989 A JP33722989 A JP 33722989A JP 2799613 B2 JP2799613 B2 JP 2799613B2
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Description
【発明の詳細な説明】 ［産業上の利用分野］ 本発明は、加圧崩壊性球状粉体及びこれを配合した化
粧料に関する。更に詳しくは、使用時の塗布操作により
徐々に崩壊する加圧崩壊性球状粉体、及びこれを配合し
た、肌への展延性、使用感触等に優れ、ケーキングがな
く、塗布体への移行性が良好な化粧料に関する。The present invention relates to a pressure-disintegrating spherical powder and a cosmetic containing the same. More specifically, a pressurized collapsible spherical powder that gradually disintegrates by a coating operation at the time of use, and which is blended, has excellent spreadability to the skin, excellent feel in use, etc., has no caking, and is easily transferred to a coated body. Related to good cosmetics.
［従来の技術］ 従来、化粧料使用時の皮膚への展延性、スライド感、
均一塗布性の向上、プレス状化粧料の場合における化粧
料表面の固化（ケーキング）防止、パフ、スポンジ等の
塗布体への移行性向上等の手段として、タルク、マイ
カ、雲母チタン、カオリン等の無機顔料やナイロン末、
ポリエチレン末、結晶セルロース、デンプン等の有機粉
末を配合することが一般に行なわれている。[Prior art] Conventionally, spreadability on skin when using cosmetics, sliding feeling,
As means for improving uniform application properties, preventing solidification (caking) of the cosmetic surface in the case of press-type cosmetics, and improving transferability to a coated body such as puffs and sponges, talc, mica, mica titanium, kaolin, etc. Inorganic pigments and nylon powder,
It is common practice to mix organic powders such as polyethylene powder, crystalline cellulose, starch and the like.
また、上記問題点の、より効果的な解決手段として、
球状粉体を化粧料に配合し、その形状に起因する特性を
利用することも行なわれている。例えば、特定粒径を有
する球状無水ケイ酸を配合した化粧料が知られている
（特開昭54−55379号公報、同54−140736号公報）。Also, as a more effective solution to the above problems,
It has also been practiced to blend a spherical powder into a cosmetic and utilize the properties resulting from its shape. For example, cosmetics containing spherical silicic anhydride having a specific particle size are known (JP-A-54-55379, JP-A-54-140736).
一方、近年、粒径の小さな粉体基剤を造粒して粒径の
大きな加圧崩壊性球状粉体を用い、化粧操作の初期には
粒径の大きな加圧崩壊性球状粉体の働きにより肌へのの
びがよく、塗布操作で加圧崩壊性球状粉体が徐々に崩壊
して粒径が小さくなることにより高い密着性が得られる
化粧料が提案されている（特開昭62−181211号公報、同
62−234008号公報等）。On the other hand, in recent years, a powder base having a small particle size has been granulated to use a pressurizable collapsible spherical powder having a large particle size. A cosmetic has been proposed which has good spreadability to the skin, and which has a high adhesion due to the pressure-disintegrating spherical powder gradually disintegrating and reducing the particle size during the coating operation (Japanese Patent Application Laid-Open No. Sho 62-62). No. 181211,
62-234008, etc.).
［発明が解決しようとする課題］ しかしながら、球状無水ケイ酸をそのまま配合した化
粧料は、塗布体への移行性、展延性等の点で十分とは言
えなかった。[Problems to be Solved by the Invention] However, cosmetics containing spherical silica anhydride as they are are not sufficient in terms of transferability to an applied body, spreadability, and the like.
また、加圧崩壊性球状粉体を配合した化粧料は、その
崩壊後に使用感が大きく変化し、高い密着性は得られる
が、崩壊後も更にのび広がりが要求される場合には適当
ではなかった。In addition, cosmetics containing pressurized collapsible spherical powders have a great change in feeling of use after disintegration and high adhesion can be obtained, but are not suitable when further spreading is required after disintegration. Was.
従って本発明は、崩壊後においても優れた展延性を有
し、使用感触、塗布体への移行性、ケーキング防止性に
優れる加圧崩壊性球状粉体、及びこれを含有する化粧料
を提供することを目的とする ［課題を解決するための手段］ かかる実情において、本発明者らは鋭意研究を行なっ
た結果、特定粒径の球状無水ケイ酸を高分子を用いて造
粒して得られる加圧崩壊性球状粉体及びこれを配合した
化粧料が、従来にない新規な使用感を有し、かつ使用性
も良好であることを見出し、本発明を完成した。Accordingly, the present invention provides a pressure-disintegrating spherical powder having excellent spreadability even after disintegration, excellent feel in use, transferability to an applied body, and anti-caking properties, and a cosmetic containing the same. [Means for solving the problem] Under such circumstances, the present inventors have conducted intensive studies and as a result obtained by granulating spherical anhydrous silicic acid having a specific particle size using a polymer. It has been found that the pressure-disintegrating spherical powder and the cosmetic containing the same have an unprecedented new feeling of use and good usability, and have completed the present invention.
すなわち本発明は、平均粒径0.1〜10μｍの球状無水
ケイ酸を、水溶性高分子及び／または疎水性高分子を用
いて平均凝集粒径20〜200μｍに造粒してなる加圧崩壊
性球状粉体及びこれを配合してなる化粧料を提供するも
のである。That is, the present invention provides a pressure-disintegrating spherical particle obtained by granulating spherical silica having an average particle diameter of 0.1 to 10 μm to an average aggregate particle diameter of 20 to 200 μm using a water-soluble polymer and / or a hydrophobic polymer. It is intended to provide a powder and a cosmetic comprising the same.
本発明において用いられる球状無水ケイ酸は、平均粒
径が0.1〜10μｍのものである。0.1μｍ未満では良好な
展延性が得られず、10μｍを超えると崩壊後の感触が悪
くなるので好ましくない。このような球状無水ケイ酸
は、シリコーン等の油剤で表面被覆処理を施されたもの
であってもよく、また、比表面積が10〜800m2/gのもの
が好ましい。市販のものとしては、例えばゴッドボール
Ｅ−2C、ゴッドボールD11−796C（共に鈴木油脂工業
（株）製）、シリカビーズ（日本ケミカル（株）製）等
が挙げられる。The spherical silicic anhydride used in the present invention has an average particle size of 0.1 to 10 μm. If it is less than 0.1 μm, good spreadability cannot be obtained, and if it exceeds 10 μm, the feel after disintegration becomes poor, which is not preferable. Such spherical anhydrous silicic acid may be subjected to a surface coating treatment with an oil agent such as silicone, and preferably has a specific surface area of 10 to 800 m 2 / g. Examples of commercially available products include Godball E-2C, Godball D11-796C (both manufactured by Suzuki Yushi Kogyo KK), silica beads (manufactured by Nippon Chemical Co., Ltd.) and the like.
本発明においては、上記球状無水ケイ酸のみを造粒し
てもよいが、その他の化粧料用粉体と組み合わせること
により、結合剤量を増すことなく加圧崩壊性球状粉体の
崩壊強度が高められ、また粉体の選択により紫外線遮蔽
効果等を付与することも可能となる。In the present invention, only the above-mentioned spherical silicic anhydride may be granulated, but the disintegration strength of the pressure-disintegrating spherical powder can be increased without increasing the amount of the binder by combining with other cosmetic powders. It is also possible to impart an ultraviolet shielding effect or the like by selecting the powder.
本発明において用いられる前記球状無水ケイ酸以外の
化粧料用粉体としては、化粧料一般に用いられるもので
あれば特に制限されず、例えば酸化チタン、酸化亜鉛等
の白色顔料；黄酸化鉄、ベンガラ、黒酸化鉄、群青、紺
青、タール系色素、天然色素等の着色顔料；タルク、マ
イカ、セリサイト、炭酸カルシウム、炭酸マグネシウ
ム、無水ケイ酸（前記以外のもの）、アルミナ、カオリ
ン等の体質顔料；雲母チタン、オキシ塩化ビスマス等の
光輝性顔料；ナイロン、ポリスチレン、ポリメタクリル
酸メチル、結晶化セルロース、デンプン等の有機粉末な
どが挙げられ、これらにシリコーン等の油剤で表面被覆
処理を施したものでもよい。これら化粧料用粉体の平均
粒径は、0.01〜20μｍの範囲であるのが好ましく、特に
平均粒径１μｍ以下の粉体を適用するのが効果的であ
る。The cosmetic powder other than the spherical silicic anhydride used in the present invention is not particularly limited as long as it is generally used in cosmetics. For example, white pigments such as titanium oxide and zinc oxide; yellow iron oxide; , Black iron oxide, ultramarine, navy blue, tar pigments, natural pigments, etc .; pigments such as talc, mica, sericite, calcium carbonate, magnesium carbonate, silicic anhydride (other than the above), alumina, kaolin, etc. Brilliant pigments such as titanium mica, bismuth oxychloride and the like; organic powders such as nylon, polystyrene, polymethyl methacrylate, crystallized cellulose, starch and the like, which have been subjected to a surface coating treatment with an oil agent such as silicone. May be. The average particle size of these cosmetic powders is preferably in the range of 0.01 to 20 μm, and it is particularly effective to use a powder having an average particle size of 1 μm or less.
ここにおいて、球状無水ケイ酸とその他の化粧料用粉
体との配合比率は、100:0〜40:60、特に90:10〜50:50の
範囲が好ましい。球状無水ケイ酸の比率がこの範囲より
小さくなると本発明の効果が得難くなる。Here, the compounding ratio of the spherical silicic anhydride to the other cosmetic powder is preferably in the range of 100: 0 to 40:60, and particularly preferably in the range of 90:10 to 50:50. If the ratio of the spherical silicic anhydride is smaller than this range, it is difficult to obtain the effects of the present invention.
本発明において造粒に用いられる水溶性高分子として
は、アラビアゴム、ポリビニルアルコール、ポリエチレ
ングリコール、アルギン酸ナトリウム、カルボキシメチ
ルセルロース等が、また疎水性高分子としては、エチル
セルロース、ナイロン等が挙げられる。これら高分子に
は、結合剤としての役割のほか、その選択により、密着
感、滑らかさ等、それぞれに特有の使用感を付与する機
能もある。Examples of the water-soluble polymer used for granulation in the present invention include gum arabic, polyvinyl alcohol, polyethylene glycol, sodium alginate, carboxymethyl cellulose, and the like, and examples of the hydrophobic polymer include ethyl cellulose, nylon, and the like. In addition to their role as binders, these polymers also have the function of imparting a unique feeling of use, such as adhesion and smoothness, depending on their selection.
前記球状無水ケイ酸またはこれとその他の化粧料用粉
体の総量に対する上記高分子の配合量は、粉体100重量
部に対して0.1〜30重量部、特に１〜10重量部が好まし
い。0.1重量部未満では造粒が困難であり、また造粒し
得ても強度が弱く、30重量部を超えると高分子自体の使
用感が強くなり、好ましくない。The amount of the polymer to be added is preferably 0.1 to 30 parts by weight, particularly preferably 1 to 10 parts by weight, based on 100 parts by weight of the spherical silica or the other amount of the cosmetic powder. If the amount is less than 0.1 part by weight, granulation is difficult, and even if granulation can be performed, the strength is low.
本発明の加圧崩壊性球状粉体を造粒する方法として
は、噴霧乾燥法が好ましく、ディスク（高速回転円板）
式、ノズル（加圧ノズル、二流体ノズル等）式等の一般
に知られている噴霧乾燥機を用いて行なうことができる
が、特にディスク式噴霧乾燥機を用いるのが、比較的均
一な粒径に噴霧でき、微粒化にも適することから好まし
い。As a method for granulating the pressure-disintegrating spherical powder of the present invention, a spray drying method is preferable, and a disk (high-speed rotating disk) is used.
It can be carried out using a generally known spray dryer such as a nozzle type (pressurizing nozzle, two-fluid nozzle, etc.) type, and in particular, a disk type spray dryer can be used to obtain a relatively uniform particle size. It is preferable because it can be sprayed and suitable for atomization.
本発明加圧崩壊性球状粉体の平均凝集粒径は、造粒条
件を制御することにより、20〜200μｍとなるように調
整することが必要である。20μｍ未満では小さすぎて加
圧崩壊性球状粉体の特性が現われにくく、200μｍを超
えると粒子感を感じるようになり好ましくない。It is necessary to adjust the average agglomerated particle size of the pressure-disintegrable spherical powder of the present invention to be 20 to 200 μm by controlling the granulation conditions. If it is less than 20 μm, it is too small to exhibit the characteristics of the pressure-disintegrable spherical powder, and if it exceeds 200 μm, a feeling of particles is felt, which is not preferable.
また、本発明加圧崩壊性球状粉体の加圧崩壊性は、例
えばヘイドン表面性測定機を用い、荷重に対する摩擦抵
抗値の変化度からずり破壊強度として求めた場合、10〜
260g/cm2の範囲内であるのが好ましい。すなわち、この
範囲内であれば、これを配合した化粧料の塗擦時に容易
に粒子が崩壊し、粒子感、違和感等の残存感がなく、優
れた密着性の、きめ細かな化粧膜が得られる。ずり破壊
強度が10g/cm2未満では、機械的強度が低いため化粧料
の製造中、混合、粉砕、プレス等の工程において粒子の
破壊が生じてしまい、260g/cm2を超えると、耐摩擦強度
が大きくなりすぎ、塗擦圧で粒子の崩壊か起こらず、本
発明の目的が充分に達成されない。Further, the pressure disintegrability of the pressure disintegrable spherical powder of the present invention is, for example, using a Haydon surface property measuring instrument, when determined as the shear fracture strength from the change in the frictional resistance value against the load, 10 to 10
It is preferably within the range of 260 g / cm 2 . That is, when the content is within this range, the particles are easily disintegrated at the time of application of the cosmetic containing the same, and there is no residual feeling such as a feeling of particles and a feeling of discomfort, and a fine decorative film having excellent adhesion and fineness can be obtained. The shear breaking strength is less than 10 g / cm 2, in the manufacture of mechanical strength is low for cosmetics, mixing, grinding, breaking of particles will occur in the process such as a press, it exceeds 260 g / cm 2, rub The strength is too high, the particles do not collapse under the application pressure, and the object of the present invention is not sufficiently achieved.
本発明の加圧崩壊性球状粉体の化粧料への配合量は化
粧料の剤型、目的等により調整することができ、特に限
定されるものではないが、１〜90重量％の範囲であるの
が好ましい。The amount of the pressure-disintegrating spherical powder of the present invention to be added to the cosmetic can be adjusted according to the form of the cosmetic, the purpose, etc., and is not particularly limited, but is in the range of 1 to 90% by weight. Preferably it is.
本発明の化粧料は、必須成分である本発明の加圧崩壊
性球状粉体のほかに、製品種、目的等により、通常化粧
料成分として用いられる、白色・体質・着色顔料・パー
ル剤、天然鉱物、有機粉末、油剤、金属石鹸、界面活性
剤、保湿剤、防腐剤、香料、その他各種添加剤等から適
宜選択して配合することにより製造される。Cosmetic of the present invention, in addition to the pressure-disintegrating spherical powder of the present invention, which is an essential component, depending on the product type, purpose, etc., usually used as a cosmetic component, white, body, colored pigment, pearlescent, It is manufactured by appropriately selecting and blending natural minerals, organic powders, oils, metal soaps, surfactants, humectants, preservatives, fragrances, and other various additives.
本発明の化粧料は、製品形態、形状を問わず、粉末状
・プレス状・液状・スティック状等、または乳化タイプ
・油化タイプ等、いずれのタイプでもよく、例えば粉白
粉、ファンデーション、ほほ紅、アイシャドウ、口紅、
アイライナー、マスカラ、アイブロウ、下地クリーム、
粉体入りローション等が挙げられる。The cosmetic of the present invention may be in any form, such as powder, pressed, liquid, stick, etc., or emulsified, oiled, etc., regardless of the product form and shape. For example, powdered white powder, foundation, blush , Eyeshadow, lipstick,
Eyeliner, mascara, eyebrow, base cream,
Lotion containing powder and the like can be mentioned.
［作用及び発明の効果］ 本発明の加圧崩壊性球状粉体は、化粧操作により崩壊
して、粒径の小さな一次粒子の球状無水ケイ酸となる。[Functions and Effects of the Invention] The pressure-disintegratable spherical powder of the present invention is disintegrated by a cosmetic operation, and becomes primary particles of spherical silicic anhydride having a small particle diameter.
従って、これを配合した本発明化粧料は、崩壊前には
その比較的大きな粒径により、崩壊後には球状無水ケイ
酸の形状により、化粧操作時を通じて優れた展延性を有
し、均一な化粧膜を与える。また、使用時のざらつきも
なく、ソフトで自然な仕上りが得られる。更に、顔料や
粉末の持つ凝集性がなくなり分散性が良好となるため、
プレス状化粧料の場合にはケーキングを生じにくく、塗
布体への移行性にも優れるものである。Therefore, the cosmetic of the present invention containing the same has excellent spreadability throughout the cosmetic operation due to its relatively large particle size before disintegration and the shape of spherical silicic acid anhydride after disintegration, and uniform cosmetics. Give the membrane. In addition, a soft and natural finish can be obtained without roughness during use. Furthermore, since the cohesiveness of pigments and powders disappears and the dispersibility becomes better,
In the case of a press-type cosmetic, caking is less likely to occur, and excellent transferability to an applied body is also obtained.
［実施例］ 以下、実施例を挙げて更に詳細に説明するが、本発明
はこれらに限定されるものではない。EXAMPLES Hereinafter, the present invention will be described in more detail with reference to Examples, but the present invention is not limited thereto.
実施例１ 表１に示す成分を、ホモミキサーにて6,000r.p.m.で1
0分間混合して、均一なスラリー状物を得た。Example 1 The components shown in Table 1 were mixed in a homomixer at 6,000 rpm for 1 hour.
After mixing for 0 minutes, a uniform slurry was obtained.
次いで噴霧乾燥機〔大川原化工機社製，スプレードラ
イヤーＬ−12型（ディスク式）〕を用いて表１に示す噴
霧条件で噴霧乾燥を行ない、加圧崩壊性球状粉体を得
た。これらの物性を表１にに示す。Next, spray drying was carried out using a spray dryer [spray dryer L-12 (disc type) manufactured by Okawara Kakoki Co., Ltd.] under the spray conditions shown in Table 1 to obtain a pressure-disintegrable spherical powder. Table 1 shows these physical properties.
比較品１の粉体は、塗布時ののびは良いが、塗布操作
による崩壊後はのびが重くなってしまうものであった。
これに対し、本発明品１〜３の粉体は、塗布時ののびが
軽いばかりか塗布操作による崩壊後も一次粒子の球状無
水ケイ酸によるきめ細かなのびの感じられるものであっ
た。 The powder of the comparative product 1 spreads well at the time of application, but becomes heavy after disintegration by the application operation.
On the other hand, the powders of the products 1 to 3 of the present invention exhibited not only a small spread at the time of coating but also a fine spread of the primary particles due to the spherical silicic anhydride even after disintegration by the coating operation.
実施例２ 下記製法により、表２に示す組成のパウダーファンデ
ーションを調整し、それぞれについて20名のパネラーに
より「塗布体への移行性」、「のび広がりのよさ」、
「ソフト感」及び「ざらつきのなさ」について下記基準
に従い評価を行なった。この結果も表２に併せて示す。Example 2 A powder foundation having the composition shown in Table 2 was prepared by the following production method, and “panelability to spread”, “spreadability”,
"Soft feeling" and "no roughness" were evaluated according to the following criteria. The results are also shown in Table 2.
（製法） A.成分（１）〜（８）を撹拌混合する。(Preparation method) A. Components (1) to (8) are stirred and mixed.
B.成分（９）〜（13）を加熱溶融する。 B. Components (9) to (13) are heated and melted.
C.AにＢを添加して混合粉砕して均一にする。 C. Add B to A and mix and grind to make it uniform.
D.Cを金皿にプレス成型してパウダーファンデーショ
ンを得る。DC is pressed into a metal plate to obtain a powder foundation.
（評価基準） 評価点 非常に良い ……４点 良い ……３点 普通 ……２点 悪い ……１点 非常に悪い ……０点 判定 平均点が3.0以上4.0以下 ……◎ 平均点が2.0以上3.0未満 ……○ 平均点が1.0以上2.0未満 ……△ 平均点が 0以上1.0未満 ……× 実施例３（粉白粉） 下記成分及び製法を用い、粉白粉を調製した。(Evaluation criteria) Evaluation point Very good 4 points Good ... 3 points Normal ... 2 points Bad ... 1 point Very bad ... 0 points Judgment Average score is 3.0 or more and 4.0 or less ... Average of 2.0 Not less than 3.0 and less average value 1.0 and less than 2.0 ... average value is not less than 0 and less than 1.0 ... x Example 3 (White powder) White powder was prepared using the following components and production method.
（成分） （重量％） （１）本発明品２の粉体 40.0 （２）タルク 18.0 （３）マイカ 残量 （４）着色顔料 2.0 （５）スクワラン 5.0 （６）流動パラフィン 5.0 （７）香料 適量 （製法） A.成分（１）〜（４）を撹拌混合する。(Ingredient) (% by weight) (1) Powder of the product 2 of the present invention 40.0 (2) Talc 18.0 (3) Mica balance (4) Color pigment 2.0 (5) Squalane 5.0 (6) Liquid paraffin 5.0 (7) Fragrance Appropriate amount (Production method) A. Components (1) to (4) are stirred and mixed.
B.成分（５）〜（７）を加熱溶融する。B. Components (5) to (7) are heated and melted.
C.AにＢを添加して混合粉砕して均一にする。C. Add B to A and mix and grind to make it uniform.
D.Cを金皿にプレス成型して粉白粉を得る。Press molding D.C into a metal plate to obtain a white powder.
───────────────────────────────────────────────────── フロントページの続き (58)調査した分野(Int.Cl.6，ＤＢ名) A61K 7/02 ＣＡ，ＲＥＧＩＳＴＲＹ（ＳＴＮ)──────────────────────────────────────────────────続 き Continued on the front page (58) Fields surveyed (Int. Cl. 6 , DB name) A61K 7/02 CA, REGISTRY (STN)
Claims (3)
を、水溶性高分子及び／または疎水性高分子を用いて平
均凝集粒径20〜200μｍに造粒してなる加圧崩壊性球状
粉体。A pressure-disintegrating sphere obtained by granulating spherical silica having an average particle size of 0.1 to 10 μm to an average aggregate particle size of 20 to 200 μm using a water-soluble polymer and / or a hydrophobic polymer. powder.
と、これ以外の平均粒径0.01〜20μｍの化粧料用粉体と
を、水溶性高分子及び／または疎水性高分子を用いて平
均凝集粒径20〜200μｍに造粒してなる加圧崩壊性球状
粉体。2. A spherical silica having an average particle size of 0.1 to 10 μm and another cosmetic powder having an average particle size of 0.01 to 20 μm are mixed with a water-soluble polymer and / or a hydrophobic polymer. Pressurizable collapsible spherical powder obtained by granulating to an average aggregate particle size of 20 to 200 μm.
体を配合してなる化粧料。3. A cosmetic comprising the pressure-disintegrating spherical powder according to claim 1 or 2.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1337229A JP2799613B2 (en) | 1989-12-26 | 1989-12-26 | Pressure-disintegrating spherical powder and cosmetics containing the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1337229A JP2799613B2 (en) | 1989-12-26 | 1989-12-26 | Pressure-disintegrating spherical powder and cosmetics containing the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH03197412A JPH03197412A (en) | 1991-08-28 |
| JP2799613B2 true JP2799613B2 (en) | 1998-09-21 |
Family
ID=18306658
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1337229A Expired - Fee Related JP2799613B2 (en) | 1989-12-26 | 1989-12-26 | Pressure-disintegrating spherical powder and cosmetics containing the same |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2799613B2 (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3488719B2 (en) * | 1992-01-30 | 2004-01-19 | 株式会社コーセー | Porous spherical powder and cosmetic containing the same |
| EP1230009B1 (en) * | 1999-11-18 | 2003-08-27 | Sorex Limited | Storage-stable aerated gel composition and a process for producing it |
| JP2003104840A (en) * | 2001-09-28 | 2003-04-09 | Kose Corp | Degradable spherical boron nitride particle and method for producing the particle and cosmetic containg the same |
| JP5112928B2 (en) * | 2008-03-28 | 2013-01-09 | 株式会社コーセー | Hairdressing composition |
| JP2009155332A (en) * | 2009-01-09 | 2009-07-16 | Fancl Corp | Sunscreen cosmetic |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0696494B2 (en) * | 1986-02-06 | 1994-11-30 | ポーラ化成工業株式会社 | Cosmetics |
| JPH07116011B2 (en) * | 1986-04-02 | 1995-12-13 | 株式会社コーセー | Makeup cosmetics |
| JP2700793B2 (en) * | 1988-01-25 | 1998-01-21 | 株式会社コーセー | Easy-to-disintegrate granule-containing cosmetics |
-
1989
- 1989-12-26 JP JP1337229A patent/JP2799613B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH03197412A (en) | 1991-08-28 |
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