JP2623373B2 - High BH processing metal plate with St-St resistance - Google Patents

High BH processing metal plate with St-St resistance

Info

Publication number
JP2623373B2
JP2623373B2 JP1257891A JP1257891A JP2623373B2 JP 2623373 B2 JP2623373 B2 JP 2623373B2 JP 1257891 A JP1257891 A JP 1257891A JP 1257891 A JP1257891 A JP 1257891A JP 2623373 B2 JP2623373 B2 JP 2623373B2
Authority
JP
Japan
Prior art keywords
layer material
outer layer
inner layer
strength
property
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP1257891A
Other languages
Japanese (ja)
Other versions
JPH04241939A (en
Inventor
武秀 瀬沼
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Nippon Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Steel Corp filed Critical Nippon Steel Corp
Priority to JP1257891A priority Critical patent/JP2623373B2/en
Publication of JPH04241939A publication Critical patent/JPH04241939A/en
Application granted granted Critical
Publication of JP2623373B2 publication Critical patent/JP2623373B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Landscapes

  • Laminated Bodies (AREA)

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本発明は高いBH性を有するにも
かかわらず、ストレッチャ−ストレインが生じない加工
性に優れた金属板に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a metal plate having excellent workability, which does not cause stretcher strain despite having a high BH property.

【0002】[0002]

【従来技術】地球環境問題を含め、省エネルギ−対策は
現在の技術開発の一つの大きな課題である。そのため
に、自動車用鋼板ではこの対策の一環として軽量化がク
ロ−ズアップされており、優れた加工性が要求される外
板もハイテン化が進められている。しかし、耐面歪み性
などを考慮するとプレス加工時に強度が高すぎるのは問
題があり、プレス加工時は軟質で、加工後強度が付加で
きる形が理想的である。この要請を叶える形で開発され
たのがBH性鋼板で、成分およびプロセス条件の調整に
より加工性の良い鋼板に数ppmの固溶Cを残存させ、
塗装時の熱処理により固溶Cと転位の相互作用を利用し
て強度上昇を図ったものである。しかし、この固溶Cと
転位の相互作用による強度アップには成形性の面から限
界がもうけられている。すなわち、残存する固溶Cが多
くなり過ぎると降伏点伸びが顕著に表われ、ストレッチ
ャ−ストレインによる表面性状の劣化が生じ、外板とし
ての使用が不可能になる。従って、現状ではストレッチ
ャ−ストレインが生成しない状態で、しかも、得られる
BH性の上限は170℃で20分のBH処理で約5kg
f/mm2程度である。
2. Description of the Related Art Energy saving measures, including global environmental issues, are one of the major issues in current technological development. For this reason, reduction in weight of automotive steel sheets has been promoted as a part of this measure, and the use of high-tensile steel is also being promoted for outer panels that require excellent workability. However, considering the surface distortion resistance and the like, there is a problem that the strength is too high at the time of press working, and it is ideal that the form is soft at the time of press working and can add strength after working. The BH steel sheet was developed to meet this demand, and by adjusting the components and process conditions, several ppm of solid solution C remained in the steel sheet with good workability.
The strength is increased by utilizing the interaction between solid solution C and dislocations by heat treatment during coating. However, there is a limit to the increase in strength due to the interaction between the solid solution C and the dislocation from the viewpoint of moldability. That is, if the amount of the remaining solid solution C becomes too large, the elongation at the yield point becomes remarkable, the surface properties are deteriorated by the stretcher strain, and the use as an outer plate becomes impossible. Therefore, at present, the stretcher strain is not generated, and the upper limit of the obtained BH property is about 5 kg by BH treatment at 170 ° C. for 20 minutes.
f / mm 2 .

【0003】また、BH性鋼板に関しては特開昭59−
38337号、特開昭59−31827号、特開昭61
−26757号、特開昭62−7822号、特開昭62
−109927号、特開平1−11924号公報などの
ほかにも多くの発明が開示されており、固溶Cばかれで
なく固溶Nを利用したBH性鋼板(特開昭63−962
48号公報など)も紹介されているが、 ストレッチャ
−ストレインの生成を抑え、かつ高いBH性を保証する
技術は未だ発明されていない。
[0003] Further, regarding BH steel sheets,
38337, JP-A-59-31827, JP-A-61
No. 26957, JP-A-62-28222, JP-A-62-7822
A number of inventions have been disclosed in addition to JP-A-10-99927 and JP-A-1-119924, and a BH steel sheet utilizing solid-solution N instead of solid-solution C (see JP-A-63-962).
No. 48, etc.), but a technique for suppressing the generation of stretcher strain and guaranteeing a high BH property has not yet been invented.

【0004】[0004]

【発明が解決しようとする課題】本発明はストレッチャ
−ストレインの生成を抑え、5kgf/mm2以上のB
H性を持つ加工用金属板を提供することを目的としてな
された。
SUMMARY OF THE INVENTION The present invention suppresses the formation of a stretcher strain, and suppresses the generation of B of 5 kgf / mm 2 or more.
It was made for the purpose of providing a metal plate for processing having H property.

【0005】[0005]

【課題を解決するための手段】本発明の要旨とするとこ
ろは、2種の材料からなる3層構造を有する金属板にお
いて、外層材の降伏点伸びが0.05%以下、内層材の
BH性が少なくとも、5kgf/mm2以上、および外
層材の強度と内層材の強度の比Xが1.2以上で、かつ
外層材の板厚の総和t1と内層材の板厚t2の比とXの関
係が、下記の(1)、(2)の条件式を満足することを
特徴とする耐St−St性を持つ高BH性加工用金属
板。 X: 1.2<X<2.5の場合、 −0.05X+0.175<t1/t2<−0.05X+0.375 …(1) X≧2.5の場合、 0.05<t1/t2<0.25 …(2) にある。
SUMMARY OF THE INVENTION The gist of the present invention is to provide a metal plate having a three-layer structure made of two materials, in which the outer layer material has a yield point elongation of 0.05% or less and the inner layer material has a BH of less than 0.05%. At least 5 kgf / mm 2 , the ratio X of the strength of the outer layer material to the strength of the inner layer material is 1.2 or more, and the ratio of the total thickness t 1 of the outer layer material to the thickness t 2 of the inner layer material. And X satisfying the following conditional expressions (1) and (2): a metal sheet for high BH processing having high St-St resistance. X: When 1.2 <X <2.5, −0.05X + 0.175 <t 1 / t 2 <−0.05X + 0.375 (1) When X ≧ 2.5, 0.05 <t 1 / t 2 <0.25 (2)

【0006】[0006]

【作用】以下、本発明について詳細に説明する。上記の
課題の基づいて、発明者らは研究を重ねた結果、耐スト
レッチャ−ストレインとBH性の両方の特性を付加する
ためには、異なった特性を持つ板の複層構造によって達
成できることを見出した。そこで、この知見に基づき、
本発明の構成並びにその限定理由をのべる。先ず、本発
明における外層材の材質特性の限界条件であるが、外層
材の降伏点伸びが0.05%を超すと後述する外層材と
内層材の強度比と板厚比をどのように変えても、ストレ
ッチャ−ストレインの生成を抑えることができない。ま
た、内層材の材質特性についてであるが、内層材のBH
性が5kgf/mm2以下であるなら、本発明材のよう
な複層構造にしなくても、従来のBH性鋼板によって
も、耐ストレッチャ−ストレインとBH性の両方の特性
を得ることができる。従って、本発明材の狙いはBH性
が5kgf/mm2以上、好ましくは10kgf/mm2
以上を有し、かつストレッチャ−ストレインが生成しな
いことにあるので、内層材のBH性は少なくとも5kg
f/mm2以上であることが必要である。なお、上記各
層の材質については、研削などにより一方の層の材料を
取り除き引張試験を行なって調べることができる。
Hereinafter, the present invention will be described in detail. Based on the above-mentioned problems, the present inventors have made repeated studies and found that in order to add both the stretcher strain resistance and the BH property, it can be achieved by a multilayer structure of plates having different properties. Was. Therefore, based on this knowledge,
The configuration of the present invention and the reasons for the limitation will be described. First, the critical condition of the material properties of the outer layer material in the present invention is as follows. When the yield point elongation of the outer layer material exceeds 0.05%, how the strength ratio and the thickness ratio of the outer layer material and the inner layer material described later are changed. However, generation of stretcher strain cannot be suppressed. Regarding the material properties of the inner layer material, the BH
If the hardness is 5 kgf / mm 2 or less, both the stretcher strain resistance and the BH property can be obtained by the conventional BH steel sheet without using the multilayer structure as in the material of the present invention. Therefore, the aim of the material of the present invention is to achieve a BH property of 5 kgf / mm 2 or more, preferably 10 kgf / mm 2.
The BH property of the inner layer material is at least 5 kg.
f / mm 2 or more. The material of each layer can be checked by removing the material of one layer by grinding or the like and conducting a tensile test.

【0007】次に、複層構造に関する限定条件について
述べる。3層構造を有する板において、外層材の強度が
内層材より少なくとも1.2倍以上有り、かつ外層材と
内層材の板厚比t1/t2については、外層材と内層材の
強度比Xが1.2<X<2.5の範囲で、−0.05X
+0.175<t1/t2<−0.05X+0.375の
条件式を、そしてXが2.5以上では0.05<t1
2<0.25の条件式を満足しなければならない。そ
の理由は、外層材の強度が内層材より少なくとも1.2
倍以上でないと、たとえ条件式(1)、(2)を満足し
てもストレッチャ−ストレインの生成を抑えることがで
きないためである。このことは、外層材の強度が内層材
よりある程度大きくないと内層材に生じようとする降伏
点伸びを効果的に抑えることができないことを示唆して
いる。また、条件式(1)、(2)の下限は、たとえ強
度比が1.2以上でも外層の板厚が少なくとも、この下
限の条件より大きくないとストレッチャ−ストレインの
生成を抑えることができないことにより限定される。一
方、上限は加工性とBH性の観点から限定するもので、
板厚比が上限値より大きくなると加工性が損なわれるば
かりでなく、十分なBH性が得られなくなる。
Next, the limiting conditions for the multilayer structure will be described. In a plate having a three-layer structure, the strength of the outer layer material is at least 1.2 times or more that of the inner layer material, and the thickness ratio t 1 / t 2 between the outer layer material and the inner layer material is the strength ratio of the outer layer material to the inner layer material. X is -0.05X when 1.2 <X <2.5.
+0.175 <t 1 / t 2 <−0.05X + 0.375, and when X is 2.5 or more, 0.05 <t 1 /
The conditional expression t 2 <0.25 must be satisfied. The reason is that the strength of the outer layer material is at least 1.2
If it is not more than twice, even if conditional expressions (1) and (2) are satisfied, it is not possible to suppress the generation of the stretcher strain. This suggests that if the strength of the outer layer material is not higher than the inner layer material to some extent, the yield point elongation to be generated in the inner layer material cannot be effectively suppressed. Further, the lower limit of the conditional expressions (1) and (2) is that even if the strength ratio is 1.2 or more, the thickness of the outer layer cannot be suppressed unless the thickness of the outer layer is at least larger than the lower limit. Is limited by On the other hand, the upper limit is limited from the viewpoint of workability and BH property,
When the thickness ratio is larger than the upper limit, not only the workability is impaired, but also a sufficient BH property cannot be obtained.

【0008】本発明材の外層材と内層材の具体例は実施
例にも示すが、外層材に降伏点伸びを示さない複合組織
高張力鋼(Dual Phase鋼)や高バ−リング鋼
などを用い、内層材に固溶C、Nを残存させた軟質鋼を
用いる組み合せや、外層材に固溶C、NをTi,Nbな
どの炭窒化物生成元素で固着したIF鋼を用い、内層材
にMgを添加した高いBH性を示すAl合金を用いる組
み合せ、あるいは耐食性をも付加した外層にステンレ
ス、内層に固溶C、Nを残存させた軟質鋼を用いる組み
合せなどが自動車用薄板として適用できる。また、この
複層構造の製造方法としては、 圧延圧着法、鋳込みに
よる複層製造法、爆着法などいろいろな方法があるが、
本発明材においては複層の製造法に限定されるものでは
ない。
[0008] Specific examples of the outer layer material and the inner layer material of the material of the present invention are also shown in Examples, but a high-strength composite structure steel (Dual Phase steel) or a high-burring steel, which does not exhibit a yield point elongation in the outer layer material. A combination of soft steel in which solid solution C and N are left in the inner layer material, and an IF steel in which solid solution C and N are fixed to the outer layer material by carbonitride forming elements such as Ti and Nb. A combination using an Al alloy exhibiting high BH with Mg added thereto, or a combination using a stainless steel in the outer layer also having corrosion resistance and a soft steel in which solid solution C and N are left in the inner layer, etc. can be applied as a thin plate for an automobile. . There are various methods for producing this multilayer structure, such as a rolling compression bonding method, a multilayer production method by casting, and an explosion method.
The material of the present invention is not limited to the method for producing a multilayer.

【0009】[0009]

【実施例】表1に示す成分の材料を組み合わせて、3層
から成る複層構造の板を製造した後、その板の機械性質
および、片方の層を研削した後の外層材の降伏点伸びと
内層材のBH性を表2に示す。また、同表に外内層の強
度比と板厚分率比も示す。全板厚は0.8mmである。
ストレッチャ−ストレイン(St−St)の生成の有無
は引張試験時に目視で判断した。BH性は170℃で2
0分の熱処理前後の降伏点の差によって表した。実験番
号1、2、4、5、8、9、11、13は本発明の範囲
内でストレッチャ−ストレインの生成なしの高いBH性
を示す。実験番号3、12は条件式(1)あるいは
(2)を満足出来ないために、ストレッチャ−ストレイ
ンが生成した。実験番号6、7は外層材と内層材の強度
比Xが本発明の必要条件である1.2以下であるために
ストレッチャ−ストレインが表われた。実験番号10は
内層材のBH性が0のため、複層材もBH性を示さず、
本発明を意図するものでない。実験番号14は最終焼鈍
の2相域加熱後の冷却速度が小さかったため外層材の組
織がフェライト−パ−ライト組織になり、降伏点伸びが
生成し、ストレッチャ−ストレインが表われた。また、
発明材のうち、実験番号1、2、4、11、13は2相
域に加熱後、急冷して、外層材を複合組織にして降伏点
伸びを抑制した。実験番号5、9の外層はIF鋼を用い
て降伏点伸びを抑制した。一方、複層構造の製造方法は
実験番号、1、2、3、10、11、12、13が電子
ビ−ム溶接、実験番号4、5、6、7、8、14が鋳込
み複層、そして実験番号9が圧延圧着によったが、これ
らいずれの複層構造の製造方法にも限定されるものでな
く、本発明の範囲を満たすことにより優れた特性が得ら
れる。また、実験番号13に見られるように材料に組み
合わせによってr値が2以上の材料も製造できる。
EXAMPLE A plate having a multilayer structure composed of three layers was manufactured by combining the materials of the components shown in Table 1, and the mechanical properties of the plate and the yield point elongation of the outer layer material after grinding one of the layers. Table 2 shows the BH properties of the inner layer material. The table also shows the strength ratio of the outer and inner layers and the plate thickness fraction ratio. The total thickness is 0.8 mm.
The presence or absence of the generation of the stretcher strain (St-St) was visually determined during the tensile test. BH property is 2 at 170 ° C
It was represented by the difference in yield point before and after the 0 minute heat treatment. Experiment Nos. 1, 2, 4, 5, 8, 9, 11, 13 show high BH properties without the formation of stretcher strains within the scope of the present invention. In Experiment Nos. 3 and 12, a stretcher strain was generated because conditional expression (1) or (2) could not be satisfied. In Experiment Nos. 6 and 7, a stretcher strain was shown because the strength ratio X between the outer layer material and the inner layer material was 1.2 or less which is a necessary condition of the present invention. In Experiment No. 10, since the BH property of the inner layer material was 0, the multilayer material also did not show the BH property,
It is not intended for the present invention. In Experiment No. 14, since the cooling rate after heating in the two-phase region in the final annealing was low, the structure of the outer layer material was a ferrite-pearlite structure, yield point elongation was generated, and a stretcher strain was exhibited. Also,
Among the inventive materials, in Experiment Nos. 1, 2, 4, 11, and 13, after heating to the two-phase region, the material was rapidly cooled to make the outer layer material a composite structure, and the yield point elongation was suppressed. The outer layers of Experiment Nos. 5 and 9 suppressed yield point elongation using IF steel. On the other hand, the manufacturing method of the multilayer structure is as follows: Experiment Nos. 1, 2, 3, 10, 11, 12, 13 are electron beam welding, and Experiment Nos. 4, 5, 6, 7, 8, 14 are casting multilayers. Although Experiment No. 9 was based on rolling and pressure bonding, the present invention is not limited to any of these methods for producing a multilayer structure, and excellent characteristics can be obtained by satisfying the scope of the present invention. Further, as shown in Experiment No. 13, a material having an r value of 2 or more can be produced by combining the materials.

【0010】[0010]

【表1】 [Table 1]

【0011】[0011]

【表2】 [Table 2]

【0012】[0012]

【表2−1】〔表2のつづき〕 [Table 2-1] [Continuation of Table 2]

【0013】[0013]

【発明の効果】以上述べたように、本発明はいままで不
可能とされていたストレッチャ−ストレインの生成なし
で、しかも5kgf/mm2以上のBH性を付与できる
技術を提供するもので、耐デント性の顕著な向上が得ら
れ、板厚減少による軽量化が図られ、自動車用の外板な
どに広く使用でき、産業上極めて大きな効果が期待され
る。
As described above, the present invention provides a technique capable of imparting a BH property of 5 kgf / mm 2 or more without producing a stretcher strain, which has been impossible so far. A remarkable improvement in the dent property is obtained, the weight is reduced by reducing the thickness, and it can be widely used for an outer panel of an automobile, etc., and an extremely large effect is expected in industry.

Claims (1)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 2種の材料からなる3層構造を有する金
属板において、外層材の降伏点伸びが0.05%以下、
内層材のBH性が少なくとも5kgf/mm2以上、お
よび外層材の強度と内層材の強度の比Xが1.2以上
で、かつ外層材の板厚の総和t1と内層材の板厚t2の比
とXの関係が、 下記の(1)、(2)の条件式を満足
することを特徴とする耐St−St性を持つ高BH性加
工用金属板。 X: 1.2<X<2.5の場合、 −0.05X+0.175<t1/t2<−0.05X+0.375 …(1) X≧2.5の場合、 0.05<t1/t2<0.25 …(2)
1. A metal plate having a three-layer structure made of two kinds of materials, wherein the outer layer material has a yield point elongation of 0.05% or less;
The BH property of the inner layer material is at least 5 kgf / mm 2 or more, the ratio X of the strength of the outer layer material to the strength of the inner layer material is 1.2 or more, and the total thickness t 1 of the outer layer material and the thickness t of the inner layer material A metal sheet for high BH processing having high St-St resistance, wherein the relation between the ratio of 2 and X satisfies the following conditional expressions (1) and (2). X: When 1.2 <X <2.5, −0.05X + 0.175 <t 1 / t 2 <−0.05X + 0.375 (1) When X ≧ 2.5, 0.05 <t 1 / t 2 <0.25 (2)
JP1257891A 1991-01-11 1991-01-11 High BH processing metal plate with St-St resistance Expired - Fee Related JP2623373B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1257891A JP2623373B2 (en) 1991-01-11 1991-01-11 High BH processing metal plate with St-St resistance

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1257891A JP2623373B2 (en) 1991-01-11 1991-01-11 High BH processing metal plate with St-St resistance

Publications (2)

Publication Number Publication Date
JPH04241939A JPH04241939A (en) 1992-08-28
JP2623373B2 true JP2623373B2 (en) 1997-06-25

Family

ID=11809242

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1257891A Expired - Fee Related JP2623373B2 (en) 1991-01-11 1991-01-11 High BH processing metal plate with St-St resistance

Country Status (1)

Country Link
JP (1) JP2623373B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104647823A (en) * 2013-11-25 2015-05-27 中国兵器工业第五二研究所 Shock-resistant energy-absorbing material and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104647823A (en) * 2013-11-25 2015-05-27 中国兵器工业第五二研究所 Shock-resistant energy-absorbing material and preparation method thereof

Also Published As

Publication number Publication date
JPH04241939A (en) 1992-08-28

Similar Documents

Publication Publication Date Title
US3397044A (en) Aluminum-iron articles and alloys
EP1293581B1 (en) Steel pipe for use in reinforcement of automobile and method for production thereof
WO2008018531A1 (en) Dr steel sheet and process for manufacturing the same
KR102130690B1 (en) Clad using high entropy alloy and manaufacturing method of the same
JP7056699B2 (en) Non-oriented electrical steel sheet and its manufacturing method
EP2468909A1 (en) Highly processable steel sheet for three-piece welded can and method for producing same
JP2001220641A (en) High strength thin steel sheet and high strength gavlanized thin steel sheet excellent in ductility and low in yield ratio and producing method therefor
JP5094888B2 (en) Manufacturing method of high strength and low specific gravity steel sheet with excellent ductility
WO2019043882A1 (en) Titanium sheet
WO2021104292A1 (en) Multi-layer rolled composite board and manufacturing method therefor
JPH04143236A (en) High strength alpha type titanium alloy excellent in cold workability
JP2623373B2 (en) High BH processing metal plate with St-St resistance
JP3280692B2 (en) Manufacturing method of high strength cold rolled steel sheet for deep drawing
JP2002012943A (en) Thin steel sheet for press molding and its production method
JP3718865B2 (en) Manufacturing method of lightweight can with excellent bottom pressure strength
JP2735381B2 (en) Method for producing cold-rolled steel sheet for deep drawing with surface distortion and dent resistance
JPS59179772A (en) Manufacture of high strength pure titanium plate
JP2735380B2 (en) Method for producing cold rolled steel sheet for processing having aging resistance, surface distortion resistance and dent resistance
JP2717604B2 (en) Method for producing cold-rolled steel sheet for processing excellent in St-St resistance and BH resistance
JP3001136B2 (en) Composite metal sheet with excellent BH properties and workability
JP3001135B2 (en) Composite metal sheet with excellent BH properties and workability
JP3466300B2 (en) Manufacturing method of hot rolled steel sheet with remarkably excellent fatigue properties, shape freezing property and workability
JP3262940B2 (en) Manufacturing method of steel sheet with excellent fatigue resistance
JP2826261B2 (en) Fe-Cr alloy with excellent workability
JPS60194052A (en) Production of high-strength pure titanium sheet

Legal Events

Date Code Title Description
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 19970114

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20080411

Year of fee payment: 11

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20090411

Year of fee payment: 12

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20090411

Year of fee payment: 12

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20100411

Year of fee payment: 13

LAPS Cancellation because of no payment of annual fees