JP2627488B2 - Method for producing glass product having decorative pattern - Google Patents

Method for producing glass product having decorative pattern

Info

Publication number
JP2627488B2
JP2627488B2 JP6158072A JP15807294A JP2627488B2 JP 2627488 B2 JP2627488 B2 JP 2627488B2 JP 6158072 A JP6158072 A JP 6158072A JP 15807294 A JP15807294 A JP 15807294A JP 2627488 B2 JP2627488 B2 JP 2627488B2
Authority
JP
Japan
Prior art keywords
glass
fine powder
composite
base
decorative pattern
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP6158072A
Other languages
Japanese (ja)
Other versions
JPH082938A (en
Inventor
道夫 浅井
Original Assignee
ヒカリ電工株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ヒカリ電工株式会社 filed Critical ヒカリ電工株式会社
Priority to JP6158072A priority Critical patent/JP2627488B2/en
Publication of JPH082938A publication Critical patent/JPH082938A/en
Application granted granted Critical
Publication of JP2627488B2 publication Critical patent/JP2627488B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/02—Surface treatment of glass, not in the form of fibres or filaments, by coating with glass
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
    • C03C17/007—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/40—Coatings comprising at least one inhomogeneous layer
    • C03C2217/43—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
    • C03C2217/46—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase
    • C03C2217/465—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase having a specific shape

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Composite Materials (AREA)
  • Joining Of Glass To Other Materials (AREA)
  • Glass Compositions (AREA)

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【０００１】[0001]

【産業上の利用分野】本発明は装飾模様を有するガラス
製品の製造方法に関する。The present invention relates to a method for producing a glass product having a decorative pattern.

【０００２】[0002]

【従来の技術】ガラスは多種類のものが存在するが、実
用製品のガラスは殆ど酸化物ガラスであり、その中でも
重要なものは珪酸塩ガラスである。珪酸塩ガラスはＳi
Ｏ2を主成分とし、その他の成分としてＮa2Ｏ、ＣaＯ、
ＰbＯ、Ｂ2Ｏ3等を含み得る。一方、ガラス繊維はガラ
スを引き延ばして極端に細くした人造繊維である。2. Description of the Related Art Although there are many types of glasses, practically used glasses are mostly oxide glasses, of which silicate glass is important. Silicate glass is Si
O 2 as a main component, and other components such as Na 2 O, CaO,
It may include PbO, B 2 O 3 and the like. On the other hand, glass fiber is an artificial fiber obtained by stretching glass and making it extremely thin.

【０００３】一般にガラス繊維の溶融温度はガラスより
高く、またガラス繊維の膨張係数はガラスに比べ著しく
低く、溶融温度及び膨張係数において両者は大きく相異
する。従ってこの両者を溶融合体させると、焼成初期、
焼成中、焼成完了時の何れかで割れ、破砕し、極薄ガラ
ス繊維を使用しても経時変化で２〜３日で破砕するとい
う問題点があった。In general, the melting temperature of glass fiber is higher than that of glass, and the expansion coefficient of glass fiber is significantly lower than that of glass, and both differ greatly in melting temperature and expansion coefficient. Therefore, when these two are fused and united,
There has been a problem that, during firing or at the completion of firing, the glass is broken or crushed, and even when ultra-thin glass fibers are used, the crushing takes place over a few days with the lapse of time.

【０００４】[0004]

【発明が解決しようとする課題】本発明の目的はガラス
とガラス繊維を溶融合体させ、種々の装飾模様を有する
ガラス製品を提供することにある。SUMMARY OF THE INVENTION An object of the present invention is to provide glass products having various decorative patterns by fusing glass and glass fibers.

【０００５】[0005]

【課題を解決するための手段】本発明はガラス微粉末と
ＰｂＯを撹拌混合して得られる低融点ガラス微粉末とガ
ラス繊維の複合物を素地ガラスに溶融合体させて得られ
る装飾模様を有するガラス製品の製造方法に係る。Glass having a decorative pattern obtained by the present invention SUMMARY OF] is a composite of low-melting glass fine powder and glass fibers obtained by mixing and stirring the glass fine powder and PbO melted polymer into a green body glass It relates to a method for manufacturing a product.

【０００６】本発明ではＳiＯ2を主体とするガラスに特
定の割合のＰbＯを添加することにより低融点の混合ガ
ラス微粉末を得る。ＰbＯの割合はガラス中３０〜５０
重量％が好ましく、特に４０〜４５重量％が好ましい。
３０％未満ではガラス微粉末は溶融せず、また５０％を
越えるとガラス微粉末は著しく黄味を帯びて感性の悪い
製品になる。ガラスとＰbＯをそのまま混練する乾式粉
砕により、低融点ガラス微粉末を得ても良く、或いはガ
ラスとＰbＯの混合物にカルボキシメチルセルロース
（ＣＭＣ）糊等の糊または水を混練する湿式粉砕により
低融点ガラス微粉末を得ることもできる。その際、亜麻
仁油、テレピン油等の油を併用することもできる。この
ような低融点ガラス微粉末の混練物をシルクスクリーン
等で均一の被膜にすることもできる。In the present invention, a mixed glass fine powder having a low melting point is obtained by adding a specific ratio of PbO to glass mainly composed of SiO 2 . The ratio of PbO is 30-50 in glass.
% By weight, and particularly preferably 40 to 45% by weight.
If it is less than 30%, the glass fine powder does not melt, and if it exceeds 50%, the glass fine powder becomes extremely yellowish and becomes a product with poor sensitivity. A low-melting glass fine powder may be obtained by dry grinding in which glass and PbO are directly kneaded, or a low-melting glass fine powder is obtained by wet grinding in which a mixture of glass and PbO is mixed with glue such as carboxymethyl cellulose (CMC) glue or water. Powder can also be obtained. At that time, oils such as linseed oil and turpentine oil can be used in combination. Such a kneaded product of the low melting glass fine powder can be formed into a uniform film by a silk screen or the like.

【０００７】上記で得られた低融点ガラス微粉末をガラ
ス繊維に浸透させて得られたガラス微粉末とガラス繊維
の複合物を、素地ガラスの表面に載置し焼成することに
より、両者を溶融合体させることができる。本発明では
例えば、予め上記ガラス微粉末とガラス繊維の複合物を
作っておき、それを素地ガラスの上に置いても良く、或
いは素地ガラスの上に上記複合物を塗布し、その上にガ
ラス繊維を置いても良い。また、素地ガラスの上に上記
複合物を塗布し、その上にガラス繊維を置き、更にその
上から複合物を塗布しても良く、またこの上に更にガラ
ス繊維を載せても良い。上記したようにガラスとガラス
繊維は溶融合体させても必ず破砕する問題点があった
が、本発明の上記低融点ガラス微粉末を使用するとき
は、このような破砕が防がれる。ガラスにＰbＯを加え
ると膨張係数は高くなり、一方、ガラス繊維の膨張係数
は低いままであるので、両者の膨張係数の差は増大し、
ますます破砕しやすくなると考えられるのに、実際には
両者は何ら破砕しない。これは全く予期し得ない効果で
ある。[0007] The composite of glass fine powder and glass fiber obtained by impregnating the glass powder with the low melting glass fine powder obtained above is placed on the surface of the base glass and baked to melt both. Can be combined. In the present invention, for example, a composite of the above glass fine powder and glass fiber is prepared in advance, and the composite may be placed on a base glass, or the composite may be applied on the base glass, and the glass You may put fiber. Further, the composite may be applied on the base glass, glass fiber may be placed on the composite, and the composite may be further applied from above, or glass fiber may be further placed on the composite. As described above, there is a problem that the glass and the glass fiber are always crushed even when they are melted and united. However, such crushing is prevented when the above-mentioned low melting glass fine powder of the present invention is used. When PbO is added to the glass, the expansion coefficient increases, while the expansion coefficient of the glass fiber remains low, so that the difference between the two expansion coefficients increases.
Although they are thought to be more easily crushed, they do not actually crush at all. This is a completely unexpected effect.

【０００８】また本発明では上記ガラス微粉末とガラス
繊維の複合物を２枚の素地ガラスの間に載置して同様に
２枚の素地ガラスの間に装飾模様を有するガラス製品を
得ることもできる。ガラス微粉末とガラス繊維の複合物
の載置方法は上記と同様である。In the present invention, the composite of glass fine powder and glass fiber is placed between two base glasses to obtain a glass product having a decorative pattern between the two base glasses. it can. The method for placing the composite of glass fine powder and glass fiber is the same as described above.

【０００９】また本発明では上記複合物をそのまま載置
して焼成すると素地ガラスに手漉和紙感の装飾模様が得
られるが、例えば複合物を素地ガラスに載置した時点
で、その複合物を指或いはローラー等で適宜流動させて
模様状とすることにより種々の装飾模様を有するガラス
製品とすることができ、例えば雲竜紋様、布目質模様等
を有するガラス製品を作成することができる。In the present invention, when the composite is placed and fired as it is, a decorative pattern of handmade Japanese paper is obtained on the base glass. For example, when the composite is placed on the base glass, the composite is removed. A glass product having various decorative patterns can be obtained by appropriately flowing it with a finger or a roller to form a pattern shape. For example, a glass product having a cloud dragon pattern, a cloth texture pattern, or the like can be produced.

【００１０】本発明において焼成温度は通常７００〜８
５０℃、好ましくは７５０〜８００℃程度とするのが良
い。７００℃未満ではガラス微粉末は溶融せず、８５０
℃を越えると素地ガラスそのものも溶融して著しく変形
する。In the present invention, the firing temperature is usually 700 to 8
The temperature is set to 50 ° C., preferably about 750 to 800 ° C. Below 700 ° C., the glass fine powder does not melt,
When the temperature exceeds ℃, the base glass itself melts and is significantly deformed.

【００１１】本発明の装飾模様を有するガラス製品は各
種の用途に用いることができる。例えば皿、コップ、ビ
ン、化粧品、工芸品等の食卓用、家庭用品用ガラス、電
球バルブ、蛍光灯、ネオンランプ、水銀ランプ、電灯シ
ェード、グローブ、石油ランプ等の電気用、照明用ガラ
ス、ガラスレンガ、ガラスタイル、ガラスカワラ、ドア
ーの一部等の建築用ガラス、ガラスボタン、ガラスビー
ズ、人造宝石、人造真珠、マーブル玉、アクセサリー、
ネックレス、ペンダント、イヤリング、ブローチ、髪か
ざり等の装身具用ガラスなどに用いることができるが、
これらに限定されるものではない。尚、本発明のガラス
製品を食器等に用いるときは素地ガラスの面が飲食物と
接するようにする。The glass product having a decorative pattern of the present invention can be used for various applications. Tableware for dishes, cups, bottles, cosmetics, crafts, etc., glass for household use, bulbs, fluorescent bulbs, neon lamps, mercury lamps, electric shades, gloves, oil lamps, etc. Architectural glass such as bricks, glass tiles, glass wall tiles, part of doors, glass buttons, glass beads, artificial jewelry, artificial pearls, marble balls, accessories,
Necklaces, pendants, earrings, brooches, hair ornaments and other accessories can be used for glass,
It is not limited to these. When the glass product of the present invention is used for tableware and the like, the surface of the base glass is brought into contact with food and drink.

【００１２】[0012]

【実施例】【Example】

実施例１ 無鉛フリットガラス６０gにＰbＯ（４０g）を加えてポ
ットミルで６時間混練して低融点ガラス微粉末を得た。
このガラス微粉末１００重量部に３％ＣＭＣ水溶液４５
重量部加えたものをガラス釉薬とする。素地ガラス面に
上記ガラス釉薬を筆で塗布し、その上にマット状のガラ
ス繊維を置き、更にガラス釉薬でおさえる。その上に２
５〜３５mmにカットしたガラス繊維を適当にばらまき手
漉和紙感を表現する。十分乾燥後、７５０℃まで徐熱で
２時間かけて焼成し、３〜１０時間徐冷して手漉和紙感
の装飾模様を有するガラス製品を得た。Example 1 PbO (40 g) was added to 60 g of lead-free frit glass and kneaded with a pot mill for 6 hours to obtain a low melting glass fine powder.
A 3% CMC aqueous solution 45 was added to 100 parts by weight of this glass fine powder.
Add the parts by weight as glass glaze. The above-mentioned glass glaze is applied to the base glass surface with a brush, a mat-like glass fiber is placed thereon, and the glass glaze is further closed. 2 on it
The glass fibers cut to 5 to 35 mm are scattered appropriately to express the feeling of handmade Japanese paper. After drying sufficiently, the glass was calcined to 750 ° C with slow heating for 2 hours, and gradually cooled for 3 to 10 hours to obtain a glass product having a decorative pattern of handmade Japanese paper.

【００１３】実施例２ 無鉛フリットガラス６０gにＰbＯ（４０g）及び３％Ｃ
ＭＣ水溶液４５gを加えてポットミルで６時間混練して
低融点ガラス微粉末からなるガラス釉薬を得た。素地ガ
ラス面にバルク状ガラス繊維を載置し指またはゴムロー
ラーで雲竜紋様を作成する。この上に上記ガラス釉薬を
塗布し、生乾き状態で紋様を確認しその上に再度薄くガ
ラス釉薬を塗布し十分乾燥後、７５０℃まで徐熱で２時
間かけて焼成し、３〜１０時間徐冷して雲竜紋様の装飾
模様を有するガラス製品を得た。Example 2 PbO (40 g) and 3% C were added to 60 g of lead-free frit glass.
45 g of MC aqueous solution was added and kneaded with a pot mill for 6 hours to obtain a glass glaze made of low melting glass fine powder. Bulk glass fiber is placed on the base glass surface, and a cloud or dragon pattern is created with a finger or a rubber roller. Apply the above glass glaze on it, confirm the pattern in a freshly dried state, apply a thin glass glaze again on it, dry it sufficiently, bake it with gradual heating to 750 ° C for 2 hours, and gradually cool for 3 to 10 hours As a result, a glass product having a decorative pattern of a cloud dragon pattern was obtained.

【００１４】[0014]

【発明の効果】本発明によれば従来溶融合体させること
が困難もしくは不可能であったガラスとガラス繊維を溶
融合体させることができ、得られた複合物を用いて種々
の装飾模様を有するガラス製品を得ることができる。According to the present invention, glass and glass fiber, which were conventionally difficult or impossible to be melt-blended, can be melt-blended, and glass having various decorative patterns can be obtained by using the obtained composite. Products can be obtained.

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 ＦＩ 技術表示箇所 Ｃ０３Ｃ 27/12 Ｃ０３Ｃ 27/12 Ｎ ──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. 6 Identification number Agency reference number FI Technical display location C03C 27/12 C03C 27/12 N

Claims (2)

(57)【特許請求の範囲】(57) [Claims] 【請求項１】 素地ガラスの表面にガラス微粉末とＰｂ
Ｏを撹拌混合して得られる低融点ガラス微粉末をガラス
繊維に浸透させて得られるガラス微粉末とガラス繊維の
複合物を載置し焼成し、素地ガラスと複合物を溶融合体
させることを特徴とする装飾模様を有するガラス製品の
製造方法。1. A glass fine powder and Pb on a surface of a base glass.
A composite of glass fine powder and glass fiber obtained by infiltrating glass fiber with low-melting glass fine powder obtained by stirring and mixing O is placed and fired, and the base glass and the composite are melted and united. A method for producing a glass product having a decorative pattern. 【請求項２】 ２枚の素地ガラスの間に、ガラス微粉末
とＰｂＯを撹拌混合して得られる低融点ガラス微粉末を
ガラス繊維に浸透させて得られるガラス微粉末とガラス
繊維の複合物を載置し焼成し、素地ガラスと複合物を溶
融合体させることを特徴とする、２枚の素地ガラスの間
に装飾模様を有するガラス製品の製造方法。2. A composite of glass fine powder and glass fiber obtained by infiltrating glass fiber with low melting point fine powder obtained by stirring and mixing glass fine powder and PbO between two base glasses. A method for manufacturing a glass product having a decorative pattern between two base glasses, wherein the base glass and the composite are melted and united.
JP6158072A 1994-06-15 1994-06-15 Method for producing glass product having decorative pattern Expired - Lifetime JP2627488B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP6158072A JP2627488B2 (en) 1994-06-15 1994-06-15 Method for producing glass product having decorative pattern

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP6158072A JP2627488B2 (en) 1994-06-15 1994-06-15 Method for producing glass product having decorative pattern

Publications (2)

Publication Number Publication Date
JPH082938A JPH082938A (en) 1996-01-09
JP2627488B2 true JP2627488B2 (en) 1997-07-09

Family

ID=15663690

Family Applications (1)

Application Number Title Priority Date Filing Date
JP6158072A Expired - Lifetime JP2627488B2 (en) 1994-06-15 1994-06-15 Method for producing glass product having decorative pattern

Country Status (1)

Country Link
JP (1) JP2627488B2 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007034513A1 (en) * 2005-09-19 2007-03-29 Societa'vetraria Biancadese S.A.S. Method for producing decorated glassware

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2566386A1 (en) * 1984-06-22 1985-12-27 Labo Electronique Physique INTAKE MIXTURE FOR AN INSULATING COMPOSITION COMPRISING A LEAD-BASED GLASS, PRINTING INK HAVING SUCH A MIXTURE AND USE OF THIS INK FOR THE PROTECTION OF HYBRID MICROCIRCUITS ON A CERAMIC SUBSTRATE
JP2828522B2 (en) * 1991-06-13 1998-11-25 日本板硝子株式会社 Sterilizing agent
JP3158504B2 (en) * 1991-06-27 2001-04-23 株式会社島津製作所 Fiber reinforced glass and method for producing the same

Also Published As

Publication number Publication date
JPH082938A (en) 1996-01-09

Similar Documents

Publication Publication Date Title
EP0402007B1 (en) Glass composition for use in glazes
JP3183942B2 (en) Glaze composition and glaze method
CN101875567A (en) Exquisite glaze, exquisite ceramic and preparation process of exquisite ceramic
CN101200345A (en) Crystal color ceramic, crystal color glass, composite material for crystal color illuminating layer and technical method thereof
US3069773A (en) Dental porcelains
CN108298818A (en) Enamel ceramics mica titanium perlatolic glaze and its glaze slip preparation method and application
JP4167015B2 (en) Lead-free enamel composition, corresponding enamel and glass-ceramic products, new lead-free mineral glass
CN110342820A (en) A kind of manufacturing method of copper system furnace transmutation glaze
JP2627488B2 (en) Method for producing glass product having decorative pattern
CN103193515A (en) One-process fast-fired transparent microcrystalline brick and production process thereof
JP2002128577A (en) Glaze composition, method of manufacture and glazed product
US6824877B1 (en) Clay compositions and objects including clay compositions
JP3034015B2 (en) Manufacturing method of ceramic products using colored glaze
CN1042627C (en) Vitreous jewel colour sand and preparation method
US5275978A (en) Colored crystallized glass article and method for producing the same
KR101918381B1 (en) Manufacturing method of cloisonne crafts and cloisonne crafts manufactured thereby
US2174198A (en) Method of producing colored flatware
CN109354410A (en) A kind of red temmoku ceramic glaze standby for ceramic system and preparation method thereof
CN102218960B (en) Manufacture method for polished electrooptic mirror face ceramic product
CN110981552B (en) Cera flava-imitated ceramic tile and preparation method thereof
CN100363306C (en) Crystal diffusion drying granule for ceramic product and preparation process thereof
CN109665809A (en) The production method of anti-folding anti-thermal shock far infrared fine faience batch, anti-folding anti-thermal shock far infrared fine pottery product
SU727585A1 (en) Avanturine glass
JPH06166540A (en) Crystallized glass ornament and it production
SU1680651A1 (en) Raw mixture for obtaining lining material